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As part of the Bureau of Mines program to reduce U.S. reliance on foreign suppliers of strategic and critical metals, research was conducted to improve technology for the recovery of critical metals from hardface alloy grinding waste, a form of superalloy scrap. This report describes a hydrometallurgical process that demonstrated on a laboratory scale that 79 pct of the chromium, 97 pct of the cobalt, 99 pct of the manganese, 99 pct of the nickel, and 90 pct of the tungsten could be recovered in chemical form from hardface alloy grinding waste. The process involved deoiling the grinding waste, followed by chloride-based dissolution of the deoiled material. A high-grade calcium tungstate (CaW04) product was recovered from the resultant leach residue by caustic leaching and precipitation. Iron, cobalt, man-ganese, and nickel chlorides were sequentially recovered from the leach liquor by solvent extraction. Amine extractants were used to extract the iron, cobalt, and manganese; decanal oxime was used to extract the nickel. Market-grade cobalt chloride (CoCI2), manganese chloride (MnC12), and nickel chloride (NiCl2) products could be produced directly from the resultant strip liquors. The final raffrnate was a relatively pure chromic chloride (CrCI3) solution that compared favorably with commercial solutions.

Jan 1, 1988

By Motyka J, Adamczyk AF, Witczak S

A case study of migration of a paper factory fluid wastes, on the distance of 5 km from an underground disposal site to an ore mine is presented. The ore mine in question, situated in SW Poland is pumping 3.5 m3/s (ca 300 000 m3/day) of groundwater, producing a cone of depression about 150 m deep and several kilometers wide. The migration of wastes (pollutant) occurs within the carbonate karstic aquifer of Triassic age. The aquifer is about 100m thick and is characterized by the coefficient of hydraulic conductivity equal to 8 m/day on the average. The results of systematic measurements carried out for 13 years enabled to estimate the mean breakthrough curve of the pollutant. On this basis and taking into account the coefficient of hydraulic conductivity as well as the mean hydraulic gradient between the disposal site and the ore mine, the migration parameters of the polluting material, i.e. the real flow velocity, the effective porosity and the longitudinal disper- sivity have been calculated. As the measurements considered a long migration distance of the pollutant, the obtained hydrodynamic dispersion constant (dispersivity), in the authors opinion, is reliable enough to be applied for regional groundwater calculations, regardless of the "scale effect".

Jan 1, 1988

By Patricia R. Devine

This appendix documents the mathematical approach to deriving the components of change presented in this report. The formulation closely follows that contained in Chapter IV of the documentation for the BEA 1977 Input-Output Tables.' The basic elements for the calculations include the "use" matrix (U), the "make" matrix (M), and any of the ten columns of final demand (generically represented by the symbol y). The use matrix contains information about changes in the technological processes of production, while the make matrix describes the nature of secondary product production in each industry. We adhere to BEA conventions in maintaining careful distinctions between commodity output (c) and industry output (x). The industry-by-industry 1-0 tables supplied by NYU for use in this analysis are square matrices, with the number of commodities and the number of industries both equal to 85. The BLS table for 1982 (commodity by industry) was aggregated and adjusted to be consistent with the earlier tables. The three basic steps for estimating components of change proceed as follows for each column of final demand. 1) Calculate the actual change in output of each commodity for each of the four time periods: 1963-72, 1972-77, 1977-82, and 1963-82.

Jan 1, 1988

Polish coal mines are well equipped with methane monitoring systems,nevertheless the worsening conditions force a continuous impro- vement in the field of environmental monitoring. Application of modern electronic components make it possible to design the new modular telemonitoring system incorporating the best features of the older systems,widely employed in Polish collieries, eliminating their weak points. Several new sensors and portable instru- ments for methane monitoring and early fire detection have been developed and tested in mining conditions.

Jan 1, 1988

By Bush P. R, Hale M, Dixon C. J, Wheatley M. R

Barium anomalies in drainage sediments can act as indicators of barite mineralization and path- finders for lead-zinc mineralization. Their detection in an arid climate has been investigated in two areas of Saudi Arabia. At Rabigh, 150 km north of Jeddah, barium anomalies found in wadi sediments reflect barite veins which occupy Tertiary faults in Precambrian metavolcanics and granodiorite. In the Wadi ad Dawasir area, 650 km east of Jeddah, the sediments of wadis draining the Jabal Tuwayq escarpment have been found to contain anomalous concentrations of barium derived from diagenetic barite in the Sudair formation siltstones and shales. Barium dispersion in these wadis is predominantly clastic. Near to the source rocks, barium occurs in relatively coarse grains of barite. Owing to the three well-developed cleavages of barite, its crystals readily break into cleavage flakes during fluvial transport in flash floods; as a result, the longest anomalous dispersion trains are found in the 250 to 600 um fraction. Wadi sediments finer than 250 um have relatively constant and low barium contents, being dominantly composed of windblown sand.

Jan 1, 1988

By G. G. Goble

Significant progress has been made in the past decade in determining the load bearing capacity of pile foundations. Developments in the means of prediction of pile capacity as limited by soil strength have been substantial, particularly in the use of dynamic methods. The use of currently available equipment, analytical procedures, and practices in the field, will often produce material economies on a job by allowing increased loads with proven factors of safety. This approach justifies the minimum number of piles required for a safe foundation in a wide range of job sizes and soil conditions. To avoid exposing the reader to excessive detail in the body of this paper, technical topics have been covered more thoroughly in several appendices. I. Wave Equation Analysis of Piles Appendix A II. Dynamic Monitoring and the Pile Driving Analyzer Appendix B III. Case Method Capacity Calculation Appendix C IV. Case Pile Wave Analysis Program Appendix D 1 Preliminary Analysis In designing driven pile foundations, there must be a close relationship between design, construction control procedures, driving practices, and the size of the job. Small commercial buildings or residences involving loads that are only a fraction of the pile capacities do not justify the expense of detailed design processes or elaborate construction controls. Nevertheless, some preliminary analysis of the job requirements and a limited subsurface investigation must be made to understand existing conditions and the possible foundation solutions. In other words, it is necessary to determine that driven piling is the best overall choice of foundation.

Jan 1, 1988

By Gennaro G. Marino

Documented case histories of surface ground movements from mine subsidence were utilized to help determine when the initial collapse of the overburden occurred above longwall panels. By studying this relationship between initial movement at the surface and the amount of face advance, the least-complex conditions exist for empirically assessing the span capacity of the overburden. The objective of this work was to obtain a better understanding of the overburden response to longwall mining. This knowledge will give a better insight on the long-term effects that different overburden types have on the stability and the subsidence potential of room and pillar mines, as well as, the influence of the overburden on subsidence over longwall panels. Theory on the overburden span capacity was developed and correlated to field observations. Data were used on the overburden lithology, depth, width, and face advance of the panel, and the subsidence conditions that were noted on the surface. The subsidence measured on the surface was used to determine when complete failure in the overburden rock had occurred. According to spans predicted by theory and the subsidence measured in the field, the competent lower units failed at a face advance less than when significant subsidence was observed on the surface. In each case studied, there were competent lower beds; however, the full overburden weight was not sustained to the point of subsidence. The best correlation with the surface movement was found with the most shallow, competent bed. Elastic plate solutions with various support conditions were found to best monitor the surface subsidence of these upper roof units.

Jan 1, 1988

By E. G. Davis

The Bureau of Mines studied tailings samples from 11 large-scale western copper operations to determine the potential for recovery of rutile and other critical and strategic minerals. Up to 15 pounds per short ton (lb/st) Ti02 was found ion these samples; however, only 9 to 44 pct of the Ti02 was liberated rutile. For one sample, gravity preconcentra-tion, grinding, and flotation recovered 34 pct of the Ti02 in a 54.8-pct-Ti02 concentrate. Over 0.38 Ib/st W was found in some of the tailings sampleso Scheelite was identified as the major W mineral. Nine of the eleven samples contained about 0.02 to 0.18 Ib/st Co. Pyrite was the principal Co-bearing sulfide mineral, with Co contained in about one-fifth of the pyrite grains. Up to 30 pct of the Co was concentrated in a bulk sulfide flotation concentrate.

Jan 1, 1988

By J. Douglas Causey

In 1987, at the request of the Bureau of Land Management, the U.S. Bureau of Mines studied 13,374 acres of the 14,994-acre Ireteba Peaks Wilderness Study Area (NV-050-438) in order to evaluate its identified mineral resources. The study area is located in Clark County, NV, about 4 miles south of Nelson, NV. No identified resources were found within the Ireteba Peaks study area, although there are identified subeconomic resources just outside of the study area boundary. Most of the area is underlain by Tertiary granitic rocks, which apparently postdate mineralization. The area is virtually surrounded by mining districts with mines developed in older rock units. On the north side, quartz monzonite, volcanic tuff, and tuffaceous sediments in the Eldorado mining district host deposits of gold, silver, copper, zinc, and mercury. On the south side, Precambrian gneiss, intrusive andesite porphyry, and hornfels in contact with Quartz monzonite in the Searchlight mining district host gold, silver, copper, and lead deposits. The Newberry mining district to the southeast had copper, gold, and silver mineralization in Precambrian gneiss and andesite.

Jan 1, 1988

By Brumley J

The development of the SECV brown coal open cut at Loy Yang will require depressurisation of aquifers both within and below the coal seam sequence in order to maintain open cut stability. Prediction of future open cut dewatering requirements at Loy Yang Open Cut and evaluation of the regional consequences of dewatering has required development of a detailed hydrogeological model of the Loy Yang area. The complex stratigraphy of the coal seam and aquifer/aquitard sequences at Loy Yang have been analysed and integrated with the hydrogeological concepts developed from regional groundwater studies to formulate a realistic hydrogeological model as a basis for finite-element flow modelling.

Jan 1, 1988

By R. E. Burleigh

'Gold-telluride mineralization was deposited in quartz veins which cut a Late Cretaceous tonalite pluton emplaced near the southern margin of the Peninsular tectono-stratigraphic terrane in south-central Alaska. The gold-bearing veins formed shortly after the development of a widespread Cu-Mo sheeted quartz vein system. Early mineral assemblages consist of quartz, white mica, pyrite, and arsenopyrite (wall rock only). Subsequently, pyrite. sphalerite, chalcopyrite, zoned tetrahedrite and gold precipitated within multiply fractured veins. Late stage galena, tellurides (altaite, nagyagite, coloradoite), and Pb-Sb or Pb-Cu-Bi sulfosalta with gold constitute bonanza ore assemblages that are variably associated with quartz, white mica, ankerite, and calcite. Fluid inclusion evidence coupled with mineral assemblage paragenesis suggests the depletion of volatiles (C02, H2S) and cooling resulted in the precipitation of high grade gold mineral assemblages.

Jan 1, 1988

By Bourke J. H, Ashcroft T. B

Many changes have occurred in the world market for manganese over the last five years. Among these, the emergence of divided steel processes for the hot metal refining of pig iron is affecting the use of both ferruginous manganese ore and ferro manganese, at this stage particularly in the Japanese steel industry. Subsequent demand for higher quality manganese materials is promoting the use of thermally beneficiated products such as sinter. In addition, many processes are being developed for the direct smelting of fine manganese ores, of which plasma technology is the most advanced. Cost pressures and product quality requirements are encouraging pre- viously self sufficient countries such as The People's Republic of China and the USSR to import high grade manganese ores to supplement indigenous lower quality supplies. At the same time, Brazil has been provided with the impetus to convert its substantial reserves of ore to value added products.

Jan 1, 1988

By S. J. Page, P. Bolsaitls, W. E. Wallace, C. A. Hill, M. J. Keane

"Boiling respirable quartz dust in water for 10 to 40 minutes decreases the cytotoxicity for both erythrocyte hemolytic potential and pulmonary macrophage release of lactate dehydrogenase in vitro. The potential is reduced to near zero in the boiling concentration range of 1 to 10 mg quartz per ml water in boiling times of 20 to 40 minutes. Below this range the detoxification occurs over a longer boiling time. Above this range the hemolytic potential remaining after 40 minutes of boiling approaches native quartz potential with increasing concentration up to 30 mg quartz per ml water. Replacing the media with fresh at the midpoint of boiling results in full detoxification through 20 mg per ml. Pre—boiling the medium with quartz or silica gel reduces the effect of subsequently boiling test samples. Detoxification persists after mild drying at 110 C for 8 hours, and persists after three days of resuspension in water at room temperature. Additional data on persistence of the effect, on the use of acidic and basic media treatment, and on surface analyses are presented, with a discussion of a working hypothesis and research needs.IntroductionResearch underway to determine interactions of quarts and other mineral dust surfaces with pulmonary fluids and alveolar macrophages in culture led to the observation that when dusts were autoclaved in aqueous suspension, their cytotoxic effects on macrophages wore suppressed, in some cases fully and even after several days incubation with the cells. This finding was in direct contradiction to earlier results from both short term macrophage lysosaal enzyme release assays, as well as longer term cytotoxicity assays from macrophages in culture; in those studies, dusts were steam autoclaved at 121 121 ºC with no liquid water but with steam present. (1,2) However detoxification under boiling conditions has been reported in other research.(3). It was decided to use the hemolysis assay to further investigate these findings, because of its sensitivity, simplicity and cost."

Jan 1, 1988

By Stitt P. H

In Australia, the term "heavy mineral deposits" is used to denote sands which contain variable but economic quantities of the minerals rutile, ilmenite and zircon, often with minor amounts of monazite and xenotime as co-products. Australia has been a significant producer of rutile, ilmenite and zircon from such sands for fifty years and has long been the leading producer of rutile and zircon. The industry had its beginnings with the mining of present day beaches in northern NSW in 1934. Early work was small scale and in some cases involved hand winning of naturally concen- trated mineral for direct export. During World War II and immediately after the industry became increasingly mechanised and by the 1970s on the east coast operated between Newcastle, NSW north to Fraser Island in Queensland. Deposits worked included present day beaches, fossil strand lines up to 5 km or more inland from the present coast and aeolian concentrations. In the mid 1950s, operations commenced on the west coast of WA, south of Perth. Western Australian mineral sands tend to be rich in ilmenite as compared to the east coast. However the WA ilmenites are lower in chrome oxide and make a better syn- thetic rutile feedstock.

Jan 1, 1988

By William H. Schiffbauer

The Bureau of Mines is conducting research that is aimed at making the mining industry more efficient in term of both productivity and the health and safety of the worker. As part of this research the Bureau of Mines has integrated a testbed composed of computer and related peripheral hardware to form an intelligent base for performing autonomous mining machine experiments. Although this particular application was con- figured for use on a Joy 16 CM mining machine, its generic structure facilitates its attachment to a variety of mining machine types. The multitasking multiuser computer can be set up for other applications by changing a bubble memory cartridge. The Joy 16 CM implementation includes 96 digital input-output (1-0) ports, 32 analog inputs, 8 analog outputs, 2 serial data channels, and 1 printer port. Operation of the machine can be performed either through a local terminal or remotely through a modem hookup. This report describes a testbed for autonomous mining machine experiments (TAMME)--its hardware, software, and complete system integration--so that it can be used as a foundation for other applications.

Jan 1, 1988

By R. Hogg

"The problems of sampling particulate materials, and of characterizing the distributions of particle size and composition are reviewed. Requirements for sampling from comminution systems are discussed and a simple formula is presented for estimating the minimum sample size needed. The limitations and errors associated with the techniques available for particle size analysis are evaluated and guidelines are suggested for the selection of appropriate methods. The use of microscopic and macroscopic approaches to the characterization of particle composition are discussed.INTRODUCTIONComminution is a process of particle size reduction in which the goal is to produce a material with a specified particle size distribution from a coarser feed. In mineral processing applications, the product size distribution is often qf secondary importance to the extent to which individual mineral grams can be liberated from one another. However, due to poor understanding of the nature of the liberation process and the lack of reliable procedures for characterizing it, the actual specification is normally in terms of particle size.Particle size distribution can be regarded as the fundamental characteristic of a particulate system. The distributions of particle shape and composition among the various particle sizes present are often sufficient to define the bulk properties and behavior of the system. Description of the distributions of size; shape and composition of the different phases which may exist within individual particles is necessary to complete the picture and is especially important for predicting liberation etc., in comminution processes. It is quite obvious that · the complete characterization of real particulate systems is a formidable, if not .impossible task. Practical characterization procedures should involve ·evaluation of those characteristics which are deemed to be important and which can be measured. In comminution systems, this should ideally include the particle size distribution, the size-by-size distributions of particle composition, and as much information as can be acquired on the internal composition and structure of individual particles. In most cases, of course, we fall far short of even this rather limited goal."

Jan 1, 1988

By Z. Yang, R. W. Smith, Jr. Wharton

"Microorganisms have the ability to remarkably adsorb and/or absorb heavy metal ions. Hence they are being studied widely as a means of removing metal ions from aqueous solutions both in order to clean up toxic streams and to recover valuable metals from these and other streams. It is often difficult to harvest organisms such as bacteria and unicellular algae since they are usually too small to be readily screened out. Froth flotation may prove to be a feasible method to harvest such organisms subsequent to the ad/absortion of the metal Ions. The present paper discusses the surface/electrokinetic properties of microorganisms and the modifier-collect conditions under which they should float. The zeta potential of the green alga Chlorella vulgaris was measured in the presence of AI(III) and Pb(II) ions and in the presence of dodecylammonium chloride and sodium dodecylsulfate. Present and past data suggest that the organisms should behave similarly to other finely divided, charged (polar) solids with their behavior sometimes modified by the non-polar surface regions present.IntroductionThe overall field of bioengineering is growing at a remarkably accelerating rate. Hydrometallurgy and mineral processing are included among those disciplines where there has been actual or proposed commercial use of bioorganisms. Further, the actual or proposed use includes bacterial enhancement of leaching of a number of different types of ores (1-5), modification of the flotation or oil agglomeration separation of minerals by bacteria (6,7) and microorganism (algae, bacteria or fungi) concentration of metal ions present in effluent or other mineral processing or hydrometallurgy aqueous streams (8-23)."

Jan 1, 1988

The Bureau of Mines, in an effort to improve resource conservation, mine planning and development, is currently investigating the loading behavior of pillars in multiple-seam developments. The simultaneous mining of two or more coalbeds may cause instability between room-and-pillar operations resulting in an interaction known as pillar load transfer. Although pillars may be adequately designed for single-seam mining, the development of a second seam may complicate loading conditions in both operations. If pillars are not adequately designed to contend with this load transfer, failure of the mine structure may result. To improve multiple-seam development and pillar design, the Bureau studied the loading characteristics of pillars in three separate multiple-seam operations. In all three cases, instrumented pillars recorded increasing pressure after development of the second seam. Increases in the average pillar pressure ranged from 7 to 110 pct over predicted overburden loads. An analysis of pillar loading before and after second-seam mining indicates that the ratio of overburden to innerburden thickness is a critical factor influencing load transfer. Based on this relationship, safety factors for case study pillars are calculated and alternative design considerations are discussed.

Jan 1, 1988

"Depletion of known ore reserves and increased demand for precious metals have caused a revolution in biohydrometallurgical processing technology for gold recovery. Known ore deposits and future discoveries are most likely to be lower grade sulfide ores that can be difficult to recover with current leaching technology. Future metal recovery operations will increasingly use bio-oxidation techniques.Bacteria are an integral part of mineral cycling and mineral transformation in nature. Although biological processes are recognized as part of the mineralization and oxidation reactions in some ore deposits, they have only recently been applied to enhancing metal recovery in hydrometallurgical procedures. This paper explores the traditional metallurgical application of biological leaching and oxidation reactions and reviews the complete range of bacteria available for metal recovery systems. Pre-treatment of ores with bacteria improves metal recoveries in tank leaching systems and shows promise for heap leaching methods.IntroductionThere is no longer any question that bacteria playa natural role in the on-going transformation of some ore deposits (1,2). As applied to sulfide ores, a few strains have been specifically identified that exhibit a natural leaching potential (3). These bacteria can be isolated from waters and soils in old mining districts where they contribute to continuing leaching and pollution problems in acid drainage and heavy metal solubilization. Sulfur and iron bacteria as well as many heterotrophic strains have also been found in ore deposits and sedimentary rocks at depths up to 2000 meters (4). Their presence in both ore deposits and processed ores shows the microbial association with natural leaching and the potential role that bacteria can play in the development of new leaching technology."

Jan 1, 1988

By R. V. Ramani

In this paper, the application of the concepts of reliability engineering to the evaluation of longwall system performance is illustrated with data from an operating longwall face. A number of cases are analyzed to highlight the impacts of longwall equipment, geological conditions and outby haulage on systems reliability and availability.

Jan 1, 1988