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By B. R. Mohal, F. F. Aplan, S. Chander

"The wetting behavior of coal has been determined in the presence of nonyl and octyl series of nonionic surfactants containing polyethoxy groups of different sizes. The wetting behavior was determined by a modified Walker technique and contact angle measurements. The results show that the wetting rate of coal varies with coal rank, structure of the hydrocarbon chain and number of ethoxy groups in the hydrophilic group of the surfactant. A close relationship has been observed between the wetting rates and the short-time advancing contact angles.INTRODUCTIONNonionic surfactants are used in many applications to improve wettability of solids. They can be used as dispersing agents [ 1 ] or dust suppressants [ 2-5] and to control the flotation, flocculation, filtration and flowability of particulates. This study was undertaken to study the effect of a series of nonionic surfactants on the wetting behavior of coal. Two series of surfactants, namely, ethoxylated nonyl and octyl phenols were used. The nonyl phenol series contains a linear hydrocarbon chain containing nine carbon atoms ( CH3 ( CH2 ) 8-C6H4-( OC2H4 )""' where n is the number of ethoxy groups). The octyl phenol series contains a branched hydrocarbon chain containing eight carbon atoms ( ( CH3 ) 3CCH2C ( CH3 ) 2-C6H4-( OC2H4)"").Initial wetting rates - modified Walker techniqueWalker et al. [ 6] developed a sink test to determine the wettability of coal particles. In this technique, coal particles are dropped individually onto the surface of surfactant solutions of different concentrations, and the most dilute concentration in which coal would sink ""instantaneously"" is determined. This technique is a variation of a procedure initially developed by Draves and Clarkson [ 7] to determine the effect of surfactants on wettability of cotton fibers."

Jan 1, 1989

By J. Douglas Causey

In 1988, at the request of the Bureau of Land Management, the U.S. Bureau of Mines studied part of the 12,740-acre Blue Canyon Wilderness Study Area (OR-003-073) in order to evaluate its identified mineral resources. The study area is in Malheur County, OR, about 27 miles northwest of Jordan Valley. The study area is underlain by Tertiary welded tuff, tuff, perlite and tuffaceous sedimentary rocks capped by basalt. Jasper has been mined from several localities. Some mining has been done by hobbyists. However, the area has been covered by mining claims since 1964, with mining done by commercial operators. This region has been a source of "Owyhee picture" and other similar jaspers. More recent exploration has focused on the gold potential of nearby areas such as Quartz Mountain and Red Butte.

Jan 1, 1989

By S. M. I Kytö, J .. K. Mäkinen, K. Saarhelo

"At the Outokumpu Oy Harjavalta Copper Smelter the control philosophy of the flash smelting process has been changed from the slow feed-back control to feed-forward control. This is important as the fluctuations in the flash smelting furnace matte grade and slag temperature are desired to be minimized.The system is based on a specially designed automatic sampling device and the Outokumpu Courier 20 on-stream X-ray fluorescence analyzer. A microcomputer-based Analyzer Operator Station (AOP) controls the system and calculates the process parameters for the furnace from the analyzed chemical composition and other existing data.A considerable reduction in the deviation of the matte grade and slag temperature has been gained. This has resulted in conservation of energy and refractories, lower copper losses and higher through-put in the flash smelting furnace and converters.1.0 IntroductionThe flash smelting technology for copper concentrates was developed at the Outokumpu Oy Harjavalta Smelter soon after the World War II. The incentive for this development was shortness and high price of any form of energy. The fact that smelting can be carried out autogenously, without external energy by utilizing the latent heat of sulfide combustion was known decades before, but Outokumpu Oy was the first company to take the advantage of this knowledge in practical operation. A further advantage of this technology was that the SO2 containing gases suited well for sulfuric acid production, thus minimizing the detrimental effects on the environment (1).The very heart of the flash smelting process is the reaction shaft of the flash smelting furnace (see Appendix I). Heating up of the dried feed mixture, dissociation of several compounds, ignition and oxidation of the feed take place very intensively in the reaction shaft during 2 - 3 seconds, which the fine grained particles reside in the reaction shaft. A very accurate control of the amounts of the feed materials as well as of oxidizing gases, fuel, etc. is of primary importance."

Jan 1, 1989

By Lee W. Abramson, William H. Hansmire

The H-3 Project is planning, design, and construction of a 10-mile (16 km)-long final segment of new highway that traverses the Koolau mountain range in Oahu. Interstate H-3 traverses North Halawa Valley on one side of the Koolau Mountains and Haiku Valley on the other side. The project includes a tunnel through the mountain range. The one-mile (1.6 km)-long twin-bore Trans-Koolau Tunnel will have two lanes in each direction. The total roadway width including shoulders in each bore will be 38 ft (11.6 m). The geologic and geohydrologic conditions along the alignment present a variety of tunneling problems. Geologic conditions consist of volcanic materials deposited generally in fairly thin basaltic layers. These volcanic materials generally weather down to "MH" soils which are compressible but relatively strong. Perched ground water that is recharged by heavy rainfall is present in the mountains. The paper presents results of initial geologic surveys and exploratory boring, and plans for exploratory tunneling and testing programs. A site specific classification method developed to characterize the weathered profile is presented.

Jan 1, 1989

By Adam J. Szladow

"INTRODUCTIONThe low calorific value and the high moisture and ash contents of run-of-mine (r.o.rn.) lignite limits the utilization of Saskatchewan lignites to thermal power plants in Saskatchewan, Manitoba and western Ontario. On the other hand, the low sulphur content and the low mining cost make lignites potentially attractive for new coal markets, if suitable processes can be found for upgrading. Economic upgrading to a higher quality fuel would make lignites more acceptable for industrial and utility boilers.This paper presents a summary of the process engineering evaluation of coal upgrading technologies conducted in support of a study of selected lignite upgrading processes. The summary presents the relative advantages and offers specific comments on the application of coal upgrading technologies for lignites. ResourcesLignite comprises the largest fossil fuel energy deposits in Saskatchewan. The total resources of immediate and future interest exceed 27 billion tonnes. The measured and indicated lignite resources of immediate interest are large enough to last for over 200 years at the current production rate of about 10 million tonnes per year (Table 1).Saskatchewan lignitedeposits are present in three different geologic formations: (I) the Ravenscrag Formation of Paleocene Age in southern Saskatchewan; (2) the Swan River Formation of Lower Cretaceous Age in central north Saskatchewan; and (3) the Judith River Formation of Upper Cretaceous Age in central west Saskatchewan. The deposits in the Swan River and Judith River Formation are not currently of economic interest.The Ravenscrag deposits are confmed to four lignite basins, namely: the Estevan, the Willow Bunch, the Wood Mountain and the Cypress basin (Fig. 1). The estimated resources of immediate interest in the four basins are over 7 billion tonnes (Table I). These resources include lignite seams at least 1.5 m thick, at depths of less than 45 m.The average quality of lignite varies relatively little between the four basins considering the distance between deposits (Table 2). There is, however, a progressive increase in moisture and ash content, and a decrease in calorific value and carbon content as one moves westward from the Estevan to Wood Mountain and Cypress basins. The Estevan area deposits are of higher rank despite the fact that they are stratigraphically younger than the Willow Bunch deposits (Cameron and Marconi, 1979).In upgrading lignite to a higher quality fuel, it is important to know not only the average proximate and ultimate analysis (Table 2) but also other lignite characteristics influencing the product quality . For example, Figure 2 shows the effect of lignite HIC ratio on the product equilibrium moisture for hydrothermal treatment of lignite. It is apparent that lignites with a higher HIC ratio, or high liptinite content yield much better quality product for the same hydrotreatment conditions. Other examples of lignite characteristics which are important in upgrading include distribution of sulphur forms and mineral matter, maceral composition and degree of surface oxidation."

Jan 1, 1989

By W. F. Riggs

INTRODUCTION Flotation equipment is becoming more definitive in design as well as greater in dimension. The last ten years have witnessed the implementation of large flotation cells ranging in size from 28 to 85 cubic meters. However, small plants still operate with cells as small as 3 cubic meters. These changes have increased the operational sensitivity of the flotation system to the chemical reagents used. No scientific study has been undertaken to develop the relationship between the size of equipment and the response of reagents in the flotation system. Hence, this article is an attempt to present several observations from past experience for the purpose of stimulating future research in an area previously ignored and perhaps subsequently not used to advantage. CONVENTIONAL FLOTATION Recent advances in conventional flotation cell design have been made in two areas: a. Flotation cells are becoming larger, and b. Basic design of flotation cells has changed. They can be classified into two types: deep cell and shallow draft cell. Size and design changes of flotation cells have a greater effect on frother performance than on the performance of other chemical reagents. Hence, the discussion in the following sections is restricted to the impact of frothers in the flotation system. Flotation Cell Size The advent of increasing flotation cell size has resulted in the increase of frother consumption. There appears to be a correlation between reduced horsepower (kilowatt) consumption and increased frother consumption per ton of ore processed in the circuit. This is more prevalent when the frother chemistry remains unchanged. Another reason for increased frother consumption is the increased distance between the rotating central shaft and the lip of the cell for larger flotation machines. Increasing this distance results in increased surface area corresponding to the larger cell size. Reduced power input per ton combined with the need for longer, stronger load support of the froth bubble as a result of increasing cell size has resulted in the development of a new series of stronger and more persistent frothers. By the same token, these newer, stronger frothers are difficult to control when applied to the smaller cells. This is true even at lower dosages because the break point between too much frother and not enough frother for optimum metallurgy is normally very narrow. This problem is often exaggerated when operators have established an optimum setting for pulp level and air for the particular frother in use. Generally, the tendency is to operate the flotation cells simply by adjusting frother dosage. The increase in frother strength to accommodate the large cells often results in the realization, after a retrofit, that the existing pump box or sump which is still handling the same volume of concentrate is no longer adequate in size. Flotation Cell Design The two most common flotation cell designs installed during the past ten years are the deep cell and the shallow draft cell. The deep cell provides for complete mixing of air and pulp at the bottom of the cell. The shallow draft cell does all the mixing/pumping in the bottom haft of the cell whereas the mixing of the air is performed further up the shaft and is brought into contact with the pulp midway up the vortex. There are many preferences for one or the other. It is the author's contention that both designs have very valid concepts and must simply be suited to the particular situation as required by the operator. The following comments are subjective observations which should be explored in greater detail. The deep cell mixes both air and pulp together at the bottom of the cell requiring a full depth ascending of the homogenized air to the surface to form the froth layer. This design, in combination with charged air, provides for good concentrate grade control under adverse conditions of selectivity, especially when faced with a fine grind and a slime-laden gangue. A selective frother can be applied without a competitive loss in recovery. One of the conditions for good selectivity in this environment is operating at medium pulp solids concentration in the range of twenty-six to thirty-four per cent (26-34%). When a higher solids concentration is used in combination with a coarse grind, it becomes difficult to maintain the same recovery with a selective frother due to higher pulp viscosity. This condition sometimes results in an unacceptable coalescence of the air bubbles as they ascend the full height of the deep cell. The increased pulp viscosity at higher solids concentration can also retard the flotation kinetics. The combination of decreased surface area of dispersed air and slower kinetics can result in reduced recovery causing coarse particles to continue to drop

Jan 1, 1989

By M Stewart

Alluvial gold deposits in the area studied are preserved on the valley floor and elevated terraces due to a sequence of glacial/interglacial events during Pleistocene and Recent times. Continued regional uplift has overprinted these events. Prospecting by drilling and bulk sampling has demonstrated a complex alluvial gold resource which is now being mined.

Jan 1, 1989

Interest in industrial minerals in recent years has increased to such an extent that it has taken them into the mainstream of the Australian mineral industry. Notwithstanding that time series data on the values of production, exports, and imports show that industrial minerals are overshadowed by metals and energy minerals, their contribution to the national economy is important and more significant than would seem to be indicated by the statistics. Whereas the ex mine value of metals generally includes some processing (at least to a concentrate stage), most industrial minerals are valued at little more than their extraction cost, in addition to which such costs are generally low because most industrial minerals are exploited in low-cost surface operations. Consequently, values of mine production of metals and industrial minerals are not strictly comparable in that values of mine production of metals tend to be overstated Short term growth of the industrial minerals sector is assured because of several new projects already commissioned but not yet reflected in the statistics. Longer term growth is also assured, based on various other major projects that are likely to come on stream in the early to mid 1990s.

Jan 1, 1989

By B. M. Das, V. J. Hucka, J. H. Tu

Subsidence can cause serious damage to surface installations such as railroads, highways, pipelines, buildings and other facilities over a period of many years. Although total elimination of the effects of subsidence is difficult, the damage can be minimized through a systematic analysis. An example of such a study for reducing the effects of subsidence on pipelines is presented in this paper. Subsidence-induced stresses on a pipeline over some coal mining properties in Utah have been analyzed using a computer with graphics capabilities. The results are useful in predicting the extent of damages due to mining subsidence. In view of the gradual replacement of room-and-pillar mining by longwall with caving, this sort of analysis will become more and more important. In the next phase of this study the predicted results will be compared with the permissible stress levels on pipelines over actual subsided areas in an actual case.

Jan 1, 1989

Despite a long history of production of industrial minerals and rocks, New South Wales still offers significant opportunities for exploration for and development of these minerals. Exploration for opal, sapphires, and zeolites in the State has been particularly encouraged by pioneering geological studies by the Department of Minerals and Energy, which have resulted in the development of important new geological concepts and exploration techniques. Large areas with potential for these minerals have not yet been tested. In the case of sapphires, the studies have identified a new type of deposit which is'the source of most of the sapphires mined from alluvial deposits. Recent price increases for heavy minerals, a re-evaluation of previous exploration in coastal regions, and a recognition of suitable environments in inland New South Wales have stimulated renewed exploration both onshore and offshore and have led to increased production. Significant potential also exists for development of a number of other minerals, including: topaz, which occurs in large, unusual and perhaps unique deposits in northern New South Wales; dimension stone (particularly granite); bentonite; diatomite; and silica for metallurgical use. Potential also exists for development of construction material resources, particularly construction sand, which is in short supply in the Sydney region.

Jan 1, 1989

By Abbott T. M

Alcoa of Australia operates three Alumina refineries in the South West of Western Australia at Kwinana adjacent to the South suburbs of Perth and at Pinjarra and Wagerup in rural settings 100 and 150 kilometres south of Perth respectively (see Figure 1). Alcoa's total alumina production is currently around five million tonnes per annum and this will increase to 5.5 million tonnes by early 1990. Further expansion of production is likely if current world aluminium demand trends continue. Alcoa's refineries utilise bauxite mined in the nearby Darling Range which is low grade by world standards having around 32 % by weight extractable alumina (by comparison Weipa bauxite yields around 55% alumina). This means that for every tonne of alumina produced two tonnes of solid wastes remain and therefore while we in Western Australia can boast of hosting the largest alumina industry in the world with around 18% of total world production we suffer from having the lion's share or 40% of the world's bauxite residues to dispose of. In its Western Australian setting the management of these residues in a manner which is acceptable to the community creates many challenges. These are primarily due to the mass and volume of waste produced, its chemical and physical characteristics and the environmental features of the local area including close proximity of neighbours, competing land uses and the presence of natural resources such as surface water and groundwater. In addition the trend towards more stringent statutory environmental controls and greater political and community awareness of environmental issues means that we must be able to demonstrate improvements that will reduce the considerable adverse impacts of past practices. Of course we must also try to keep the overall cost of residue disposal as low as possible to maintain our competitiveness with refineries which may have much smaller volumes of waste to dispose of and less environmental constraints.

Jan 1, 1989

The first principle one usually Learns about blasting is that cunpetence in this field is best gained by experience in making blasts rather than by reading a book or by listening to a lecture. The reason for this is that there are a large number of variables affecting blasting results and not all of these can be accounted for by a few rules or a few sets of equations. Even an experienced blaster when operating in a new area, may have to make one or two shots just to acclimate himself to the new conditions with which he is faced.

Jan 1, 1989

By Bibby P. A, Leupen R. A

A 24,300 tonnes per year state of the art Silicon smelter is being constructed for Barrack Silicon Pty Ltd at Kemerton, 20 kilometres north of the City of Bunbury in Western Australia. The plant is designed for the reduction of high purity quartzite lump to metallic silicon in two 27MVa Demag submerged arc electric furnaces. The primary reductant, a high purity charcoal, will be manufactured at the plant from locally sourced jarrah wood waste (Eucalyptus Marginata). Commercial silicon production is scheduled to commence in October 1989. Keywords: Silicon, Smelter, Quartzite, Furnace, Charcoal, Jarrah, Wood, Eucalyptus Marginata.

Jan 1, 1989

By N. C. Matheson

The West's Shell Pile has been used on sites with very soft ground conditions for over 60 years. Fibre reinforced precast concrete shells 900mm long are threadled onto an internal mandrel which can be extended according to the depth driven to attain the load bearing resistance. On completion of driving the mandrel is removed leaving the precast shells to form a permanent lining to the cast insitu concrete core. To give resistance to high contamination, a tar based epoxy coat is sprayed on the outside of the shells or a flexible PVC liner is installed inside the shells to protect the core. Fundamental to the resistance to contamination is the quality of the precast fibre reinforced concrete shell, the mix design and method of manufacture. A series of detailed laboratory experiments were carried out using samples immersed in concentrated acid and sulphate solution. The long term effects of exposure to contamination is recorded in the case studies of existing piles at two gasworks sites.

Jan 1, 1989

By Riggin P. R.

"IntroductionIndustrial Relations combines two very important relationships - employee relations and union relations.Employee relations always come into play when people are hired to perform tasks. Because mineral processing plants cannot be operated successfully without people, at least not yet, if they ever will be, employee relations must exist in an operatingplant.If the employees choose to be represented by a union, then a relationship with the union as an institution also comes into play. It is very important to note that unionization does not mean that the employee relationship is replaced by a relationship with the union. The latter is superimposed on the former, but it does not replace it. Similarities and overlaps in the two relationships will be present, some of which are of fundamental importance. Nevertheless, they are two different relationships and the reader should bear this in mind when reviewing those parts of this chapter which discuss unionization, collective bargaining, collective agreements, and work stoppages.These two important relationships, which we have chosen to combine and call industrial relations, have crucial roles to play in the social system which interrelates people performing the necessary tasks involved in the operation and maintenance of a plant. The technological organization - equipment, process layout and so forth - and this social system are interdependent and complementary. This chapter attempts to show that the potential level of effectiveness of both the technological organization and the social system depends on the recognition and nurturing of this nexus between them.Occupational health and safety and training are subjects for another chapter. But, both of these have been critical and longstanding employee relations topics . They are destined to take on added importance in the future. As issues in collective bargaining, they are also attracting increasing attention in all union relations. It is hoped that the reader will not isolate from industrial relations those topics which are being dealt with in another chapter. They are very much a part of it and we cannot refrain from making some reference to them."

Jan 1, 1989

By Peters S. G, Beams S. D

CONCEPTS AND REGIONAL GEOLOGY The Charters Towers region holds many keys to the metallogeny associated with the complex geological development of eastern Australia during the Palaeozoic. Tectonic, magmatic and volcano-sedimentary depositional episodes can be identified and related to the chronological development of batholithic host rocks (Clarke & Paine, 1970; Henderson, 1986; Murray, 1986). Pre-batholithic basement rocks in the north (Charters Towers Metamorphics) consist of a package of amphibolite grade schists interlayered with and intruded by gabbros and diorites (Peters, 1987). To the south (Seventy Mile Range Group) greenschist facies Cambro-Ordovician rocks overly some of the basement. The lower age of this basement is not constrained, parts of it could be as old as Pre-Cambrian. Mid-Ordovician (approx. 470 my) to Lower Devonian (approx. 400 my) age I-Type granitoid plutons of the composite Ravenswood batholith intrude the pre-batholith basement and the Seventy Mile Range Group. Igneous activity was initiated again in the Carboniferous with the extrusion of rhyolitic lavas and pyroclastics associated with porphyry and high-level intrusive complexes (Wyatt et al., 1971). The Ravenswood block is bounded by Devonian and Tertiary sedimentary sequences of mainly continental provenence.

Jan 1, 1989

By S. S. Gajin

The paper deals with parametric vibrations of an axially loaded pile. The dynamic model is derived by means of Hamilton's principle and reduced to a partial differen­tial equation with variable coefficients and corresponding initial boundary conditions, taking into account the influence of the axial force. By means of Galerkin's method, the partial equation is further reduced to a Matheu-Hill's matrix partial differential equation of the second order. Since the problem of the dynamic stabili­ty has been expressed only for standing piles, the paper analyses in detail two stan­ding piles, one which is restreined, whereas the other is hinged at the toe. In both cases it is assumed that head horisontal displacement is prevented. Using Ruunge-Kutt's method, a computer analysis in the time domain is given for the characteristic parameters and possible boundary conditions. The paper analyses the stationariness of the process, as well as the dependance of the critical excitation frequency upon the pile parameters. The results have been illustrated by respective diagrams.

Jan 1, 1989

By D. Mohan

Soft to medium dense silty and clayey soils are found in many parts of India and conventional friction piles have normally been used for foundations of high rise buildings and other structures on such soils. The author investigated the use of Bored Compaction Piles and these have been used on these soils achieving substantial economies in cost over conventional friction piles. Similarly highly expansive clays, commonly known as Indian Black Cotton Soils occupy about 20 percent of the Indian land area. Short bored underreamed piles have been developed for such soils and a very large construction of various types of buildings and other structures have come up on such piles over the last thirty years in various parts of the country. The paper describes investigations leading to the design and development of both these type of foundations.

Jan 1, 1989

By Junbiao Liu

Rutile is mostly produced from placer sands. Its beneficiation from primary deposits has rarely been investigated. However, there is interest in primary deposit because of the depletion of sand deposits. The Zaoyang deposit in China is the only rutile primary deposit currently mined. The plant employs a Tabling-Magnetic process which recovers only 20% Ti02 at a grade of 87%. This study shows that significant improvement on the recovery (52% at the same grade) can be achieved. This study includes a detailed mineralogical examination and the development of a processing flowsheet of the ore. The gangues are primarily amphiboles, garnets, zoisites, and chlorites. The liberation of rutile occurs at about 200 mesh. Gravitational, flotation, and magnetic separations are all employed in the process developed, depending on the mineral characteristics and experimental results. The flotations circuit utilizes benzyl arsonic acid to float rutile and sodium fluosilicate to depress the gangues. This is a new reagent scheme for rutile flotation.

Jan 1, 1989

By B. R. Mohal, S. Chander

"The adsorption and wetting behavior of freshly ground and aged coals has been determined in the presence of a nonionic surfactant. The amount of surfactant adsorption changes with the concentration and ""age"" of the coal. The freshly ground coal has smaller amounts of adsorption at lower surfactant concentrations than the ""aged"" coal whereas at large surfactant concentrations, the order is reversed . In the latter case, more surfactant is adsorbed on fresh coal than on the ""aged"" coal . . It is proposed that at low concentrations, the surfactant adsorbs through both hydrophobic and hydrophilic interactions with the molecule lying parallel to the· surface, whereas at higher concentrations surface micelles form at the hydrophobic sites. The wetting behavior correlates well with the adsorption behavior.INTRODUCTIONNonionic surfactants have many applications in the coal and mineral processing industry. They can be used as dispersing agents to modulate flotation, flocculation and filtration of particulates (1). They can also be used to increase the wettability of hydrophobic solids such as coal and can hence be used as dust suppressants (2,3). Although the adsorption of representative nonionic surfactants such as Triton N-101 (an ethoxylated nonylphenol with 9.5 moles of ~thylene oxide and HLB equal to 13.4) have been studied extensively on substrates such as calcium carbonate (4), silica (5) carbon black (6) and graphite (7), very few studies are available for coals. Coals differ from other substrates with respect to two important characteristics: 1) coal are porous and 2) coals consist of a patchwork of hydrophobic and hydrophilic sites (8). Since the adsorption characteristics of a surfactant are influenced significantly by the nature of the substrate the characteristics of the coals must be taken into consideration."

Jan 1, 1989