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By O A. Cottrill, G A. Oldfield, S B. Nowell

Host-rock û wallrock major and trace element geochemistry associated with epithermal gold mineralisation in the Hauraki Goldfield of New Zealand is poorly documented, even though rock geochemistry is a recognised tool in exploration. Such responses assist in recognition of the regional scale imprint of fossil hydrothermal activity, and indicate targets for detailed evaluation within these alteration zones.   Recent investigation of gold deposits in the Waihi (Gladstone), Golden Cross (Empire), Thames (Waiotahi) and Coromandel (Tokatea) areas indicate enrichments of Au, As and Sb in the andesitic wallrocks hosting mineralisation. Of the other elements examined, Si, K and Rb are enriched, and Na, Ca, and Sr are depleted at all deposits. These trends are best developed in the vicinity of veining. In deposits with clay alteration dominating (Waiotahi and Tokatea) there is also depletion of Mg, Mn, Zn and Cu. Ba and Cr are variably enriched or depleted within different styles of alteration. Base-metal enrichment in the wallrocks is not a feature of Hauraki deposits.

Jan 1, 1990

By M. Rieber

The potential for the wide-spread commercialization of superconductivity, the disappearance of all resistance to a direct current (D.C.) electric flow, began in 1986-87 with the development by Bednorz and Muller at IBM's Zurich Laboratory of an yttrium -barium -copper oxide conductor which attained zero resistance at 90t:. Although the status of superconductivity is still pre-bench scale, it is useful to forecast its probable effects on the copper industry. I t should not be forgotten that at their inception, the impacts of transistors, semi-conductors, thin films and fiber optics on the electric/electronics sector of this industry, were largely underestimated. Superconductors are not metals, but a class of ceramics. They represent an efficiency increase of one or more orders of magnitude. If their development is to be a boon to the copper industry, rather than a reduction of metal demand through miniaturization or material substitution, vastly expanded copper containing electrical uses must be in prospect. In this paper the projected uses of high temperature superconductivity are examined, followed by the remaining problems to be overcome. Assuming success, a time horizon for maturation is estimated. The penalties for the non-recognition of new markets and material substitution are shown on the basis of past forecasts. Finally, the application of successful superconductivity to the copper industry over the forecast period is estimated.

Jan 1, 1990

By Johnson RW, Rogerson R

New perceptions of the nature of volcanic hazards on Bougainville Island have resulted from a recent remapping of the geology of the island. Ignimbrites and calderas have been identified at six Quaternary centres (Emperor Range, Tore, Kunua, Billy Mitchell, Loloru, and Laluai), and large-scale explosive activity now must be identified as a significant volcanic hazard on the island. Billy Mitchell and Loloru volcanoes are identified as the most likely sites of future, major, explosive activity. Billy Mitchell was recognised formerly as an extinct volcano, but is now known to have produced major eruptions 370 and 918 years BP. Five ignimbrite units recognised at Loloru range in age from about 12 700 to 3200 years BP. Bagana is an active volcano in central Bougainville, but its explosive activity is relatively minor and does not significantly affect areas beyond the uninhabited area of the volcano itself. Balbi is the largest volcano on Bougainville and has an extensive geothermal area at its summit. It was thought to have been in eruption last in the early nineteenth century. However, 370 and 940 year BP plinian ashfalls from Billy Mitchell cover the central area of Balbi, so the latest significant activity from Balbi may have been at least 1000 years ago.

Jan 1, 1990

By G. A. Dawe, E. G. Kelly

Because of the nature of the breakage in the Barmac vertical spindle impactor, the 80% reduction ratio is very small, so that when an energy efficiency is calculated from Bond's method, it appears to be very low. However, the product size distribution contains a high proportion of fines. It is argued that the production of these fines accounts for the high energy consumption, and Bond's method is modified to account for this, by considering the crusher to be, effectively, a number of smaller crushers in parallel, each having a different reduction ratio.

Jan 1, 1990

LITHOPROBE is a national, collaborative research grogram with the general objective of understanding the teotectonic evolution of the North American continent through multidisciplinary lithospheric studies in carefully selected areas of Canada. Six transect areas are investigating Precambrian evolution, although only in two of these is the research well evolved. The Archean Kapuskasing Structural Zone in Ontario is confirmed as an upthrust slice of upper to mid crust exposed at the surface. The Late Proterozoic Keweenawan mid-continent rift is shown to be the deepest known rift on Earth and the Grenville collisional zone of Ontario and Quebec involves crustal scale imbrication and ramping of deeply buried rocks to the surface. Two transect areas are investigating Phanerozoic evolution. In the Newfoundland Appalachians the geologically defined tectonostratigraphic domains do not coincide with lower crustal blocks defined by seismic reflection data. The Southern Cordillera Transect in western Canada is examining the nature, timing and dynamics of the assembly of the Cordillera, and particularly the role of accreted terranes. Work in the eastern and central segments has extended the known western limit of the North American craton at least IOO km westward and crustal-scale ramps associated with metamorphic core complexes have been identified.

Jan 1, 1990

By D. G. Chedgy

Environmental improvement efforts are focusing with increasing intensity on pollutants resulting from combustion. The high cost of removing these pollutants at the power station is well documented. Physical coal cleaning has always been and should remain the most economic method of reducing sulfur oxide emission from coal combustion. It is critical in the selection of preparation plant circuitry to consider capital and operating costs, as well as the level of sulfur reduction. This paper describes the technical criteria which must be used for efficient process selection and summarizes the cleaning systems available or in development.

Jan 1, 1990

This paper presents a resume of the likely profitable mining areas in New Zealand. It covers the main 'minerals' û gold, coal, oil and gas, ironsands, silica sands, clays, lump silica, perlite, sulphur and limestone. The potential mining projects are depicted on a map of New Zealand together with the associated works involved in hydro-electric and geothermal power development requirement for industries such as aluminium, nickel ferro-silicon or silicon carbide production. The political need for mining development to relieve unemployment and reverse emigration is stressed. A case is made for exploration and development assistance by government in labour re-training, energy supply and transportation, if the tremendous losses through lack of use of human and industrial resources are to be rapidly reduced. These losses are currently estimated at $10 000 000 000 per year. The need for protection of the sanctity of contract and security of tenure of all mining operations is touched on briefly as is the need for a reasonably balanced view on conservation. However, as both of these are more properly covered in papers on the legal and environmental aspects of the mining climate, they are presented here only as they affect the economy of the mining operation. Finally, there is a brief comment on the mining climate in New Zealand relative to Australia and South Pacific mining operations.

Jan 1, 1990

Large GDP increases in the Pacific Rim countries have been accompanied by similarly large increases in demand for oil products. In the case of residual fuels, this demand has been tempered by the substitution of other energy products such as coal or gas. In the region's developing and newly industrialised nations, it has not been possible to make the very large investments in infrastructure which allow other energy sources to be used for transportation. As a result, GDP growth has been mirrored in the demand growth for automotive fuels. Other non-substitutable products such as lubricants have also benefitted by the region's GDP growth.   The combination of a number of years of sustained growth, coupled with increasing quality requirements is now stretching the upgrading capacity of the region's refineries. IT, as seems likely, the region continues to enjoy a high GDP growth rate, then this will be accompanied by increasing reliance on finished products coming out of the Middle East.   The owners of the most simple form of refinery in which crude is simply distilled and the naphtha reformed into petrol will face major capital investments. If they decide not to bear this cost, they will face increasing problems in selling their surplus residual fuel oil at an economic price. Quality will become an increasingly important issue. Not only in the well publicised areas such as unleaded petrol, but also for products such as lubricants which play a major role in the efficiency of modem equipment. Quality of service such as hours of opening, ease of access, and service station facilities will also become increasingly important as the oil companies use these to attract customers and gain brand differentiation.

Jan 1, 1990

By M. Fiset, D. Belley

"To better understand the wear process of various materials that may be used as blades on snow removal equipment, the first step is to evaluate the influence of the load applied and the moving speed on road wear rates of one type of steel and three types of polymers. While the behavior of steel conforms to Archard's law, wear rates of polymers increase to a power of ex of the load applied according to a model implying that the wear of these materials is due to fatigue. The wear rate of some of the polymers varies considerably in terms of speed, unlike the steel. The wear resistance of some of these polymers outclasses the steel tested as long as the speed is not too great. They, therefore, present interesting alternatives for snow removal on more fragile surfaces such as sidewalks and zone made of inter-block slabs.IntroductionSince the dawn of the Industrial Revolution, the massive use of machines has brought with it a number of different problems regarding wear. Snowplowing roads, parking lots and sidewalks is an activity that generates enormous expense in a country such as Canada. To better understand these wear processes and in the hope of stimulating new approaches designed to reduce the costs related to this sector of activity, this paper presents the behaviour of several materials (steel, polymer and rubber) as they wear on an asphalt-fines matrix surface lubricated with water. Also discussed is the effect of various parameters such as the load applied and speed."

Jan 1, 1990

By N. A. Abdel-Khalek

An experimental study was carried out to compare the results of laboratory column flotation versus conventional flotation for the cleaning of fine coals of different rank and their oxidized samples as well as discrete size fractions. Surface oxidation caused a significant reduction in the flotation yields achieved with both methods. However, the column flotation produced concentrates? of lower ash content. The recovery -size curve achieved with column was similar in shape to that obtained with conventional cell, with superior results in the region of fine fractions. The influence of some column operating parameters was also discussed.

Jan 1, 1990

By J. E. Garlanger

Each year, Florida mines approximately 40 million tons of phosphorite, most of which is ultimately converted to various commercial fertilizers. The phosphorite is mined from within the bottom portion of the 40-to 60-ft. thick surficial aquifer, using open pit mining techniques. The ore zone or "matrix" is generally overlain by relatively permeable fine sand to silty and slightly clayey fine sand. The ore itself is highly variable in nature but, in Central Florida, typically consists of less permeable clayey phosphatic sands and sandy clays with stringers of permeable sand. The ore is much more sandy in the north Florida mining area.

Jan 1, 1990

By Stuart F. McTavish

Mechanically suitable grinding mills became available to the mining industry in 1908. Since then, mill operators have been searching for the best material and design with which to line the mills. These liner systems had to fulfill several criteria. Most important, they had to last long enough in an operating mill to protect its structure from the abrasive wear of the ore and the grinding media. In addition, they had to be capable of efficiently transferring the energy from the mill to the mill charge in order to facilitate the grinding process. And these liners had to be easy to install and remove. The first liners used were generally made of cast white iron, Hadfield manganese, unalloyed high-carbon steel and composites of steel and concrete or cemented in flint blocks or natural stone. In the early 1920s, pieces of solid rubber truck tires were used as emergency repairs for broken cast metal liners. Thus was rubber first introduced as a mill liner material. The first patent for rubber mill liners was awarded in 1921 to James Denny and Rolla Watson, both of the Coniagas Mine in Cobalt, Ontario, and to Dale Barnum of the Comstock Lode in Virginia City, NV. This original design was covered under US Patent No. 1470597. It had a fabric backed rubber that was bonded to the shell of the mill.

Jan 1, 1990

By B S. Utting, W J. Cowie

The alluvial gold industry of New Zealand is based on the placer deposits in Otago and on the West Coast. Production from these since discovery in the 1850s has been an estimated 480 t (15 Moz) of gold. Annual output has expanded continuously since 1980 and is expected to be over 2 t of gold for 1989. Following a historical review, the characteristics of typical operations, which use hydraulic excavators and mobile trommel units are discussed. Descriptions are then given of alluvial activities in Otago and on the West Coast.

Jan 1, 1990

By M. Leroux, P. Lacombe, S. R. Rao, J. Y. Kim, J. A. Finch, G. Labonté, N. Macminn, M. Ounpuu

"Laboratory investigations on two complex ores, the A1 zone ore from Les Mines Selbaie and the Lyon Lake ore from Mattabi Mines Ltd. (Division of Noranda Minerals), have been carried out to determine some of the main variables in collectorless flotation. In particular, the effect of pulp potential (controlled by gas composition), conditioning time, pH and grinding media have been studied.Chalcopyrite showed the greatest response to collectorless flotation among the four major sulphide minerals present, followed by galena. Flotation of sphalerite was variable from minimal to important depending on the mineralogy and the pre-treatment performed. Appreciable silver recovery was achieved collectorlessly for the Lyon Lake ore while it could not be achieved for the A1 zone ore of Les Mines Selbaie. It appears that the difference between the two ores is related to silver's predominance as tetrahydrite in the Lyon Lake ore while it is as argentite and native silver in the A1 zone ore.The response of the ores to collectorless flotation is strongly dependent on the pulp potential, Ep, and pH. Using different gas compositions and different conditioning times it was found that collectorless flotation occurs when Ep is +195 to +295 mv (vs SHE). The actual on-set potential for collectorless flotation is dependent on the ore. A too high potential or prolonged oxidation leads to a decrease in selectivity. Some other factors were examined, notably the effect of pH and the type of grinding media on the selectivity achieved in the laboratory.Preliminary results from a plant trial at Mattabi Mines Ltd. confirmed that collectorless flotation occurs and that it is preferential for chalcopyrite and to a lesser extent galena. Collectorless flotation was not attempted at Les Mines Selbaie. However, examination of the distribution of collector between the different addition points in the copper circuit suggests that it may be present."

Jan 1, 1990

By S. P. Mathew

The ISASMELT Lead Process is a continuous two stage process for the production of crude lead from concentrate. It is based on the use of a top entry submerged Sirosmelt lance to produce turbulent baths in which high intensity smelting or reduction reactions can occur. The process involves oxidizing the concentrates in the first stage to produce a high lead slag. This slag is tapped continuously and transferred down a launder to a second furnace where it is reduced with coal. Crude lead and discard slag are tapped continuously from this furnace through a single taphole and separated in a conventional forehearth. Process and engineering design work for a commercial scale Lead ISASKELT plant designed to produce 60000 tpa crude lead has been completed. This plant is planned to be operational in 1991.

Jan 1, 1990

By J. A. Sekhar

Solidification processing/casting is increasingly being adopted as the preferred manufacturing technique for the fabrication of net shaped complex geometry components. Modeling of solidification processes is important both for design purposes as well as for understanding the physics of morphological evolution of the solidification microstructure. A fundamental aspect of such modeling involves the precise understanding? of heat transfer through the two phase solid/liquid region. A scheme to do this will be presented where the nonlinearity of the fraction liquid with change in temperature can be incorporated into the numerical calculations. The importance of properly accounting for the non-linear mushy zone will be discussed. Typical processes like squeeze casting and electromagnetic stirring will be discussed to illustrate how precise modeling of the solid/liquid region can aid in the calculation of accurate heat transfer coefficients for these processes.

Jan 1, 1990

By N. S. Dalal, Xianglin Shi

"INTRODUCTIONEpidemiologic studies of workers in chromate-ore related industries, 1-3 and stainless steel welding and related occupations4 have shown that they have about 20-40 times higher risk of throat or respiratory track cancer than controls. Although the actual carcinogenic substances were not identified in these statistical studies, Cr(VI) compounds (for example, calcium chromate, zinc chromate, and lead chromate) were implicated as the causative agents, whereas Cr(III) compounds were not suspected as carcinogens. s These suggestions were supporte4 by laboratory studies wherein many Cr(VI) compounds produced sarcomas at the implant or injection sites.1,5 Squamous cell carcinomas and adenocarcinomas closely resembling human lung cancer were induced by intrabronchial implants of calcium chromate in rats, 6·7 whereas Cr(DI) oxide and Cr(lll) sulfate did not induce any tumor formation.6,7While the mechanism of the chromate-induced carcinogenicity is not fully understood, it is generally thought8 that it involves some damage to DNA. Specifically, it has been reported that: a) the chromate ion, henceforth referred to as chromate, can pass through the cell membrane and enter the cell while CR(DI) does not, 9 b) chromate does not interact with either native or denatured DNA 10 while Cr(III) does, 11 and c) the final Cr-DNA complex isolated from cellular reactions of chromate is Cr(III)-DNA, with Cr(III) binding to the phosphate groups.12,13 Thus the important question is: since Cr(DI) cannot pass through the membranes, how does Cr(III)-DNA complex form? For this to happen, Cr(VI) must be reduced to its lower oxidation states, 14 ultimately to Cr(III), by some reductants in the cellular environment. Unless this reduction occurs, the DNA would not be damaged and therefore no chromate carcinogenicity would ensue. Thus the reduction of chromate to its lower oxidation states seems to be a key step in the chromate carcinogenicity .1s One of the major reductants in cellular environments is thought to be glutathione (GSH), both outside and inside the cells.16-lB Some evidence for the role of GSH in the chromate toxicity was provided by recent studies showing that exposure of hamster cells to non-toxic levels of added selemite increases the levels of GSH as well as the Cr(VI)-induced DNA strand breaks,19 and that such DNA strand breaks in hepatocytes also change in direct proportion to the GSH content. 20,21 These observations were interpreted as implying that the reduction of chromate by GSH to some reactive intennediate is an important step in the chromate carcinogenicity. 20.21 In · the present undenaking22 we have used electron spin resonance (ESR) and spin-trap methodology to investigate the reduction of chromate by GSH and find evidence for the involvement of the glutathionyl radical (GS ·) as well as Cr(V)-intermediates."

Jan 1, 1990

By R. A. Jankowski

The U.S. Bureau of Mines has conducted a study to identify the sources of respirable dust and appropriate dust controls applicable to today's high tonnage longwall faces. The primary source of respirable dust identified is the cutting action of the shearer; however, the pct contribution of dust from coal transport through the stageloader/crusher was significant. This was primarily due to the high rate of mining, requiring rapid and constant coal transport. Techniques implemented for the control of shearer-generated dust included high drum water flow rates, deep cutting, shearer-clearer-type external water spray systems, and radio-remote control. The high water flow rates, and an enclosed stageloader with scrubber, were used to control dust during coal transport. No novel or effective control technology exists to control dust during support advance. Administrative controls for dust avoidance, and manual and batch-activated electro-hydraulic control systems were used to keep support movers out of the dust generated during support advance.

Jan 1, 1990

Reduce the potential of haulage related injuries in underground mines by providing a method for quickly assessing the state of repair of mine haulage track. The Problem Currently, there are no established standards or procedures for inspection or cleaning of underground mine haulage track. Many track defects are hidden from an inspector because of layers of dirt and debris on the ballast, spikes, fishplates, etc. When a visual inspection can be performed, it may be highly subjective, except for a few items that can be categorized or counted, such as missing bolts or spikes. Track inspectors may even become tolerant of defects that can gradually worsen. For these reasons, mechanical inspection methods are needed to supplement visual inspections. Approach The Bureau investigated this problem and designed a towed vehicle to both mechanically clean and inspect underground coal mine haulage track. The vehicle was developed using a systems approach, paying particular attention to human factors issues such as operator field of view, operator ingress-egress, control positioning, and seating design. The prototype was built using simple fabrication techniques and off-the-shelf components.

Jan 1, 1990

By M. G. Dellow, D. W. Hendriks

"In early 1988 the decision was made by Noranda Minerals Inc. to install pressure filters at the GECO mill to replace the vacuum disk filters and bunker-C fired rotary kiln dryers. Two filters were installed, one for copper concentrate and one for zinc concentrate. Completion of the project was scheduled for the third quarter of 1989. The filters were made operational in October 1989. Some work remains to be done yet on loadout conveyors for total project completion. Capital expenditures for the project have been approximately $2,700,000 to date. The paper describes the selection criteria for the filter, the installation, startup and associated problems.1. INTRODUCTIONThe filter model chosen for the project was the Verti-Press model VP-50-6(7) (Figures1 ,2 and 3) by Filtra Systems of Farmington Michigan, USA. The decision to purchase the Filtra Systems filter was based on gaining familiarity with a different, mechanically simpler pressure filter than the Larox design and to a lesser extent a necessity for repairs to the the disc filter, rotary kiln dryer system used at the GECO operation for its' copper and zinc concentrates. The fact that it is manufactured in North America was an important consideration. The same basic principles of pressure filtration as the Larox machine are used but the implementation is quite different and somewhat simplified with some interesting innovations. 2 filters were installed to allow direct and immediate comparison of the same machine on both fine and coarse materials. Copper concentrate is reground for cleaning on the flotation circuit while zinc is not. Screen analysis of composited samples of concentrates for 1988 indicated that expected copper concentrate would be approximately 66% minus 400 mesh and zinc 50% minus 400 mesh (Tables 1 & 2).The filter is composed of six horizontal chamber module layered vertically and held together in a frame by 1 O large bolts; torqued down to 4000 ft-lbs. 6 individual belts are used; each with its own drive system. The belts themselves are of a 3 piece design with a filter cloth portion, a support belt and a rubberized intermediate portion. They are held together with steel clipper lacings. A basic description (1) of the filter operation is as follows. ""The horizontal filler chamber is closed by hydraulically pressurizing seals across each end of the filter chamber to 200 psi. The feed pump then pumps slurry into the filter chamber. Suspended solids are retained on the filter belt and the filtered solution drains into a lower drip tray and flows from the filter by gravity. At the end of the filtration or feed cycle, a rubber diaphragm in the filter chamber is pressurized hydraulically to 100 psi pressure. This removes all free liquid from the filter chamber and the filter cake. After the diaphragms are retracted the filter cake is blown with compressed air to remove any residual cake moisture. The seals are then retracted and the belt is advanced to discharge the filter cakes. During the cake discharge the belts are washed with a spray header located at the drive end of the filter. The belt assemblies move one (1) complete revolution during the cake discharge cycle. The cycle automatically repeats until the filter is shut down by the operator."

Jan 1, 1990