Search Documents

By Halagowder Devaraj, Mostafa Sheykhnazari, Veer P. Bhavanandan

"A sensitive colorimetric assay for detecting mucins and glycoproteins rich in 0-glycosidically linked saccharides is reported. The method combines the susceptibility of N-acetylgalactosamine terminating 0-glyco idically linked saccharides to P-elimination with the Morgan-Elson reaction for N-acetylhexosamines with free reducing ends. All mucin and mucin-type glycoproteins but none of the serum-type glycoproteins tested resulted in characteristic color production. All mucins tested gave linear responses in the range 5 to 200 ""g and the assay was also adapted to the microscale involving the use of 96-well microtiter plates. The microassay in which the volumes of samples and reagents are scaled down 2.5-fold was particularly useful in monitoring of mucins, in the presence of other glycoconjugates, in large numbers of samples obtained during fractionation procedures. Cesium chloride, cesium bromide, potassium thiocyanate, and various detergents do not interfere with the colorimetric determination. Guanidine hydrochloride, cesium triftuoroacetate, and B-mercap- . toethanol decreased color by 30 to 45%; however, the interference was not serious to prevent the use of the method for detection of mucins in their presence. The use of the method for the specific detection of mucin during fractionation by gel filtration and density gradient centrifugation of cystic fibrosis sputum samples is demonstrated. Mucins are an important class of biomacromolecules whose structure-function relationship is poorly understood (1,2). The investigations of mucins are hampered by difficulties in purifying these very large size molecules which appear to avidly bind other components of the mucus (3,4). One of the problems during purification is the specific detection of mucins. For example, during the various purification steps, the fractions containing mucins are typically detected by assaying for neutral sugars (hexoses) (5,6), for sialic acids (7), or for periodate oxidizable saccharide units (8). However, these methods are not entirely satisfactory because neutral sugars, sialic acids, and periodate-oxidizable saccharides are also components of other glycoconjugates. In addition, the neutral sugar and sialic acid measurements are also subject to interference from high levels of proteins and nucleic acids."

Jan 1, 1990

By R. Hogg, T. F. Dumm, L. G. Austin, M. Yekeler

"Dedicated to Professor Kurt Leschonski on the occasion of his 60th birthdayAbstractThe kinetics of batch grinding quartz from a feed of 600 by 425 Jim to a product of 80% less than 10 µm have been determined using screening and laser diffractometer sizing for size analysis. The specific rates of breakage decreased by a factor of about three when the material became less than about 100 µm in size, but the primary breakage distribution function also changed to give proponionately more fine material, so that the grinding efficiency expressed as the development of surface area (B.E:T.) per unit of energy input did not decrease. Analysis of the shape of the particles in the 2S x 38 µm size range showed that particles of this size produced by roll crushing or by 8 minutes of grinding of a 42S x 600 µm feed were not different but at long grinding times the particles were rounded. This suggests that the breakage mechanism changes to give more chipping and abrasion and less disintegrative fracture. As the material approached the ultrafine size range it adhered to the mill case and there was no further size reduction. However, a technique for striking the mill case to dislodge the particles was successful in allowing further grinding to 400Jo by weight less than 2 µm.1 IntroductionIt has long been known that it is difficult to accomplish ultrafme grinding in a tumbling ball mill. It has been reported [12, 13] that there is no further size reduction after some hours of grinding cement clinker in laboratory ball mills. Austin and Bagga (1] and Shah and Austin [16] have given an analysis of the kinetics of dry grinding in a laboratory ball mill, introducing the concept of a slowing-down factor K, which is the ratio of the specific rates of breakage at some long time of grinding to the normal specific rates of breakage. They showed that this factor decreased as fine material accumulated in the mill charge. Cottaar and co-workers [8-10] showed that the movement of solid in a dry laboratory ball mill was influenced by the fineness of the solid and by the presence of air, and that evacuation of air from the mill caused particle sedimentation and low rates of breakage.The concept of the slowing-down factor has also been used in wet grinding [17, 18]. At very .high slurry concentrations it appears to be correlated with a steady decrease of mill power caused by the build up of a layer of deposit sticking to the mill case. This reduces the effective mill diameter and, eventually, the balls start to adhere in the layer and centrifuge. A decrease of mill power always indicates less lifting and tumbling of the media and, hence, less breakage. However, slowing-down of breakage rates was also observed at lower slurry concentrations where there was no change in mill power."

Jan 1, 1990

By Chris McKee

Quartz has been of interest in occupational health for years because it can cause silicosis after prolonged exposure. New OSHA regulations (Air Contaminant; Final Rule) list perlite as a nuisance dust. They conclude that perlite is nontoxic when air-borne total particulate concentrations are 15 mg/m3 or below and when quartz content is less than 1% crystalline silica. OSHA has established an 8-hour PEL of 15 mg/m TWA for total perlite dust containing less than 1% quartz. OSHA has established a 5 mg/m3 TWA PEL for respirable perlite. These limits will protect workers from significant risk of eye, skin, or other physical irritation. This regulation is based on a Group 2A classification as a probable carcinogen in humans, at the 0.1% crystalline silica level, by the International Agency for Research on Cancer (IARC 1987a, b). IARC found sufficient evidence for carcinogenicity of crystalline silica in animals and limited evidence in humans. Perlite is not listed as a carcinogen by OSHA or the National Toxicology Program.

Jan 1, 1990

By Carl Hendricks, Malcolm Scoble

There currently exists no viable means of obtaining continuous feedback on blast efficiency. This paper describes the adaptation of a loading shovel to serve as a diagnostic tool to evaluate the success of ground preparation. Work undertaken in a large western Canadian open pit involved microprocessor-based instrumentation for the performance monitoring of an electric mining shovel. The monitored shovel responses proved to be reliable indicators of variations in muckpile diggability. This approach is considered to provide a very comprehensive survey of post blast conditions since such a shovel interacts which every cubic yard of a blast.

Jan 1, 1990

By H. Sevim

Three transportation systems in surface coal mines: 1-Truck Haulage, 2-Belt Conveying, and 3-Coarse-Coal Slurry Transportation are compared from the operations and cost point of Views. Computerized design and cost models were developed and cost data banks were compiled for each system. These models can be used to evaluate transportation systems and layouts that are practiced in most of the U.S. surface coal mines. A typical midwestern area strip mine was considered for illustration purposes. Sensitivity analysis on critical parameters such as production rate, transportation, distance, etc. was conducted and the outcomes are presented.

Jan 1, 1990

By Harold L. Gibson, David H. Watkinson

"Volcanogenic massive sulphide deposits of the Noranda Camp cur throughout the Noranda Shield Volcano but are concentrated and along the margins of the Noranda Cauldron. The deposits are realized along synvolcanic faults that also accommodated subsince and controlled the location of eruptive centres. Deposits within e 3 000 m thick Mine Sequence formed during a period of active volcanism and subsidence coinciding with the onset of two cauldron subsidence cycles. The Noranda Cauldron was a restricted site of 10malously high heat flow and structural permeability that favoured e development of a high-temperature hydrothermal system. Metals may have been derived from leaching of aquifer rocks by convecting a water or directly from a shallow underlying magma chamber, now presented by the Plavrian Pluton, that was at its highest position !thin the crust during cauldron subsidence. The deposits formed rough a combination of sulphide precipitation from exhaled fluid td replacement at and below the seafloor in a manner analogous to ose on the modern seafloor.RESUMESi les dépôts de sulfures massifs volcano gènes du camp minier de ~uyn-Noranda sont présents dans les différentes parties du volcanluclier de Noranda, ils se trouvent concentres toutefois, en plus ·and nombre, sur le pourtour de la caldeira (cauldron) de Noranda. ~s dépôts sont localises le long des failles synvolcaniques qui ont cilite la subsidence et contrôle la position des centres d’éruption.~dépôts situes dans la séquence des mines (3 000 m d’épaisseur) sont formes durant un épisode d' activité volcanique et de subsiden qui coïncide avec l' amorce de deux cycles d' affaissement de la rldera (cauldron) de Noranda. Celle-ci Jut le site exclusif d’unflux : chaleur anormalement élevé et d’une perméabilité d’origine cucturale qui ont favorise le développement d’un système hydrothermal a haute température. Les métaux proviennent soit directement d’une chambre magmatique situee afaible profondeur, so it d’un lessivage des roches de l’aquifère par l’eau de mer circulant par convection. Cette chambre magmatique, représentée maintenant par le pluton de Flavrian, se trouvait à son niveau le plus élevé dans la croute au moment de l’affaissement de la caldeira (cauldron). Les dépôts se sont constitués par un mecanisme combinant remplacement et précipitation de sulfures à partir des fluides exhalatifs, au niveau ou au-dessous du plancher océanique, de la même manière que se forment de nos jours, les dépôts de sulfures massifs au fond des océans."

Jan 1, 1990

By A. J. Getz

The paper reviews the status of the major precious metals projects in Australia, Papua New Guinea, Indonesia, the Philippines, and New Zealand. The projects may be at the stage of exploration, development, operation, or expansion. The paper covers project location, reserves, method of resource exploitation, anticipated production, and other unique conditions.

Jan 1, 1990

P.IISTRACTThe Pacific Rim is advantaged by the uniqueness and diversity of its geological features. Why then is geology given so little regard in the education systems of the countries of this region? Not that these countries differ greatly from those in other parts of the world. Papers presented during the Precollege Geoscience Education session at the 28th International Geological Congress (28th IGC) held in Washington, July, 1989, indicated strongly that the problem is universal. There is a marked decline in interest in the Earth sciences and many nations are looking towards methods that might change this trend. Problems affecting geological education include the lack of purpose and direction, its obsolete curricula and the difficulty in attracting gifted students.The world-wide plight of geology comes at the very time when it should be fundamental to a public understanding of the global effect of human population pressure. There is a universal awareness of "the environment" but very little awareness of the science that has supplied most of the data. Geology, as the science of the Earth, is of paramount importance to an understanding of our life on this planet, particularly in its role as the source of our every need.

Jan 1, 1990

By Rospigliosi RT, Krouse HR

The San Vicente stratabound zinc-lead rhythmite deposit, Peru, is hosted in carbonates of the Late Triassic - Early Jurassic Pucara Group. These strata were deposited in a large, shallow water, carbonate platform which extended nearly continuously for 150 kilometers (north-south) in the eastern part of the Pucara basin.The distinctive sulfide-bearing rhythmites occur in three dolomite units which, from bottom to top, include the San Judas horizon with one sulfide-bearing manto; the San Vicente horizon with seven sulfide-bearing mantos including the main ore horizon; and the Alfonso horizon with three sulfide-bearing mantos. The dark gray sulfide-bearing dolostone layers range in thickness from a few millimeters to a few centimeters and contain variable amounts of carbonaceous material, pyrite, quartz, fine-grained sphalerite and galena. They are bordered on each side by selvages of yellow to red-brown coarse-grained sphalerite containing minor amounts of galena. Coarsely crystalline white or gray sparry dolomite is found between the coarse-grained sphalerite layers. Although commonly stratiform and uniform in thickness, the dark layers curve, "pinch out," coalesce, and form "islands" and "peninsulas."Mineral replacement textures, the paragenetic sequence, and presence of sparry dolomite, bitumen, intraformational breccias and isotope data support a hydrothermal replacement origin by metal-bearing solutions that deposited the ore and related minerals in space previously occupied by dolomite and evaporite minerals. The alignment of the Zn -Pb deposits, and at San Vicente the orientation of the mantos, the spatially and temporally associated igneous sills and the tourmaline-bearing sandstone support hydrothermal mineralization driven by a magmatic heat source in a tensional regime.

Jan 1, 1990

By J. T. Furey

"A pilot plant study was conducted to evaluate the performance of column flotation in the recovery of gold from a gold/tellurides bearing sulphide ore, and to compare the performance of column flotation to conventional ""mechanically agitated"" flotation.Tests were conducted in a 60 liter glass column with ground flotation feed split from a concurrently operating conventional pilot plant, thus permitting direct comparison between the two processes. During the test program, the effects of wash water rate, gas holdup, froth depth, residence time and flow bias were examined in detail.The ore had an average ""as tested"" feed grade of about 5 g/t gold and 1 % sulphur, with the gold occurring primarily as inclusions of montbragite (Au2Te3) in pyrite, with minor amounts of native gold. Conventional flotation using 60 minutes residence time across four roughing stages recovered about 97% of the gold into concentrates grading about 50 g/t Au. A single stage of column flotation roughing using 25 minutes residence time matched the conventional circuit recovery of 97%, but produced grades of+ 150 g/t Au. INTRODUCTIONColumn flotation is the most significant innovation that has occurred in the mineral processing industry in recent years and has become an important alternative to mechanical flotation. Column flotation has been most widely accepted and applied in cleaning service where it has frequently proven to be superior to mechanically agitated flotation. Roughing in columns has not been ignored, but early testing indicated that columns may not be capable of achieving adequate recovery and, to date, columns have not been seen as serious competitors for mechanical roughers."

Jan 1, 1990

By Richard K. Sandaas

Start Date: April 4, 1988 Completion Date: Dec. 29, 1989 Contractor: SCI Contractors Past and present transportation centers will come together at International District Station, located at the south entrance to the tunnel next to the turn-of-the-century Union Station train depot. The area will bustle once again with activity as commuters and visitors converge on the modern transit station at the edge of Seattle's International District. Buses coming from south Interstate 5 and Interstate 90 will enter the tunnel through this station. [ ] International District Station is an open-air station, 1,060 feet long and 82 feet wide (about 15,400 cubic yards of concrete were used to build the station). A concrete lid over the southern portion of the station staging area is held in place by 131 support piles. The station will include entrances on Jackson Street and King Street. Union Pacific Realty is planning to build an office and retail complex upon the lid. The station also has an international flair. Symbols of the Chinese zodiac will be etched into the station plaza floor. The station platform walls will be lined with large steel panels embellished with designs in origami?a Japanese folded paper art form. [ ]

Jan 1, 1990

By Zhen Y. Y, Cook A, Jell J. S, Fleming P. J G

Remapping of the Burdekin Basin has resulted in subdivision of the three interfingering basin-wide megafacies previously recognised in the Early to Middle Devonian Fanning River Group. Eleven carbonate and siliciclastic facies are now identified within the three megafacies, representing coastal plain, shoreline, nearshore, and shallow marine shelf depositional environments. The facies reflect two phases of a major transgression. An initial phase, in the Early Devonian, was confined to the far north of the basin, whereas a second, main phase, resulted in the encroachment of the sea from the east or southeast in the Middle Devonian.The proposed depositional model begins with the drowning of a coastal plain and the transgression of shoreline and nearshore facies between granitic and metamorphic headlands and/or islands. This was followed by the deposition of a patch reef and fringing reef complex including stromatoporoid and coral bioherms, biostromes, and oncolitic, crinoidal, and brachiopod-dominated banks/shoals, together with foreslopes and submarine channels, carbonate rubble deposits and terrigenous sediments. Sedimentation during the peak of the transgression was dominated by sheltered carbonate shelf facies, the maximum, flooding surface being recognisable across most of the Burdekin Basin. Progradation of muddy and sandy nearshore bay and shoreline facies soon followed, terminating carbonate deposition.

Jan 1, 1990

By Matthew Janes

Quality control procedures are increasingly important with today's higher capacity foundations and complex loading conditions. The need for a mobile, repeatable, nondestructive and economical load test method led to the development of an entirely new approach. The system described involves using solid propellant fuels to accelerate a reaction mass off the test pile. The force required to accelerate the reaction mass upward acts equally downward on the pile. Very high forces may be applied to the pile in a controlled, linearly increasing manner. The duration of the applied load is approximately 100 milliseconds. This rate of loading is slow enough to allow the pile and soil to react together as a composite rigid body. Pile/soil accelerations and velocities are low, typically 1 g and 1 m/s respectively. The effects combine to produce pile and soil response no longer dominated by the transfer of force via stress pulse (as with impact). Instead the pile force increases throughout the length of the pile, with pile top and toe stresses building in unison with time. This emulates the stress condition during static pile loading. Finally, state of the art instrumentation systems are used to obtain test data. Displacement is monitored directly using a laser datum and integrated receiver located at the centre axis of the pile. Force is also monitored directly using a calibrated load cell. Data is acquired and digitized using a 386 PC with user friendly software capable of producing load deflection curves and time histories in the field seconds after testing.

Jan 1, 1990

By T. Cienski

The paper presents and discusses the results of a detailed study conducted on the subject of energy consumption in the comminution of industrial minerals. The study was based on pilot circuit testing, plant operating data collection, detailed equipment data and literature research. The areas covered by investigations include: high efficiency classification; air classifiers for cement grinding circuits; grinding aids in dry grinding: dry grinding circuit, control based on particle size measurement. Results obtained indicate a large potential for the reduction of energy consumption, in particular in the traditionally high cement clinker grinding circuits. Better classification techniques and correct application of grinding additives can significantly reduce power used per ton of product and also substantially increase grinding circuit output.

Jan 1, 1990

By G. P. Larson

We define a specialized mineral market as follows: Specialized Markets are markets where a low volume of a given mineral is used to convey a large benefit to a specific product. Sales of these value added minerals to small markets generally require a different marketing approach compared to bulk or commodity markets for traditional minerals. Specialized and commodity markets are differentiated by several characteristics as listed in Table 1.

Jan 1, 1990

By Stanley C. Suboleski

1977 was the modern day low point for productivity in the coal industry. At that time, no one could have predicted that the industry was about to enter a productivity rise that would continue unabated through the 1980s. Thirteen years later, the cause of this phenomenon is still not well understood. While many government studies focused on the fall in productivity from 1969 to 1977, none have been undertaken to explain the rise. Some of the likely causes of the gain in productivity during this period will be discussed here. An attempt will also be made to quantify the value of some of the technical innovations that have taken place. The remainder of the gain is assumed to come from non-technical sources. The nature of these sources, although largely non-quantifiable, is also discussed. Since the number of mines that have adopted the technical innovations noted here is largely unknown, the actual contribu¬tion of technological changes to the overall productivity gain can only be estimated.

Jan 1, 1990

Structural Controls Interpretation of regional aeromagnetics, radiometrics and satellite image data has identified three structural domains (fig 2): The Fairyland Domain: a general N - S structural trend. The Cracow Domain: a general NW - SE structural trend. The Bald Mountain Domain: a general N- S structural trend. Known mineralisation is confined to the Cracow Domain in which there occurs two major NW - SE trending fault zones. The Cracow Fault Zone (CFZ) and the Immy Creek Fault Zone (ICFZ). Enhanced detail of the CFZ (fig 3) shows three main structural trends within it: NW-SE structures which include the mineralised White Hope South fault zone and the Golden Mile fault zone. NE-SW structures which have an influence on mineralisation in the Orange Creek, Fernyside and Golden Plateau areas. N-S structures comprising several major structural zones.

Jan 1, 1990

By Ed D. Doney

Based on the subsidence data collected through a comprehensive subsidence monitoring program con: ducted over two longwall panels in an Illinois coal mine, mathematical models have been proposed for predicting final and dynamic subsidence in the Illinois coal basin.

Jan 1, 1990

The Great lady gold deposit presented the challenge of providing a new grade control system for an usual type of orebody in the Eastern Goldfields. Mineralisation occurs as secondary enrichment about a quartz sand - granite saprolite contact 30m below surface. The ore horizon, which averaged 2.5m thickness, was near-horizontally disposed in contrast to the typical steeply dipping, shear hosted deposits of the region. A trial mining operation was undertaken on the richest, most continuous portion of the deposit to test the economic viability of this type of orebody. Controlling and minimising vertical ore dilution was considered crucial to the profitability of the operation.An understanding of the grade distribution combined with the practicalities of mining produced a grade control system which allowed for the mining of 1/2rn composited grades on level lm benches. Ore mining was combined with strict monitoring of levels, truck destinations and ore boundaries. Ore reconciliation results showed this system to be effective.

Jan 1, 1990

By R. C. Bunge

A magnetogravimetric separation is the consequence of two competing forces with opposing directions, i.e., magnetic buoyancy and gravitation (or centrifugal force). While magnetic buoyancy is a function of particle volume, gravitational force depends on particle mass, thus permitting a separation according to specific gravity. Since magnetic buoyancy is not a phenomenon of common knowledge, this chapter is meant to briefly introduce the theory of magnetogravimetric separations. A particle that is suspended in a magnetic fluid which is exposed to an inhomogeneous magnetic field experiences a repulsive force -the so called magnetic buoyancy. In order to illustrate this effect, an analogy with the more familiar hydrostatic buoyancy is drawn. Hydrostatic buoyancy occurs due to unsymmetrical pressure distribution 'above' and 'below' a suspended particle (fig. 1).

Jan 1, 1990