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By Steven B. Van Kouteren

Added value is a term loosely used in the industry, but what exactly does it mean? What does it take to make a value-added product and more importantly how does a company maintain the value added to its products? Most people agree that value-added means the value of a mineral minus the cost to produce it. But what is misleading is that producing value added products does not necessarily guarantee the profitability of the products. In some cases firms that make "value-added" products are not very profitable. It is not only important to understand how to make a value-added product but also how competitive forces in the market can erode the value added. Therefore, when we look at value-added opportunities, we must understand how to obtain the value added and more importantly how to maintain the value. There are four major factors that limit a company's ability to add value to its products. This paper will examine these factors and will use the ground calcium carbonate and mica industries as examples.

Jan 1, 1990

02, NaCI03, H202, Na0CI and Ce+4 have been examined as oxidants in an alkaline carbonate system for uranium in in situ leaching. The South Texas and New Mexico ores contained up to 2.6 meqJg of reducing compounds which consume oxidants in the leading operation. Leaching rates did not increase linearly with the oxidation potential of the oxidants. A mild oxidant can be used to maximize uranium oxidation selectively and oxidant efficiency. 02 can oxidize most of the uranium mineral with an adequate rate and high oxidant efficiency.

Jan 1, 1990

By Teixeira

An experimental investigation on the kinetics of oxidation of As(III) with H202 in synthetic effluent solutions followed by precipitation of Fe/As (V) compounds was carried out. The variables investigated were: As concentration (200 -3000 mg/l) , oxidation pH (2.0 -11.0), oxidation temperature (25 -800C) , H202 stoichiometric excess (50% -100%), precipitation pH (5.0 -7.0), precipitation agent (Fe2+ -Fe3+). Fixed conditions were, Fe/As molar ratio (6:1) and stirring speed (560 rpm). The results were empirically modelled. The precipitates obtained were amorphous. The precipitates were checked upon their environmental stability according to the United States Environmental Protection Agency (U.S.E.P.A.) Toxicity Test, and were considered to be adequate for deposition in impermeable waste dumps. The combined Fe/H202 detoxification process, in selected conditions, was able to reduce the As contents of effluents containing 1600 mg/l As to 0.1 mg/l, in about 2 1/2 hours of total processing time.

Jan 1, 1990

This chapter contains the edited transcript of the "Gold Heap Leach Information Exchange" session that was held at the 1990 SME/AIME Annual Meeting in Salt Lake City, Utah. The exchange occurred on the afternoon of February 27, 1990. The session was intended to act as a forum for discussing some of the more prominent operating problems associated with heap leaching precious metals. The information exchange was very successful. The exchange consisted of several panelists introducing and discussing different topics, follow by a comment and question period. This transcript contains the panelists' presentations as well as comments and questions from the floor and the panel. Extraneous comments and remarks have been edited out. Some wording has been changed for clarity, but the transcript is basically an accurate account of what was said. At the end of the transcript are two papers submitted as part of the panel discussion

Jan 1, 1990

By J. Kazakoff

"The success of gold recovery at the Jolu gold mill depends on many variables. The most important ones are the people, the ore body, plant design parameters, equipment selection and cost control. This paper will briefly hiqhlight the above, the main focus, however will be on the gravity gold circuit.The gravity circuit requires judicious operator attention in order to operate properly. In return the circuit gives immediate visual results for mill peopleIntroductionThe development of the Jolu property to the production stage was carried out quickly, efficiently and economically. The property became a gold producer ahead of schedule and under budget.The Jolu property is a joint venture between International Mahogany Corp., a 70% partner, and Corona Corporation, a 30% partner. Corona Corporation operates the Jolu Gold Mine, located 140 kilometers north of LaRonge and 520 kilometers north of Saskatoon."

Jan 1, 1990

By Jaffrey Y. Foley

Placer gold and platinum-group metals (PGM) In the Slate Creek area, northern Chistochina Mining District, are derived from silicified and carbonate-altered, Cretaceous-Tertiary (?) dikes and related mafic and ultramafic rocks. Gold In the placer deposits is also derived from Tertiary conglomerate and altered Jurassic-Cretaceous argilllte. The argilllte and Igneous bedrock sources show a unique Ag-Au-Cu-Hg-PGM association that Is attributed to a combination of magmatic, hydrothermal, and supergene processes. The bedrock and placer deposits contain a variety of gold silver-lead-copper and PGM alloys. The observed geochemical, mineralogic, and alteration features are consistent with current geological models for turbidite-hosted gold deposits. No economic gold or PGM lodes were Identified, but several areas warranting more detailed investigation were Identified. Conventional geochemical sampling and analysis of small sample splits weighing between 10 and 30 grams were shown to be unreliable as a consistent means of identifying gold- and PGM-bearing bedrock. Pan concentration of pulverized rock samples was shown to be a more effective, but still Imperfect means of Identifying gold and PGM source rocks. Geochemical data and mineralogic examination indicate that gold and PGM in potential lode sources are very finely and erratically disseminated, are chemically combined with other elements, and may not be entirely free-milling or amenable to simple gravity concentration.

Jan 1, 1990

By Frank E. Chase

Geologic structures have been responsible for numerous underground accidents and fatalities, and are a constant-source of down time. During - longwall mining, ground control problems associated with geologic anomalies are aggravated by the abutment pressures which develop as the panel is retreated. Therefore, it is imperative that these structures be recognized and properly supported in head- and tailgates. Fractures, faults, clay veins, igneous dikes, and ancient stream channels (paleochannels) disrupt the lateral continuity of the mine roof and can cause falls in gateroads. Horsebacks and kettle bottoms are also hazardous because abutment pressures tend to "pop out' these structures into the gateroads. This Bureau of Mines investigation describes the physical characteristics associated with hazardous geologic structures, identifies the coal fields where-they have been observed, and, where possible, suggests support strategies and other mine plan modifications to help minimize their effect.

Jan 1, 1990

By C. W. Whitten

Iron ore deposits in south-central Missouri have emerged as a possible resource for the rare-earth elements. The Pea Ridge Iron Mine is one such deposit. Rare-earth minerals at the Pea Ridge Iron Mine are contained in breccia pipes consisting primarily of silicon oxides and feldspars. These pipes extend up through the magnetite ore body and appear to be alterations and replacement of earlier hematite. The mineralogy of these pipes is very complex and varied, which could complicate the concentration and extraction of the rare-earth minerals. This U.S. Bureau of Mines !eport represents a study by characterization of the mineral phases to assess the amenability and development of concentration and extraction techniques. Previous characterization of rare-earth minerals has been mainly by transmitted light microscopy. This method along with reflected light microscopy, scanning electron microscopy, and X-ray diffraction was used to identify and characterize the rare-earth and associated minerals. The minerals identified were the major ore minerals, magnetite and hematite; the rare-earth phosphates, monazite and xenotime; the rare-earth silicate, allanite; the minor associated minerals, cassiterite, pyrite, and apatite; and the gangue minerals, feldspar, quartz, and actinolite.

Jan 1, 1990

By I. Chatterjee

The application of microwaves has a demonstrated potential for the ultimate removal of water from fine coal. The principle of microwave drying of fine coal is based on the selective absorption of microwaves by water. Coal is a poor absorber of microwaves. As a result, water can be removed from fine coal by selectively heating water molecules. One of the difficult problems drilling microwave heating is the exact determination of temperature in the core of the materials. The electromagnetic energy absorption in coal/water mixtures during microwave drying is controlled by several factors including the dielectric properties of the constituents. In this paper the dielectric properties of various ranks of coal are presented as a function of frequency and moisture content. The measured dielectric data are incorporated into electromagnetic and thermal models of coal which predict the energy absorption and temperature distribution during microwave heating.

Jan 1, 1990

By Patrick J. Hannigan

The pile foundation designer typically performs a subsurface exploration program and static pile capacity calculations before selecting a pile foundation type, length, and capacity. During construction, a pile installation criterion must be established to meet these design requirements. This installation criterion usually consists of a minimum penetration resistance or blow count to confirm pile capacity and may also include a minimum embedment requirement. This text will focus on use of wave equation analysis and dynamic measurements to meet design requirements. BEFORE THE WAVE EQUATION Since the mid-1800s, over 450 dynamic formulas for pile driving control have proliferated. In their simplest form, these formulas relate hammer energy to the work of soil resistance, or simply: W ? h = R ? s (1) Where W = ram weight h = ram drop height or stroke R = pile capacity s = pile penetration per blow

Jan 1, 1990

The consideration of environmental constraints and issues is a fundamental component of all stages of planning, development, operation and decommissioning mining and quarrying projects. Provision needs to be made at all stages for the cost of environmental components since it is of fundamental importance that they be recognised as an integral component of any project. This paper presents an approach to environmental costing, suggested levels for budgeting, and the cost benefits.

Jan 1, 1990

By Large RR

Underlying the 15 million tonne, high grade Hellyer volcanogenic massive sulphide deposit of western Tasmania is an extensive, well developed, and well preserved stringer system. Pervasive alteration of the footwall mafic volcanics occurred as the hydrothermal system initiated. Mineralogical zoning exists within the footwall alteration pipe, with a central siliceous core giving way to zones of chlorite, chlorite-carbonate, sericite-chlorite, and finally sericite-quartz on the margins (stringer envelope zone). However, the alteration morphology and zonation is not symmetrical around the central siliceous core; eastward the alteration zones are steeply dipping and terminate abruptly under the massive sulphide, while westward they extend out under the ore body in a blanket fashion. Geologic evidence indicates that the pervasive alteration started with the development of sericite-quartz which was subsequently overprinted by chlorite and finally quartz-sericite as the hydrothermal system became focused towards the centre of the stringer system.

Jan 1, 1990

Two independent sets of observations from rifted con-tinental margins suggest a way to reach a quantitative under-standing of how the topography of rifted margins erodes. First, a prominent erosional escarpment, which demarcates an elevated, inland region of low relief from rugged, deeply-incised terrain on the seaward side, is the main feature of the geomorphology of many rifted continental margins. Second, apatite fission track ages from the southeast Australian and southwest Saudi Arabian margins scatter about constant Paleozoic ages over the higher elevations inland from the escarpment, but decrease systematically seaward of the escarpment to near-rifting ages approaching the coastlines. We have developed erosion models based on conservation of mass principles to explain these observations. These models seek to explain the "rejuvenation" of erosion at the time of rifting, initiation of the observed erosional escarpment, and its migration inland with time at a rate on the order of 1 km/10 yr. We find from the modeling that erosion at rift flanks and passive margins is fundamentally a non-linear pro-cess. The erosional development of passive margin topogra-phy has much is common with travelling wave solutions to non-linear diffusion-type problems, and to self-similar sto-chastic processes, such as diffusion-limited aggregation. We suggest that the fission track data record the thermal effects of erosional unroofing at rift flanks and passive continental margins. Models intended to explain the erosional develop-ment of continental margins must explain both the geomor-phology and the fission track observations as well.

Jan 1, 1990

By W. C. Hirt

Deposits of ferromanganese crust containing cobalt and nickel occur on the seafloor in the Pacific Ocean near the Hawaiian Islands and Johnston Atoll. This paper describes developmental flotation metallurgy to separate crust from its associated substrate gangue. Important variables in ferromanganese crust flotation include reagent type, aeration rate, conditioning time and agitation intensity, pH, temperature, water type, and feed size distribution. Flotation in seawater of minus 600 ~m (-28 mesh) material assaying 6.2% Mn, 0.2% Co, and 0.13% Ni with diesel fuel-crude tall oil-sulfonate collectors produces concentrates assaying 15% Mn, 0.6% Co, and 0.3% Ni with recoveries of 89-95% while removing 62% of the feed weight.

Jan 1, 1990

By Neil Hillhouse

The Porgera gold district, like many other large gold deposits, has a long history of awareness, but only in the last five years has a geologic understanding of the district permitted the discovery of economically attractive gold reserves. The following sequence of events highlights the various significant steps in the evolution of the discovery process. The history of the district goes back about 50 years, and for several decades it was known only for its placer gold. Gradually, as gold became a more interesting metal, more and more attention was centered on the district. The sequence of events does not overstate the problems caused by isolation and climate, but the reader can imagine the difficulties inherent in such an area.

Jan 1, 1990

Gold-rich porphyry copper deposits areimportant sources of gold in the circum-Pacific region: 26 major deposits contain >7000 tonnes of gold. The deposits occur in a variety of subduction-related settings, and may be underlain by crust that is undergoing either extension or compression and that is either oceanic or cratonic in character. The deposits are associated intimately with composite porphyry stocks, which commonly were emplaced into coeval andesitic volcanic piles. The stocks range in composition from low-K calc-alkaline through high-K calc-alkaline to potassic alkaline. Much of the copper and gold were introduced as components of K-silicate alteration, which may undergo partial overprinting by intermediate argillic assemblages. Advanced argillic alteration is widespread in the shallow parts of the systems whereas sericitic alteration at deeper levels tends to be restricted. Gold distribution generally follows that of copper, which is present mainly as chalcopyrite with or without bornite. The gold is in the native state and occluded by cr in close proximity to the copper-iron and/or iron sulphides. The magmas and metals necessary for the generation of gold-rich porphyry deposits were derived mainly from subcrustal sources, with the subducted slab believed to play a pivotal role.

Jan 1, 1990

The Southwest Pacific is a region of active volcanism and geothermal systems. Only in New Zealand have the geothermal systems been exploited for electricity generation and industrial processing. At present, approximately 280 MWe of geothermal electricity is generated in New Zealand. A considerable amount of further exploration work is required before the total geothermal potential of the region can be assessed and before the significance of these resources can be judged against other local energy sources.

Jan 1, 1990

By Black LP, Law SR, Oversby BS, Mackenzie DE, Wyborn D

Three volcanic sequences of different ages occur close together in the Burdekin Falls area, southeast of Charters Towers in northeastern Queensland. The oldest is equated with the Cambro-Ordovician Mt Windsor Volcanics, and consists mostly of strongly deformed, regionally metamorphosed rhyolitic lava and minor feldspathic to quartzose sandstone. This unit is overlain by folded but unmetamorphosed Upper Devonian-Lower Carboniferous volcanics (DCv) of the lowermost Drummond Basin sequence. The primary volcanic facies of (DCv) principally comprises andesitic and rhyolitic lavas, and dacitic ignimbrites. Similar volcanics are widespread in the lowest formations of the Drummond Basin sequence elsewhere, and dominate that sequence east of the Anakie Inlier. The youngest volcanic sequence is Late Carboniferous and composed of lower, more deformed, compositionally diverse ignimbrites, lavas and conglomerates, overlain by generally less deformed rhyolitic ignimbrite sheets. The upper part is equated with the Bulgonunna Volcanics which extend 90km south to the Mt Coolon area. The Burdekin Falls area contains an ignimbrite stratigraphy different from that in the south. However, one of the most voluminous ignimbrites (Locharwood Rhyolite) in the southern stratigraphy is also present in the north, enabling the two to be correlated.Each of the three volcanic sequences reflects proximity to eruptive sources. Both the volcanics at the base of the Drummond Basin sequence and the Late Carboniferous volcanics are largely the products of subaerial eruptions. The former were erupted from several intermediate-composition volcanoes, and the latter from multiple-vent silicic calderas. All three sequences are considered to be prospective for precious and/or base metal mineralisation. Polymetallic massive sulphide deposits occur in the Mt Windsor Volcanics farther west, and many epithermal gold prospects and mines are hosted by the volcanics at the base of the Drummond Basin, especially east of the Anakie Inlier. The Late Carboniferous volcanic sequence is deeply eroded, and co-magmatic high-level plutons are widely exposed; this sequence may therefore be more prospective for deeper-than-epithermal mineral deposits.

Jan 1, 1990

By Gibbons S. L, Ritchie I. M, Murr D. M

Fundamental studies on the transformations of iron oxides have been carried out and related to the solution conditions in the Becher process. The results show that a number of iron oxide interconversion reactions occur in the aeration reactor with the products depending on the pH, temperature and oxidation potential of the aeration liquor. It is concluded that the lack of process control in the aeration reactor of the Becher process significantly hinders the ability to predict and produce high quality single phase iron oxides of a consistent colour.

Jan 1, 1990

By M. J. Hannan

Considerable interest has arisen in developing analytical methods suitable for measuring resource commodity substitution patterns. some of this work has applied the Translog method to estimate actual elasticities of substitution. Recent examples incl.uae Privolos and Dunietz (1987), Kopp and Smith (1983), and Moroney and Trapani (1983). Another method, one which has received attention earlier in the work of Fisher and Pry (1970), is that of the logistic or diffusion function. We believe that the latter method has properties suitable for analyzing current problems of material substitution. The present study thus evaluates this method in its original logistic form as well as an extended version incorporating additional explanatory influences. The analysis is applied to copper/aluminum substitution and iron ore beneficiation. Substitution for copper by aluminum is examined in the building wire and cable, and magnet wire end-use markets. For iron ore, the substitution of pellets for sinter is considered for the U. S. market.

Jan 1, 1990