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By L G. B Wadley

The Australian gold industry has made large steps forward in the last few years. This progress has been driven by improvements in mining and processing technology, the high price of gold and by a favourable legislative, political and taxation environment. This paper concentrates on improvements in gold project development, process engineering and technology as seen by BHP Engineering, Perth, Australia. The paper describes technical aspects of successful gold project development including metallurgical test work, feasibility studies, choice of process flow sheet (gravity, heap leach, carbon in pulp (CIP), carbon in leach (CIL) or other routes). It sets out our views on plant design, plant construction, procurement and project management. A case study for a small plant recently completed in the Philippines is presented as a solution to the problems often encountered in treating quartz vein gold deposits.

Jan 1, 1990

By B. L. Razzaboni, P. Bolsaitis

"The formation of reactive oxygen species resulting from the interaction of silica dust particles with red blood cell membranes was investigated; particularly, the effect of surface hydroxyl (silanol) group concentration on the rate of formation of such reactive oxygen species was investigated. The rate of formation was measured indirectly through the effect of catalase, a hemoprotein peroxidase, on silica-induced hemolysis. It was found that the addition of exogenous catalase to erythrocytes markedly reduces the hemolysis caused by silica particles. Furthermore, the amount of catalase required for deactivation of silica per unit area of particle surface is lower for fumed silica particles and calcined crystalline particles than for uncalcined, crystalline silica, suggesting a correlation between the concentration of OH groups at the silica particle surface and its potential for generation of H2O 2• The addition of albumin, a copper chelator, also decreases hemolysis. These results suggest that the hemolysis caused by silica particles is at least partly related to the formation of H2O2 at the particle surface and its subsequent reaction with Cu+ ions. The relationship between the concentration of surface silanol groups on the silica surface and the amount of catalase required to decrease hemolysis may also provide a method for testing potential fibrogenicity of respirable dusts. IntroductionReactive hydroxyl groups on silica surfaces are known to be cytotoxic and are believed to play a major role in silicosis (1-9). It has been proposed that this cytotoxicity results from hydrogen bonding to cell membranes and a resulting increase in membrane fluidity and permeability (4). Surface hydroxyl groups on silica surfaces have also been shown to interact with carbonyl oxygens in cell membranes (1,5). An extensive study by Nolan et al. (6) of the relationship between the negative surface charge resulting from ionized silanol groups and the hemolytic activity of crystalline a-quartz (Min-U-Sil) has shown a positive correlation between hemolytic activity and the surface concentration of silanol groups. These authors demonstrated that the hydrogen bonding of polyvinyl-N-oxide (PVPNO) with silanol groups, as well as the bonding of metal cations to the ionized sm- groups, results in significant decreases in hemolytic activity. Furthermore, it has been found that the complete removal of surface hydroxyl groups from the surface of respirable silica particles nearly eliminates the hemolytic potential of silica (7), suggesting that hydroxyl groups might be involved in other cytotoxic processes associated with silica-induced lung injury. Reactive oxygen species have been .implicated in cellular damage caused by respirable silica particles. Evidence for the presence .of oxygen radical species (02, OH°, H2O2) generated by silica, especially on freshly formed surfaces, has been produced by various investigators. Kalbanev et al. (8) detected H2O 2 in aqueous suspensions of quartz. Electron spin resonance and spin trapping by Shi et al. (9) confirmed the presence of OH"" radicals in aqueous suspensions of quartz, and Gulumian and van Wyk (10) suggested that both glass and quartz produce hydroxyl radicals in the presence of H2O 2 • Gabor et al. (11) detected the presence of malondialdehydereactive lipid peroxides (i.e., lipid-0°) in cultures of macrophages and respirable silica particles using the thiobarbituric acid (TBA) reaction test. Will (12), however, reported that iron enhances the TBA value of peroxidized lipids, and Scheulen and Kappus (19) found that catalase augmented malondialdehyde formation, thereby increasing the TBA values."

Jan 1, 1990

By F. H. Mertens

The costs of an open-pit operation can be classified according to the following hierarchy : -overall cost of production (per ton of ore) -costs of basic operations and functions -costs of auxiliary operations -costs of machines and equipment -maintenance costs. Production cost is a measure of the open-pit mine performance and should be the final target of the management control. It is also a measure of the share of the mine in the processing stages.

Jan 1, 1990

By Moxon N. T

A series of low shock energy water resistant emlulsion based explosives have been developed by combining inert materials, such as Perlite P500, into the formulation. The material handling, water resistance and explosive properties of these mixtures were determined as a function of inert additive type, density, charge diameter and emulsion base. Of the emulsion bases tested Emulite produced the best and most stable low density mixtures ranging in density from 0.8 to 1.35 g/cm3 producing velocity of detonations (unconfined) ranging from 3000 to 5500 nits. The mixtures could be detonated successfully at these densities at diameters as low as 25mm. Low shock mixtures formed by combining Emulite with Perlite P500 were successfully trailed at the Cadjebut zinc mine in Western Australia. The performance of the explosive, at three densities, was monitored using both continuous and point to point VOD techniques. The fragmentation produced by the blasts were compared by photographic analysis. During this trial the low shock emulsion mixtures were shown to be as effective as the currently used explosives (packaged emulsion) at a significantly reduced cost.

Jan 1, 1990

By John McEwen, Ian R. Jonasson, David H. Watkinson

"Mine Gallen is a zinc-rich pyritic volcanogenic massive sulphide deposit that occurs in a fault-bounded block of intermediate volcanic rocks. The block is completely surrounded at the present erosion level by the eastern part of the Lac Dufault granodiorite. The volcanic succession includes a massive feldspar porphyry that is probably a subvolcanic intrusion, an andesitic flow unit and lapilli tuffs. The latter are variably sericitized and pyritic, especially in the vicinity of the massive sulphide into which they grade.The ore body is predominantly pyritewith local sphalerite contents as high as 20%; minor chalcopyrite and trace galena are disseminated, but are found mainly along late cleavage. Most ore is a breccia of massive to banded pyrite-sphalerite, veined by massive and complexly banded sulphides. These structures formed by repeated blocky jointing, cracking, sealing, healing and annealing as hydrothermal fluid repeatedly passed through a developing sulphide mound. The deposit is interpreted to have grown on the seafloor in a manner similar to active mounds in the Galapagos rift.RESUME La Mine Gallen exploite un gisement de sulfures massifs volcan géniques comprenant essentiellement de la pyrite riche en zinc. Ce gisement se trouve a /'intérieur d’un bloc de roches volcaniques de caractère dacitique a andésitique, limite par failles et entoure de tout cote par la granodiorite du Lac Dufault. La séquence volcanique comprend des coulées andésitiques et des tufs à lapilli ainsi qu'un porphyre feldspathique massif sub-volcanique. Les tufs sont sericitises et pyritises, tout particulièrement au voisinage des sulfures massifs."

Jan 1, 1990

By R. W. Lawrence, J. B. Austin, P. B. Marchant, J. T. Chapman

"Biohydrometallurgy is the use of microbiological reactions to assist in the extraction of metals. Bioleaching offers an innovative alternative for the treatment of refractory gold-bearing sulphides (1). One particular cost advantage of bioleaching is the potential to enhance gold extraction after only partial sulphide oxidation. The apparent selective sulphide oxidation is more prevalent where the refractory gold is associated with arsenic and antimony (2). Oxidation of the pyrite minerals and arsenopyrite at different oxidation rates can result in high gold extractions at relatively low levels of sulphide oxidation due to preferential, or selective, oxidation of the arsenic mineral. Arsenic extraction rates in a bioleach process typically exceed the iron extraction rate. Therefore, in concentrates in which the precious metals are principally associated with arsenic minerals, liberation of the precious metals may be possible with high recoveries and less than complete sulphide oxidation. The capital and operating cost advantages of partial sulphide oxidation are inherently obvious and are briefly illustrated herein.Ultra fine milling (UFM) is another alternative for enhancing gold extraction from refractory sulphides. Some refractory gold is simply particle size sensitive and UFM can improve gold extraction without the need for costly sulphide oxidation (3). Fine grinding technology for enhanced gold recovery developed by Metprotech, South Africa, is currently producing 2 - 4 micron ground product using a single pass, stirred ball mill. Proper application engineering has ensured that plug flow occurs through the mill. Plug flow from the feed inlet at the bottom of the reactor ensures that short circuiting of feed does not occur and as a result, the mill product does not require classification.A combination of UFM as a pretreatment for bioleaching could provide a mechanism for enhanced selective sulphide biooxidation and/or increased overall gold extraction following biooxidation due to improved particle liberation ( 4). The effect of UFM on biooxidation costs will be discussed. Only sulphide concentrates are considered herein for application of UFM in combination with biooxidation."

Jan 1, 1990

By B. K. Mishra

The motion of the charge inside a grinding mill is of considerable practical importance. The dynamics of grinding mills have been the subject of study by a number of workers because it can accurately predict: i) the power drawn by the mill, ii) the distribution of forces inside the mill, and hence the wear rate of balls as well as the liners, and iii) mass transport of milled product through the porous ball charge. Some of the earlier analyses of the motion of a charge of particulate material in a tumbling mill were reported by White (1904), Davis (1919), and Dyer (1945) and have been reviewed by Rose and Sullivan (1958). In these works, frictional force at the wall of the mill and between the colliding balls, and the interaction of different ball trajectories, was not considered. Moreover, it was assumed that the profile of the tumbling charge is independent of the degree of filling, which is generally not true. However, all this work led to the identification of so-called "equilibrium surface" which is the plane that separates the rotating charge into two regions. The inner region is static; here there is no motion relative to the mill shell. The other region is a shear region where either the balls flow down the surface of the charge (cascading motion), or are projected out of the surface and follow approximately parabolic paths (cataracting motion).

Jan 1, 1990

By Tim Q. Haldane

The ability to efficiently process lowgrade ores has allowed the Gold Fields Mesquite Mine in Imperial County, CA to expand from a 2.1 Mt/a (2.3 million stpy) rate in 1986 to its present 7.3 Mt/ a (8 million stpy) processing rate. Increased tonnage demands led to the 1989 construction and startup of a dump leach pad to supplement the existing heap leach operation. This resulted in an excellent opportunity to compare the two processes at the same operation. Additional operating costs associated with the crushed ore heaps are justified through enhanced recoveries, even at very low ore grades. Gold Fields' Mesquite Mine is a gold heap leach facility located about 55 km (35 miles) east of Brawley in southeastern California. Five open-pit mines will be developed over the projected life of the property, covering a total area extending to a maximum of 5.5 km (3.4 miles) to the east and west, and 2.4 kin (1.5 miles) to the north and south. Mesquite will process 7.3 Mt (8 million st) of ore and produce more than 6.2 t (200 000 oz) of gold in 1990.

Jan 1, 1990

By J. J. Kellar

The near-infrared (NIR) (12,000-4,000 cm-1) region of the electromagnetic spectrum, between the mid-infrared and visible, has often been viewed by spectroscopists to be of limited utility. This is unfortunate, and recently the use of the NIR has increased greatly, primarily for the quantitative analysis of food and agricultural products. However, many other areas of application of NIR spectroscopy remain unexamined. In this paper a novel use of NIR in the area of flotation chemistry is demonstrated. Specifically, it is shown that NIR/Internal Reflection Spectroscopy (IRS) can be used to quantify collector adsorption reactions in-situ.

Jan 1, 1990

By George D. Raitt

Anyone who has spent any time in and around the drilling and blasting profession knows that probably the most critical part is the drilling portion. A blasthole is nothing more than a cylindrical vehicle designed and strategically situated to hold and contain an explosive charge so that it can be detonated in the most efficient and optimum manner possible. It matters very little if the latest “State-of-the-Art” explosive or detonation system Is employed if the hole is poorly placed; i.e. excessive burden and spacing, sized incorrectly for desired results, insufficient in depth etc.. This is not to mention that the drilling phase is the most expensive, requiring sizeable initial outlays and upkeep. It’s also true that improper drilling can cause costs to skyrocket throughout the remainder of the work cycles such as excavating and hauling, crushing, screening and so on.

Jan 1, 1990

By F. Alsobrook

Industrial minerals are receiving increased attention by metals, coal and other companies seeking to diversify and stabilize earnings. Each industrial mineral has a unique set (and sub-sets) of business dynamics, however, and the diversity can present a bewildering maze to the corporate planner. Shrugging off this complexity and relying on serendipity for entry opportunities often results in unsuitable acquisitions. An effective alternative used in exploration can also be applied to strategic planning. By providing focus and direction, this flexible methodology can prevent wasting corporate resources on random pursuits and result in a quicker, more satisfactory achievement of diversification goals.

Jan 1, 1990

By Myers I. A, Peters S. G, Bultitude R. J, Dowling K

Gold-quartz and antimony-gold-quartz veins in the Hodgkinson Province are hosted by subgreenschist to greenschist facies metasediments and show no spatial association with granitic rocks. They commonly parallel axial plane foliations or occur in brittle to brittle-ductile shear zones. Detailed mapping in the Hodgkinson goldfield indicates that vein systems are isolated in distinct structural and lithologic domains by post-mineralization faulting. Gold-quartz and antimony-gold-quartz veins have distinctive mesoscopic textures characteristic of the mesothermal vein environment. Some of the antimony-gold-quartz veins are located on domain boundaries which truncate the gold mineralization. In. some areas, tin and tungsten-tin mineralization which are spatially related to Late Palaeozoic granitoids appear to postdate the gold-quartz and antimony-gold-quartz mineralization.Oxygen and hydrogen isotopic studies of vein and alteration assemblages associated with these diverse ores provide constraints on fluid sources and have implications for the origin of mesothermal gold mineralization. The available isotopic data are consistent with a dominantly magmatic source for tin and tungsten-tin mineralization although there is evidence of a late-stage meteoric component in some tin-mineralizing systems. Although a distal magmatic contribution cannot be entirely discounted, the gold-quartz and antimony-gold-quartz veins were probably deposited from deeply

Jan 1, 1990

By Thomas A. Davidson

The Bureau of Mines Helium Field Operations has developed a method for determining the helium-3 CHe) content of natural gas and mixtures eontaining 0.5% to 100% helium. The helium is preconcentrated by passing samples through anhydrone, a liquid-nitrogen-cooled chareoal trap, and a titanium absorption trap. The mass spectrometer used to analyze the samples is tuned to 3He at mle ::=; 3.016. Hydrogen deuteride (HD+) interference is minimized by the titanium absorption trap and high instrument resolution. Sample measurements are compared with identically made measurements of a gravimetrically prepared primary standard. The method has a limit of detection of 0.15 ppb with a relative deviation of 13% below the 1~ppb level. The relative deviation is less than 7% for gases eontaining over 100 ppb 3He. The helium isotope ratios of natural gases from the Bureau's Tuck-Trigg Dome Red Cave, the Bush Dome Red Cave, and the Bush Dome Brown Dolomite Formations are distinguishable from one another and from the isotope ratio of crude helium produced from the Panhandle-Hugoton Gasfield.

Jan 1, 1990

By G. R. Cope, J. S. Getsinger, K. D. Lund, T. Neale

"Mineral exploration in the Sicker Group, a belt of Paleozoic volcano-sedimentary rocks on Vancouver Island, has traditionally centred on auriferous polymetallic volcanogenic massive sulphide deposits such as those currently mined by Westmin Resources Ltd. near Buttle Lake. Recently, however, the focus of exploration in the Sicker Group has shifted toward targets of structurally controlled gold concentrations, with notable success. Major north and northwesterly-trending structural features such as the Cowichan-Horne Lake break (one of several regional high-angle thrust fault s active throughout a long period of geological time) and related fault systems have contributed to localization of gold mineralization.Using the extensive information database compiled by MPH Consulting Limited during numerous exploration projects in the Sicker Group, two cross sections through areas with significant gold occurrences southeast of Port Alberni are presented. The cross sections combine geological, geochemical and geophysical data in an attempt to emphasize the relationship between structural trends and gold mineralization. Examples from specific properties, including gold discoveries along the Mineral Creek fault zone, are used to illustrate this relationship."

Jan 1, 1990

By R. B. Stein

"Countercurrent decantation circuits(CCD) are often employed in hydrometallurgy to effect solids-liquid separation in combination with a barren solution wash to reduce losses of valuable solution component(s) from the tails. Bechtel Corporation uses its BEMSIM flowsheet-modelling PC computer program to simulate a CCD circuit where the ""dirty"" wash solution contains significant amounts of soluble components. An algorithm successfully models this condition and is simplified to a single expression when the wash solution is a ""clean"" solution containing no solubles. The CCD calculation module is compared to operating data from uranium and nickel-cobalt CCD circuits.IntroductionHydrometallurgical process schemes have often relied on countercurrent washing methods to reduce soluble losses of valuable product in the tails. Commonly used equipment to effect this operation is a CCD circuit of N thickeners in series, where a slurry is fed to thickener I and a wash solution to thickener N; clear pregnant solution overflows thickener I and washed tails exit as underflow from thickener N. CCD circuits of this type are typically employed when the solids tend to slime heavily and where a filter is not economic.A typical CCD circuit usually employs from two to five thickeners and can employ either a ""clean"" washing solution of, say, pure water or else the hydrometallurgical circuit may generate a ""dirty"" barren solution containing an appreciable amount of soluble component which may be advantageously returned to the process as CCD wash solution. Various authors have treated the case for clean washing solutions (Svarkovsky 1977, Merritt 1970). For the case of dirty wash solutions, an algorithm has been developed to enable efficient modelling by the BEMSIM computer program, because the need for an accurate method to calculate soluble losses is required when performing an economic trade-off analysis of the value of product lost in the tails as a function of the number of thickeners."

Jan 1, 1990

By Alain Simard, Sylvain Lacroix, Louis-Martin Dubé, Pierre Pilote

"The Harricana-Turgeon belt (HTB) is a poorly known volcano sedimentary belt in the NW part of the Abitibi Sub-province; it includes the Matagami, Joutel, Brouillan and Casa-Berardi mining districts. The HTB is dominated by volcanic rocks, which covers 65% of its surface area, followed by sedimentary (18%) and plutonic (17%) rocks. It is also transected by numerous deformation zones located either at the contacts of volcano-sedimentary units and granitoid bodies or cross-cutting them. A preliminary geological synthesis shows that mineral deposits are associated with certain regional geologic elements.The volcano-sedimentary units are grouped here into twelve band-shaped lithotectonic domains, most of which extend for more than 150 km E-Win the HTB. Each domain is defined by lithologies and facies associations, and gradiometric and electromagnetic signatures.Eight domains are composed of basaltic or basaltic to komatiitic associations, interlayered with thin pelagic sediments, representing sub-marine lava plains. Two domains are composed of basaltic to rhyolitic associations that are interpreted as volcanic arcs formed by one or several central volcanic complexes.The sedimentary rocks are grouped into two lithotectonic domains. Each is composed of rhythmic sequences of turbiditic sandstone- siltstone-shale, Algoma-type banded iron formations and conglomerates bearing plutonic and volcanic pebbles. These three facies come partly from mass flow at the bottom of a slope in a moderately deep marine environment. In each domain, a conglomerate sandstone- siltstone sequence, containing poly genetic pebbles of local provenance, is similar to Timiskaming-type alluvial deposits.The nineteen granitoids, found within the HTB and at its border, belong to numerous petrographic suites, and have been grouped into four structural families: pre-tectonic, pre- to early-tectonic, syn- to late-tectonic, and late- to post- tectonic. The pre- to early-tectonic plutons are presumed to be sub-volcanic and are generaly associated with the volcanism of central complexes.The HTB mineral resources consist essentially of polymetallic (Cu-Zn-Ag-Au) and gold (Au-Ag) deposits. The polymetallic deposits are located exclusively in the two lithotectonic domains composed of basaltic to rhyolitic associations (Matagami-Brouillan and Joutel Raymond). All gold deposits are associated with deformation zones superimposed on lithotectonic domain contacts and highlighted by graphitic units. Most of the deposits are hosted in the Casa-Berardi and Douay deformationzones, located at the contact of the Cartwright basaltic to komatiitic domain and the Taibi sedimentary domain"

Jan 1, 1990

By R. R. Klimpel

The grinding of coal-water slurries has received increasing industrial attention during the last decade. In particular, there is long-term interest in the use of pulverized coal-water slurries to replace oil in combustion equipment and the development of coal gasification/liquefaction processes which require coal-water slurries as feed. More specifically, the use of coal-water slurries in gasification requires grinding a high density slurry containing the smallest amount of water consistent with slurry pumping and spraying. As part of a fundamental engineering research support program aimed at the industrial implementation of dense coal-water slurry grinding, this author has published several papers on how specific rates of breakage vary as a function of slurry rheology, Klimpel (1982, 1982/83). These papers demonstrated that there is a consistent pattern of change in specific rates of breakage of coal in dense slurries with controlled variations in slurry rheology. By matching rheological data with laboratory grinding results, it was possible to identify directly slurry conditions that correspond to: (1) slowing down of breakage rates, (2) the occasional acceleration of breakage of some sizes, and (3) conditions where chemical additives will increase rates of breakage.

Jan 1, 1990

By R. L. Grayson

Productivity achievements in underground coal mining over the past ten years highlight the improvement of management practices as well as the adoption of new technology. Research findings and results from operational studies characterize the aspects of good management that translate into high productivity. In concert with these findings, the Mine Management Support System (MMSS) is being developed, under co-sponsorship of the U.S. Bureau of Mines and the West Virginia University Energy and Water Research Center, as a knowledge-based system to enhance more efficient management of underground coal mines. Concentrating on capturing the intricate knowledge needed to manage a mine effectively, MMSS will encompass information and rules on work scheduling, desired work practices, regulations impinging on operations and planning, responses to operating problems, and the labor-management work agreement.

Jan 1, 1990

By John J. Sammarco

The U.S. Bureau of Mines seeks to increase safety and efficiency in U.S. coal mines. One approach is to develop technology for automation of a continuous mining machine. Realization of an autonomous mining machine requires development of subsystems for machine intelligence, navigation-positioning, and computer control. This report focuses on investigation of one subsystem, an onboard heading system, which would be responsible for determining and controlling machine heading. The onboard heading system investigated is a multisensor system to determine machine heading, pitch, and roll. A directional gyroscope provides heading (yaw), fluxgate sensors provide a compass heading, and gravity-referenced clinometers give machine pitch and roll. The system utilizes a dedicated microcontroller networked to an external system of computers. Tram commands, supplied to the network from external computers, are executed by the onboard system. Sensor feedback is employed for closed-loop control of machine heading by controlling pivots and turns. The report discusses operating limitations and error sources of system sensors and presents test results of closed-loop control of machine heading. Results of tests with a mining machine are used to exhibit various sensor shortcomings and to evaluate control of pivots and turns.

Jan 1, 1990

By Arthur L. Holloway, James C. Mugford

"The Underground Research Laboratory (URL) is located in southeastern Manitoba, in the Lac du Bonnet granite batholith of the Canadian Shield. It was constructed by Atomic Energy of Canada Limited (AECL) to conduct geotechnical research for the Canadian Nuclear Fuel Waste Management Program, assessing the concept of permanent disposal of nuclear fuel waste deep in plutonic rock.One of the primary objectives of the research program at the URL is to develop a nondestructive rock mass characterization method that can be used during siting, design and construction of a used fu el waste disposal vault. An experimental program was established to assess radar reflection profiling as a technique for fracture characterization in granite. The highly resistive, homogeneous nature of the Lac du Bonnet granite is ideal for the propagation of electromagnetic energy at the radar range of frequencies and water-filled fracture zones act as excellent reflectors because of their contrasting electrical properties.Radar reflection profiling was undertaken to characterize a major fracture zone located between 5 m and 10 m below Room 211 on the 240 m level of the URL. The profiling was done at a frequency of 120 MHz, on a 1m grid laid out on the bare rock floor of the room. Reflectors identified in the analog data were correlated between the profile lines, digitized, and a three-dimensional surf ace for each recognizable reflector was constructed. These surf aces were then compared with data obtained from the examination of numerous cores from adjacent boreholes intersecting the fracture zone. A very good correlation was found between the major radar reflectors and the most intensely fractured regions of the zone. Modelling studies also showed that a series of prominent shallow radar reflectors were caused by a borehole drilled close to Room 211."

Jan 1, 1990