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Studies of electric pulse (EP) disintegration were conducted on ores of disseminated precious minerals, 'on platinum-bearing chromitites of the Konder Complex, Russia, on diamond-bearing impactites of the Popigai meteoritic crater, Russia, and on and diamond-bearing metamorphic rocks of Northern Kazakhstan. It was shown that EP disintegration ~s a technology that achieves ideal liberation of disseminated minerals, and is a new efficient method to study accessory minerals.

Jan 1, 1991

By Lucia Kuizon

In 1986 and 1987, at the request of the U.S. Forest Service, the U.S. Bureau of Mines studied the Diamond Peak area comprising 183,000 acres in the Challis and Targhee National Forests in order to evaluate its identified mineral resources. More than 3,000 mining claims were located in three mining districts between the years 1882 and 1986. Approximately 230 mining claims in and the 150 claims adjacent to the study area were current in 1986, when Bureau of Land Management mining records were researched for this study. A total of 1,270 samples were collected from these sites (30 were for alluvial placer). Results of the investigation help determine the suitability of the study area for inclusion into the National Wilderness Preservation System. Lead-, silver-, zinc-, copper-, and gold-bearing minerals occur as veins and replacement bodies in shear and fault zones in Precambrian and Paleozoic calcareous Sedimentary rocks that have been complexly folded and faulted. Total production from the three mining districts in the study area was more than 150,000 tons of ore between 1901 and 1982. Approximately 11,600 tons of subeconomic resources consisting of lead, silver, zinc and copper were identified within the area. Over 37,500 tons of lead and zinc subeconomic resources were identified just outside the area. In addition, lead-, silver-, and zinc-mineral resources were identified at 4 mines within 2 miles of the study area. Iron mineral resources were also identified just outside the area.

Jan 1, 1991

By Nicola Robjohns, Kenneth A. Grace, Jane Spooner

"The important volume end use sectors for the rare earth elements and yttrium continue to be in steelmaking, petroleum cracking catalysts and glass polishing. The market sectors which may provide future high volume demand, to replace the older sectors where demand has declined over the past decade, include magnets, automobile catalysts, ceramics and superconductors. Increases in production capacity in all major rare earth producing countries are expected to restrain large price increases for high purity rare earth oxides over the short term. A sharp increase in demand for yttrium in advanced ceramics and superconductors would lead to a shortage in separation capacity, however, and to a corresponding rise in prices for separated rare earths.IntroductionWhile visiting the Geology Department of the University of Toronto in 1981, Professor Lu from the Institute of Geochemistry of Academia Sinica at Gweiyang in China introduced one of his seminars with the observation that in China, rare earths are not rare at all.Indeed, while being rare in terms of abundance as measured by, say, the Clarke scale, the rare earth elements, like many other low abundance elements, are subject to geological, geochemical and mineralogical concentration.The rare earth elements comprise the fifteen inner transition elements of Group IIIB, Period 6, of the periodic table, from lanthanum to lutetium (the lanthanides), as set out in Table 1. The rare earths constitute a distinct group as they have extremely similar chemical characteristics due to the uniformity of their outer electron shells. The element yttrium is usually, by convention, included in the rare earth group as it occurs with the rare earths in nature and has properties very similar to them.The rare earths are divided into two subgroups, the ""light"" rare earths, made up of the first seven elements of the series, lanthanum to europium, and the ""heavy"" rare earths, comprising the remaining eight elements, gadolinium to lutetium, plus yttrium. These two subgroups are also referred to as the cerium subgroup and the yttrium subgroup, respectively. The subdivision is based on differences in the atomic radii resulting in somewhat different properties for the two subgroups."

Jan 1, 1991

The U.S. Bureau of Mines investigated CaF2-assisted H2SO4 leaching to extract Mn from domestic silicate manganese resources. A pyroxmangite ((Mn,Fe)Sio3) ore containing, in pct, 34 Mn, 23 Si, 3 Ca, and 1 Fe was leached at 90° C for 3 h in a solution containing, in g/L, 12 Mn, 140 H2SO4, 130 (NH4)2SO4, and 5 CaFz. Manganese extraction of 92 pct was achieved. Manganese of greater than 99 pct purity was prepared by electrolyzing the purified pregnant solution at a current density of 50 mA/cm2. The current efficiency was 65 pct.

Jan 1, 1991

By Craig M. Sams

Matching mill? drives to mill power draws is a relatively new practice with the introduction of variable speed drive arrangements. Semi-autogenous grinding (SAG) mills are the focus of this paper as ball and rod mill characteristics are easily charted as charge loading and speed change. In addition, a look at types of drives available in the market and mechanical ratings is outlined to match the specifics of each drive.

Jan 1, 1991

By K. Englehardt

J BERESFORD introduced the subject of the paper which is the use of polymeric slurries to support the sides of diaphragm wall and bored pile excavations during construction. In the opinion of the authors the use of a suitable polymeric fluid offers financial and technical advantages compared with traditional bentonite based slurries. Under quiescent conditions a support slurry must have the following properties. - sufficient viscosity to support the sides of the excavation, to prevent infiltration into soils and to hold loose soil particles in suspension. - when agitated it should thin quickly to assist pumping transfer and cleaning and allow free passage of the grab or drill. - viscosity should be low enough during concreting to facilitate placement but high enough to prevent contamination of the concrete.

Jan 1, 1991

By Gray N. B, Grimsey E. J

A steady state heat and mass balance simulation of the Western Mining Kalgoorlie Nickel Smelter (KNS) flowsheet was developed within the framework of the commercial software METSIM. The KNS simulation can achieve all plant setpoints through the adjustment of controlled process inputs, and provides a useful tool for the evaluation of the current flowsheet and potential flowsheet developments The simulation model and a number of applications are discussed in this paper.

Jan 1, 1991

By J. Howarth

Two electrochemical processing methodologies have been used to electrogenerate bromine-laden solutions for gold-leaching purposes. In the first process, a laboratory-scale cell in which the anode and cathode compartments were separated by a cation-exchange membrane was employed. The bromine produced by electrolysis of a 4% bromide solution was used to leach gold from a low-grade ore. The pregnant leach solution was then returned to the cell to recommence the cycle. High current efficiencies (90-93%) were maintained over six cycles. In the second process, an undivided hypochlorite generating cell (Chloropac"') was used to generate bromine from a simulated leach solution. Electrolyses were performed on a pilot-scale (100-150 gallons) with solutions containing different levels of bromide ion. The current efficiencies were also high (80-90%) and unaffected by the bromide concentration (over the range 2.5-5%) provided the electrolysis was run to low conversion « 15%). The Chloropac module was capable of delivering 0.6 kg bromine per hour at a power cost of $0.09 per kg. Using these figures, a detailed economic assessment for a 1000 metric tonnes (MT) per day gold ore processing plant was made. Electrolytic regeneration of bromine in a gold leach/recovery circuit dramatically improves the process economics over cyanidation.

Jan 1, 1991

By w. w. Fraser

"In late 1985, Hudson Bay Mining and Smelting Co., Limited announced the Namew Mine/Mill project. Environmental baseline monitoring and planning began in early 1985 while a major drilling program was under way to delineate the ore deposit. This paper overviews the environmental assessment work conducted for the mine/mill operation, and outlines the tailings and water management practices.Planned environmental works and approach were affected in late 1988 when a massive water problem was encountered in the mine. The requirement to depressurize the rock surrounding the underground workings led to the need to develop, on short notice, an environmentally-acceptable procedure to dispose of a large volume of slightly-saline water.Biological toxicity tests performed on the depressurized effluent proved the effluent to be non-toxic and thus allowed resolution of the disposal problem. This resolution includes the conversion of a large water body from native fish species to a rainbow trout fishery."

Jan 1, 1991

By B. R. T. Simoneit

The conversion of organic matter to petroleum by hydrothermal activity is an easy process, occurring in nature in many types of environments. Geologically immature organic matter of marine sediments is being altered by this process in Guaymas Basin (Gulf of California), Escanaba Trough and Middle Valley (northeast Pacific), Bransfield Strait (Antarctica), and Atlantis 11 and Kebrit Deeps (Red Sea). Contemporary organic detritus and viable microorganisms are also converted in part to petroleum-like products by the same process when present to become entrained, as for example on the East Pacific Rise at 13o N and 21o N and on the mid-Atlantic Ridge at 26oN. The hydrocarbon products (methane to asphalt) generated in all these areas have been elucidated in terms of composition, organic matter sources, and analogy to reservoir petroleum. This petroleum represents a major input of carbon to the primary chemosynthetic productivity of hydrothermal vent systems and may be important to interactions with metals in hydrothermal ore formation.

Jan 1, 1991

By Seymour K. M, Sampson D. B, Walker I. W

Ashton Mining Limited is the operator of two wholly-owned gold mine/mill complexes at Laverton and Leonora. In addition, Ashton owns 43% of the Bardoc Joint Venture mine/mill complex, which is operated by Aberfoyle Pty Limited. All three of these operations are located in the Eastern Goldfields region of Western Australia (Figure 1). At Laverton, milling capacity is in the order of 1 million tonnes per year in 3 mills (Duketon 200,000 tpa, Cork Tree Well 650,000 tpa and Craiggiemore 150,000 tpa). These mills service a distance of 80 km, from Baneygo in the north to Craiggiemore in the south. Mineral tenements cover a 150 km long stretch of a series of sub-parallel mineralised structures. At Leonora, the Harbour Lights mill is designed to treat 750,000 tpa of sulphide ore, and has treated oxide ores at an annualised rate of over 1 million tonnes/year. The mill is supported by several tenement blocks that lie within a 50 km trucking radius of the mill. The most important of these is the Mertondale tenement block, which covers approximately 25km of the Mertondale Shear Zone.

Jan 1, 1991

By A. J. Neale, B. C. Flintoff

"In most mineral processing operations the term audit is usually reserved for the exercise of checking financial records and/ or safety practices. While these activities are time consuming, no one disputes their necessity or value. If we subject these areas to such careful scrutiny, why is it that we don't normally apply the same principles to critically examine process operation. After all, the operating efficiency of the plant impacts directly on the measures of profitability.A mineral processing plant is a complex system that has a number of distinct, but mutually dependent elements: process equipment, instrumentation, operating policies, maintenance policies, control strategies and people. To ensure maximum economic performance, in the dynamic environment that characterizes a concentrator, requires a periodic review of each of these areas. However, to be useful, the study must be based on sound metallurgical principles and be conducted in a highly focused manner. Experience teaches us that the exercise is very revealing and potentially very rewarding.This paper will discuss the process audit process and illustrate its potential value through illustration taken from plant studies.IntroductionThe last twenty years have seen tremendous technological and organizational changes sweep the minerals industry. Process control systems, on-stream analyzers, and gold recovery techniques barely conceived twenty years ago are now incorporated in virtually all new installations in an effort to maximize operating efficiencies. In conjunction with these developments, changes in the way plants are managed, down-sizing of technical staff, reduction in the size of operating crews, and the flattening out of the management structure have significantly reduced operating costs. As a result, plants are making more efficient use of our natural resources, minimizing the costs of production, and in turn maximizing operating profits. Or are they?"

Jan 1, 1991

By J. E. Hamak

This publication contains analyses and related source data for 144 natural gas samples from 19 States. Of the total samples, 139 were collected during calendar year 1990. The remainder were collected earlier, but releases granting permission to publish were not received until 1990. All samples were obtained and analyzed as part of the U.S. Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free-market economies. This survey has been conducted since 1917. The analyses were made by mass spectrometer and chromatograph.

Jan 1, 1991

By Pietrobon M. C, Ralston J, Smart St C R

In an on-going study of the chemistry of base metal sulphide flotation, the effect of the inclusion of cyanide in the reagents suite has been studied, with special reference to ore from Pasminco Mining's Elura mine. Cyanide has been variously described as an iron sulphide depressant, a preventor of sphalerite activation and as an activator of galena. In the case described here, the cyanide appeared to act as an enhancer of the galena flotation performance, raising the lead recoveries by 25 per cent but leaving the sphalerite and pyrite responses unaffected. The lead rougher flotation performance with and without cyanide was investigated over a wide range of redox potentials (0 mV to 400 mV SHE). In all cases, the inclusion of the cyanide brought about an increase in the galena recovery and was responsible for a faster rate of galena flotation during the initial stages of the beneficiation. A surface characterisation study (XPS) of the lead flotation stage, with and without cyanide, indicated that the reagent interacted specifically with the galena and pyrite minerals. It was possible to correlate the surface absorption of the cyanide on the lead and iron sulphides with improvements to the flotation performance using the combination of surface spectroscopy and laboratory flotation Testwork.

Jan 1, 1991

By Ann M. Hagni

Microscopic and sub-microscopic gold commonly occurs in the sulfides pyrite (FeS2) and arsenopyrite (FeAsS). To recover refractory gold from pyrite and arsenopyrite, these sulfides are roasted to create porosity and permeability prior to cyanide leaching. A new technique of adding Ca(OH)2 and roasting. lime roasting. is being tested for retention of contaminant sulfur and arsenic and effectiveness of gold extraction. The lime roasting of pyrite at 500°C contains anhydrite (CaS04). oldhamite (CaS). calcium sulfite (CaS03). hematite (Fe2O:J), magnetite (Fe304). and minor amounts of pyrrhotite (Fe1.xS) and pyrite. At 600°C. 650°C and 700°C. the main constituents are anhydrite. oldhamite. and hematite. At 750°C. 800°C. and 850°C. anhydrite and hematite are the predominant phases with minor oldhamite. The roasted arsenopyrite at 450°C contains arsenic sulfides. calcium sulfite. hematite. and minor oldhamite. magnetite. and pyrrhotite. At 650°C. 700°C, 750°C. and 800°C, anhydrite, oldhamite. arsenic sulfides, and hematite are present. At 850°C. the same minerals are present with only minor oldhamite. The textures indicate excellent porosity and permeability at high temperatures. At lower temperatures, rims of low porosity and permeability surround many of the pyrite and arsenopyrite particles, and the complete oxidation process from pyrite to pyrrhotite to magnetite to hematite can be observed in individual particles. Additional process mineralogy techniques employed in this study are electron spectroscopy for chemical analysis (ESCA) and cathodoluminescence microscopy (CIM) in the determination of the calcium-sulfur-oxygen phases. Automated scanning electron microscopy-energy dispersive spectroscopy was utilized to analyze particles for gold content. Reflected light microscopy (RIM) revealed arsenopyrite and pyrite encapsulated in quartz particles of the gold-bearing concentrate, gold roast calcine, and cyanide leach residue.

Jan 1, 1991

By Stefan K. Schwank

The paper describes the two foundation techniques - mini piles and postgrouted bored piles. The mini pile system is presented with its design and installation parameters, especially the drilling technique. Two case histories demonstrate the application under extremely limited space and traffic conditions and the required modifications of the equipment. After the description of the postgrouted bored piles and its grouting technique, the paper gives a comparison of postgrouted piles and standard piles on a large basic test in Germany. The Brooklyn Queen's Expressway, N.Y., case history shows the application of this technique after redesign of the original proposal. 1. General Increasing requirements to improve existing foundations to carry additional loads and to increase the bearing capacity of bored piles leads to two new piling techniques: the mini-pile and the post grouted bored pile.

Jan 1, 1991

By R. H. Crist

Reactive components of algal cell walls include uronic and alginic acids: In addition, many marine species have half ester sulfate groups which function as fixed anions. Associated metals vary with the media, eg., Ca and Mg in fresh water (FV) and Na, Ca, Mg in seawater. . These metals readily exchange with aqueous phase protons or metal cations. A plot of the total amount of metal cations displaced by protons vs .. pH shows one inflection at pH 4 for FV algae and' in addition a second inflection at pH 2, 3 for marine algae. The first inflection is interpreted as. Indicating the cations associated with carboxyl groups ,and the ,second with half ester ?Sulfate groups. The exchange capacities of various aigal ,species vary widely. When FV algae is placed in a Pb2+ solution,- the amount of Pb2"' deposited on the algae is. Equivalent to the. Total Ca2?, Mg2, and H+ displaced? thereby confirming the ion exchange mechanism. Ion exchange equilibrium constants are reported for the displacement of ca2+ from Vaucheria. With Mg2+, sr2+, Cd2+, Pb2+_ and Na+ as well as the reverse reactions. Cd2+ can .be removed partially from algae by precipitating it as CdS or Cd(OH) 2 Pb2+ and Cu2+ are also partially removed as the hydroxides. Rates of reaction for various alkali hydroxides decrease with increasing .unhydrated cation radius. It is concluded that theory is useful in predicting viable applications for algae in pollution abatement.

Jan 1, 1991

By Ashley P, Neale T

Alluvial gold was discovered on Sudest Island in 1888, and by 1893, an official production of 10 000 oz had been won by expatriate miners from shallow alluvial and colluvial workings. Hardrock sources were located and while one was developed at Mt Adelaide, production is unknown. Sudest Island comprises mostly phyllites and lesser coarse grained rocks which are cut by metamorphic quartz veins and basic (locally shoshonitic) intrusives. Sheared and altered basalts and serpent- inites represent are believed to be elements of an ophiolitic suite inferred to be associated with metamorphic core complex development and thus similar to tectonic environments on Misima and the D'Entrec- asteaux Islands. No epithermal-style quartz suggestive of a target similar to that on Misima Island has been identified on Sudest. A hardrock source for the alluvial and colluvial gold is interpreted to be metamorphic quartz veins similar to those in the Bendigo- Ballarat Zone of central Victoria, possibly remobilising gold derived from the meta- sedimentary and meta-igneous rock pile. The present focus is on development of a small scale alluvial gold mining operation in conjunction with exploration for hardrock targets. This latter programme remains at a reconnaissance stage.

Jan 1, 1991

By Suresh K. Bhatt

This U.S. Bureau of Mines report reviews major developments in continuous haulage technology for underground coal mines. Haulage systems, both in use and under development, were investigated through a comprehensive literature search and visits to mines and manufacturers. The systems include flexible conveyor train, mobile conveyor, monorail bridge conveyor, multiple-unit continuous haulage, extensible, and belt turning systems. Strengths and weaknesses of the systems are assessed in light of their operating under remote control and their application to the computer-assisted continuous mining machine research being conducted by the Bureau. Through mining scenarios, candidate haulage systems are conceptualized to be consistent with the capabilities of the mining machine.

Jan 1, 1991

By Lu Peiyan

A computation model of soil-pile (wall) interaction under lateral loading is presented in this paper. The model has been applied to some engineering projects, and the comparison between computation result and measured result shows good agreement, so the model is proved to be correct and practical.

Jan 1, 1991