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By D Brown, Z Tabor

Projects must be flexible to account for the rapid development of new technologies and changing stakeholder expectations. Coupled with calls for bleeding-edge solutions, customers, shareholders, and regulators demand robust, safe products and systems-of-systems. Developing and integrating these solutions is becoming increasingly complex and maintaining the flexibility required to ‘pivot’ to effective solutions can be a serious challenge. The necessary flexibility is fundamental to the Agile ethos, and this family of methodologies therefore offers a potential solution to this challenge (Beedle et al, 2001). These have traditionally been delivered with systems engineering applied through a Waterfall methodology. Agile Systems Engineering combines both approaches and presents a means to achieve these goals without compromising flexibility, quality or safety. A robust methodology for the application of Agile Systems Engineering is required to enhance practical outcomes and reduce risk for real-world mining projects.

Sep 1, 2024

By B Taylor, S Evans

Bulk explosive technology for underground mining has not seen any significant technological advances since the widespread transition from ammonium nitrate fuel oil (ANFO) to ammonium nitrate emulsions (ANE) commencing in the 1980s. The in-hole energy profile that conventional ANE systems deliver is limited by the physics of chemical gassing and simple control systems. This compromises the range, precision, and accuracy of energy delivery into the blasthole, and in some cases limits the length of charge that can be delivered. Orica’s 4D™ bulk system removes many of these constraints, enabling better blasting performance across all underground mining methods. This paper reviews work completed at three mining operations across Australia, the United States, and Chile with a focus on how this system can improve mining operations and deliver sustained commercial and productivity benefits into the future. These benefits include improved ore recovery, reduced dilution from waste rock, and reduced overall explosives consumption. This paper also reviews how this new technology can be applied for planning future mining operations.

Sep 1, 2024

By T Zhao, K Wang, Z Zhang

Tailings pond safety monitoring is vital for preventing dam failures and ensuring environmental safety. Unmanned Aerial Vehicles (UAVs) can enhance tailings pond monitoring with flexible operational cycles and the ability to collect remote sensing data from inaccessible areas. While many mining operations have adopted UAVs for tailings pond management, their full potential in data acquisition and subsequent analytical processing remains largely untapped. This paper explores various case studies where UAVs have been utilised for monitoring key aspects of tailings ponds such as beach line indicators, dam displacement and erosion, slurry discharge processes, and tailings pond capacity. We also present examples where data derived from UAVs have been instrumental in slope stability analysis, seepage modelling, Tailings Dam Breach Analysis (TDBA), and risk prediction. By integrating UAV technology with traditional ground-based sensor techniques, this approach significantly enhances the precision and reliability of hazard prevention and management in tailings pond operations.

Sep 1, 2024

By H Utama, R Heryadi

PT Indo Muro Kencana (PT IMK) is a surface gold and silver mine located in Mt. Muro area, Central Kalimantan province, Indonesia. The mining operations of multiple open pits using combination of excavator and haul truck is operated. This operation is performed in two shifts in a day. The articulated dump truck (ADT) with capacity of 40 t and 60 t deliver ore to the mineral processing plant and discard waste material to the waste dump area. Overall, PT IMK’s mining operation department is consisting of two sections, namely mining operation section and drill and blast section. Firstly, mine operation section is responsible to manage loading, hauling, pit service (mine dewatering, earthwork, road maintenance) and mine operation engineering. Secondly, drill and blast section is in charge to manage drilling and blasting (blast engineering, blasting operation, explosive permit and magazine or explosive storage). Additionally, conventional blasting method (ore-waste blasting) with non-electric initiation system is used and sleep blasting is undertaken as bulk explosive is buried for maximum two days. The first purpose of this paper is to elucidate about role of mining engineer in mining operation department (mining operation engineer and D&B engineer). At this point, mining operation engineering practice (fleet management system, production control and mining manpower management) and also blasting daily practice will be elucidated. Daily blasting practice is consisting of surface blast design, explosive engineering, sleep blast practice and the concept of scaled depth of burial to ensure a safe work environment in blasting activity. Next, the second purpose of this paper is to explore workforce evolution and future skills for mining engineer in surface mining operation. Furthermore, strategy to advance future skills such as mining continuous improvement program, training and skills development for mining engineer (mining operation engineer and D&B engineer) in order to develop their skills is also discussed. It is expected that in the future, these future mining leaders will become new mining leader, for instance mining superintendents, D&B superintendents and mining managers. In conclusion, it is clear that awareness about workforce evolution, professional development, training, skills development, mining economics awareness and mining continuous improvement program are essentially required as professional development for mining engineer (mining operation engineer and D&B engineer), in order to be commercially competitive in their future career and in order to be adapted with future workforce evolution in mining.

Sep 1, 2024

By M Rea, E O’Connell

Decarbonising explosives manufacturing and catalysing low-carbon mining supply is a significant global challenge. Low-carbon manufacturing precincts – clusters of geographically close businesses across multiple industries that share a goal of adopting firmed renewable energy and decarbonising process emissions – offer one potential solution. In an Australian first, Orica commissioned tertiary catalyst abatement technology in 2023 to mitigate greenhouse gas (GHG) emissions at its Kooragang Island (KI) facility in New South Wales (NSW), Australia. The EnviNOx® technology (ThyssenKrupp Industrial Solutions AG, Dortmund, Germany) used reduces nitrous oxide (N2O), a potent greenhouse gas arising as a by-product of nitric acid manufacture. As a result, mining customers in NSW are now benefitting from ammonium nitrate (AN) products that are almost 50 per cent less emissions-intensive than those Orica previously offered. The $37 million project is a private-public partnership that has involved partners across Federal and State government, global engineering and technology vendors, local community groups and local carbon advisors to overcome financial barriers.

Sep 1, 2024

By J Herd, J Rowe, M Cutbush, d F. Aziz

WearApp provides expertise for assessing the degradation of removable screening media panels on vibrating screens right in a user’s pocket. Through the WearApp application, users can simply take a picture of a panel using their mobile, enter some basic information and have the application assess the wear to provide a recommendation for whether the panel needs to be replaced. Where traditional mechanisms for assessing panel wear only measure a few points across the panel face and rely on having personnel with specialised knowledge available to perform the assessment, WearApp uses deep learning models to analyse the entire panel face and support the user to make an informed decision. The application works through analysing a panel image and using a model to automatically detect the corners of the panel. Given the known dimensions of the panel, this enables the application to calibrate the pixel size against a known reference. A second set of models then detect the apertures and measure their dimensions. With the aperture dimensions defined the application assesses the wear of the panel through referencing a stored 3D model of the aperture. Finally, the data from each aperture is collated and the wear of the entire panel face defined. Since WearApp performs measurement of the entire panel face, it also allows the user to perform a more detailed analysis of the panel’s wear profile. Where typically, the panel wear is only measured in a few locations, WearApp’s analysis enables users to visualise the panel wear across the entire panel face, identifying areas of high wear that could be leading to premature panel replacement. Additionally, because the entire panel face is measured the change in screening efficiency can be calculated accurately for the worn panel, even taking into account the impact of aperture pegging by small rocks.

Sep 1, 2024

By L Muñoz, L Steffen, W Vilas Boas, G Gontijo, R Macedo, C Braga, d D Machado, G Stevenson

Mines operating close to communities face growing challenges, especially with their drilling and blasting activities. Proper management of environmental and community impacts is critical to provide sustainability to the mining business in the long-term, by enabling the licensee to operate. This paper will present new technology solutions to minimise the impacts to communities and the environment from blasting operations. A case study of the wireless initiation projects conducted at Kinross Morro do Ouro Mine (located in Paracatu, Minas Gerais – Brazil), will be presented. Focused on overcoming the complex challenges in the mine, Orica and Kinross searched for initiatives to optimise the drilling and blasting operations. The team evaluated the WebGen™ wireless initiation system for controlling environmental impacts as well as operational flexibility and productivity. Since January 2023, three planned wireless blasts to demonstrate the technology and applications were executed. In the tests, the vibration level was able to be maintained lower than the limit of 3.0 mm/s while dust and flyrock impacts were well controlled. The main benefits of using this technology for the Morro do Ouro Mine are: reducing the number of blasts while increasing the blasted mass per month; control of projection of fragments using additional cover; dust control by watering the bench easily; lightning initiation risk reduction due to the absence of wires or tubes on the surface; flexibility in changing the blast day to better control the noise and dust; flexibility in mine planning mining (potential application in the future). The use of the WebGen™ wireless initiation system, enables improved productivity while enhancing safety and reducing impacts to communities. Implementation of this technology has enabled Kinross Morro do Ouro Mine to build trust with its neighbours, maintain the license to operate, and helping to mobilise resources in a sustainable way. This has allowed Kinross to position Morro do Ouro Mine as a world reference operation, especially in relation to innovation, safety, and social responsibility.

Sep 1, 2024

By L Abrahamsson

The aim with this paper is to discuss experiences from the ongoing research project ‘Attract: A roadmap to attractive, inclusive, and safe mining workplaces’. The project’s aim is to analyse possibilities, effects, and consequences of the green and digital transformation in the Swedish mining industry from workplace, socio-technical and gender equality perspectives. The research project (2022–2025) at Human Work Science at Luleå University of Technology is financed by the strategic innovation program Swedish Mining Innovation (a joint venture by the national research funds Vinnova, Formas and the Swedish Energy Agency). The project includes a multidisciplinary research group of five senior researchers and five PhDstudents and a broad repertoire of methods, eg literature reviews, qualitative interviews with both managers and workers, workplace observations, workshops, surveys, and project seminars where the researchers and the company representatives together analyse the results. One important part of the project is the applied approach where the researchers work together with two mining companies and one subcontractor company. The project has two parallel main subprojects.

Sep 1, 2024

By P Mugebe, M Yahyaei, M S. Kizil, R Low

This paper seeks to establish an empirical relationship between the impact of mining technological innovation implementation and a company’s market value. The company’s market value is represented by its stock price. In a bid to ascertain the relationship, a stock price prediction model is sought to be established using the firm-specific factors impacted by the implementation of innovative technology. This work is performed under the watch of the prevailing macroeconomic factors. The background anchors in the understanding that the difference between the economic status of a mineral deposit and its uneconomic status lies in the level of mining technological innovation most prevalent at a given time (Hartwick, Olewiler and Preuss, 1986; Wellmer and Scholz, 2017; Wright and Czelusta, 2003). This is derived from productivity improvement, resulting in sustainable profitability due to technological innovation. Unfortunately, there is not an adequately established relationship that links this technological innovation impact to the share price performance of the mineral commodity company.

Sep 1, 2024

By R Daiyan, G Burge, M Haider Ali Khan

Australia’s mineral and metal exports have a substantial carbon footprint, twice that of its domestic emissions, mainly due to fossil-fuel-dependent downstream processes like processing into secondary metals and their transport. The country’s vast renewable energy and low-carbon hydrogen potential offer a promising alternative to mitigate this impact. These resources can be leveraged to displace fossil fuel use and become embedded into the metals value chain. Ultimately, it will yield ‘Green Metals’ that can be scaled to reduce the environmental footprint and provide an avenue for Australia’s vast green resources to be embedded (incorporated during production and supply) in green metals that can be exported. One potential green metal is copper, which is in great demand and likely to drive global decarbonisation through renewable electrification due to its role as an energy conductor. Given that Australia is a large producer and exporter of copper, this paper provides a techno-economic model of the copper value and applies it to Queensland (a hub of Australia’s copper production) as a case study. The results show that under incumbent hydrogen (A$8/kg) and renewable energy costs, the cost of green copper would be A$9704/t (~10 per cent higher than current copper costs). Further analysis revealed that the cost of hydrogen is a major cost driver; therefore, if the cost of hydrogen can be reduced to A$2/kg (a 2030 target of the Australian government), the cost of green copper would become competitive. Furthermore, if a carbon pricing regime ($54–79/kgCO2) is introduced, green copper would become competitive at a hydrogen cost of A$3/kg. Altogether, these findings provide insights for a future green copper export opportunity in Australia. Additionally, as the next step, the model can be extended to include other metals and released as an open-source resource for assessing global green metal opportunities.

Sep 1, 2024

By W Midgley, M Torok, I Canbulat, J Katupitiya, S Saydam, S Akdag

The green energy transition is expected to require a range of valuable minerals, which could be supplied through deep-sea polymetallic nodule mining. Deep-sea polymetallic nodules are mineral deposits with a composition well suited to produce lithium batteries, which are expected to be a necessary energy storage solution (Diouf and Pode, 2015; Paulikas et al, 2020) for the energy transition. By 2050 the annual demand for both cobalt and lithium is estimated to increase by around 450 per cent from 2018 levels (Hund et al, 2023), with the annual demand for nickel being greater than 2 million tons, and copper greater than 1 million tons. Polymetallic nodule mining is well positioned to provide these minerals in the near future. An intricate and comparatively unexplored ecosystem thrives within and surrounding the nodule fields (Smith et al, 2008). Deep-sea mining operations have the potential to disrupt and permanently damage this ecosystem through introduced pollution, artificial noise and light, and habitat destruction. Hence, there is a pressing need for new engineering and scientific endeavours to focus on developing new technologies to reduce any environmental impact from mining.

Sep 1, 2024

By L H. G McClean

Diversity, equity and inclusion are often cited as ‘important priorities’ by mining companies and industry organisations in their public presentations and reports, but is the minerals industry really making strides forward? The mining industry is the least gender diverse industry in Australia (WEGA, 2023). Women make up just 22 per cent of the mining workforce and mining has a gender pay gap of 15.1 per cent (WEGA, 2024a). Only 8 per cent of the CEO roles are female and 20 per cent of boards have no female members (WEGA, 2023, 2024a). Gender diversity, equity and inclusion is a highly topical issue with the recent release of the Respect@Work report, Western Australia Parliamentary Inquiry as well as the publication of company specific workplace culture reports and the national legislative changes to implement a positive duty for organisations to prevent sexual harassment in the workplace. This comes at a time of a skills and labour shortage in the minerals industry as well as declining geoscience study and participation. This is a perfect storm for our future workforce. Governments, industry associations, networks and companies are developing and supporting initiatives to make strides towards equity and inclusion, with some shining examples on both an industry and company level, but the dial is only moving slowly and, in some ways, going backwards. Every company is unique, but every company can review and support gender diversity, equity and inclusion. Actions to progress gender parity could include establishing a clear company position; ensuring that this position is cascaded throughout the company with appropriate training; reporting and reviewing gender participation as well as supporting positive workforce initiatives and a positive culture with a people-centric issues reporting process. At the industry level, there are clear gaps in the support for gender diversity and inclusion including a national voice and ‘one-stop-shop’ to support women in the industry and provide resources. Recommendations include improved co-ordination and collaboration of support for women as well as improved promotion of the suitability (and safety) of the industry for women. The new independent organisation, Women in Mining and Resources Australia (WIMARA) has the objective to address the challenges of gender diversity and inclusion as well as foster co-ordination, co-operation and collaboration between the different stakeholders and state or territory groups and amplify reach. To deliver the future workforce that the minerals industry needs, the time is now for the industry to make some giant leaps for womankind.

Sep 1, 2024

By H Zhang, M Karimi, M Hassan, S Saydam, B Li

With the prevalence of Mine Internet of Things (MIoT), different types of sensors have been widely deployed in mine sites for environmental monitoring and operational management. Currently, sensors in mine sites are mainly powered by cables or batteries. However, the deployment and maintenance of a power supply network can be difficult and expensive, and batteries have a limited lifespan. The vibration energy harvesting (VEH) technology can be used to provide power for lowpower sensors in mine sites. This presentation briefly introduces three widely used VEH methods (ie piezoelectric, electromagnetic, and electrostatic). The performance of a commercial electromagnetic energy harvester (ReVibe model D) is evaluated based on the vibration of a lab vibrator (3 g, 50 Hz) and an idling SUV automobile (0.3 g, 25 Hz). Experimental results indicate that a ReVibe energy harvester can generate adequate electricity to power a sensor, and its power output depends on the load resistance as well as the vibration frequency and amplitude of vibration sources. To apply VEH to mining applications, this study also analyses the characteristics of vibration sources at the mine site based on the vibration data collected from various operating machines in a coal handling and preparation plant (CHPP). The vibration analysis results indicate that all the measured vibration sources in the CHPP can generate stable and abundant vibrations, characterised by substantial amplitudes (up to 5.55 g) and low dominant frequencies (ranging from 14 Hz to 25 Hz), which are sufficient for VEH.

Sep 1, 2024

By A Tsang, D La Rosa, L Julian, W Hunt, R Pratama

Mineral extraction is facing the twin challenges of finite resources and increasing environmental and economic costs. Society’s growth is matched by an increase in demand for the earth’s resources. It is incumbent on us as contemporary mining professionals to promote and facilitate ethical and efficient practices. Technological developments have and will continue to allow a decrease in viable cut-off grades, creating new economic opportunities from deposits that were previously uneconomic. Mining low-grade deposits however, even with perfect recoveries, will have a significant environmental cost for the metal won. The greatest opportunity to increase metal with the least environmental cost is to increase the metal yield from existing mines. The determination of mining polygons is a critical juncture where rock is typically subjected to the binary grading of either ore or waste. This is undertaken using a number of factors, such as the mining equipment being used and the recovery in the processing plant. Traditionally, mining polygons were generated on the in situ grade control model. This ignores the complex differential blast dynamics that occur during blasting. Two opportunities exist to improve metal yields: optimise the blast design to achieve the post-blast muck pile that will support the greatest outcome; and generate optimised polygons on the post-blast muck pile. A data set from a Canadian Gold deposit is used to demonstrate the potential benefit of iterative blast movement modelling and grade control polygon optimisation on metal yield. The impact of blasting on the total recoverable metal is presented, highlighting blast design as a critical process in the mining value chain.

Sep 1, 2024

By D Connelly

High purity alumina (HPA) is a processed, premium non-metallurgical alumina product characterised by its purity level ie 99.99 per cent (4N) or 99.999 per cent (5N). The market price, application, and performance of HPA varies widely according to its degree of purity. High purity alumina is a form of aluminium oxide (Al2O3) with growing use in LED lighting and coating on the ceramic cathode separator sheets in lithium ion batteries. This paper describes a study on producing high purity alumina from feldspar to produce HPA and potash for use as a fertiliser. The project was positive for a number of reasons. High potassium extraction (>99 per cent) was achieved in the alkali leach using sodium hydroxide as the leaching agent and full dissolution of the alkali leach residue was achieved using hydrochloric and sulfuric acid. The potential to produce a high purity alumina product via a complex but promising emerging process was assessed. The potential to extract potassium as potassium sulfate to add value to the project was also demonstrated with the test work.

Sep 1, 2024

By T Hicks

Designers of mining facilities play a significant role in defining the overall mine greenhouse gas emissions performance. This demands an appreciation of all the greenhouse gas emissions sources, including Scope 3 emissions, which will form an increasing fraction of the emissions as we transition our generation sources to renewable energy. Traditionally overland conveyors are designed to operate as fast as practical, and through this approach, achieve relative minimisation of: conveyor belt tensions; belt width; mechanical equipment masses; structural steel quantities; and concrete quantities. It is well understood that higher belt speeds reduce capital cost and improve project economics. Operating at higher speeds introduces operating costs through system energy losses and increased wear rates. This paper assesses the life cycle greenhouse gas emissions for a typical iron ore overland conveyor to demonstrate how the design criteria and engineering decisions impact greenhouse gas emissions and project economics. An analysis of the decarbonisation potential and project economics using a range of operational parameters has been completed, developing a marginal abatement cost for each system configuration, creating a basis for integration of low emission overland conveyor designs as part of the broader facility decarbonisation strategy.

Sep 1, 2024

By E. Matinde

Human beings have been dependent on metals and alloys for livelihoods since time immemorial. In fact, there is irrefutable evidence that successful ancient civilizations achieved supremacy over their environments through the mastery of metals and alloys (Miller, 1995; Mtetwa, 2022). Over time, metals and alloys have evolved to become ubiquitous engineering materials indispensable to mankind, with applications in industrial and residential infrastructure, agriculture, energy generation and storage, transportation and communication systems, and manufacturing, among others (Elshkaki et al., 2018; Watari et al., 2021). Population growth, technological developments, and increase in urbanization and industrialization are all intricately linked to the intensity of use of metals and alloys. With up to 5 billion people estimated to live in urban areas by 2030 (Armstrong, 2009), the demand for metals and alloys will inevitably increase in order to satisfy the increased demand for infrastructure, machinery, and other human needs (Elshkaki et al., 2018; Watari et al., 2021). According to LePan (2022), urbanization and growth of mega-cities will increase the demand for metals and alloys, such as nickel, steel, aluminium, and copper by 116%, 50%, 57%, and 26%, respectively, between 2019 and 2035. Naturally, the production of metals and alloys from natural ores, secondary resources, and/or a combination of both, to meet this increased demand will invariably lead to the increase in generation of deleterious emissions in the form of wastes. In fact, mining and metallurgical wastes currently constitute the world’s largest anthropogenic streams by mass, often containing a high concentration of elements and compounds that can cause potential damage to natural ecosystems and humans (Hudson-Edwards et al., 2011; Lottermoser, 2011; Matinde et al., 2018; Seetharaman et al., 2022). Obviously, society’s heavy reliance on new mineral resources to drive the emerging energy transition entails that the legacy of these waste streams will continue unabated for the near-foreseeable future. The scarcity of high-grade mineral reserves, coupled with deliberate efforts to solve the anthropogenic circularity conundrum, therefore introduces a high level of urgency in the metal extraction industry to develop nascent and more eco-friendly processes and technologies. Integrating circular economy principles based on intentional configurations of circular industrial ecosystems in order to maintain the value of materials and resources in the economy for as long as possible is widely accepted as a practical approach to mitigating the negative externalities imposed by

Sep 1, 2024

By J Wen, P Hou, W Yu, M Hu, Z Jiang, C Bai

Vanadium titano-magnetite (VTM) is one of the important iron ore resources in the world. High viscosity and low fluidity are the basic characteristics of hot metal containing vanadium and titanium during the ironmaking process. Clarifying the influencing mechanism of the melt viscosity would be a significant issue for the high efficiency smelting of VTM. In this paper, a self-developed melt viscometer based on the principle of torsional vibration theory was employed to measure the viscosity of hot metal accurately. Simultaneously, the thermodynamic calculations and some modern detection methods were also used to investigate the precipitation behaviour of high-melting-point phases in hot metal containing vanadium and titanium. The measuring results show that the viscosity of molten iron gradually increases with the increase of titanium content when the mass fraction of titanium is between 0.09 wt per cent – 0.50 wt per cent. Meanwhile, the viscosity of the hot metal was affected significantly by the vanadium content. When the vanadium mass fraction was higher than 0.30 wt per cent, the viscosity of hot metal increased sharply, which will have a serious impact on the fluidity of the hot metal. Furthermore, it was revealed by thermodynamic calculations that an increase in titanium and vanadium content would result in the precipitation of high melting point phases such as TiC, TiN, VC, and VN in the molten iron, ultimately resulting in a decrease in its fluidity. Meanwhile, it was confirmed by Scanning Electron Microscope (SEM) observation that the precipitates in the hot metal were compounds consisting of V, Ti, C, and N elements, which agrees well with the thermodynamic analysis results.

Aug 21, 2024

By M A. Rhamdhani, R Z. Mukhlis

Removing the ledge formation in the Hall-Heroult cell during the electrolysis process may significantly reduce the energy requirement of the aluminium production process. In the absence of the ledge, however, the sidewall-material types become heavily restricted since the cryolite is very corrosive at the electrolysis temperatures. This paper study the corrosion behaviour of sintered nickel ferrite, nickel aluminate, and magnesium aluminate refractories (as possible candidates for sidewall material) in molten aluminium and cryolite melts with various alumina content at 980°C. Immersion tests of refractories with various porosity were conducted to assess the suitability of the refractories in the corrosive environment of the electrolysis cells. Microstructural change of the refractory after immersion were analysed using secondary scanning electron microscopy (SEM). Sampling of the melts were taken at 0, 10 min, 30 min, and each hour up to 6 hrs, and subsequently analysed by Inductively Coupled Plasma (ICP) spectroscopy. Based on the projected concentration of the refractories constituents in the melts, it was predicted that the corrosion rate of NiFe2O4, NiAl2O4 and MgAl2O4 in cryolite with 11 wt per cent Al2O3 were 461 × 103, 1.03 × 103, and 798 × 103 cm/a, respectively. Much lower corrosion rate of 2.3 cm/a for NiFe2O4, 2.6 cm/a for NiAl2O4 and 0.3 cm/a for MgAl2O4 were predicted if the refractories in contact with aluminium melts. Erosion played an important role in the corrosion as the concentration of the refractory constituents in the melts were beyond its solubility limit. It is therefore crucial to increase the densities of the refractory and improve its wetting characteristics.

Aug 21, 2024

By K Saito, M Hasegawa

In steelmaking processes, it is known that P2O5 in dephosphorisation slags often exists in solid solutions between Ca2SiO4 and Ca3P2O8, <C2S-C3P>SS, and thus the solid solutions play an important role in the dephosphorisation reaction. Hence, the knowledge of thermochemical properties, ie phase relations and activities of components, in slags containing <C2S-C3P>SS are necessary for the effective removal of phosphorus from hot metal. In this study, the P2O5 activities in <C2S-C3P>SS were measured through the gas equilibrium method. In the present experiment, oxide samples were equilibrated with Cu-P liquid alloys at 1573 K under a stream of Ar + H2 + H2O or Ar + H2 + CO2 gas mixture in which oxygen potential was fixed and then equilibrium phosphorus concentrations in the Cu-P alloys, [mass%P]Cu, were analysed with ICP-OES.

Aug 21, 2024