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By C. J. Newman, K. Molnar, A. G. Storey, G. Macfarlane

"The Kidd Creek copper smelter started operation in June 1981 using the Mitsubishi Continuous Smelting Process. A steady increase in plant production rates has been demonstrated, and the annual tonnage of concentrate smelted is now double the original design rate. This paper summarizes recent modifications made to increase concentrate feed rates, increase on-line time, reduce copper losses and control the impurity level in anode copper. It includes improvements made to furnace design, improvements to reduce downtime f or boiler cleaning, and improvements made to the acid plant to allow handling of increased gas flowrates and higher gas strengths while maintaining low acid plant emission rates. IntroductionThe Kidd Creek Division of Fal conbridge Limited operates a base-metal mining and metallurgical complex, located in Timmins, Ontario, which includes an underground mine, a 13 500 tonne/day concentrator, a 130000 tonne/year zinc plant and a copper smelter and refinery, The copper smelter and refinery were commissioned in 1981, with an installed capacity of 59 000 tonnes/ year of cathode. The smelter, utilizing the continuous smelting technology of the Mitsubishi Process, has subsequently been expanded in production capacity, and in 1991 produced 113 500 tonnes of blister copper The capacity of the refinery, which uses Onahama No. 3 tankhouse technology, has been increased to 96 000 tonnes/year of cathode. The capacity increase at the smelter has been realized through the input of additional oxygen to both the smelting and converting furnaces, without increasing the process off-gas flowrate through the associated waste heat boilers.In this paper, a brief review of smelter operation and modifications in the period 1982 to 1987 is presented, together with a more detailed discussion of operation during 1988 to 1991, and a discussion of future planned improvements."

Jan 1, 1992

A study was undertaken to remove the Se from waste solutions using a raw form of the biomass called Iota Chips derived from the seaweed, Eucheuma spinosum. Removal of Se from solutions was investigated as a function of time, pH, conc. of Se in solution (0.1 to 100 ppm) and lota Chips to liquid ratios of 10-2 to 10-5. For solutions containing initial conc. of 0.1 ppm Se, with the addition of Iota Chips at a solid to liquid ratio of 10-3, the Se conc. decreased to 0.03 ppm in about 3 hours. Iota Chips absorption capacity to the Se and its application to the treatment of the metallurgical processing effluents are discussed.

Jan 1, 1992

By Miguel N. Herrera, Abbas H. Mirza, Fiona M. Doyle

The standard test methods used to determine the pyrite content of coal and mineral wastes, and their propensity to release acidic drainage, are critically reviewed. In addition to analysis of total sulfur by combustion, test methods using selective oxidation of pyrite by HNO3 and H2O2 are available. The oxidation kinetics of pyrite vary appreciably from sample to sample, and it is difficult to ascertain whether complete dissolution has occurred in heterogeneous materials. The reliability, reproducibility and suitability of different standard test methods were studied, using well characterized ore and coal pyrite samples. The kinetics of pyrite dissolution were also investigated. The results are discussed in terms of the fundamental chemical and physical characteristics of each sample, and the implications for waste characterization are considered.

Jan 1, 1992

By Richard S. Kunter

Artech Recovery Systems, Inc has developed a low pressure and temperature? leach process called the "Cashman Process" to extract metals from arsenical flue dusts and residues and fix the arsenic in an environmentally stable form as ferric arsenate (scorodite). The process was pilot tested at Hazen Research in an integrated plant including continuous recycle from August 1989 to October 1989 during which several tons of flue dust were processed. Based on this pilot program, the process was deemed technically feasible and produced commercially salable products. Residues from this pilot program were subjected to a long-term stability test jointly designed by PTI environmental services and the USEPA. The process, its versatility, and the nature of the products is discussed in some detail.

Jan 1, 1992

Dimension stone is the term generally given to rock used in building construction. During early European history in Otago, locally available dimension stone products were easily obtained. Crude rock shelters built on river banks with schist rock within Central Otago soon gave way to more established and sophisticated permanent homesteads constructed with the same materials. Victorian architectural achievement is celebrated in Otago with many fine bluestone block buildings. When the University Council decided to build substantially in stone, it narrowly escaped disaster. It was well known at the time that brick in Dunedin was of an inferior quality and that it soon wasted. Rev Dr Stuart said before the 1879 Commission that æthe Council had some old-world notions and liked to have the University with some architectural styleÆ. Contemporary utilisation of dimension stone is generally restricted by expense to a simple veneer. Stone products produced from Otago quarries have found ready markets in other areas in New Zealand , particularly prior to the share market crash in 1987.

Jan 1, 1992

(Quality can be defined as that which is acceptable to the market and can be supplied with a predictable degree of uniformity and dependability at a low cost. The market for any mining product is downstream processing, whether it be an alumina refinery, a gold processing plant or a flotation plant. The cost of that downstream process is partly dependent on uniformity of its feed material both in physical and chemical terms. With more operations adopting procedures which require quality assurances in line with International Standards, from their raw material suppliers, miners must look to their grade control processes to provide uniformity and predicability.This is not a new concept. The mining industry has constantly been working with ahighly variable raw material supplied by Mother Nature, from whom we cannot demand quality assurances. Through the processes of exploration, resource and reserve definition, long and short term mine planning and day to day grade control an end product has been supplied which consistently meets our customers requirements, in an economic fashion. When any of these processes fail, then penalties are incurred which can range from increased mineral processing costs to loss of markets and in the ultimate case, failure of a mining operation.

Jan 1, 1992

By Lumley G. I, Duffy W. J

The risk involved with incorporating new/unfamiliar technology into mines has, in the past, largely been evaluated by the supplier of the technology. The implications on safety and productivity has been accepted as part of the process of `getting up and running'.This has changed. As companies see the lost productivity and accidents actually costing significant dollars, risk assessment is becoming an important part of the implementation of new equipment. Regulatory authorities are also seeing the preventable incidents and in some cases are now requiring a risk assessment to be undertaken on new equipment at a Mine.

Jan 1, 1992

By Mary Cocklan-Vendl

Regulatory processes associated with development of a world class lead-zinc mine, Red Dog Mine, in northwestern Alaska were reviewed and evaluated. Informal interviews with key project personnel, consultants, and agency field and permitting specialists provided perspective on the regulatory successes and failures of the project. Due to potential impacts to air quality, water quality, wetlands, and National Park lands, an Environmental Impact Statement was required. By developing a comprehensive baseline of information on the existing environment to aid in minimizing impacts during project siting/design and through regular coordination of evolving project plans with regulatory agencies, the mine developers were able to acquire necessary permits in a timely and cost effective manner. The only major exceptions occurred when inadequate information was collected on dispersal of airborne particulates, rates of surface water run-off, and groundwater quality. These deficiencies resulted in the need for design changes, unscheduled construction, additional environmental monitoring costs, and delays in issuance of the NPDES permit.

Jan 1, 1992

By E. Marques Coelho

Cationic flotation of quartz is currently utilized in the concentration of iron ores and the cleaning of phosphate concentrates. The present work deals with depression of quartz in the presence of aluminum aqueous species during cationic flotation. It was established that aluminum species depress the flotation of quartz with an amine, especially under neutral and slightly alkaline conditions. With an amine as the collector, studies of the adsorption (abstraction) of Al species on quartz surfaces, as a function of pH, correlated well with the depression of this mineral. The presence of Al species also enhanced the depressant action of corn starch on quartz. In addition, the sodium salt of ethylenediaminotetraacetic (EDTA) was found to be an effective complexing agent to suppress the depression caused by aluminum ions.

Jan 1, 1992

By Georges J. Kipouros

Anhydrous neodymium trichlorids (NdCl3), containing ~1 weight percent neodymium oxychloride (NdOCI) was prepared by the dehydration of neodymium trichioride hexahydrate (NdC13.6H2O). Dehydration of the hexahydrate was conducted in three steps. First, the hexahydrate was slowly heated in air to about 250 °C until all the low temperature water of crystallization was removed. In the second stop, the neodymium hydroxychloride (Nd(OH)2C1) fanned in the first step was decomposed by heating under argon to 430 ° C. Finally the salt was ground and then treated with HCl gas at 330 °C until practically all of the NdOCl was converted to NdCl3.

Jan 1, 1992

Most people are familiar with Euclidean dimensions: zero for a point; one for a line; two for a plane; and three for a volume. Howeverbobjects are not actually Euclidean, but lie somewhere between Euclidean æend-membersÆ with a non-integer fractal (or æfractionalÆ) dimension. The fractal dimension D is a measure of the relative importance of large versus small. Consider the trace of a coastline on a map. It has a fractal dimension (1 =D =2) somewhere between a line (dimension = 1) and a plane (dimension = 2). The more tortuous the coastline, the higher the fractal dimension, and the closer it becomes towards a plane. The concepts of fractals and spatial geometry can be applied to a wide range of geologicaVmining problems as well as than those dealing with space. One commonly quoted fractal relation is the log-log relationship of ore-grade and tonnage. Until recently, we have never been able to define or measure spatial-geometry, but new developments in mathematics have provided a means by which to quantity and apply it to our problems.

Jan 1, 1992

By T. R. Raponi, D. Barnes

The Williams Mine mines and mills 6000 t/d (6600 stp’d) of gold ore using SAG/ball milling, leaching and CIP, electrowinning and refining. Electrowinning, high-pressure cathode washing, filtering, retorting and refining are based around the use of knitted stainless steel mesh cathodes. Their primary advantage over conventional steel wool cathodes is that electrowon gold can be washed off and the cathode can then be reused. Typically, the knitted cathodes have a useful life of up to 15 months. Gold production of up to15 t/month (50,000 oz/month) is easily processed with this system. Presented is a description of this operation, including a review of the equipment and performance data.

Jan 1, 1992

By G A. Challis, A B. Christiel

Microprobe analyses of electrum grains in some Hauraki Au-Ag deposits indicate that gold fineness is in the range of 500 - 800 (50 - 80 per cent Au), but for most deposits the range is usually narrower than this. The electrums contain minor amounts (<0.8 per cent) of copper, arsenic, antimony, mercury, iron, and sulphur. Platinum and palladium were analysed for but were not detected (detection limit 0.24 per cent for Pt or Pd). For some deposits (eg Waihi), the average fineness values for the analysed electrums correspond fairly well with the electrum fineness determined by assay during the historic mining operations.

Jan 1, 1992

By D. Park, V. Gall

The three-dimensional finite element technique combined with a progressive failure approach were used to simulate stress distributions in a complete mine section that occur in response to a longwall mining operation. Due to the availability of a Cray supercomputer, a large-scale, three-dimensional, finite-element model was developed for the analysis. The Hoek-Brown failure criterion, which describes a realistic behavior of rock masses, was used for the simulation of progressive failure. A comparison of calculated and monitored stresses in the mine has shown that the model gives a good representation of stresses in the mine structure.

Jan 1, 1992

By L. K. Walker, G. A. Kosick, P. D. Young

"MillEX is an information management system designed by mineral processors for mineral processors. The system utilizes ""cutting edge"" software technology to gather and store all automatically and manually recorded data from the plant operation and laboratories. This data is delivered to the desk of superintendents, metallurgists, technicians and managers, and permits the user to query, correlate, graph, report and present this data in minutes. In the past this task would have taken days and even weeks of tedious work to complete.MillEX allows the engineer/analyst to quickly develop a very thorough understanding of the complex relationships of process variables and equipment that exist in the plant, and their effect on product quality and quantity. The time and resources that are currently wasted on duplicating data entry will be an effort of the past.This paper describes the structure of MillEX and how it conforms to the needs of mineral processing personnel.INTRODUCTIONPicture a personal computer on your desk which will carry out the following commands:1. Plot a graph over the last six months, using weekly averages, of percent minus 200 mesh material in the primary cyclone overflow.2. Overlay this graph with a graph of concentrate grade versus recovery over the same time period.3. Retrieve a prior month end report, update all operating supplies tables and metallurgical performance with this months data, and embed the graphs created above.4. Edit text and print the current month end report. This is only one example of the type of power MillEX isbringing to the mineral processing industry."

Jan 1, 1992

By Associates

The headwaters of Skippers Creek and the Shotover River are reputed to be among the richest alluvial gold catchments in the world. This alluvial gold has no doubt been derived from reef systems similar to, and associated with, the Bullendale lodes. Physiographically the prospect covers steep ridges and deeply incised gullies between the Richardson Mountains in the west and the Harris Mountains in the east. Vegetation is mainly tussock with bush either side of Murdochs Creek. Access to the area is by metalled road to Skippers and then by 4WD track to Bullendale. Alternatively the prospect area can be reached by helicopter from Queenstown in around ten minutes.

Jan 1, 1992

By L. S. Jen

Canadian copper, nickel, zinc, lead and molybdenum mines are characterized by the mining of ores from which more than one metal is recovered. During the 1980s, approximately 15% of the gold, 25% of the zinc, 30% of the copper, 55% of the molybdenum, 80% of the silver and 90% of the lead produced from Canadian mines were produced as co-products and by-products of base metal mining operations. This trend is not expected to change significantly in the near future. The presence of co-products and by-products affects the level of production and the level of revenue from base metal mines in several ways: (I) in general, production of one base metal cannot be expanded or cut back without affecting the amount of production of another metal;(2) the commercial success of certain base metal mining operations depends on the substantial bonus revenues from co-products and by-products; (3) the quality and economic viability of many ore deposits are significantly improved by the presence of co-products and by-products; and (4) while coproduction is critical to the survival of some mines, bonus revenue from by-products can also be life saving to others during economic downturns. For these reasons, deposits with significant co-product or by-product values are likely to continue to be significant targets for exploration and for acquisition.

Jan 1, 1992

By Hendon G. W, Carr F, Jiang Y

A vast majority of the operating longwall sections use shield-type face supports to provide ground control in the United States. As a co-operative research program between the University of Alabama (UA) and Jim Walter Resources, Inc.(JWR), a joint research program is underway to study interaction of shields with surrounding rock masses. A series of analyses on the response of shields are performed using monitored data at a longwall face in a deep coal mine. In this paper, various effects of parameters, such as leg pressure, setting load, developing load, maximum loading rate, pressure in capsule, and convergence between canopy and base, are discussed and recommended as stability indices. A microcomputer program is being developed for instantaneous interpretation of the shield monitored data, and for giving warnings of potential problems. The preliminary results define the effects of the setting load, developing load, and rate of developing load or leg closure rate. The objective of the study is to understand the shield characteristics and their interaction with surrounding strata in real time, then develop a reliable program for maintaining longwall stability.

Jan 1, 1992

By Kenneth L. Driggs

The Environmental Protection Agency's Clean Air Act of .1970 provided the driving force for the current Magma Smelter configuration. The historical and technical perspectives of those process developments are reviewed. Innovations in procedures and equipment have allowed compliance with the requirements of the regulating authorities. The wet scrubbing of converter gasses and the monitoring of converter operations by a controlling foreman are two of the major contributors to these successes. The Clean Air Act Amendments of 1990 have posed many new concerns for all U.S. industry, including the few (seven) primary copper smelters remaining. Future concerns include tightening the sulfur dioxide ambient standard from the current three-hour averaging period to one hour"

Jan 1, 1992

By Musa Karakus

Reflected light microscopic (RLM) examination of dust particles from lead and copper smelters can effectively characterize their mineralogy, texture, and origin. Scanning electron microscopic-energy dispersive spectroscopic (SEM-EDS) analysis provides confirmation of the optical identifications and chemical data on the phases. Studied lead smelter dust samples were from the: I) blast furnace, 2) sinter plant scrubber, 3) sinter plant crusher, 4) dross furnace, and 5) refinery. Phases identified included galena fragments, melted PbS, metallic Pb and Cu, Cu-Ni, Cu-Zn, Zn-Ag, Zn-Cu-Ag, Ni-Cu-Sb, and Ni-Cu-Zn-Ag metal alloys, Ni-sulfide, Cu-sulfide, and Cu-Pb-sulfide dross .phases; slag and sinter particles, coke fragments, unreacted original feed phases: pyrite, chalcopyrite, sphalerite, siegenite, bravoite; and oxidized particles: iss, bornite, chalcocite, covellite, magnetite, hematite, and goethite. Dust from a secondary copper refinery were found by RLM and SEM to consist of tenorite, cuprite, cassiterite, two silicate phases. Magnetite, hematite, Fe-Al-Cr-Mg spinel, periclase, forsterite, and wollastonite were derived from the furnace linings during initial cleaning.

Jan 1, 1992