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By Xuan Cheng

The electrochemistry of sulfide mineral flotation is reviewed with particular emphasis on galvanic interaction among minerals and grinding media, and its relevance to flotation of complex sulfide ores is discussed. Surface alteration due to galvanic interactions among chalcopyrite, pyrrhotite and mild steel is analyzed in terms of voltammetric and chronoamperometric studies on individual minerals and through galvanic current measurements in 2- and 3- electrode combinations. The results are related to laboratory flotation behaviors of chalcopyrite-pyrrhotite mixtures simulating copper-nickel bearing Duluth gabbro.

Jan 1, 1993

By Fernando JAS Barriga

The world-class Neves-Corvo deposits were intersected by drilling in 1977. They occur in the (Carboniferous) Iberian Pyrite Belt (IPB), Western Europe&apos;s largest stock of base metals (see Bamga, 1990, in Dallmeyer RD, & Martinez E, eds, Pre-Mesozoic Geology of Iberia, Springer-Verlag). Massive and stringer sulfides in the area sum up to about 200 Mt (109 kg), in five main orebodies (Neves, Corvo, Graca, Zambujal and Lombador). They include unique, extremely high grade copper and tin ores ( - 33 Mt Cu ores, -7.5% Cu, and -4 Mt Sn ores, -2.6% Sn, - 12.5% Cu). Also present are -50 Mt polimetallic ores (-6% Zn, 1.2% Pb, 64 ppm Ag). The remaining are relatively low grade pyritic massive and stringer sulfides (Cu < 2%. Sn < 1%, Zn equivalent < 4%). The geological setting is one of bymodal submarine volcanism, with predominant felsic, explosive volcanism and associated sedimentation (detrital and chemical), which took place on a shelf-facies, quartzite-phyllite basement (of Upper Devonian age). The plate tectonic setting has been the object of much debate. Current interpretations favour that the IPB volcanism took place in a tensional fore-arc region, associated with oblique subduction and collision (Silva et al., 1990, same volume as above). At Neves-Corvo there are many different ores, that may be grouped in four main types: fissural (at the base), breccia, massive (intermediate) and "ruban6 " (at the top). Fissural ores seem to correspond to stockworks in contrasting types of host rocks (gray to black shale, sericitic, chloritic and graphitic, and light gray volcanic rock). Massive ore may contain significant shaly gangue, at the base of individual orebodies, and silica-rich (cherty) varieties towards the top. The more sulfide-rich varieties predominate, and are usually well banded.

Jan 1, 1993

The tankhouse of the electrolytic zinc plant at Nordenham is operating with a very high operating efficiency of 99 per cent. This has been achieved not only by strict control of the quality of the zinc sulphate cell feed solution but also by all the improvements in housekeeping in the tankhouse developed during the past years: aluminium cathode specification, cathode stripping cycle, edge strips, copper contacts, anode isolators, cell cleaning, fittings and washing devices. During 1987 to 1992 the casting department was completely remodelled in order to improve the quality of the zinc products, the safety of the operations and the flexibility. The remodelling includes the enlargement of the area for the casting shop, the storage buildings and the five casting lines on the same ground level. New lines for alloying products and for SHG25 kg zinc ingots have been constructed. The line for galvanising products has new equipment in some parts and the other lines have been modified.

Jan 1, 1993

By Howarth W. J, Sowerby B. D, Watt J. S

On-line analysis systems have found widespread application in the metalliferous mineral and coal industries. The continuous analysis and rapid response of these systems has led to improved control of mining, processing and blending operations, with increased recovery of valuable minerals and coal combustibles.The paper reviews developments in on-line analysis by CSIRO and Mineral Control Instrumentation Ltd which led to the award of the Australia Prize 1992. These commercialised systems analyse mineral and coal slurries; determine the ash and moisture contents of coal on conveyors, and the moisture content of coke on conveyors; and determine the carbon content of fly ash. These gauges are estimated to have resulted in productivity increases valued at $50 million per year to Australia.

Jan 1, 1993

By G. Naud, J. Robitaille, M. Buonvino, A. Veltmeyer, A. R. Laplante

"A B6 Falcon concentrator was tested on several systems: a synthetic magnetite-silica ore, a massive sulphide gold-copper ore, a fine gold-pyrite-silica flotation tail, and a high grade gold ore in a low sulphide gangue (cyclone overflow).The Falcon demonstrated its ability to achieve separation in all cases, but with varying degrees of success. For the magnetite-silica system, separation proceeds until the concentrate bed overloads, at a mass of 300 to 400 g of magnetite. Recovery increased with decreasing particle size, down to the 25-37 µm and in some cases even the -25 µm class. Bowl geometry (angle) and gangue size distribution were the most significant operating variables. Results with the massive sulphide ore were the poorest, with gold recoveries typically around 10 to 20% at very low upgrading ratios, 1: 1 to 5: I. Gold recovery from the fine flotation tail ranged from 30 to 70% at upgrading ratios of 5 to 15; actual plant application would require a continuous unit (Falcon C20). The high grade gold cyclone overflow yielded a wide range of gold recoveries, but a very consistent relationship between recovery and mass processed. A concentrate of 0.5% Au could be processed at a recovery of 50%.The paper also presents results of a C20 application to recover fine iron from a magnetic tail. The unit is capable of recovering approximately 70% of the fine liberated iron in a high density product, with modest upgrading below 105 µm, and virtually complete rejection of the + 300 µ m product."

Jan 1, 1993

By Roberto Folchi

"This article deals with the excavation of a tunnel below the town of Isola LIRI, nearFrosinone, in central Italy. The tunnel was driven into a conglomerate formation, of lacustrine_fluvial origins, consisting in carbonate clasts with a sandy_silty matrix and calcitic cement. ""Drilling andblasting"" had to be adopted in place of a tunnel boring machine which had showeduneconomical performances. Good advance speed rates were achieved notwithstanding thepresence of some above structures to safeguard. The nearest structure (an old votivechapel) was less than 10 meters (33 ft.) far from the tunnel crown; the nearest residentialstructure was at about 15 m (49 ft.)."

Jan 1, 1993

By R. F. Hammen

Heavy metal contamination of water is a problem of immense national and international proportions. However, effective cleanup is complicated both by the toxicity and the low concentrations of metals in wastewater streams. Using high performance chelation chromatography, the solid phase extraction and purification of extremely dilute metals from water was highly effective. The process is based on selective displacement of metals from a chromatographic column containing a chelating resin. The resin is characterized by extremely efficient adsorption kinetics which allow rapid and complete removal of the metals.

Jan 1, 1993

Geostatistical analysis, resource estimation and three-dimensional modelling of the gold grade distribution was undertaken using exploration drillhole data taken from the Mt Leyshon gold mine. The main aims of the project were to provide an independent estimate of the primary gold resource and to improve the estimate by better understanding the statistical distribution of gold and the establishment of more robust variograms. These criteria have been achieved by the removal of low grade sub-populations, increased sample size and access to data from the most recent drilling program. The outcome of this statistical study has led to a lowering of the sill and nugget variance of the variograms used. Distinct geometric anisotropy was identified in all the resource estimation zones and was used to model gold grade distribution.Two independent resource estimates were established from the primary gold resource, one based on a geostatistical estimator (kriging) and the other on a traditional estimator (inverse distance weighting). Both methods were compared with a contemporary kriged estimate by Mt Leyshon Gold Mines Ltd.

Jan 1, 1993

By William M. Dowall

The recently completed in-pit crushing and conveying project at Phelps Dodge&apos;s Morenci Mine is rated among the world&apos;s leading materials handling projects. The operation involves the crushing and transport of more than 109 kt/ d (120,000 stpd) of copper ore, using regenerative conveyors capable of providing more than 5.5 MW (7000 hp) of equivalent electrical energy. The Morenci Mine is located 330 km (200 miles) east of Phoenix, AZ. Phelps Dodge Corp. owns an 85% interest in the mine. The remaining 15% is owned by Sumitomo Metal Mining Co., Ltd. and Sumitomo Corp. Copper has been continuously produced from the Morenci district since the late 1800s. Until 1989, run-of-mine ore was transported from active mining faces to the Morenci and Metcalf concentrators by truck and rail haulage. In that year, a system of in-pit, semi-portable crushing plants and overland conveyors was commissioned. This substantially reduced truck haulage and effectively eliminated rail haulage in the pit. The system used two semi-portable, in-pit crushing stations equipped with 60/89 gyratory crushers. The crushed ore from both plants reported to the first of two overland belt conveyors, arranged in series, for transport from the pit to a coarse ore stockpile. The system was "backed-up" by existing locomotive rail haulage.

Jan 1, 1993

Backfil ling of excavated Sub Level Open Stopes has been underway since March 1989 and as at December 1992 some 1 100 000 cubic metres of Cemented Aggregate Fill have been placed. During these three years significant developments in fill quantities, types and cost have taken place.Operational improvements have reduced the quantity of Cement Aggregate Fill by 40 per cent. These results have been achieved by:ò rescheduling stopes,ò designing smaller primary stope, and ò use of uncemented rockfill.Unit cost for Cement Aggregate Fill have fallen in the order of 50 per cent through:improving fill hole reli ability,simplified barricade construction procedures, reducing the cement content,ò substituting dune sand for deslimed mill tailings, ò improved maintenance at the Backfill plant, and ò renegotiated site freight agreement.This paper will review the historical developments of backfill use at Olympic Dam.

Jan 1, 1993

By Gerald T. Homce

A system capable of monitoring mine electrical power systems and detecting impending component failure could significantly improve power system safety and reduce unscheduled equipment downtime. Such monitoring would require a method of evaluating electrical parameters, calculated from terminal values, for indications of component deterioration. The U.S. Bureau of Mines has targeted electrical failure of squirrel cage induction motors and examined the use of mathematical models to aid in this evaluation. The initial stage of this work is complete, and has produced polynomial networks called adaptive learning networks (ALN&apos;s) that can detect and quantify winding insulation leakage simulated on laboratory motors. In this modeling process, empirical data from laboratory motors were used to select the electrical parameters most significant for assessing motor conditions, and mathematical expressions relating these parameters to simulated deterioration were formed. ALN&apos;s developed thus far can process readily measured motor terminal information and quantify power and current levels of laboratory-simulated leakage to within 1% and 3% of full load values, respectively, for motors in the 10- to 150-hp size range. The next stage of this research is validation of these ALN&apos;s for actual motor failures; this stage is currently underway, using accelerated life testing of laboratory motors.

Jan 1, 1993

By Chaves AP

This paper describes an investigation on the surface properties and mechanisms involved in the agglomeration of iron ore. For this purpose, an organic binder (carboxyl-methyl-cellulose (CMC)) was used in substitution of bentonite, the classic binder in iron ore concentrate agglomeration. Recently, a renewed interest of the iron ore producers in Brazil to replace bentonite for an organic binder, because of the economy that can be achieved in the, blast furnace operation. These savings are mainly due to the lower aluminum silicate addition which decreases slag volume and the improved pellet metallurgical properties which have the potential for lowering hot-metal production costs. Also organic binders are effective at lower addition levels, which results in lower storage and transportation costs. It is very important in Brazil because of the vast geographical area since transportation is made mainly by truck. Another advantage of organic binders is that they have low ash contents, and therefore most of the binders bum. off during the pellet firing operation. Previous studies have demonstrated the possibilities of the use of CIVIC, but in addition to its high cost, the pellets presented improper behavior at high temperatures or when prepared with high moisture levels. In the investigation here described, these problems have been solved through the addition of other reagents to CMC.

Jan 1, 1993

By D. C. Lynch

While a sizable amount of data exist as to the activity and distribution of minor elements between matte and metal, there has been no unifying theory presented delineating the form of dissolution of these elements in molten sulfides. In order to alleviate that deficiency the literature concerning the behavior of As, Sb, Bi and Pb in mattes is reviewed. Models present in the literature, regarding the thermochemical behavior of minor elements, are tested, and new models are presented and evaluated using thermodynamic theory. The results of those analyses are used to predict optimum conditions for the volatilization of minor elements. The dearth of data on the behavior of minor elements in nickel mattes requires that this review focus on copper- iron mattes. An effort is made, however, to utilize basic knowledge regarding nickel sulfides and the interaction of nickel with the minor elements to predict the behavior of those elements in nickel-copper and nickel-iron mattes.

Jan 1, 1993

By R. McCulloch

Exploration activity in metallic minerals continued to decline in Montana in 1992 as companies either reduced budgets or left the state. The number of active projects dropped another 50% from 1991. Expenditures were 3% to 6% of 1989&apos;s 28.6 million. Many of the major mining companies closed offices in Montana. Although depressed commodity prices have hurried the exodus, continuous changes in environmental regulations, as well as the Mining Law of 1872, without regard to economic effect have had the most serious impact. Many companies indicate that Third World countries present a more stable business environment than the United States. Grassroots projects are nearly non-existent, while late-stage programs continue cautiously. Exploration activity continued at the following projects: Garnet, Pegasus Gold; Southern Cross, Asarco; Elkhorn, Goldfields; 7-Up-Pete, Phelps Dodge and Canyon Resources; Miller Mountain, Pegasus Gold; Sheep Creek, Cominco American Resources; Checkerboard, Kennecott and BHP Utah International; Emigrant Creek, Pegasus Gold; and Crevise, American Copper and Nickel. All mineral activity, whether on private, state or federal land, is regulated by the Montana Department of State Lands under three classes of permits - Small Miner Exclusion Statements (SMES), Exploration Licenses and Operating Permits. A total of 230 Exploration Licenses are active in the state with 26 of those being new. However, there are only 433 projects current in Montana, with many of those in the reclaiming stage. The majority of exploration projects consist of individuals expending time rather than money on properties. The number of mines functioning under operating plans declined by one when W.R. Grace closed its Zonolite operation.

Jan 1, 1993

Mineral exploration is the business of finding and defining ore deposits. Ore bodies are developed into mines and mines supply every mineral and metal upon which our society is built. Whether it be steel for our bridges, cement and aggregate for our concrete, coal for our power stations, copper for our wire, phosphate for our fertiliser or gold for our jewellery it first must he found, then mined and processed before we can use it. There is no other way.

Jan 1, 1993

By Mohammed Z. Islam

As cities are growing all over the world, the need for urban transportation facilities are on the rise. Designers (of these facilities) today are faced with a number of constraints for their design, of the most is the space limitation and impact of new construction activities to the community. A typical subway station, as the focus of this paper, is approximately 600 to 1000 feet long, 50 feet wide and 2 to 3 story high. With such a large volume of construction activities, it is easily realized why underground stations are becoming obvious choice for larger cities eventhough the cost could be 2 1/2 to 3 times as much as an aerial station and 4 to 5 times that of an at-grade station [O&apos;Neil et. al.(1977)]. Since cost is an important factor which is always increasing, therefore, the designer should have a good planning, consider alternatives for design and come up with a realistic design with minimum impact to the community. This paper is about the geotechnical considerations that the designer should be aware of. PLANNING A 1977 report [O&apos;Neil et. al.(1977)] on the construction costs for a number of underground subway stations indicate that about 4 0% of the cost is site-controlled, 35% is structural items, and 25% is finish and equipment. It is seen that of opportunity exists for cost savings in the site selection and proper use of the site. Once the site is selected, the cost of construction become controlled by urban conditions at the site, geotechnical conditions, station size and depth. Therefore, the design-solution is very much site-specific. The geotecnical designer should collect the following information at the early phase of the design:

Jan 1, 1993

Segregation roasting tests were carried out on Zaire cobalt oxide ores assaying about 2% Co and 3.5 to 6.5% Cu. The major parameters tested during the laboratory investigations were temperature, dosage and type of reducing agent, dosage and type of chloridizing agent, and particle size. Results showed that standard conditions suited to the segregation of copper ores, i.e. low temperature and low dosages of reducing and chloridizing agents, resulted in the segregation of copper only, while conditions suited to the segregation of lateritic nickel, i.e. higher temperature and increased dosages of reducing and chloridizing agents, led to a successful segregation of both copper and cobalt. Under the best conditions, 88% of the cobalt and 98% of the copper could be recovered in a concentrate assaying 32.5% Cu and 8.5% Co. Alternatives to process such a concentrate are briefly reviewed.

Jan 1, 1993

By R. Tremblay, M. Burrows

"In the summer of 1990, pilot scale testing of a Jameson cell was carried out at Falcon bridge Limited, Kidd Creek Division. The Jameson cell is self aspirating and has fewer mechanical parts, thus it has a lower operating cost compared to conventional cells. This lower operating cost combined with positive pilot scale results, justified the evaluation of two full scale cells in the plant. The plant test had two mandates:1. Gain a thorough understanding of the cells operation and design constraints.2. Develop a flow sheet to replace three divisions of copper cleaner flotation.This paper provides an overview on the installation, commissioning and evaluation of the two Jameson cells acquired. The current status of the test program is also discussed.IntroductionThe Falcon bridge Limited-Kidd Creek Division concentrator is located in Timmins, Ontario. The concentrator, commissioned in 1966 and expanded in 1978, consists of four parallel grinding and flotation divisions utilising small cell (60 ft3) technology. With increasing pressure to maintain low operating unit costs a series of studies were undertaken to assess the impact of new technologies in the flotation circuits. The goals of the project were to improve productivity through increased metallurgical performance and/or reduced operating costs.One of the technologies investigated was the Jameson cell designed by Dr. Graeme Jameson of the University of Newcastle and marketed by MIM Holdings Limited, Australia. This style of column technology was chosen based on its potential for reduced capital and operating cost versus large conventional cells.The success of pilot testwork in 1990 led to the installation of two production sized Jameson cells beginning in October 1991. The units were to be used to confirm pilot results and determine equipment requirements for flotation modernisation. This paper will discuss the results and experiences Kidd Creek has had with the Jameson cell from pilot scale through installation and commissioning of the plant units."

Jan 1, 1993

By David R. Wilburn

The U.S. Bureau of Mines investigated the resources, costs, capacities, market relationships, and short-and long-term supply of bauxite, alumina, and aluminum. The 45 evaluated mines and deposits in 14 market economy countries (MEC&apos;s) have a demonstrated resource of 8.4 billion mt of bauxite and an aluminum content of approximately 2.1 billion mt. Developed world bauxite resources and existing primary aluminum smelting and refining capacity are sufficient to satisfy demand through at least 1995, when additional properties (with higher cost levels) would need to be developed to satisfy future demand levels. It is anticipated that new alumina or aluminum production most likely would occur in developing regions with large bauxite potential, low-cost energy sources, and a close proximity to refining and/or smelting capacity. An increase in aluminum recycling capacity would help meet future demand increases. A series of network model supply analyses was performed for the period 1988 through 2000. Based on announced future production levels and assuming demand grows at the level outlined in the analyses, model results indicate there is sufficient material available to meet demand until 1998, where-upon an aluminum shortfall is projected. Additional analyses investigated the effect of a reduced growth rate of demand and regional production variations in Venezuela on the international aluminum industry.

Jan 1, 1993

By Christopher J. Bise

Volume II of this collection of research reports, entitled "Model Training Program," provides the framework and details for developing a tailored training program for a specific mine based upon documented human-performance deficiencies. To do this, several steps must be followed prior to program implementation: 1) background information must be gathered (database analysis), 2) direct observation of indicated problem areas should be conducted (safety sampling), and 3) separation of those deficiencies to be addressed through training from those which would be better addressed by workplace or equipment redesign (trainability assessment). Once training is determined to be the appropriate strategy for addressing the noted deficiencies, several approaches can be taken, depending upon whether the problem is related to repetitive work procedures in a predictable, a variable, or a dynamic workplace with a substantial amount of interaction between workers, equipment, and the environment. Although this volume and the subsequent seven volumes provide examples of how the training information was field tested using various strategies (for example, loss control, task training, etc.) and techniques (for example, microcomputer-based exercises, lectures, etc.), the ultimate selection of the delivery method is based on cost/benefit analysis. Therefore, the Model Training Program has incorporated a Training Cost Model as a desirable component.

Jan 1, 1993