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By J. R. Goode

The first part of this paper comprises a general discussion on refractory gold ores and their mineralogy processing methods now in use are reviewed and test procedures for the important methods are discussed. Factors determining the selection of a process are outlined. The paper includes a survey of production plants using pressure oxidation, roasting and biological oxidation to process refractory ore. The status of processes under development is briefly reviewed.

Jan 1, 1993

The new legislative regime applying to the mining industry has been in force for nearly two years. However the parameters for the permits required under the Crown. Minerals Act 1991 and the resource consents required under the Resource Management Act 1991 are still being established. Mining operators will benefit from participating in the development of policies and plans currently being formulated by local authorities. The Energy Legislation Amendment Bill currently before the House contains amendments to the Crown Minerals Act to clarify points of uncertainty and to reduce transaction costs where possible.

Jan 1, 1993

Recent work on computerised mineral resource databases at the Institute of Geological and Nuclear Sciences Limited has concentrated on the development of the GERM, REGCHEM, and MINLIT databases, and their integration in a Geographic Information System using MapInfo software on an IBM-compatible microcomputer local area network. GERM (GEological Resource Map) is a mineral deposit inventory with national coverage and more than 10 300 entries. REGCHEM (REGional Exploration GeoCHEMistry) is a database of stream sediment analyses from open-file mining company reports, containing more than 14 000 sample sites from the Coromandel and west Nelson regions. MINLIT (MINeral LITerature bibliography) is an annotated bibliography of literature on topics relating to the exploration and geology of mineral deposits in New Zealand, and includes more than 5000 entries for published books and papers, and unpublished mining company reports, university theses, and government reports. Master sets of GERM and MINLIT continue to be maintained on a VAX mainframe network but REGCHEM is operated only in the PC environment using the Microsoft ACCESS database management system software.

Jan 1, 1993

By Arturo Ressi di Cervia

The utilization of diaphragm wall construction in Hong Kong began in 1974 with the construction of the New World Center, the first diaphragm wall job built in the British Colony. That landmark job of which I am presenting a few slides and a schematic description, embodied all of the difficulties and problems which are encountered in the difficult geology of Hong Kong. A small rocky island in the South China Sea, Hong Kong provides one of the finest natural harbors in the world. It is its splendid harbor, coupled with the enterprising attitude of the Hong Kong Chinese and the laissez-fair attitude of the British government which has resulted in the explosive growth of this speck of land soon to revert to the political control of mainland China.

Jan 1, 1993

By K. A. Natarajan, K. S. N. Murthy

Growth of Thiobacillus ferrooxidans on pyrite mineral surfaces and in 9K leach media was studied through estimation of bacterial protein in the different phases. Bacterial attachment was found to be governed by particle size of the mineral, period of incubation and by stationary or agitation conditions used during incubation. Increased bacterial growth in the liquid as well as on the solid phase was observed with decreasing particle size and increasing incubation periods. Increased bacterial attachment to pyrite mineral surfaces was observed to promote iron dissolution.

Jan 1, 1993

By Jinrong (Patrick) Zhang

Improvement of conventional flotation efficiency, separation of carbonates from apatite, recovery of phosphate values from phosphatic clay and other ways of utilizing the clay, disposal of clay slurries and subsequent reclamation of the settling areas, and conservation of resources and energy remain major challenges in the beneficiation area for the phosphate industry. These problems have been actively investigated by the industry, government agencies, and research organizations for decades with modest success. However, some recent research activities have generated promising results and possible new technologies. The dominant position of the Crago process in phosphate beneficiation is being challenged by some of the single stage processing schemes. Heavy media separation enables one producer to process a portion of high carbonate ores. Separation of dolomite from apatite by reverse flotation of carbonates with phosphate depressants showed potential for industrial application. Consolidation of phosphatic clays in mine cuts using a modified "sandwich" process is being tested. Beneficiation in the acidulation plant or grinding at the mines may be considered in the future.

Jan 1, 1993

By Jean M. Kenney

Frequencies of haulage-related accidents in metal and nonmetal surface mines for the years 1988 through 1990 were investigated and compared with those of non-haulage-related accidents. This study was part of the U.S. Bureau of Mines program to improve mining haulage safety. Data were obtained through the U.S. Bureau of Mines Accident Data Analysis (ADA) program. The chi-square test was used to compare frequencies of haulage-related and non-haulage-related accidents for each of the following variables: degree of injury, age, total number of years of mining experience, and shift time. Significance was determined for degree of injury between haulage-related and non-haulage-related accidents. Age of injured did not vary significantly between haulage-related and non-haulage-related accidents, but total number of years of mining experience was found to be significant. Shift time for the accident proved to vary significantly between haulage-and non-haulage-related accidents. Events causing injury for haulage-related accidents were tabulated, and the most frequent determinants of haulage-related accidents were identified. Accident descriptions for both fatalities and permanent disabilities were studied, and the primary causes of these accidents were identified. These findings suggest that haulage-related jobs are among the most dangerous when considering accidents experienced by all workers in the metal and nonmetal surface mining work force.

Jan 1, 1993

By C. R. Stephan, N. B. Greninger, J. R. Lipscomb

The U.S. Bureau of Mines and the U.S. Mine Safety and Health Administration (MSHA) are participating jointly in a research program to evaluate the strength characteristics and air-leakage resistance of various proposed seal designs for use in underground coal mines. The full-scale seals were constructed in the USBM's experimental mine at the Lake Lynn Laboratory, air-leakage tested, then subjected to pressure pulses of 20 psig or greater. bjected to pressure pulses of 20 psig or greater. In experiments prior to this study, seven seal designs using solid-concrete blocks were tested. Only the standard-type seal passed the explosion and air-leakage criteria. Tests also were performed on four seals constructed with low-density foam blocks. All four of these seal designs withstood the pressure pulse. In more recent studies, nine cementitious foam seal designs of varying thicknesses and densities were investigated. Six of the nine designs successfully survived the explosion overpressures. Six wood- block convergence seals also have been tested. The typical 3-ft-thick, wood-block seal design currently used in many coal mines did not maintain its integrity, in the absence of convergence forces, following the explosion test. Five modified wood-block seals successfully withstood the 20-psig pressure pulse. Based on these tests, three alternative seal construction materials, cementitious foam, low-density foam block, and wood, have been approved by MSHA for use in underground coal mines.

Jan 1, 1993

By John J. Sammarco

This report details the testing and evaluation of a modular azimuth and positioning system (MAPS) to provide navigational information for a continuous mining machine. Vehicle navigation is part of the U.S. Bureau of Mines research program in computer-assisted mining serving as a tool to increase mining health, safety, and productivity. The Bureau is investigating other navigation systems, but MAPS seems to have the most promise. MAPS was installed on a continuous mining machine. An operator used the machine to cut coal while researchers collected machine and MAPS data. A comparison of MAPS data for xy position and data obtained with an electronic transit showed an increasing error for MAPS. After 30 min of operation, the easting position error was -0.02 m, and the northing position error was 0.019 m; after 60 min of operation, the easting position error was -0.19 m, and the northing position error was -0.26 m. Modifications to MAPS software and to the operational procedure of the machine significantly reduced this error by a factor of 3.7. Researchers continue to reduce these errors.

Jan 1, 1993

By Michael R. Norland

Surface and subsurface stabilization of mining-related wastes through revegetation depends upon the physical, chemical, and biological condition of the waste following mining. Mining disturbances can significantly alter the soil physical, chemical, and biological characteristics of a site, reducing or eliminating mycorrhizal fungi from the soil. Mycorrhizae are economically and ecologically important because they can alleviate environmental stresses caused by lack of proper soil condition and because they are vital to stabilization of mining waste by increasing plant survival and biomass through increased nutrient and water uptake. This report discusses some of the ecological factors that may affect mycorrhizae-plant associations on mining-related wastes and provides general information on mycorrhizae inoculation technology.

Jan 1, 1993

By J. Sottile, J. L. Kohler

Component failures in the electrical control circuits of mining machines account for a large percentage of the total downtime of the machine. Once a failure has occurred it is always a tedious and usually a time-consuming task to locate the failed component. Moreover, the pressure to quickly locate the cause of a delay can lead to compromises in safety. Thus an onboard diagnostic system, essential for an automated machine, would be a very useful addition to existing machines. This report details U.S. Bureau of Mines development of a generic procedure for synthesizing diagnostic systems for electrical-control-circuit failures in mining machinery. A continuous mining machine is used as the testbed to illustrate the application of the developed methodology. Substantive differences among mining machine control circuits made it impossible to achieve a generic diagnostic system, but a generic approach for the synthesis of the diagnostic system was possible. As the research progressed, it became apparent that an algorithmic approach was better than an expert- system-based implementation. A prototype system was constructed and used to evaluate the diagnostic system. Prototype implementation issues are also examined.

Jan 1, 1993

By Xiangwen Wang

Electrochemical measurements associated with the electrowinning of lead metal from concentrated brine (NaCI) - lead chloride (PbCI,) electrolytes at temperatures in the range 328 to 353°K (55 - 80°C) were conducted. The electrodeposition of lead metal onto a lead rotating-disk electrode may be described by the electrodic reaction: {PbCl 4 2 + 2e- = Pb° + 4Cl-} The deposition-overpotential requirements are low (approximately 41mV per decade of current density - Am+), with a corresponding high exchange current (approximately 0.018 A.cm2). The diffusion coefficient of the electroactive PbC142- species in a 3.5 NaCl electrolyte at 353°K was insensitive to the total PbCI, concentration (0.01 to 0.1M), and its value was found to be (1.21*0.1)~10-5 cm2Is with a temperature-sensitivity coefficient (E,/R) of approximately 1.98x103K-1 (328OK(T<353OK).

Jan 1, 1993

By S. I. Sobol

Completeness of cobalt recovery from slag requires decomposition of maggemite and non - ferrous metal desorption with polymerized silicon-acid. Cobalt losses are reduced in leaching tai1s up to 200 g/t of iron.

Jan 1, 1993

By B. J. Arnold

Froth removal rate is perhaps the most important parameter in scaling up from laboratory tests to plant froth flotation circuits. The WEMCO froth factor, the percentage of the froth height over the lip of the cell, accounts for the difference between laboratory and plant froth removal rates. As laboratory tests are generally run with a high pulp level, laboratory results are directly comparable to plant results only when a high froth factor (high pulp level) is run in the plant. When a plant does not have a high pulp level, laboratory results must be modified by using a ratio between laboratory and plant kinetics to predict plant results. This ratio, which accounts for the froth factor is important in testing any new reagents or reagent dosage levels. CQ Inc. researchers have used predictive scale-up equations using this froth factor coupled with equations for kinetics and the residence time distribution in the froth flotation cells. These equations show that modifying the froth factor in the plant can have a large impact on flotation cell yield and reagent use. EQUATIONS DESCRIBING FROTH FLOTATION Scaling up from laboratory- to plant-scale coal froth flotation has been the subject of much research and debate over the years. Determining the proper rate equation to describe flotation kinetics and an equation to describe the residence time distribution in a bank of flotation cells have been particular areas of study. As shown in Tables 1 and 2, various rate equations and residence time distribution equations have been proposed in the literature. These equations consist of one or two parameters giving the rate constant(s) in units of time-1 and a parameter for recovery at infinite time, [Roo]. Dowling, Klimpel, and Aplan (1985) evaluated the rate equations in Table 1 for their ability to fit froth flotation kinetic data and found that all of the equations give reasonably low standard errors. Several of these equations, however, proved to have superior confidence limits for the parameters. Other equations have also been proposed to describe the recovery versus time profile. Most recently, Diao et al. (1992) proposed a first-order form with a sine wave distribution. As indicated in Table 2, investigators have suggested many equations to describe the residence time distribution in continuous froth flotation. To measure the water residence time distribution in a bank of cells, a soluble tracer is often used, with the level of tracer being measured over time at the tailings discharge. This response is then put on a dimensionless basis as described by Austin et al. (1984) in order to compare mixing behavior between cells or under different conditions. Coal flotation cells are generally of the flow-through or hog-trough variety allowing for some degree of backmixing and short-circuiting. While the water residence time distribution (see Figure 1) at the end of one cell in a bank of 1.4 cu ft WEMCO froth flotation cells may approximate perfect mixing conditions (Arnold, 1989), the water residence time distribution at the end of a bank of cells does not. Figure 2 shows the RTD for various flotation cell types compared to that for perfect mixers in series. To better describe the water residence time distribution in coal froth flotation cells, Van Orden (1986) used an equation similar to the perfect-mixers-in-aeries equation. This

Jan 1, 1993

By J. F. Hutwelker

A pilot plant was constructed and operated to investigate the column flotation of 20 x 200 mesh North Carolina phosphate ore, using high throughput, high solids operating conditions developed at the NCSU Minerals Research Laboratory. Flotation was performed at 45% solids in a 9.5 cm (3.75 in.) diameter by 2.26 m (7.4 ft.) tall column at throughputs of 19.1 t/hr/m2 (2.0 stph/ft2) and 31.7 t/hr/m2 (3.3 stph/ft2). Recoveries in excess of 98% of the phosphate value were obtained at the lower throughput -- while obtaining concentrate grades containing over 28% P205 (61.2% BPL) at that recovery. Recoveries of about 95% of the phosphate value were obtained at the higher throughput, while making a concentrate averaging 27.6% P209 (60.3% BPL). In addition, a better understanding of the variables governing the column flotation of coarse nonmetallic minerals was gained. Low air flow rates adversely affected concentrate grade at the lower throughput. At the higher throughput, phosphate recovery decreased at an elevated air flow rate. An unexpected result of the study was the effect that frother type had upon phosphate metallurgy. Use of Nottingham Econofroth 925 provided better flotation selectivity than American Cyanamid F-65 at the low throughput. This is significant since the high&apos; throughput tests were conducted with F-65 exclusively. It is reasonable to expect further improvement in high throughput performance when the optimal frother type and dosage are determined.

Jan 1, 1993

By Forssberg KSE

The behaviour of cationic and anionic collector mixtures in the feldspar-quartz flotation system has been investigated througl conductivity, surface tension, zeta-potential and flotation studies. Tht results show the formation of molecular complexes between oppositel; charged collector ions through charge neutralisation. The molecular complexes are found to have a higher surface activity than the individua components. The mole ratio of the mixed composition is found to have, significant effect on flotation. Mole ratio less than unit} (anionic/cationic) of collector mixtures increases the flotation recoveries If the mole fraction of the anionic collector is greater than the moh fraction of cationic collector in a mixed composition, flotation ceases The flotation selectivity principally depends on the inherent differences it the surface charges of feldspar and quartz at the flotation pH values of

Jan 1, 1993

By T. W. Camm

The Bureau of Mines conducts studies of the economic impacts of regulations on federal lands. These studies are part of the Bureau Potential Supply Analysis (PSA) program. To meet the needs of these studies, a methodology was developed to estimate operating and capital costs for a mineral deposit given its tonnage, grade, and depth. The format for the cost models in this study was developed at the Bureau&apos;s Western Field Operations Center (WFOC), Spokane, W. A., for studies of known and undiscovered resources on Federal lands. These cost models are described in a Bureau publication by Camm (1991).

Jan 1, 1993

By Raymond G. F

Geostatistics - a tool used by geologists and mine planning engineers to estimate grades and rapidly evaluate alternative mining strategies has reached an advanced stage of development for the silver-lead-zinc orebodies at Isa and Hilton Mines. Geostatistics has been used for over a decade in the massive copper orebodies but the stratiform lead-zinc orebodies are much more complex and provided a completely different set of challenges. Recent increases in computer processing speed and power provided by the Integrated Mine Planning System (IMPS) has aided the development of the geostatistics package. Also the formation of a project team and the subsequent in-house development which has drawn together the expertise of geologists, engineers and system analysts has contributed significantly to the success of the project.The most important feature of any approach to modelling the lead-zinc orebodies is that the kriging search must consider estimate and sample points according to their positions relative to bedding surfaces. By transforming co-ordinates as perpendicular offsets from a plane representing the local strike and dip, it is possible to elongate the ellipsoidal influence to parallel bedding. By interactively modelling surfaces using CAD facilities and then specifying these surfaces as &apos;hard&apos; or &apos;soft&apos; boundaries, the geologist has complete control over the kriging process.

Jan 1, 1993

By Richard F. Hammen

Mineral extraction from sulfide ore deposits usually leads to the combined action of oxygen and water on the newly exposed ore. The result is acid mine drainage, a low pH solution of various metal sulfate salts and sulfuric acid. Paradoxically, the valuable metals dissolved in acid mine water are a liability because they are too toxic for discharge but too dilute to recover economically. The expense of compliance with water quality release standards has reduced the profitability of many mining operations. Solid phase extraction (SPE) columns have been developed to extract metals from acid mine water. These columns are designed to remove the toxic elements from water and recover the metals as purified fractions. This article describes the results of a Phase 1 bench-scale project to test the performance of the SPE columns. The tests were conducted with water collected from the abandoned Berkeley Pit copper mine in Butte, MT.

Jan 1, 1993

By Nevolina VG, Zakharova IB

The results of a study on the flotation of baddeleyite and associate minerals are presented, together with effective flotation reagents. Detailed microcrystallomorphological analysis of the benefication products were made to find out the features of distribution of different baddeleyite generations between froth and chamber products. To reveal the dynamics of interaction of technological properties of minerals with their morphology and constitution, a method of onthogenetic analysis was used. It is well known that the difference between technological properties of the particles of the same mineral depend greatly on its genesis, but also the relation is direct - by means of constitution (habit). Thus, flotation behaviour of minerals depends on morphology microinclusions, distribution of impurities, dislocations and physical properties of individual particles. The microrelief of baddeleyite grains and crystals from froth and chamber products was studied with an electron scanning microscope. Chemical composition was determined by means of laser, microprobe and chemical analyses. The difference between baddeleyite generations, their distribution in benefication products, and the effects of grain sizes, number of inclusions and chemical compositions were valuated. Conclusions on baddeleyite flotation properties were made. Mineralogical study on eudialite grains from rough ore and eudialite concentrate was carried out. The interrelation between eudialite and associate minerals and negative effect of aegirine on technological properties of eudialite were revealed as well.

Jan 1, 1993