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By J. A. Jirestig

Laboratory investigations on the possibility for magnetic separation of sulphide minerals are reported. A survey of several sulphide ores and flotation concentrates shows that magnetic separation in most cases is not a suitable primary method of beneficiation. However encouraging results have been obtained in concentrate purification. At the Boliden complex sulphide ore concentrator in Garpenberg a Allis-SALA MK III carousel High Gradient Magnetic Separator (HGMS) is used together with a small flotation circuit to recover sphalerite lost to the galena concentrate in lead flotation. The result after four years of refining the HGMS process, show increasing zinc recovery and enhanced quality of the lead concentrate.

Jan 1, 1993

By I. Gaballah

Spent hydrorefining catalysts may contain 4 to 6 % of COO and/or NiO, 8 to 16 % of Moo3 and up to 10 % V205 generally supported by alumina. Raw samples are roasted in order to eliminate carbon, sulfur and hydrocarbons contained in the spent catalysts. The roasting optimum temperature and time are 500 "C and 7 hours. Selective chlorination of roasted samples with Cl2 + air, Cl2 + N2 and Cl2 + CO is investigated in order to recover the valuable metals. Depending on the chlorination it is possible to recover more than 80 % of the Ni and Co about 95 % of the Mo and up to 80 % of vanadium compounds. Cobalt and nickel chlorides are obtained by leaching the chlorination residues' by acidified water. Molybdenum and vanadium chlorides and/or oxychlorides are obtained by selective condensation from the vapor phase. The chlorination of the catalyst support, Al2O3, can be limited to less than about 5 %. Besides the reaction temperature and time, the oxygen partial pressure of the chlorinating gas mixture appears to be the key factor for the reactions' selectivity.

Jan 1, 1993

Thank you chairman, good afternoon ladies and gentlemen. In my talk this afternoon I intend to cover a brief history, some of the recent experiences and an overview of the McArthur River project.If we consider the themes of this forum, Obstacles and Opportunities, I can confidently say that in attempting to develop the McArthur River deposit Mount Isa Mines Limited (MIM) must have encountered almost every obstacle that can be imagined. However the large size and the high grade of the deposit has ensured an opportunity, from which it is very difficult to walk away from.The McArthur River Here's Your Chance (HYC) Deposit is located in the Northern Territory of Australia. It was discovered by Mount Isa Mines Limited geologists in 1955 and is one of the largest known sedimentary stratiform zinc-lead-silver deposits. The deposit has been the subject of numerous investigations and considerable expenditure culminating in a major feasibility study in 1979. There were a number of factors which prevented development, these being the size of the project, the fine grained mineralization, geographical location, market, social and capital cost. The latter had been estimated in the 1979 study to be $800 million at that time.

Jan 1, 1993

By A. R. Negele

Kaolin-based pigments are the most widely used pigments in the paper industry. Several types are available and include standard hydrous, delaminated, calcined, chemically-structured, and most recently, composite pigments. Within each category, a spectrum of products is available to satisfy the application requirements of paper producers. The paper industry has a broad range of applications including fillers in woodfree and groundwood-containing papers, pigmented size press applications, ultra-lightweight and lightweight coated papers, coated merchant papers, cast coated papers and coated paperboard. Each application has its own set of performance criteria and suppliers must work with mills to identify appropriate product(s) to fulfill these requirements.

Jan 1, 1993

By S. V. Cherty

The utilization of natural gas in non-ferrous industries during smelting and refining stages of copper , aluminum, zinc and lead was studied. The total amount of nonelectrical energy consumed in the production of zinc, copper, lead and aluminium, are 96.5% ,93%,92%, and 6 % respectively. It is calculated that 9.45 wt %of air of stoichiometric amount can be substituted by natural gas to the total air input in the nonelectrical energy utilization processes. The results showed that the non electrical energy may be substituted to an amount of 71 % ,52 % ,35 % ,32 % ,and 26% ,in the production of lead, aluminium (plates, foils) copper, aluminium, zinc, respectivelly. Similar calculations are carried out in terms of energy in Btu for the total production of non-ferrous metals in the U.S. It shows that 51.866~106 millions of Btu of nonelectrical energy can be substituted by 54.58~106 cu. ft of natural gas. Finally, the substitution of non electrical energy in terms of equivalent coal energy is discussed. 1t is shown that total non electrical energy is equal to 1.852 million tones of coal .If this 1.852 million tones of coal is replaced by natural gas, a total savings of 22.14 million dollars are achieved. The total or partial substitution of coal by the natural gas in the existing industrial processes and modification of redesigning the processes is discussed.

Jan 1, 1993

By Jarvensivu M, Ylinen R, Jamsa-Jounela S-L

The paper presents a new integrated system for control of concentration processes. The system is based on cluster-based modelling taking the ore quality into account and a new on-line particle size analyser capable also for reliable measuring of particle size distribution of concentrate. A metallurgical precontrol audit was performed at the Hitura concentrator in order to design the control strategy of the integrated grinding and flotation control. A new analyser PSI-200, was used to the measurement and control of the distribution of nickel in the total particle size range. An expert control system using the cluster model together with a new control strategy for decision of necessary control actions is outlined. The method has been tested to real data from mineral processes. The results are in good correspondence with empirical process knowledge. KEYWORDS: Cluster analysis, expert control, flotation control, mineral processes, modelling, particle size.

Jan 1, 1993

By Kenji Sasaki

Tamano Smelter started its operation in January, 1972 adopting FSFE ( Flash Smelting Furnace with Furnace Electrodes ) type smelting furnace at a production capacity of 101,00Ot/y of anode copper and 285,00Ot/y of sulfuric acid. Since then, it had experienced several production expansion program, it had twice as production capacity as start. 196,000t/y of anode copper and 436.000t/y of sulfuric acid. This time, we have completed the plan for increasing production capacity up to 226,000t/y of anode copper and 510,000t/y of sulfuric acid, by the oxygen enriched operation. We carried out several improvements and modifications, changing of cooling system ill FSFE, enlargement of converter and anode furnace, and some progresses in sulfuric acid plant and environmental facilities.

Jan 1, 1993

By C. P. Broadbent

The process metallurgy of many nickel laterite smelting operations is controlled largely by the physical chemistry of the slag system. Consequently, accurate phase diagram information and physicochemical property data are essential to interpret and predict the behaviour and optimisation of the overall process. The system (SiO2 - MgO - FeO) first described by Bowen et al. between 1914 and 1935 and the system (SiO2 - MgO - FeO - Fe2O3) determined by Muan and Osborne in 1956 are of particular relevance to the study of nickel laterite smelting slags as these systems form a reasonable approximation of many industrial slags. This paper will review the literature for these (and other relevant) phase systems. In addition data available from the ternary and (quasi)ternary phase diagrams will be compared with data obtained from industrial slags. The physico-chemical properties under consideration will include; melting and crystallisation behaviour (solidus and liquidus temperatures), viscosity - temperature relationships, heat flux considerations, electrical conductivity, surface and interfacial tension.

Jan 1, 1993

By L. Diestelow

Evaporation and crystallization processes are used extensively in the mining industry to provide many pro-ducts. In the case of solution mining evaporators are used to concentrate, or to concentrate and crystallize the raw materials being mined. In the case of underground, or strip mining dissolving and crystallization are used in many processes in order to purify the ore to saleable materials. Presently evaporators and crystallizers are being used in the production of sodium chloride, potassium chloride, sodium carbonate, sodium sulfate, lithium chemicals, aluminum, and many others. The evaporator is a device designed to remove water or solvent from a solution. In an evaporator the energy released by steam condensing on one side of the heat transfer surface is transferred to the product solution on the other side of the heat transfer surface. As long as the boiling temperature of the product liquor is below the condensing temperature of the steam, the product solution will absorb heat. This heat absorption causes vaporization of the water (solvent) in the product solution resulting in concentration of the product. The simplest evaporator is the single effect evaporator. If we assume the feed introduced into the single effect evaporator is at its boiling point, ignore radiation losses, and assume the steam into the heat exchanger is dry and saturated, then the heat transferred will correspond to the latent heat of vaporization. Therefore, one kilogram of condensing steam will produce one kilogram of evaporation. Economies in energy usage compared to the single effect evaporator can be made by using multiple effect evaporators, or vapor recompression evaporators.

Jan 1, 1993

By Vynne J. F

Drill monitors for blasthole and exploration drills have been available to the mining industry since the 1970s. The early monitors were pen strip chart recorders which were developed for the oil drilling industry and adapted to mining. They recorded drilling parameters such as depth, pull-down pressure, torque, RPM, and bailing air pressure. While these recorders could generate a large volume of paper, the amount of useful data was minimal. The data was not summarised and required an engineer to interrupt the chart traces. Being a mechanical recorder, the devices were also susceptible to frequent failures.

Jan 1, 1993

The investigations described in this paper aim at the development of a new impact mill. The objective is to produce particle size distributions below 10 .tm without using an air classifier. Circumferential rotor speeds of up to 200 m/s are strived for.

Jan 1, 1993

By A. F. Barsotti

Apart from jewelry, holistic apparel, and special collections of color and sometimes rare crystal specimens, the average layperson has little or no appreciation of the omnipresence of minerals or mineral derived products in the home. From concrete in the driveway to aspirins in the medicine cabinet, minerals, especially industrial minerals, play a major role in day to day living. For a better appreciation of this let's look into the a day of the life of a fellow named John, and see how much we depend on industrial minerals. The sounds of soft violins nudged John from his sleep. The melodic sounds of Beethoven's Pastoral coming from his radio alarm clock brought him out of his dreams. He reached for the reading light switch, then checked his watch--6:30 a.m., and another day of work. As he got up, the darkness outside reminding him of winter coincided with the soft voice of the all night disk jockey forecasting the fall of four inches of snow. Warm beads of water beating on his face removed all remnants of sleep and, like a stimulant, the morning shower brought thoughts of yesterday and plans for a new day. These carried over as he looked himself in the mirror while shaving and brushing his teeth.

Jan 1, 1993

By Jim A. King

The total pressure oxidation of copper concentrates is a potentially viable option for treating copper concentrates that are either low grade or contain significant impurities. Both concentrate types are heavily penalized in smelter contracts. The total pressure oxidation process involves autoclaving the copper concentrate at temperatures of 200-220 C under oxygen pressure. The autoclave discharge can be separated into a solid (oxidation residue) and a liquid (oxidation solution) product. The oxidation solution can be treated for copper recovery by solvent extraction - electrowinning or by direct electrowinning. The direct electrowinning recovery of copper requires prior removal of selenium and tellurium by cementation on finely divided scrap copper. The oxidation residue is washed thoroughly to remove acid and dissolved copper prior to precious metals recovery by conventional cyanidation in the presence of lime. The results of a benchscale investigation involving a number of copper concentrates are reported. Copper recoveries in autoclave oxidation and gold recoveries by cyanidation of the oxidation residue exceeded 99%. The results of benchscale experiments to demonstrate copper recovery are described. Various flowsheet options are presented.

Jan 1, 1993

By John J. Moore

This paper discusses the application of a video technique to construct stability diagrams for the combustion synthesis of ceramic-metal composites. Several model exothermic combustion synthesis reactions have been used to investigate the effect of the reaction parameters, eg. stoichiometry, green density, etc, on the stability of the propagating combustion reaction front and subsequent product morphology. The effect of varying the reactants and their stoichiometry to provide a range of reactant and product species ie. solids, liquids and gases, in the synthesis of both dense and expanded (foamed) ceramic and ceramic-metal composites was also investigated with respect to their corresponding combustion front stabilities.

Jan 1, 1993

By Gunter Swoboda, Harald Wagner

Until a few years ago tunnel construction was based exclusively on experience. In recent years, however, numerical models have increasingly become an integrated part of tunnel design [2]. These models permit good evaluation of the tunnel's support behavior even before it is designed. In particular, numerical methods are highly suited for the development of new construction methods. The prerequisite for this is the application of high-performance pre- and postprocessors, permitting the design engineer to come to a quick interpretation of the analysis results. In future, 3D analysis will take on increasing significance, for which reason this paper also deals with this type of models.

Jan 1, 1993

By Plamer D. J, Newman O. M G

The Effluent Treatment System at Pasminco Metals - EZ (PMEZ) was commissioned in December, 1991 and has operated satisfactorily, ensuring that aqueous discharges from PMEZ comply with the Tasmanian Environment Protection Act. The system treats both spills and run-off from the Zinc Plant, and acidic liquor generated in the gas cleaning section of the Sulphuric Acid Plant. The spills and run-off from the Zinc Plant are collected in a large catchment pond. The pond liquor, after partial neutralisation with sodium hydroxide to pH 4, and removal of suspended solids, is preferentially recycled to the Zinc Plant, for example, for washing of residues. Liquor which cannot be recycled, is treated in the Lime Neutralisation Section. The other input to the Lime Neutralisation Section is the acidic liquor from the Sulphuric Acid Plant from which mercury has been removed by contact with aluminium pellets in a fluidised column. In the Lime Neutralisation Section, the liquors are blended and neutralised to pH 10 by the addition of slaked lime. The heavy metals and most of the fluorine are precipitated. The precipitated solids are removed in a thickener with part of the thickener underflow being filtered. Most of the thickener underflow is recycled to generate solids that settle rapidly and filter well. The filter cake is returned to the Zinc Plant for the recovery of contained heavy metals while the thickener overflow is discharged to the Derwent River.

Jan 1, 1993

By D. R. Lanners

Samples of the same coal measure overburden spoil were obtained from three different mine sites. Site A used a 27-m3 tub-mounted dragline, Site S used a front-end loader and truck combination, and Site C used a 6-m3 crawler-mounted dragline. The spoils were analyzed in the laboratory for the strength parameters using drained triaxial tests conducted on 150-mm diameter specimens. Regression analysis was utilized to determine the appropriate failure criterion for the strength data from each site. Spoil obtained from Site S yielded higher shear strengths than Sites A and C.

Jan 1, 1993

By E. Bloomstein

The Lone Tree gold mine is located about 4S kilometers east from Winnemucca on the west flank of Lone Tree Hill in Humboldt County, Nevada. The deposit occurs at the north end of the low, rolling Havallah Hills and is about 1 kilometer south of Interstate Highway 80, in sections 11 and 14, Township 34 North, Range 42 East, Mount Diablo Base and Meridian (Fig. 1). The Lone Tree deposit is outside of any previously established mining district and all lands are owned or controlled by Santa Fe Pacific Gold or affiliated companies.

Jan 1, 1993

By K. N. Han, P. B. Queneau, A. Stojsic, M. J. Collins, V. J. Ketcham, R. M. G. S. Berezowsky, W. D. Vardill

The bulk of the ore found in the Lihir Island deposit is refractory in nature, with the gold contained in auriferous pyrite. In support of an evaluation of the development of this deposit by Kennecott (a wholly owned subsidiary of RTZ) and Niugini Mining Ltd., testwork has been carried out at the Sherritt Research Centre to demonstrate the amenability of the Lihir ore to pressure oxidation pretreatment to liberate the refractory gold. The results of pilot plant treatment of the Lihir ore in a continuous circuit with a feed rate of between 10 and 30 kg/h ore are described. The integrated circuit comprised pressure oxidation, residue washing, and gold recovery from the washed residue by carbon in leach or carbon in pulp cyanide leaching. Significant factors affecting gold recovery included temperature and retention time in the pressure oxidation step, and the concentration of soluble chloride in the feed. Gold extraction from well washed ore, after oxidation at 210°C for 66 minutes in the autoclave, was typically between 94 and 96%, compared with less than 30% by direct cyanidation.

Jan 1, 1993

By Koppe J. C

This study presents the procedure of mine modelling and reserve evaluation by means of statistics, computer interpolation methods and aerophotography interpretation. All data are from Carbonifera Treviso, Laura Muller City, Santa Catarina State, southernmost Brazil. From 22 bore holes and nine trenches opened in the coal seam outcrops, a data base including level references and thickness of all rock formations was created.Using this information, basic statistic analysis was carried out, showing that there are three different populations (three modal distribution). These populations defined three geological blocks with different characteristics of overburden removal and mining methodology. This mathematical approach for analysing geological data is very important for correct mine planning and complementary prospection.

Jan 1, 1993