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By Kristiansen J

A series of laboratory blasting and ball mill grinding tests have been done on four different types of hard and competent rocks. The results show that exposing these rock types to a higher level of explosive energy will enhance their grindability. True blasting optimisation should therefore look at the whole comminution process from solid rock to a marketable product.

Jan 1, 1995

By W. J. Wolfe

"Quartz Hill is a large, low- to moderate-grade quartz vein stockwork porphyry molybdenum deposit, discovered in 1974 during a regional stream sediment geochemical reconnaissance survey of southeast Alaska conducted by United States Borax and Chemical Corporation. Mineralization is localized in the upper parts of an Upper Oligocene (30 Ma) composite quartz monzonite stock which is emplaced discordantly into older Cretaceous to Early Tertiary terrain of the Coast Range igneous metamorphic complex of the northwest North American Cordillera. Subsequent fault-controlled, complex multi-stage intrusion, concentrated in the core of the Quartz Hill stock, produced successive pulses of hydrothermal alteration and molybdenum mineralization at about 27 Ma. Overall, the deposit is tabular and flat-lying and well suited to open pit mining. The 0.05% MoS2 grade limit covers an area of approximately 1500 m by 2750 m and extends to a maximum depth of 520 m below surface. Details of grade distribution show two separate lobes of higher grade material within the larger low-grade deposit.A ten year program of exploration drilling, underground development, sampling and metallurgical testwork led to a 1983 feasibility study based on a resource of 1600 million tonnes grading 0.127% MoS2 at a 0.08% MoS2 cutoff The large size of the deposit and its homogeneous grade distribution, typically showing gradual outward decrease of grade, makes in pit grade selection practical at several cutoff levels. Cominco Ltd. now reports a Probable Resource of 210 million tonnes averaging 0.22% MoS2 with a further Possible Resource of 1100 million tonnes averaging 0.12% MoS:z. At low molybdenum metal prices which have persisted for 10 years since the molybdenum price spike of the late 1970s and early 1980s, the Quartz Hill deposit is sub-economic."

Jan 1, 1995

The direct removal of lead ions from D2EHPA-kerosene using metallic zinc as the reducing agent was evaluated. The electrochemical process, called galvanic stripping, is a potential alternative stripping technique when standard chemical methods are not adequate. Four parameters found to be important in the rate of lead removal were studied in a factorially designed experiment. The variable evaluated included D2EHPA concentration, temperature, zinc surface area and solution agitation. Temperature and surface area were found to be the most significant, while agitation and D2EHPA concentration had less influence on the reaction. An activation energy of 22.5 Kcal/mole was calculated indicating a chemically-controlled process. The reaction was also sensitive to the concentration of oxygen in the system. The zinc required was considerably in excess of stoichiometry, possibly due to the dissolution and redeposition of lead: In general, the results were encouraging and demonstrated that lead impurities could be removed from D2EHPA using cementation type reactions.

Jan 1, 1995

By Byron T. Darnton

Gravity concentration at the Pegasus Gold/Montana Tunnels Mine, near Helena, MT, began in June 1991 when a coarse-gold-scalping circuit was commissioned. It processes a small portion of the ball-mill circulating load to reduce the risk of gold particles that are too coarse to float from advancing to flotation. The circuit also cost-effectively enhances overall gold recovery and payable gold ounces. This gravity circuit has been a major success. Since the circuit was commissioned, throughput has increased 30%. Several modifications and improvements were made during the last three years that allowed the gravity circuit to keep pace with the higher tonnage. The overall approach to gravity concentration at Montana Tunnels has always been to optimize production rather than maximize the gold ounces produced. This philosophy has now yielded a circuit expansion and relocation project. It will allow for an estimated 50% increase in gravity gold production, while significantly reducing the unit costs of production.

Jan 1, 1995

By X. Xie

The dissolution behavior of palladium powder in thiourea solutions has been studied. The variables studied included temperature, stirring speed, and concentrations of thiourea, acid and ferric ion. Palladium was found to be soluble in thiourea solutions in the presence of an oxidant such as ferric ion. The dissolution of palladium in thiourea solutions was found to be chemical reaction controlled with an apparent activation energy of about 2S.3 kJ/mol.

Jan 1, 1995

By H. L. Gibson, T. N. Setterfield, J. J. Watkins, R. W. Hodder

"The McDougall-Despina fault set in the Noranda district of northwestern Quebec defines the eastern margin of the Despina cauldron, nested within the district-scale Noranda cauldron. The faults are stratabound in that they displace stratigraphy of the cauldron fill, but do not off-set the cauldron cover. The faults are occupied by dikes that acted as eruptive centers to volcanic members of the cauldron-filling sequence. Measurable displacement across the McDougall-Despina fault set is greater than 750 m, and coincident with post-cauldron volcanism. Feeder dikes cross-cut each other and are typically depleted in Na2O and CaO, and enriched in MgO, K2O, Fe2O3and MnO relative to fresh flows. Economic and subeconomic massive sulfide deposits occur adjacent to the McDougall-Despina fault set at different levels over a stratigraphic thickness of 3000 m. These include the Corbet deposit, the subeconomic D-68 Zone deposits, and the subeconomic stringer zones of South Rusty Hill and Bedford Hill. Numerous copper occurrences and abundant hydrothermal alteration occur in and immediately adjacent to the fault set.The McDougall, Despina, and adjacent, parallel, ancillary faults define a synvolcanic fault set which controlled the location of magmatism, hydrothermal alteration and mineral deposition during the early evolution of the Noranda cauldron. Significant sulfide mineral deposition commonly occurred in proximity to the intersection of the McDougall-Despina fault set with northeast-trending synvolcanic faults. Recognition of synvolcanic faults is therefore a major objective of exploration programs for volcanic-associated massive sulfide deposits."

Jan 1, 1995

By Seedsman R. W

Good roads are essential in moving men and materials to and from the underground workplace. Coffey Partners International Pty Ltd (Coffey) has recently completed a underground coal industry funded project on underground mine road construction and maintenance. This paper discusses practical approaches to construction and maintenance of underground mine roads using transferrable civil technologies and innovative techniques. Mine pavements are generally low-cost (relative to civil roads), constructed to varying standards using locally available materials to best meet the mobility needs of the mine. Performance of pavements is thus largely dependent on the environmental conditions, quality of the available road making materials, maintenance policies and available resources. The paper will detail `what causes bad roads?' in various underground environments, available management strategies, construction and water control techniques, road maintenance and vehicle considerations.

Jan 1, 1995

By J E. Nethery

At the Red Dome and Mungana deposits in north Queensland, Australia, it is proposed that mineralisation and alteration developed as a 'telescoped' overprinting continuum, ranging in style from hypothermal to epithermal, reflecting the major changes that developed in the regional setting over the period circa 325 - 290 Ma. Regional assessment suggests that this also applies to many other precious and base metal deposits within a 40 km length of the host Siluro-Devonian Chillagoe Formation.   A ten stage paragenetic sequence of structural preparation, multi phase intrusion and associated mineralisation, alteration and brecciation is postulated for the Chillagoe district.

Jan 1, 1995

By C. Flores

A novel process using solid metals for the direct reduction of more noble metal ions from solvent extraction organics has been developed. Base metals recovery has been the principal focus of investigations to date but feasibility tests have now also been made on galvanically stripping selected precious metals. In this study gold (III) was loaded from an aqueous HAuCI4 .3H20 solution into a mixed organic 40 vol.% TBP, 10 vol. % D2EHPA in kerosene. The direct precipitation of metallic gold from the loaded organic phase using zinc powder and iron, aluminum and copper slabs at 70 °C was successfully demonstrated. The gold reduction rates were relatively fast even though the conductivity of the organic solutions is very low. The reaction rates were studied as a function of the variables zinc particulate size, oxygen and nitrogen atmosphere, water content in the organic phase, organic ratios and temperature. The gold morphology was usually powdery or dendritic in nature but continuous films were obtained in some instances. Activation energies were calculated and possible reaction mechanisms are discussed. In general, the results obtained were very promising and showed that gold can be successfully cemented from selected organic solvents by galvanic stripping using less noble solid metal reductants.

Jan 1, 1995

By Y. Ikeda

Typical electric appliances were dismantled into component pieces to study the recyclability of these discarded goods. Types and weight ratios of these component materials were investigated and characterized. The results showed that if they are dismantled properly, these goods could be classified into several groups of similar materials and/or structures, namely those consisting of single materials, metal-plastic combinations, metal-metal combinations and complex combinations of many different materials. By separating each combination into recyclable materials and isolating hazardous materials, it was found that the final waste for disposal could be reduced and the recycling efficiency could be improved markedly as compared to the conventional shredding method. The metal-metal combinations account for 60% by weight of the total metal contents in electric appliances, and therefore, it becomes important to segregate these metals. For the complex combinations, a process consisting of pyrolytic decomposition of plastic contaminants followed by smelting of the residue is proposed. It is anticipated that nearly zero-emission recycling of electric appliances will be achieved by applying this treatment process.

Jan 1, 1995

In order to fully understand why Amax Coal puts such extreme emphasis on the drilling and blasting programs at each of our mines, we must review the past. This paper will discuss the drilling and blasting techniques we used in the 1970s and their evolution to current practices. As time progressed, major changes influenced the surface mining of coal through new more restrictive governmental controls and local communities organising into groups with two goals in mind, one to shut down the mines and the second to try and get rich by making false and unjust damage suits against the mines. In virtually all of our midwest surface operations we have at one time or presently are facing litigation that has reached into the millions of dollars. Amax Coal has worked in co-operation with the United States Bureau of Mines in the areas of blast vibration, shot design, highwall safety, blast casting studies and many more. Today we are continuing to work with Dr David Siskind and his expert staff seeking answers to old and new problems addressing the blasting of overburden and parting seams.

Jan 1, 1995

By D T. Froedge

With successive generations of the Iso-Seismic System, we are acquiring more and more information about the actual behavior of blast induced ground, and airborne vibration, as it propagates through the environment. Some of the original “truths” that have been long accepted may have to be \revised.

Jan 1, 1995

Commodities statistics and other information are available through the following three systems: Internet Access: To access the USBM Gopher server on Internet, connect to: gopher.usbm.gov port 70, using gopher client software. Or contact the Systems Administrator for technical questions: Matt Klevemann, 412-892-6499 (klevemmc@miner.usbm.gov) These USBM materials are available on Internet, with more to come in the future: Publications and other research findings, including this bimonthly publications list, newsletters, tech transfer updates, environmental technology research, health and safety information. USBM software products Media materials and speeches. Mines Data: Computer bulletin board. Log on via modem through 202/501-0373, or call 202/501-0406 for technical assistance. Mines FaxBack Return fax service. 1. Use the touch-tone handset attached to your fax machine's telephone jack. (ISDN [digital] telephones cannot be used with fax machines.) 2. Dial 202/219-3644. 3. Listen to the menu options and punch in the number of your selection, using the touch-tone telephone. 4. After completing your selection, press the start button on your fax machine.

Jan 1, 1995

By S F. Simmons, J Fleming

Alteration and mineralisation at the Island Copper deposit is related to the intrusion of Early Jurassic quartz feldspar porphyry dykes into surrounding comagmatic Bonanza volcanic rocks. The pyrophyilite alteration zone forms an upward flaring cone, largely hosted within a breccia body that cross-cuts the Co, Mo, and Au-rich ore shell. This alteration zone contains pyrophyllite, dumortierite and diaspore and resembles alteration occurring in some high-sulfidation deposits, but which is barren. Fluid-mineral equilibria and fluid inclusion studies indicate formation at approximately 300 ¦C from fluids dominated by steam and gases. These fluids appear highly acidic, but sulfur poor, leading to extreme base leaching within the breccia body and surrounding rocks.

Jan 1, 1995

In all the industries that require blasting operations using explosives, there exists numerous unwanted side effects of the blast which may pose as environmental hazards. These hazards face prominence, especially in India, where there are very stringent rules and regulations governing the use of explosives. The environmental hazards associated with blasting operations as a whole can be tacked successfully to a certain extent depending upon the ultimate expectations of ,the post-blast effects and the limitations of the environmental obligations as specified by the authorities from time to time and from place to place. The main parameters which require attention to limit the post-blast results to the optimum level are ground vibrations, dust pollution, gas pollution, air blast effects, noise pollution & fly rocks etc.

Jan 1, 1995

By . Menad Gaballah I

Three samples of solid wastes generated by the non ferrous metallurgy were characterized. These residues contain up to 42 % of valuable metal compounds ( Cu, Pb and Zn ) and 23 %of toxic compounds t As, Hg, Cd and Se ). These sample were subjected to thermal treatments between 200 DC and 800 °C in controlled oxidizing. reducing and chlorinating atmospheres. Up to 99 % of As, Cd, Hg and Se were eliminated from these industrial wastes. Cu, Pb, and Zn compounds were concentrated in the treatments' residues of these samples. A Global Decontamination Factor' GDF ' was defined to measure the efficiency of the elimination of toxic elements and the recovery of valuable elements for a specific sample submitted to a given treatment. It seems that the thermal treatment in a reducing atmosphere was the most efficient in decontaminating these solids and the concentration of valuable elements. a.

Jan 1, 1995

By Lars Arne Granlund

Due to the coarse structure of mining explosives, one has to model a finite reaction zone,contrary to C-J calculations, describing their detonations, i.e they become dependent of diameter and confinement, An effort within the DYNO group has been to investigate if the DSD theory ( originally developed by Bdzil, Stewart / Los Alamos ) can be used to describe major groups of civil explosives.The groups of explosives tested are dynamite, anfo, aluminised emulsion, heavy anfo and straight emulsions.

Jan 1, 1995

By Jack Eloranta

This paper documents the relationship between material handling and processing coete compared to blasting cost. The old adage, "The cheapest crushing is done in the pit", appears accurate in this c!ase study. Comparison of the accumulated cost of: powder, selected wear materials and electricity; indicate a strong. inverse correlation with powder factor (lbe powder/long ton of rock). In this case, the increased powder cost is more than offset by electrical savings alone.

Jan 1, 1995

By G. L. Watt

Fine sized titanium diboride (TiB2) powders have been synthesized in a thermal plasma reactor. Precursor for the synthesis were rutile, boron oxide, and methane. The effect of plasma gas type, precursor ratio, and input power on the synthesis was studied. The produced powders were characterized by X-ray diffraction and chemical analysis. The purified powders were CIP'd, HIP'd, sintered and characterized for porosity, hardness, and microstructure and the results compared with a commercially available TiB2 powder sample.

Jan 1, 1995

By J. G. Groppo

In 1992, 48 million tons of fly ash (not including bottom ash, boiler slag and FGD material) was produced in the United States, according to the American Coal Ash Association. Of this amount, 27.2% was utilized; although the percentage of fly ash utilized increased from 20% in 1980, there is significant potential to increase utilization. One of the primary driving forces behind increased utilization is increased disposal costs due to more stringent environmental controls and regulation. Fly ash is classified as a natural pozzolan and finds significant use as a cement additive. It has been found to increase the plasticity of the cement mixture while lowering the amount of mix water needed. In addition to improving leveling and finishing properties, fly ash improves pumpability as well as decreases the heat of hydration of the concrete mix which is particularly important in massive concrete structures such as dams where the concrete needs to cool as quickly as possible. The Loss on Ignition (LOI) of fly ash is an important quality when considering utilization. The LOI is primarily due to the presence of unburned carbon and the standard specifications for the use of fly ash as a mineral admixture in Portland cement concrete are given in ASTM C618-89a. which sets an LOI limit of 6%. However, many states have set a more stringent limit of 3%. The primary reason for the lower LOI specification is that carbon adsorbs air entraining agents which limits freeze-thaw resistance. This is particularly important in climates such as the midwestern US where multiple cycles of freezing and thawing are typical in winter.

Jan 1, 1995