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By Gregory A. Knapp

Treatment of industrial wastewaters generally advances with specific chemical concentration and mass-flow targets, established by National Pollutant Discharge Elimination System (NPDES) permits. Treated discharges must also address toxicity to test and receiving water organisms. Various parameters might need consideration during treatment design and planning, such as the known toxicants, hardness, alkalinity, solids, nutrients, metals in both the dissolved and particulate state, and even flow. Since toxicity is used as a "catch all" regulatory monitoring tool, design of treatment systems should focus on the various factors contributing to toxicity.

Jan 1, 1996

By Peter Bates

"HIsmelt has faced and overcome many challenges in the understanding and development of injection technologies that satisfy process and engineering requirements for further scale up to a commercial plant.An overview of the design basis of bottom and top injection systems with plant results are described in this paper.IntroductionAn appropriate way to introduce this paper is to initially reflect on the genesis of the HIsmelt Process.It is appropriate that Professor Womer is the one we are honouring as it can be claimed that by the involvement of CRA in the WORCRA process that the concepts for irijection systems in iron and steel pyrometallurgical processes achieved significant attention by the company. The development of water cooled injection lances and their application injecting solids and gases with success was certainly a pre-cursor to the development of other injection systems commonly used today in arc furnaces and for top injection at HIsmelt.HistOrically it was the work of Savard and Lee in Canada with shrouded tuyeres and the subsequent commercialisation of this technology at the Maxhiitte Steelworks spawning the suite of bottom oxygen blown process as known as QBOP; OBM and the subsequent combined blowing process such as KOBM that first commercially succeeded in injecting solids under a molten metal bath. The next progressive step from the injection of calcined lime in the technology development was the injection of coal for coal gasification as developed by Klöckner technologies being called KG, KSG and KMS and also the injection of coal for increased scrap melting.A paradigm shift in thought process to leap from steelmaking and coal gasification to direct smelting by injecting coal and iron ore into a molten metal bath in the correct stoichiometric ratio to maintain the bath at a constant temperature and carbon level was the true genesis .of HIsmelt.A good overview of the state of the art of tuyere type injection technology is given in Ref. 1."

Jan 1, 1996

By Milton Blander

A review of concepts and theories for predicting thermodynamic solution properties of multi- component high temperature liquid solutions is reviewed. During the last 50 years the ability to predict :such properties for molten salts, silicates and metals based on the generally known properties of the lower order (often binary) systems has been developed and shown to provide predictions which are quite useful in science and technology. There are many gaps in our understanding of these high temperature solutions, especially for metals, and considerably more work is needed.

Jan 1, 1996

By Ljiljana Solujic

The need for the removal of mercury from the precious metals extraction circuits may be influenced by process, environmental, as well as by occupational hazard reasons. In these circuits mercury is mainly present as cyanide complexes. The effectiveness of any stabilization method will be influenced by the high thermodynamic stability mercury-cyano species exhibit in an aqueous solution. In this study, we have investigated the utility of the trisodium salt of trimmercapto-s-triazine (TMT) for precipitation of mercury from the corresponding cyano-complexes. The influence of pH molar ratio of TMT to Hg, coagulant and flocculant additions, excess of free cyanide, as well as the presence of other metal-cyano species on the effectiveness of mercury precipitation were investigated in detail. Also, a "teal world" precious metals mill effluent initially containing ~7 ug/mL (ppm) of Hg was treated and A was found that greater than 99.8% of the mercury was removed from the solution as am insoluble Hg/TMT complex.

Jan 1, 1996

By S. D. Bearden

China was the world’s leading producer of barite during 1995 with 35%. The United States followed with14%. India produced 9%. Other producers included Morocco, Turkey, Mexico and Germany. Domestic production of barite during 1995 was estimated to be 600 kt (660,000 st). Nevada produced 85% of the total. Georgia was the second leading barite-producing state. The United States is the world’s largest consumer of barite. During 1995, it used 1.6 Mt (1.8 million st). US reliance on imported barite during 1995 was about 63%of total consumption, according to the US Geological Survey.

Jan 1, 1996

The results of about 30 years of exploration and mining activities and research studies in the Kambalda mining district, Western Australia, have led to general agreement that the komatiite-associated Ni sulphide ores formed as a result of igneous processes (Ross, 1974; Ross and Hopkins, 1975; Gresham and Loftus-Hills, 1981; Cowden, 1988; Lesher, 1989 and many others). Despite this agreement, the controls on sulphide supersaturation and concentration of the resulting sulphide in a limited zone, remain uncertain and controversial. A major uncertainty is the source of sulphur in the ore deposits. Two principal sulphur sources have been proposed: 1. komatiite lava/magma (Hudson, 1972; Naldrett, 1973; Lesher et al, 1981; Cowden, 1988; Foster et at, 1995), and 2. sedimentary material (Groves, Barrett and McQueen, 1979; Lesher, Arndt and Groves, 1984; Lesher, 1989; Lesher and Campbell, 1993). Resolution of the uncertainty regarding the sulphur source is required for a complete understanding of the controls on ore formation, which in turn would significantly impact exploration strategies in the Kambalda mining district and elsewhere. This paper reviews the constraints on sulphur sources for the komatiite-associated Ni sulphide ores in the Kambalda mining district. The focus is on the general characteristics of the ores and surrounding rocks: individual ore deposits are not described, though specific examples are noted where appropriate. The stratigraphic and volcanic settings and geochemical (major and trace element and isotopic compositions) characteristics of the ore deposits and surrounding rocks are considered within the context of the competing sulphur source models, and future directions of research in the district are noted.

Jan 1, 1996

By Rainer Kahrger

During the last decade, advances were made in solvent extraction/electrowinning (SX/EW) technologies. Combined with heap leaching, these technologies made it viable to exploit large, low-grade oxide copper deposits. The El Abra Mine is a good example for such a deposit. The deposit is situated in northern Chile at an elevation of about 4,000 m (14,000ft), 70 km (45 miles) north of Calama. Codelco sold 51% of the El Abra to Cyprus Minerals in June 1994, with Codelco retaining the balance. In 1993, Cyprus and the engineer on the project began discussions withinternational companies regarding the materials-handling system requiredfor the project. These early discussions were considered critical for this fast-track project.

Jan 1, 1996

By K. Mallikarjuna Rao

There are several methods available to estimate deflection and ultimate Capacity of laterally loaded piles. In this investigation an attempt has been made to verify the existing methods for prediction of ultimate lateral resistance and deflection with the laboratory and field test results reported in the literature. A 75 pile loading test data obtained from the literature was used to evaluate two methods designed to predict the ultimate lateral resistance of rigid piles and three methods designed to predict the lateral deflections of rigid piles and four methods designed to predict the lateral deflection of flexible piles subjected to lateral loads. The accuracy and precision of each method is quantified statistically. The statistical results of the overall analysis indicate that the mean values of the ratios of predicted to measured lateral capacities vary from 0.62 to 1.14 with an average of 0.88. However, the settlement predictions were much more widely scattered than the ultimate load predictions and in general all the methods have a tendency to under predict the deflections. A new method is proposed by modifying the Broms's method to estimate the lateral deflections of free headed rigid and flexible piles separately. The proposed modified methods were found to be reasonably good in comparison to existing methods and to overestimate deflections.

Jan 1, 1996

By S. M. Grillo, Fiori. M., R. Bornioli, C. Marini, S. Fadda

Abstract - The Na-feldspar orebodies in Sardinia occur along structures belonging to a regional ENE-WSW system that developed during the late stages of the Hercynian orogeny, and that was reactived during the Alpine orogeny. The main petrographic facies include granitoids, albitized granitoids, albitites (more or less rich in quartz), and albitites containing Mg minerals. Field observations and petrological and geochemical data point toward a metasomatic origin for the albitite orebodies. Albitization involved depletion of K from K-feldspar and biotite, dissolution of free quartz, and a lowering of Sr/Na2O and CaO/Na2O ratios in the protolith, under conditions of a positive thermal gradient. The absence of later K-metasomatism implies that, during a subsequent decline in temper- ature, the composition of the albitizing fluids was modified by an influx of meteoric or other waters.

Jan 1, 1996

By Braaksma M, Dudley K

The Girilambone Copper Mine is located in central New South Wales and has been operational since May 1993. Girilambone is operated by the Girilambone Copper Company (GCC) which is a joint venture between Straits Resources (60 per cent) and Nord Resources (40 per cent). The mine complex consists of an open cut pit, ore crushing and stacking, heap leaching, solvent extraction (SX) and electrowinning (EW) allowing for the recovery of 14 600 tpa of LME grade A cathode copper. The leaching and SX-EW plant have been described previously by Rear, Taylor and Busby (1994) and Miller (1994).

Jan 1, 1996

By G. M. Bernard

The Andacollo gold mine is located near the small town of Andacollo, Chile (population 14,000) in the fourth region. It is approximately 35 miles by paved road from the coastal city of La Serena, and Santiago lies about 300 miles to the south (see map.) Site elevation varies between 3300 feet and 4200 feet. The climate at the site is moderate but arid, with an average annual rainfall of only five inches. Because there is little rain, and the temperature varies only a few degrees (57"F to 75°F); there are no freezing, solution dilution, or pad saturation problems. The climatic conditions are ideal for heap leaching.

Jan 1, 1996

By C. C. Harvey

Asia is experiencing a growth market for industrial kaolins for use in ceramics, paper, plastics and other market sectors. Export and import data for the Asian countries reflects this growth with the Peoples Republic of China as the major exporter of clays and Japan the major importer. The growth in tonnage and product sophistication of kaolins produced on Belitung in Indonesia is typical of developments that are taking place in many locations in Asia. This region therefore presents opportunities for mineral processors and a challenge for the exploration geologist, the mineral processing engineer, the mineral economist and the marketing specialist.

Jan 1, 1996

By Louis J. Mittoni

"It is well known that gas injection systems can exhibit a wide range of dynamical behaviours, ranging from linear periodic bubbling through to highly complex turbulent jetting. Recently, it has been observed that an important intermediate regime exists under certain system conditions, where the dynamics are complex in nature yet predictable for short time periods. This paper reviews the evidence to support the above hypothesis, and discusses the invariant quantitative measures such as density, return maps, Lyapunov exponent and dimension which may be used as pattern recognition features in a mOnitoring and control strategy.INTRODUCTIONThere has been a great deal of research on the submerged injection of gases into liquids. This interest is primarily due to the large number of applications in the pyrometallurgical and chemical engineering industries. Gases are typically injected into liquids to achieve goals such as heat and mass transfer, or physical mixing and agitation. Only recently though has the possibility of using the evolution of the gas dynamics as a probe to internal system conditions been raised [1, 2].At very low gas injection rates and small upstream chamber volumes, gas normally disperses in the form of stable bubbles of constant volume [3]. With increases in gas flow rate, the dynamics become more complex, bifurcating into double bubbling, multiple bubbling and complex coalescence behaviour. Irregularities measured in pressuretime series acquired upstream of the injection port under these complex conditions have usually been treated as bothersome noise or contamination to be filtered from the signal and ignored in the analysis. These irregularities, however, may contain physically interesting and useful information on the system from which they were produced if the system may be classified as deterministically chaotic [4]."

Jan 1, 1996

By Mark S. Stagg, David E. Siskind

The mining industry occasionally blasts near pressurized transmission pipelines and has requested guidance of safe vibration levels and setback distances. the Bureau of Mines and the Indiana Department of Natural Resources cooperated with AMAX Coal Company on a study of coal mine overburden blasting. Five buried and pressurized 250-ft pipeline sections were specifically installed on the Minnehaha Mine highwall near Sullivan, IN for testing to failure. Four welded steel pipes ranging from 6- to 20- in diameter and one 8- PVC water supply pipe were monitored for vibration, strain, and internal pressure for a period of 6 months while production blasting advanced up to the pipeline field. In contrast to previous studies of small-scale blasting representing construction activities, these tests involved overburden blasts of up to 2100 lb per delay in 12-l/4-in diameter holes.

Jan 1, 1996

By D. A. Donato

It is often necessary for a mining company to extract coal from a seam underlying a previously mined coal seam. The impact of the overlying mine workings on the stress distribution within the underlying mine workings is very difficult to assess without the use of numerical modeling techniques. This paper demonstrates the usefulness of applying numerical modeling to evaluate alternate startup-room locations for a longwall panel considering the effects of multiple seam interaction. MULSIMIPC, a code adapted by the former U. S. Bureau of Mines, was used to compare stress patterns in two proposed startup-room locations. These model results were not only compared to each other, but also to results from a model with no overlying mine workings to provide baseline criteria for evaluation of the two proposed startup-room locations. The numerical modeling study was successful in providing useful information to the coal company and the regulatory agency (MSHA), resulting in a mine design that was both safe and efficient, and prevented the sterilization of a large volume of coal reserves.

Jan 1, 1996

By M. K. Rizkalla

This paper discusses the time-dependent behaviour of rock when it involves the presence of several layers of rock strata in the vicinity of mine openings, mining in sequences and the placement of backfill. The paper describes numerical techniques which proved useful when such situations are encountered in practice. The model is elastoviscoplastic. At given time stations, short term loading or changes can be made to the creep behavior of the rock. The modelling technique is first described and is followed by simulations of stresses and displacements in a potash mine with the primary objective to demonstrate the effect of such aspects as mining and fill sequences in 3-D. This involves cutting finite elements representing the strip of the mining face and simultaneously filling those elements representing the newly placed fill. The stiffness of the fill varies with the degree of compaction at each point. In this way, the effect of the time of fill placement, the gap between the top of the fill and the back as well as the degree of compaction are simulated. The second example is a 2-D problem simulating the long term effect of backfill, as a material compacting with time, on the settlement of the layers above it as well as the closure of the room.

Jan 1, 1996

By Sui Xue

A process has been developed from laboratory-scale experiments for the aqueous processing of various lead-bearing wastes. The process exploits the limited solubility of lead in sulfate-rich solutions to effectively separate lead from other metals. The lead sulfate is then completely converted to lead carbonate using sodium carbonate and ammonium carbonate. The effectiveness of this conversion was observed to be sensitive to the solution pH and carbonate concentration. The final stage of the process uses low temperature calcination of the lead carbonate to form PbO. Yellow lead oxide (massicot) is readily formed if calcination is conducted at a temperature at or iibove 50G°C, wlule red iead oxide (iitharge) is formed at temperatures near 450°?C. A complete economical analysis of the process will be discussed.

Jan 1, 1996

By Gudrun A. Saevarsdotti

For decades tile aluminium industry has been practicing gas treatment of aluminium melts. This treatment is of great importance because of its influence on 'impurity" and inclusion removal from the melt. The gas-melt interaction is greatly influenced by the gas composition, melt temperature etc. This paper gives an overview of the interaction between argon-chlorine gas mixtures and the aluminium melt. It covers the thermodynamics of the reaction between the chlorine and a number of different elements commonly found in liquid aluminium, and discusses the behaviour of reaction products in the melt. The paper reports an experimental study of the behaviour of the chlorine-molten aluminium interface, using sodium contaminated aluminium melt with and without the addition of grain refiner.

Jan 1, 1996

By A. J. Basu

Geotechnical design plays a key role in mine design. I A proper geotechnical design provides a safe working environment and facilitates efficient mining operation. There are mainly three design approaches I) judgmental, based on observational and experiential facts, 2) empirical, based on empirical design formulae, and 3) analytical, incorporating numerical analysis. Most design applications are based on the design methods one and two as mentioned earlier. However, complexities arise in deep underground mining operations and deep open pit mines. These complexities and difficult geological environment introduce more uncertainties and simple empirical formulae would not be adequate as a design tool. These situations require numerical modelling and analysis of the design problems including interpretation of the results obtained from the analysis. There are several tools available for performing the numerical modelling and analysis. A brief review of the available tools was addressed earlier (Basu and Kuruppu, 1995). The authors selected ANSYS (a general purpose finite element analysis tool) for use in mining geomechanics and geotechnical design. This paper includes several examples demonstrating the applicability of this software in designing structures applicable to mining geomechnics. The authors hope that the design examples will demonstrate the use of the numerical modelling and analysis application in excavation design.

Jan 1, 1996

By Virendra Singh

The load settlement behaviour of single pile or pile group may be obtained using computer based methods such as the finite or boundary element techniques. An alternative method of obtaining the vertical soil stresses adjacent to the Pile is presented Based on calculated stresses consolidation settlement for Piles foundation is obtained. This approach may be computationally more attractive than the more general finite or boundary element techniques.

Jan 1, 1996