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The paper discusses the special mixing requirements for Metallurgical Plant Design and outlines the problems associated with the agitation in Mineral Processing Industry today. It also covers new applications such as state of the art large leach tanks and backfill for deep mining.

Jan 1, 2004

Published experimental data on thermodynamic behaviour of cobalt-containing slags have been reviewed and used in validating a recently developed thermodynamic model. The results from the exercise show that the model provides a reasonably good description of behaviour of cobalt in multi-component slag systems. The models for cobalt containing slags, matte and oxide solid solution phases were incorporated into CSIRO?s multi-phase equilibrium (MPE) package, which was used to calculate the equilibrium distribution of cobalt between matte and slag phases under various conditions. The results agreed well with the experimental data. Furthermore, the good agreement between the calculation and the plant data indicates that the operating conditions of industrial smelting and converting processes are close to equilibrium. Two diagrams showing the effects of slag chemistry and SO2and O2partial pressures on the distribution of cobalt between phases were generated for conditions similar to smelting and converting processes. These diagrams provide some useful guidelines for developing new strategies to improve cobalt recovery.

Jan 1, 2004

By Cory J. E. Yacyshyn

Anchored steel pipe piles are being used more frequently in British Columbia for shoreline projects such as public ferries, cruise ship docks, containership terminals and locally in the expansion of the Vancouver waterfront convention center. While a 36? diameter driven pile may provide adequate compression loads it will not always achieve enough penetration to provide the required tension loading. That is why bundles of threaded anchors or strands are drilled through the center, past the pile tip, and anchored into the underlying strata. Drilling up to 250 feet deep through the piles in variable water bearing strata presents challenges. Southwest Contacting Ltd. (SWC) recently completed the three largest anchored pile projects in BC; Vancouver Port and Convention Center Expansion, Vanterm Container Terminal and the new Prince Rupert Cruise Ship Terminal. This paper will present the separate challenges encountered drilling the anchors. At Prince Rupert, the recently completed Northland Cruise Ship Dock ultimately required a cased system to drill and install triple thread bar anchors. When 200 foot long steel pipe piling was unable to penetrate the highly fractured gneiss/schist bedrock to obtain a seal and consolidation grouting was unsuccessful, a modified cased system was advanced deep enough into the rock to eventually seal. The 3-#20 bars were changed to 12-strands since the bars wouldn?t fit through the smaller cased hole. The options were limited because each dolphin only had enough room for a small hydraulic drill rig that wouldn?t have the power to fully case the holes. The Canada Place Pier Extension in Vancouver?s Harbor led to the development of an innovative tip design used later at Vanterm. The 36? diameter steel pipe piles were driven closed end but modified to permit drilling through a concrete plug at the base. The driving of the piles at Canada Place often knocked out the plug so we were faced with 50 feet of sand up inside the pile when the drilling started. This led to discussions on how to safely remove the sand, solidify the tip, and continue drilling to get past the tip without undermining the pile. Finally, Vanterm Berth Extension was completed with a unique drilling system because the pile tips stopped in hydraulic sands, as opposed to the native till. We were faced with advancing the casing to the till without undermining the base of the pile. With 100 psi water pressure at the pile base after we broke through the concrete plug, the trick was to prevent charging the sand with our 250 psi air which liquefies it and forced it up our drill casing. And of course, it has to happen just before Christmas holidays!

Jan 1, 2004

By T. Gerritsen, R. C. Delgado, J. Janzen, E. R. Veloza

The paper describes the components of an Integrated Furnace Control system for covered-arc (shielded arc) smelting with results from the recently started 75 MW Cerro Matoso Line 2 Furnace. The paper starts with a review of the mechanisms of power and feed input and heat losses in the shielded-arc smelting process, and describes how the details of the control system are tailored to the process. The control modules of a covered-arc smelting furnace are described including measured results and screen captures. This paper focuses on Integrated Furnace Controls tailored to shielded-arc smelting, but similar approaches have been recently applied to other furnace processes including immersed-arc smelting.

Jan 1, 2004

By L. Holappa

Ferroalloys like FeCr and FeMn are mostly produced in submerged electric arc furnaces. Typical of these processes is that the amount of slag is quite high. The role of slag for the process is thus essential and specific chemical, physical and electrical properties are required. Slags in FeCr process are Al2O3-MgO-SiO2 based with minor contents of CaO and CrOx. Slags in the FeMn process are principally similar, originating from silicate minerals but can have quite large composition range depending on the manganese ore and its gangue minerals. Characteristic of the FeMn process is that the slag is rich in manganese oxide up to above 30%. A common feature is that the ?ore oxides?, CrOx and MnOx in slag are not only divalent oxides but also contain some higher valent of Cr3+and Mn3+, respectively. In FeMn production conditions the slag consists mainly of Mn2+. This is a clear difference from CrOx containing slags in which both two and three valent coexist in slags in FeCr process conditions. Oxidation state of the slag depends on the ambient oxygen partial pressure and temperature in the examined process. The thermodynamics of slags in ferroalloys, production are discussed in terms of phase diagrams, activities and oxidation state of chromium and manganese oxides. Further, slag properties influencing reduction kinetics and furnace operation i.e. viscosity and electrical resistivity are discussed. Keywords: review, slags, ferroalloys, ferrochromium, ferromanganese, thermodynamics, physical properties

Jan 1, 2004

Experimental studies on viscosity of titanium bearing slags have been reviewed and the assessed data were used in extending the capability of the structurally related viscosity model for silicate melts, developed by the present authors. Experimental data on ternary and higher order systems containing CaO, MgO, MnO, FeO, Al2O3, TiO2, Ti2O3, SiO2were assessed and used. The newly extended viscosity model represented the viscosity behaviour over broad temperature and composition ranges. The structural role played by TiO2and Ti2O3in silicate network structure is discussed with respect to their effect on viscosity of melts. Keywords: viscosity model, TiOx containing silicate melts, silicate network structure.

Jan 1, 2004

By A. Lopez-Valdivieso

Particle size enlargement processes play an important role in solid/liquid separation, and in beneficiation unit operations. In the latter, not only the size of the formed aggregates but also their surface properties are very important. Oil agglomeration has a special place among such processes: it is a selective process in which hydrophobic particles are agglomerated into hydrophobic agglomerates which can be recovered by flotation. This explains the broad applications of oil-assisted beneficiation processes not only in the beneficiation of fine coal, but also in agglomerate flotation of many different types of ores, and in coal/gold agglomeration.

Jan 1, 2004

By H. Saroglou

The anisotropic behaviour of Athens Schist has been brought out through the testing of specimens with varying orientation of schistosity with respect to the major principal stress under uniaxial, triaxial and dynamic conditions. A large number of results from tests on intact rock specimens of the Athens Schist were statistically analysed and evaluated.

Jan 1, 2004

By R. M. Tyler

The importance of the heavy mineral sands to southern African economic well-being cannot be over emphasized. The value of the worldwide titanium dioxide industry is estimated at $7 billion. Six out of eight of the world?s proposed new project areas are in southern and eastern Africa, and a seventh at Tamil Nadu in India is partly owned by a South African company, Kumba Resources. The HMS industry can be highly lucrative; its return on capital is the best in the mining industry. There are, however, problems, particularly in the smelting technology. The often considerable affect of mining on environmentally sensitive coastal dunes is also becoming increasingly important. The medium-to long-term demand for Ti-dioxide pigment and ceramic grade zircon appears very healthy. If, as predicted, the costs of producing titanium metal can be reduced, then there is huge potential for the metal. In summary, the HMS industry is an attractive one to be in, with good returns and generally manageable risks. New business opportunities and their economic implications for Africa are discussed.

Jan 1, 2004

By David Ziegler

Rough sketches, field notes, an on-site conference or a phone call may no longer suffice to establish your blast plan at a job site. More and more, general contractors, site supervisors, owner re p resentatives, or the owners themselves want to know details about proposed drill and blast operations at their site, in advance. We are seeing more contracts that re q u i re a blasting plan to be submitted in writing. The purpose of this session is to discuss items that you might want to include and address in a written blast plan, and some ideas about how to present them. This is not intended to be a complete list of items that could be included in a blast plan. Contracts may list specific items that need to be addressed. Only a few of the more common elements will be covered here. The bro a der purpose of this discussion is to get you thinking, about what you might want to include in your own “standard ” blast plan.

Jan 1, 2004

By B. Stettner, J. Asante, S. Abraham

The levels of nitrogen in steel produced in various metallurgical vessels vary significantly. For example, the tap nitrogen levels in steel produced in the BOF are around 4Oppm, as compared to 70-100ppm in both DC and AC electric arc furnaces. Given the pressing need to reduce nitrogen levels in steel to satisfy customer demand, IPSCO Inc. has gained considerable experience in controlling nitrogen levels in steel over the course of the last three years. Hence, a cost effective process has been developed through an intensive nitrogen control program from steel melting in the EAF through to the continuous slab casting stage. This paper describes the practices employed at each stage of the steelmaking process that have enabled IPSCO Inc. to reduce and control nitrogen levels in steel.

Jan 1, 2004

By G. van den Berg

Anglo Platinum has initiated a project to investigate hydraulic hoisting technology for platinum mines. Hydraulic hoisting systems are categorized as pumping, fluidizing feeder or displacement feeder systems. Positive displacement piston diaphragm pumps are most suitable for pumping systems but they require that the ore be milled prior to pumping. Fluidizing feeders are unsuitable for platinum ore applications due to the large percentage of fines in the ore. The three-chamber pipe displacement feeder has been most widely used for hydraulic hoisting and is the most suitable technology for platinum mines. Eight hydraulic hoisting applications covering pumping and displacement feeder technologies are reviewed. The key factors to be assessed in selecting a hydraulic hoisting system for a platinum mine are discussed. A typical platinum mine configuration will comprise an ore preparation plant (to produce -15 mm material through screening or crushing), motive water pump on surface, high pressure water pipeline from surface to underground, ore slurrification plant, three-chamber displacement feeder, and a high pressure slurry pipeline to surface. The water and slurry pipelines are housed in a purpose drilled borehole. A hydraulic hoisting system selection chart is presented. A 150 mm diameter system with a 25 MPa pressure rating is required to hoist 60 000 t/m from a depth of 1 200 m. Generic capital and operating costs are presented . A major potential advantage of hydraulic hoisting is that the fines, which contain a high percentage of PGMs, are captured underground and transported directly to the concentrator. Hydraulic hoisting technology is ideally suited to providing supplementary hoisting capacity to existing shafts that have reached the skip hoisting capacity limit. The main advantage for new shafts is the potential to significantly simplify underground rock handling and transportation. All hydraulic hoisting system components are proven. The only risk area is the wear rates of the valves and piping. Current estimates are based on gold ore. The business cases investigated show that the financial viability of the installations are not sensitive to wear rate. Hydraulic hoisting is technically feasible and financially attractive for platinum mines. Keywords: Hydraulic hoisting, slurry

Jan 1, 2004

By A. M. Abdel-Rehim

The present work reports a study of production of thorium concentrate from Egyptian monazite by decomposition of ammonium carbonate solutions containing ammonium thorium and uranyl carbonate complexes. These solutions were obtained from the processing of monazite by alkaline leaching in ball-mill autoclaves, followed by selective separation of thorium and uranium from lanthanides by autoclave leaching of the hydroxide cake obtained with ammonium carbonate - bicarbonate solutions. The separation of thorium and uranium in the form of thorium concentrate from their carbonate complexes was achieved by different methods, including neutralization of solutions at pH = 6.7 by acid, addition of alkali at pH = 11.5, heating of solution at 100°C and processing of carbonate solution with steam under pressure in steel autoclaves. Processing of solutions of thorium and uranyl carbonate complexes in an autoclave with steam causes their decomposition. Complete recovery of thorium 99.8% and 98.4% uranium recovery in thorium concentrate was attained at 120°C and steam pressure 2 atm, within 10 min. Meanwhile, the recovery of lanthanides was low and did not exceed 1.1%. The thorium concentrate produced contains 67.82% Th, 4.6% U and 3.14% REE. All methods achieve complete separation of thorium and uranium from their carbonate solutions, but the first two methods are unfavourable for the industry due to the high cost of reagents and their inability to regenerate the ammonium carbonate. The decomposition of ammonium thorium and uranyl carbonate complexes with steam under pressure is recommended for industrial application for its simplicity and the ability to regenerate the ammonium carbonate.

Jan 1, 2004

By J. Stiksma, K. Buban, J. Oftsie, R. Kalanchey, S. Sadykov, E. McConaghy

The Kazakhmys zinc refinery in Balkhash, Kazakhstan, which employs the Dynatec Zinc Pressure Leach Process, officially launched autoclave operations on December 27, 2003. The Kazakhmys plant is the world's first greenfields zinc refinery based on Dynatec's two-stage pressure leach technology. Production of zinc was realized on February 9, 2004, when the first cathode was stripped. Currently the plant start-up is ongoing, with progression to two-stage zinc pressure leach operation and ramp-up to full design capacity continuing through 2004.

Jan 1, 2004

By Walter E. Vanderpool

Three drilled foundations for an elevated water-tank were instrumented, tested and monitored during construction and the first two years in service. One shaft was load tested by the Osterberg method. A void was detected in one shaft by cross-hole sonic logging, pulse-echo logging and concrete coring. The void was instrumented, hydrostatically tested and pressure grouted. The shaft was ?abandoned? and replaced by two smaller shafts with a straddle beam cap. One of the replacement shafts and the cap were instrumented. The strain that appeared in the abandoned shaft, the replacement shaft and the cap were monitored during the remainder of the construction, through the commissioning test and the first two years of service. The results demonstrate the precision and sensitivity of the vibrating wire strain gage.

Jan 1, 2004

By R. Hansson

Zincite and spinel phases are present in the complex slag systems encountered in zinc/lead sintering and zinc smelting processes. These phases form extensive solid solutions and are stable over a wide range of compositions, temperatures and oxygen partial pressures. Accurate information on the stability of these phases is required in order to develop thermodynamic models of these slag systems. Phase equilibria in the Fe-Zn-O system have been experimentally studied for a range of conditions, between 900 and 1580°C and oxygen partial pressures (pO2) between air and metallic iron saturation, using equilibration and quenching techniques. The compositions of the phases were measured using Electron Probe X-ray Microanalysis (EPMA). The ferrous and ferric bulk iron concentrations were determined using a specially developed wet-chemical analysis procedure based on the use of ammonium metavanadate. XRD was used to confirm phase identification. A procedure was developed to overcome the problems associated with evaporation of zinc at lowpO2s and to ensure the achievement of equilibria. An isothermal section of the system FeO-Fe2O3-ZnO at high ZnO concentrations at 1200°C was constructed. The maximum solubilities of iron and zinc in zincite and spinel phases in equilibrium were determined at pO2=1*10-6atm at 1200and 1300°C. The morphology of the zincite crystals sharply changes in air between 1200 and 1300°C from rounded to plate-like. This is shown to be associated with significant increase in total iron concentration, the additional iron being principally in the form of ferric iron. Calculations performed by Fact Sage with a thermodynamically optimized database have been compared with the experimental results. Keywords: Phase Equilibria, Fe-Zn-O, Quenching, Wet-Chemistry, EPMA, XRD, ISP.

Jan 1, 2004

By P. L. Duncanson, J. D. Toth

Since 1995, when "freeze lining" refractory systems were introduced to the ferroalloy industry, they have gained in popularity, due to the freeze lining?s reputation for reliability, safety, and the contribution it makes to profitability. As with many popular and effective technologies, however, the freeze lining has spawned low-cost pretenders that claim the "freeze lining" name. On the surface they appear to contain some of the components of the technology, such as thermally conductive materials, but they fail to incorporate all of the principles that define a true Freeze Lining. The term "freeze lining" refers to the refractory system?s ability to maintain a temperature profile that is low enough to freeze a layer of process material on its hot face, which insulates the refractory and prevents direct contact with molten metal and slag. In doing so, the common wear mechanisms found in the submerged arc furnace - chemical attack, erosion, and thermal stress - can be prevented. These wear mechanisms are all related to high temperature; thus, they are prevented by maintaining low temperatures. Certain refractory properties and design concepts are absolutely necessary for the lining system to function as a true Freeze Lining. The paper explains these requirements and why they are important - the Truth of freeze linings - and further explains why systems that ignore one or more of these requirements cannot claim to be freeze linings, thereby exposing the Myths.

Jan 1, 2004

By K. Adham, C. Lee

Over the last forty years, a number of specific fluidized bed applications in nickel extraction have been developed for commercial use. Five important processes have gained particular acceptance, namely, sulphide ore roasting, nickel sulphide (matte) roasting, nickel oxide reduction, laterite ore pre-reduction, and nickel chloride pyrohydrolysis. These applications involve different feed materials and process conditions, however, all benefit from fast reaction kinetics and high heat and mass transfer rates in the fluidized bed reactors. They have been studied, tested, and implemented by various nickel producers, who have published their results in many papers and patents. This paper examines the design issues surrounding the application of fluidized bed technology to the above nickel processes. Based on the available data in the open literature, computerized process modelling is used to provide generic flowsheets that illustrate the key features of each process.

Jan 1, 2004

By N. N. Rulyov

"Starting from fundamental principles of colloid-hydrodynamic theory of disperse systems we have shown that application of strongly non-uniform hydrodynamic fields allows to achieve not only faster rates of flocculation of suspension, but also supports significant improvements in the quality of clarified water and separation characteristics of solid phase. Specifically, it has been experimentally proven that the new treatment method based on these principles (then termed as ""ultra-flocculation"") allows:•,Increase the output of thickeners and pressure filters by 1,5-1,7 times;•,Decrease solids fall through into the filtrate in the process of vacuum filtration by 2¬3,5 times;•,Improve the rate of purification of water phase in the upright thickener by 1,5-1,9 times;•,Decrease flocculant consumption by 1,5-3 times;•,Increase the effective operational life time of cloth filters by 3-4 times;•,Ensure sustainable operation of separation equipment, i.e. decrease the sensitivity of process to variation in suspension concentration, as well as to variations of suspension composition and dispersion characteristics;•,Apply flocculant solutions of concentration 2-3 times higher, thus increasing the capacity of equipment used for solutions preparation."

Jan 1, 2004

By V. P. Mehrotra, D. W. Fuerstenau, A. -Z. M. Abouzeid

The use of pulverized coal for electric power generation results in the production of vast amounts of fly ash. One potential use for waste fly ash is the production of pellets for lightweight aggregates. This paper is concerned with the role of the physical and chemical characteristics of two different fly ashes in governing their agglomeration or pelletization behavior and their strength characteristics. In batch balling experiments, fly ash pellet growth was found to be extremely sensitive to the amount of moisture added. One ash (Mohave) exhibits marked pozzolanic activity whereas the other (Jim Bridger) does not. The pozzolanic activity has a very pronounced effect on pellet growth kinetics, moisture requirements, and the effect of various additives on growth kinetics. Slow drying under ambient conditions produces strong pellets from Mohave ash whereas Jim Bridger ash pellets lacking in pozzolanic activity are weak. Rapid drying at high temperatures results in weak pellets because water necessary for hardening is driven out of the pellet. Steam curing enhances pellet strength. Locked-cycle pelletizing experiments exhibit expected oscillation in pellet production rates and attendant fluctuations in pellet green strength.

Jan 1, 2004