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By Masayuki Kudoh, Tohru Maruyama, Yohichi. Ito

When hypo-peritectic carbon steel is quenched during unidirectional solidification, the region of fine columnar grain is observed. It is classified into two coexisting phases. One is coexisting phases of liquid, delta and gamma in the upper part of the region, and the other is coexisting phases of delta and gamma in the lower part of the region. To form the coexisting part of the three phases means that solidification in this experiment proceeds in non-equilibrium state. The size of the narrow side of one fine columnar grain coincides with the arm spacing of a primary dendrite and this result is the same as the hyper-peritectic carbon steel. However, the boundary of the fine grain in the hypo-peritectic carbon steel is formed in different location from that of the hyper-peritectic carbon steel. The former is formed in the skeleton of the dendrite, while the latter is formed in the interspacing of the dendrite. The region of the fine grain changes suddenly to that of the coarse grain when the delta phase in the coexisting part of two phases disappears completely. Therefore, the delta phase in the hypo-peritectic carbon steel might prevent the growth of gamma grain. In order to recognize it, ferrite formers such as Mo, V and Ni are added in the sample. Then, the longitudinal length of the fine columnar grain extends in the sequence of the no addition, Mo, V and Nb.

Jan 1, 2000

By James R. Hein

Rodriguez Seamount, located 150 km off the central California coast at the base of the continental slope, was studied using the ROV Tiburon aboard MBARI?s R/V Western Flyer, October 13-16, 2003. Fe-Mn crust and rock samples were collected along the SW flank of the seamount at water depths from 700 to 2100 m; bottom-water dissolved oxygen content (O2) and temperature were determined at each sample site. Fifty-three samples of bulk crusts, crust layers, and surface scrapes (~0.5 mm) were analyzed for 59 elements. Data allow for the correlation of crust compositions with precisely known water depths and seawater O2 measured at the actual site of sample collection. This is the first detailed study of Fe-Mn crust compositions in a region of strong continental-margin upwelling. Compared to open-ocean seamount Fe-Mn crusts, Rodriguez crusts have significantly higher (2-6 fold) mean concentrations of Fe (26.9%), Al (1.65%), Si (13.0%), Cr (82 ppm), Th (64 ppm), and Ag (1.7 ppm); and significantly lower (2-8 fold) mean concentrations of Ca, P, Bi, Co, Cu, Ni, Tl, and especially Te (8.2 times lower). All but one Fe/Mn ratio are >1 compared to <1 ratios for open-ocean crusts. O2 contents (0.35-2.03 ml/L) are nearly perfectly corrected with water depth and elements correlated with one are correlated with the other. The Fe-Mn surface scrapes represent 60-450 ka (mean 150 ka) of growth, whereas the dissolved oxygen contents of seawater represent an instant in time. Assuming that the entire sample set was affected uniformly by oceanographic changes, we suggest that correlation of elements with O2 may reflect oceanographic processes. O2 has a negative correlation with P, V, As, Fe, U, Be, Pb, Cr, Mg, Y, Bi, Te, and REEs (except Ce) and a positive correlation with aluminosilicate-hosted elements (Al, K, Rb, Cs). This later relationship is related solely to water depth, indicating that detritus shed down the seamount slopes accumulates in greater abundances in deeper-water crusts. Si/Al ratios indicate that the detritus includes a large component of biosilica produced by upwelling-mediated high productivity. These observations are supported by positive correlations of aluminosilicate-hosted elements with crust growth rates (range 1.2-13.0 mm/Myr). In contrast, other elements (Sr, Co, Mn, Mg, Te, As, Mo, V, W, U, Ti, Ni, REEs, etc.) are negatively correlated with growth rates. Growth rate has a weak positive correlation with O2. These compositional characteristics indicate that even though low-O2 seawater acts as a reservoir for Mn and associated elements and produces slow growth rates, which would allow for the concentration of elements and surface oxidation processes to occur, the high rate of input of detritus and high bioproductivity ameliorate the strong concentration of most metals. This dilution is significantly enhanced by the doubling of FeOOH in the crusts--the main cause of the generally high growth rates compared to open-ocean crusts. The high growth rates limit the oxidation of Co, Tl, and especially Te on the crust surface, which is reflected by their relatively low concentrations. Within the range of oxygen contents measured, O2 has less of an influence on crust chemistry than does the availability and incorporation of FeOOH and detritus.

Jan 1, 2004

By K. Hanumantha Rao, A. Javadi

Our recent studies revealed that the sulfide minerals in contact with water during grinding produced hydrogen peroxide (H2O2) where the amount of H2O2 production by the minerals found to be in the order of pyrite > chalcopyrite > sphalerite > galena. The H2O2 effect on the oxidation of pulp components and its influence on the concentrate grade and recovery in flotation have been studied and the results have been presented and discussed in this paper. Studies have also been carried out to build correlation between percentage of pyrite in the concentrate, grinding conditions and concentration of OH•/H2O2 in the pulp and as well of controlling the formation of these species through known chemical means for depressing the generation of the oxidant. Flotation tests using a complex sulfide ore with the same reagent scheme that is being used at Boliden concentrator in Sweden but with the addition of i) collector and depressant, ii) Na2S reductant and iii) inorganic (EDTA) and organic (TETA) surface modifiers, during grinding stage have been performed to judge the beneficial or detrimental role of H2O2 on the selective flotation of sulfides. The results demonstrate that the selectivity of metal sulfides against pyrite increases with increasing generation of H2O2 in the pulp liquid. H2O2 is also found to be a better oxidant in chalcopyrite-galena flotation separation than the commonly used K2Cr2O7.

Jan 1, 2016

By Isrun Bohlinger

Resources recovery of brasses for semifinished products often results in the formation of hard spots impairing the quality of following abrasive and/or surface finishing processes. A short survey is given on the recycling processes, followed by the actual knowlegde of genesis, composition, and possibilities of avoidance of hard spots. Informations on genesis and composition of hard spots are completed by data from recent experiments.

Jan 1, 1998

By K. Hanumantha Rao, A. Javadi Nooshabadi

"Formation of hydrogen peroxide (H2O2), an oxidizing agent stronger than oxygen, by chalcopyrite (CuFeS2), which is a copper iron sulfide mineral, during grinding, was investigated. It was observed that chalcopyrite generated H2O2 in pulp liquid during wet grinding and also in the solids when placed in water immediately after dry grinding. The generation of H2O2 during either wet or dry grinding was thought to be due to a reaction between chalcopyrite and water where the mineral surface is catalytically active in producing •OH free radicals by breaking down the water molecule. The effect of pH in the grinding medium or in the water in which solids are added immediately after dry grinding showed that the lower the pH value, the higher the H2O2 generation. When chalcopyrite and pyrite are mixed in different proportions, the formation of H2O2 was seen to increase with increasing pyrite fraction in the mixed composition. The results of H2O2 formation in pulp liquid of chalcopyrite and together with pyrite at different experimental conditions have been explained by Eh-pH diagrams of these minerals. This study highlights the necessity of revisiting the electrochemical and/or galvanic interaction mechanisms between the chalcopyrite and pyrite in terms of their flotation behavior.IntroductionHydrogen peroxide causes nonselective oxidation of sulfide minerals if present in pulp liquid. Oxidation of sulfide minerals takes place when they are exposed to atmosphere and during the grinding process when the particle size is reduced for flotation. The oxidation of chalcopyrite leads to iron dissolution from the particle surface and from a metal-deficient, sulfur-rich surface (Fairthorne et al., 1997). Other studies report the formation of iron hydroxide on the surface with the metal ion dislodged on the surface (Buckley and Woods, 1984; Chander, 1991). The chemical reactions for the oxidation of chalcopyrite in alkaline and in acidic solutions with the addition of oxidants, such as oxygen or hydrogen peroxide, are shown in Eqs. (1) and (2), respectively (Shi and Fornasiero, 2010)."

Jan 1, 2015

By Chu E. Ho

Jet grout column formation at large depths are prone to several uncertainties, such as inaccuracy in setting out boreholes, drilling deviation, soil variability and reduced jetting energy at the nozzle. This would result in shorter cutting distance of the jet, with potential lack of interlock between grouted columns. A design strategy for mitigating the risk should include a soil investigation program aimed at discovering potential variability in soil conditions at the locations of jetting. Determination of soil strength profiles with depth would be useful for evaluation of jetting parameters and prediction of the achievable cutting distance at any depth. Selection of design column spacing should include allowance for setting out accuracy, verticality of the boreholes and the achievable jet cutting distance. For deep jet grouting operations, it would be necessary to take into account the energy losses at the nozzle inlet; however the increase in the presiding pressure at the nozzle outlet at depth is small relative to the range of jetting pressures commonly employed and would not affect the cutting distance to any significant degree. Design column spacing should not be so close as to cause problems with ?masking? which may lead to localized ungrouted zones of soil. For effective field control, boreholes should be cased up to the top elevation of the grouted zone so that the orientation of the borehole can be measured prior to grout injection. An analytical equation for calculating the cutting distance is proposed for adjusting jetting parameters where necessary to compensate for drilling deviation and changes in soil conditions. It is preferable that jet grouting trials be executed at elevations that correspond to the actual production jet grouting depths for accurate evaluation of jet cutting performance.

Jan 1, 2008

By Chunyang Guan, Jilai Xue, Zengjie Wang, Qiaochu Liu

Molten salts electrolysis method to prepare Al-RE alloys has attracted increasing attention recently. CaCl2 and Na3AlF6 were the most often used melts for this purpose. In this work, Al-Sc alloys prepared by electrolytic deposition process in both CaCl2 and Na3AlF6 melts were investigated, respectively. It was found that Sc distributes almost uniformly and Sc contents increase with increasing current intensity in both melts. Current efficiency was measured for comparison among various current densities applied. The alloy products were analyzed using XRD and SEM, where the formation behaviors of Al-Sc intermetallics were investigated in details. The experimental and theoretical results demonstrate that Al3Sc and Al0.968Sc0.032 are the major precipitates in the Al-Sc alloys prepared by molten electrolysis. The results are useful for selection and optimization of the molten salts compositions and the parameters of electrolysis operation.

Jan 1, 2015

By Ruddle R. W.

Magnetite occurs in the reverberatory furnaces, blast furnace and converter (a) as the result of its presence in the materials charged, and (b) as the result of oxidation of the FeS in the charge in the absence of sufficient SiO2 to slag the FeO as it is produced and thus prevent its subsequent further oxidation. Magnetite is reduced by FeS according to FeS+3Fe3O4=10FeO+SO2 and similar reactions. This reaction is markedly affected by temperature and does not proceed to any important extent below about 1200°C. To ensure comparative freedom from magnetite it is therefore necessary to raise the temperature of the furnace to the highest practicable figure and to use plenty of siliceous flux. Since the maximum operating temperature is likely to be limited by the resistance of the refractories to attack by the slag, investigation of the factors affecting this attack should be helpful. It is reasonable to suppose that the formation of magnetite might be minimized by ensuring intimate admixture of matte and slag during conversion so that silica is readily available for combination with ferrous oxide as the latter is formed. The literature gives no clue to the importance of this factor and some experimental work on this aspect might be fruitful

Jan 1, 1953

By N. Hiroyoshi, R. D. Corpuz, M. Ito, Hokkaido University, C. B. Tabelin, S. Veerawattananun

"Acid mine drainage (AMD), the very acidic and heavy metal-contaminated leachate generated when pyrite-bearing rocks are exposed to surface oxidizing conditions, is a serious environmental problem encountered after the closure of mines and mineral processing operations. In this study, we investigated the effects of soluble phases and metallic oxides, which are commonly found in strongly weathered pyritic wastes, on pyrite oxidation. Strongly weathered pyrite containing melanterite (FeSO4·7H2O) as the main soluble phase was obtained from Furikusa mine, Japan. The sample was washed using two methods to vary the relative amounts of melanterite in the sample. The effect of metallic oxides on pyrite oxidation was evaluated using ultrapure hematite suspensions. Our results showed that under acidic conditions, the effect of soluble salts on the oxidation of pyrite was stronger than hematite. More thorough washing of the sample resulted in the formation of an arsenic-bearing iron-oxyhydroxysulfate coating that minimized pyrite dissolution. This oxidized layer became relatively thicker and mechanically stronger when hematite was introduced after the more thorough removal of soluble salts. Characterization of this “coating” coupled with geochemical modeling suggest that it is most probably composed of two materials: schwertmannite and scorodite. Based on these results, a new approach to suppress pyrite oxidation by directly using iron-oxyhydroxysulfate as coating material is introduced.INTRODUCTION Acid mine drainage (AMD), the very acidic and heavy metals-contaminated leachate produced in closed/abandoned mine sites (Evangelou, 1995), mineral processing and coal cleaning tailings (Evangelou, 1995), and tunnel construction waste rocks (Tabelin and Igarashi, 2009, Tabelin et al., 2012), is one of the oldest and probably the most serious environmental problem of anthropogenic origin. When released to the environment, it rapidly pollutes river, soil and groundwater systems leading to the destruction of affected ecosystems. AMD is produced when pyrite (FeS2), one of the primary gangue minerals in sulfide ores and coals, is exposed to oxidizing conditions as illustrated by the following reactions:"

Jan 1, 2016

Electrochemical measurements are presented on electro-deoxidation of silica in molten calcium chloride at 900°C, with porous silica pellets as starting material. Measurements during pre-electrolysis (to remove water from the melt) showed electrochemical noise, which is consistent with the evolution of hydrogen. Throughout, the dominant anodic reaction appears to be CO2formation, based on the observed potential at the anode, and measured anode wear. Because of the presence of dissolved CaO in the melt, some of the CO2 candissolve in the melt; the resulting calcium carbonate formation was confirmed by electrolyte analysis after reduction runs. Reduction of dissolved CO2 at the cathode is likely to contribute to the background current during the reduction process. For the electrode and cell configuration used here, most of the over potential arises from polarization of the anode, and ohmic potential drop in the electrolyte.

Jan 1, 2006

By Qingyu Deng, Shiwei Ma, Wang Hua, Guibao Qiu

"The flow properties of the blast furnace slag bearing high TiO2 at high temperature like the viscocity may change a lot due to the formation of the carbonitride inside, causing serious problems on the separation between the metal and the slag. Therefore, the critical condition of the formation of Ti(C,N) in blast furnace is vital importance for the ironmaking process with iron ore bearing titania. In this study, the formation of Ti(C,N) in blast furnace and the influences of various factors on the Ti(C,N) formation are investigated by FactSage. It is found that the mass of Ti(C,N) would reach the maximum at 1480 oC, and the product is mainly TiN below 1620 oC, while it is mainly TiC above 1620oC. The order of the factors by the importance from strong to weak was: temperature, the content of TiO2 in slag, basicity of slag, the content of MgO and Al2O3.IntroductionThe titanium dioxide (TiO2) in iron ore bearing titania will be partly reduced by carbon to titanium carbonitride (Ti(C,N)) in blast furnace, causing serious problems on the separation between the metal and the slag because of the change of flow property. Therefore, the critical condition of the formation of Ti(C,N) in blast furnace is vital importance for the ironmaking process, especially for the smelting of iron ore bearing titania. Extensive experimental data in regard to the formation of Ti(C,N) has been reported in numerous papers[1-6]. However, only some discrete data can be obtained by experiment, and it is difficult to detect the mass of Ti(C,N) in slag. In addition, the experiment is difficult to be proceeded when the temperature is above 1600oC. Therefore, it is very difficult to make clear the critical condition of the formation of Ti(C,N) by experiment."

Jan 1, 2012

By H. Krogerus, P. Niemelä, P. Oikarinen

High carbon ferrochromium is produced by carbon reduction. No replacement for carbon as reductant has yet been developed. The reduction creates a considerable amount of CO-gas. In open and semi-closed furnaces the gas is burned when leaving the burden. In closed furnaces the formed gas is sucked out by a fan, washed and utilised as fuel. The formation of carbon monoxide is presented briefly starting from thermodynamic considerations up to solid and liquid state reduction. The volume, composition and energy content of the furnace gas are discussed, focusing on the raw materials and pre-treatment processes of the furnace feed as well as on the process equipment and control. Outokumpu has been using closed and sealed furnaces and utilising the CO-gas in its Tornio Ferrochrome Works since 1968. Today in Tornio with an annual ferrochromium production of 260 000 t CO-gas production is 186 million m3, representing 68 MWh an hour. At the same time the furnace power input is 95MW. About 98 % of the CO-gas is utilised, whereof 30% in the ferrochrome production itself. This paper focuses on the characteristics and utilisation of CO-gas. CO-gas is secondary energy, which on one hand saves primary electric and fossil fuel energy in ferrochromium production and, on the other, replaces other fossil fuels at the adjacent steel works. The characteristics of the fuel, requirements for utilisation as well as health and safety aspects are discussed. Utilisation of the gas has a high impact on the total dust and gaseous emissions and on the energy optimisation at the ferrochromium and steel works.

Jan 1, 2004

By Carlos Eduardo Pinedo

A nitretação dos aços inoxidáveis tem sido objeto de diversos estudos nas últimas décadas. O objetivo primordial é promover o endurecimento superficial e com isso elevar a resistência ao desgaste, sem comprometer a resistência à corrosão. Em vista disto, a nitretação sob plasma a baixa temperatura, abaixo de 430oC, tem se mostrado um processo eficiente para inibir a precipitação de nitretos de cromo e promover o endurecimento superficial pela formação de fases expandidas pela supersaturação de nitrogênio. Este trabalho mostra a formação de ferrita expandida em um aço inoxidável ferrítico. Para isso foi utilizada o processo de nitretação sob Plasma-DC na temperatura de 400oC por 20 horas em mistura gasosa contendo 75%N2 e 25%H2. Os resultados de Difração de Raios-X mostraram que a nitretação em baixa temperatura é capaz de formar uma camada nitretada de ferrita expandida. Em Microscopia óptica observa-se uma camada homogênea com profundidade média de 32 microns de profundidade e dureza média de 1296 HV promovendo um endurecimento superficial do aço inoxidável ferrítico em mais de 5 vezes sem que ocorra a precipitação de nitretos de cromo e, com isso, preservado a resistência à corrosão.

Oct 30, 2017

By A M. Sardo, D E. Sinnett

This study uses the Q Method to examine how those living in former metal mining landscapes value this heritage and their preferences for the long-term management of mine waste. Such sites are often perceived as derelict or degraded, and of very little value. It is therefore assumed that their reuse, for example for development or recovery of metals, is likely to be beneficial. There are around 5,000 former metal mines in England and Wales, many of which are protected for their ecological, geological or cultural value. The Q Method is particularly suitable for issues where there is no consensus of opinion. We asked 38 residents of six mining areas in England and Wales to ‘sort’ a series of statements based on their resonance with the resident’s perspective; this is the Q sort. The statements covered a range of opinions of the mining legacy, its value and options for its management with a particular focus on the potential for metal recovery from the wastes. Analysis of the Q sorts revealed five perspectives on the mining heritage. All placed a high value on the cultural and ecological value of this heritage, however, they differed in their priorities for long-term management. For example, emphasis was placed on either nature conservation, cultural heritage, water quality or the opportunity for job creation through reworking the mines. Cutting across these themes there were also differing perspectives on the role of experts and local people in shaping the future management of the wastes. This research suggests that the views of local people are nuanced; they value their mining heritage but opinion is split on the most effective way to manage these sites especially where there is an impact on water quality.CITATION:Sinnett, D E and Sardo, A M, 2018. Former metal mining areas in England and Wales – local residents’ preferences for the management of wastes, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 126–134 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

"This paper presents results of ongoing research being carried out at the University of New South Wales into improved methods for estimating rock mass strength. In this paper the rock mass strength of Hawkesbury Sandstone is assessed. An estimate is first made based on an extensive database of intact rock strength data being collated by the author and the assumption that the rock mass strength can be determined following the GSI approach. The resulting strength envelope is then compared with nine documented case studies where stress induced failure has occurred in tunnels excavated within Hawkesbury Sandstone. The case studies cover a range of conditions:• construction dates from 1880s to 2006• spans from 3.2 to 12.5 m• depths from 17 to 124 m• excavation methods of drill & blast, roadheader and TBM.Finite element modelling is used to assess the likely magnitudes of the stresses present at the time of failure. The finite element models are interrogated to provide the values of major and minor principal stresses in and around the mapped failure zone. Failure and stable points are then compared to the rock mass strength envelope(s) of Hawkesbury Sandstone derived using the Hoek-Brown criterion and spalling criteria. The Hoek-Brown rock mass strength envelope differentiates between the ‘failed’ and ‘stable’ zones remarkably well.INTRODUCTIONStress induced failures of rock masses are fortunately rare in civil tunnelling. However, when they occur they provide an opportunity to calibrate an assumed rock mass strength criterion. This paper compares an estimate of rock mass strength for the Hawkesbury Sandstone with the following cases where stress induced failure occurred in tunnels excavated within Hawkesbury Sandstone.• Cataract & Devines Tunnels of the Upper Canal (Upper Nepean Scheme)• Malabar Outfall Tunnel• Sydney liquefied petroleum gas (LPG) Storage Cavern• Northside Storage Tunnel• Cross City Tunnel• Lane Cove TunnelTwo-dimensional finite element modelling is used to assess the likely magnitudes of the stresses present at the time of the failures. The principal stresses are then compared to the assessed rock mass strength envelope(s) of Hawkesbury Sandstone derived using the 2002 Hoek-Brown criterion (Hoek et al., 2002) and the spalling criterion suggested by Diederichs (2007)."

Jan 1, 2015

By Royal Jackman

Two comprehensive papers have appeared regarding the forms of copper that occur in smelter slags, one by Frank E. Lathe1 and the other by C. G. Maier and G. D. Van Arsdale.2 These authors comment on other published results and draw conclusions from their own investiga-tions. The development of X-ray examination of minerals and improve-ment in high-power microscopic methods make it possible today to get additional evidence by means that were not available to earlier investi-gators. The present work was confined to reverberatory slags obtained from five different plants. Some definite conclusions were reached regarding the forms of copper present in these slags. In most cases these agree with some of the findings of Maier and Van Arsdale but new methods of attack were used in the investigation.

Jan 1, 1933

To predict the spontaneous combustion potential of bituminous coals using a simple expression based on an easily acquired coal property. Background Approximately 20% of underground coal mine fires in the United States since 1978 have been attributed to spontaneous combustion. Spontaneous combustion fires in underground mines are most likely to occur in gob area; and are difficult to detect and to extinguish by direct fire fighting methods. Often, sections of the mine or the entire mine must be sealed for long periods, at a great economic loss to the mine operator, mine employees, and the surrounding community. It is conservatively estimated that the cost of scaling a large mine is about $50 million.

Jan 1, 1989

The paper provides an overview of the development and content of APCOM symposia since their inception in 1961. This development is set within the context of the academic environment in which much of the research published at APCOM symposia is conducted. This environment includes rigorous external assessment of research quality at national levels and against international benchmarks, which carries significant consequences for funding and for the continued existence of the academic minerals industry disciplines. Adverse consequences that undermine the academic provision of mining and resource engineering will impact negatively on the minerals industry by reducing the level of research and education resources available to it.The traditional reductionist approach to research is contrasted with the inter-disciplinary approach that is required to address the complex systems problems that the minerals industry will have to address to ensure its technical, economical and environmental sustainability. Such an approach offers a means of raising research profiles, of establishing mutually beneficial academic-industry engagement and provides an opportunity for APCOM to take a lead role in identifying the research and development agenda for the future

Sep 26, 2011

By Norman O. Lotter, Dominic Fragomeni, Jorge Oliveira, Dee J. Bradshaw, Rebecca Monnapula

"The role of mixed collectors in enhancing the metallurgical performance of sulphide flotation processes was reviewed in 2008, and later published as an integrated theory by Lotter and Bradshaw, 2009. The theory proposed that xanthates, dithiophosphates and dithiocarbamates could be synergistically combined in an optimal formula to deliver improved grade and recovery. The approach uses a five-step structure, viz.1. A mineralogical study of the ore to be treated, identifying and quantifying the economic minerals (with hosting and association) and gangue species present.2. Selection of candidate collectors from this mineralogical information and from the known pulp conditions of that operation (e.g. Eh, pH).3. Design and execution of a factorial experiment to estimate and test the main effects and interactions, and to model the response surface for an optimum formulation [Box et al., 1978].4. Use of a High-Confidence Flotation Test platform in the factorial to reduce overall errors and allow for clearer observations [Lotter, 1995; Lotter and Fragomeni, 2010].5. Statistical design of a plant scale trial to measure and validate the gains [Napier-Munn, 1995; Lotter et al., 2009]. Eland Platinum, which was commissioned in November 2007, appointed a team to apply this theory to formulate an optimized mixed collector suite for use in the operation. The West Pit ore (UG2 - Normal ore) was sampled at site and brought to Xstrata Process Support, Sudbury, Canada, for mineralogical and metallurgical testing in 2008. Microprobe and QEMSCAN measurement characterized the type, grain size and textural association of the discrete Platinum Group Minerals (PGM) present. From the mineralogical data, it was clear that a mixture of dithiocarbamate and two xanthates would be a likely reagent suite selection. A factorially designed set of High-Confidence Flotation Tests studying these was performed, concluding that an optimal suite using certain amounts of these collectors was a viable formulation that would advance the grade and recovery performance at Eland above the standard PIBX by approximately 2.13% 4E PGE. The plant trial, which used a form of the replicated block design after Napier-Munn, 1995, and Lotter et al., 2009, exceeded this estimate with an overall PGE recovery gain of 2.48% (absolute basis) and a concentrate grade gain of 26.4 g/t PGE (absolute basis), as well as reducing chrome in concentrate from 2.04 to 1.62% (absolute basis). These gains proved to be statistically significant using the analysis of variance method, and have validated the theory."

Jan 1, 2011

By Letícia Miranda Alves

Os pós fluxantes têm como base o sistema CaO-SiO2-Al2O3-Na2O-CaF2 sendo que, em alguns casos, podem conter também MgO, Li2O, K2O e B2O3. Os resíduos de mármore e granito, oriundos dos processos de produção de rochas ornamentais, são passivos ambientais na região sudeste, sobretudo no estado do Espírito Santo. As composições destes resíduos são similares a dos pós fluxantes utilizados nos processos de lingotamento contínuo e portanto serão utilizados neste trabalho para formulação de novos fluxantes. Uma mistura de granito, pó de mármore e adições foi realizada com o objetivo de produzir um fluxante similar aos comerciais encontrados no mercado. O novo fluxante foi caracterizado por difração de Raios X antes e depois de passar pelo teste de susceptibilidade de formação de fases cristalinas ou “teste de Stollberg” modificado. Os resultados mostraram que existe a formação de fases similares às observadas em fluxantes comerciais. Avanços nesta área podem viabilizar economia de matéria-prima e a diminuição do impacto ambiental causado pelo mercado de rochas.

Aug 17, 2017