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By A. D. Ramirez, L. E. Gutierrez, M. A. Garces

"Scarcity of freshwater in mining operations in arid zones in different parts of the world has led to the mining companies to think about using seawater as an alternative source in mineral processing operations. Examples of this situation are Minera Centinela (AMSA) and Minera Sierra Gorda (KGHM), both plants located in northern Chile. Previous studies showed that molybdenite flotation is depressed at high pH values in seawater as a result of the action of hydroxy-complexes of magnesium and calcium that attach to the faces of the molybdenite particles, reducing its hydrophobicity and as a result flotation recovery. In this work, a study of the interactions between molybdenite and kaolinite is presented. The effect of sodium hexametaphosphate (SHMP) dispersant on the recovery of molybdenite in the presence of kaolinite is studied in different aqueous media and it is correlated with induction time data. The results allow to conclude that kaolinite has a stronger depressing effect on molybdenite in seawater compared to its effect in freshwater. Magnesium and calcium are the cations that have the strongest effect in enhancing the interactions between molybdenite and kaolinite. SHMP reduces the negative effect of kaolinite on the floatability of molybdenite both in seawater and freshwater. The induction time data correlate well with the micro-flotation results.INTRODUCTION The need for water in mining processes in arid and semi-arid zones has led to the search for new alternatives for this resource, among which seawater has gained an important space. In Chile, most of the mining operations are located in the northern part of the country, an area that has limited availability of freshwater for the processing of copper and molybdenum sulfides (Castro and Laskowski, 2011, Castro et al., 2012 a). Seawater is an aqueous solution with high concentrations of ions such as Na+, K+, Mg2+, Ca2+, So42-, Cl-, and other less concentrated species which generate important effects in the flotation process as they modify the properties of the solid/liquid, and liquid/gas interfaces, and also increase the consumption of some important reagents used to depress pyrite such as lime. It has also been proposed that flotation of copper sulfides is negatively affected in seawater because of the reduction of oxygen solubility compared to freshwater (Millero et al., 2002; Duan and Sun, 2003). In contrast, it has been shown that the presence of ions in solution in the process of flotation of natural hydrophobic resources improve recovery as result of the compression of the electric double layer (Laskowski, 1974; Klassen and Mokrousov, 1963, Laskowski and Castro, 2008."

Jan 1, 2018

By David R. Burkhard

"Comparative roof beam performance, as measured by delamination within the bolted horizon, was used to evaluate two types of roof bolt drill hole geometries in a development setting. Short encapsulation pull tests had demonstrated a higher grip factor in drill holes featuring helical grooves in the side walls in comparison to drill holes featuring continuous smooth to slightly rough walls. The study incorporated the two geometries during development mining in which fully grouted mechanically anchored bolts were installed as primary roof support.bolts were installed as primary roof support.The study site, in an entry adjacent to a longwall panel, was instrumented with extensometers and data collected during longwall retreat. Statistical analysis was conducted to validate null and alternative hypotheses used to compare drill hole geometries. Analysis yielded no statistically significant difference between drill hole geometries. Inspection of the data does reveal less delamination within the smooth walled site in comparison to the site containing grooved hole geometry.INTRODUCTIONFrom their introduction as a means of ground control over sixty years ago, roof bolts today are the primary mechanism of roof support utilized throughout mining. Whether through suspension, keying, or beam building, roof bolts are employed to reinforce the inherent strength of the strata comprising the immediate roof with the goal of creating a competent bolted horizon of sufficient load bearing capacity to be self-supporting for a given mine's design life, stress regime, and geomechanical properties.For grouted bolts in sedimentary strata, axial loading due to vertical rock movement and bending due to horizontal rock movement are the principal means of loading (Signer, 2000). Regardless of the type of bolt and extent of grouting employed, the success of any roof bolting design is determined, to a large extent, by the effectiveness of load transfer between the rock, grout, and bolt.At San Juan Mine, an underground longwall mine located in the northwestern corner of New Mexico, a number of different roof bolt types, grades, and lengths have been used over the years in an effort to optimize primary roof support. One common denominator shared throughout has been the use of full length grout. Load transfer for full length grout is achieved primarily through mechanical bonding between the grout and rock. It is this interaction that is the focus of the study described in this paper. The study assessed and compared two types of bolt hole geometries employed during gate road development at San Juan. Underground instrumentation and evaluation of the bolted roof provided the means of assessment and comparison."

Jan 1, 2016

By W. R. Reed, J. A. Organiscak

Haul trucks have the potential to generate large amounts of respirable dust. This respirable dust has been shown to be a health hazard to personnel, especially if it has a high silica content. Lack of dust sampling data from haul trucks prompted the completion of a study to quantify respirable dust concentrations. These field studies were conducted measuring instantaneous respirable dust at stationary locations from passing haul trucks at a stone quarry and at a coal mine site. Fugitive dust levels from haul trucks were analyzed to characterize dust dispersion. This analysis indicates safe following distances for haul trucks and other heavy equipment to avoid overexposure of respirable dust from the lead haul truck.

By T. W. Beck

Overexposure to respirable dust remains a widespread health hazard to roof bolter occupations in underground coal mines. Recently implemented mist drilling technology was evaluated for its effectiveness in controlling respirable dust exposures for roof bolting personnel. This work presents the findings from NIOSH field and laboratory studies comparing respirable dust levels on mist drilling roof bolter machines to dust levels measured on machines using a conventional vacuum drilling system. Gravimetric and instantaneous respirable dust samples were collected for multiple drilling cycles. These dust measurements were used to assess the potential dust control capabilities relative to conventional drilling. Controlled laboratory tests found 0.3 mg/m3 more respirable dust with mist drilling than with the conventional vacuum method. A separate field investigation of the two techniques observed higher dust levels around the mist bolting machine.

Jan 1, 2008

By G. Aguilera

It is known that an addition of rigid particles into a fluid medium changes the flow field. Therefore, the rheological behavior of suspensions will be hardly Newtonian, such as their continuum phase. This phenomena was studied by Einstein in 1906 (Einstein, 1956) for the single case of spherical particles in a continuum liquid of a very dilute suspension. The final analysis applied for suspensions was derived from the evaluation of the behavior of ideal gases, finding a simple expression for the viscosity of the dispersion. All the following works about the hydrodynamics of suspensions at low and high solid contents was based in the Einstein´s model. For clay minerals suspensions where the physical and chemical properties of the particles are complex, it was found that the Einstein´s model is not a good approximation, even so for the most dilute dispersions. The present paper shows a new approximation that describes the non-Newtonian behavior of the suspensions of clays, and the attempt of understand how the different fine sizes, shapes and physico-chemical properties of clay particle surfaces give specific characteristics of plasticity, viscosity or visco elasticity to suspensions. Keywords: viscosity, clay minerals, einstein´s model, dilute suspensions

Sep 1, 2012

By P. Falcão Neves

A detailed analysis of the geomechanical behaviour in rock cutting with a diamond saw is provided to obtain a better understanding of the mechanisms involved in the process. The energy of elastic deformation (before failure) and plastic deformation (post failure) was determined in uniaxial compression tests as well as the energy consumed per unit volume in the cutting process. The test samples are White and Ruivina marbles from Borba - Vila Viçosa in Portugal. Correlations between total deformation specific energy and cutting specific energy, normal and tangential forces and diamond indentation are analysed, and some conclusions are presented.

Jan 1, 2012

By P. Falcão Neves

A detailed analysis of the geomechanical behaviour in rock cutting with a diamond saw is provided to obtain a better understanding of the mechanisms involved in the process. The energy of elastic deformation (before failure) and plastic deformation (post failure) was determined in uniaxial compression tests as well as the energy consumed per unit volume in the cutting process. The test samples are White and Ruivina marbles from Borba - Vila Viçosa in Portugal. Correlations between total deformation specific energy and cutting specific energy, normal and tangential forces and diamond indentation are analysed, and some conclusions are presented.

Jan 1, 2012

By John R. Hayes, Kebbi A. Hughes, John Rowson, Peter E. R. Blanchard, Jeremiah C. Beam, Andrew P. Grosvenor, Arthur Situm

Uranium ore bodies contain elements within mineral phases that need to be disposed of responsibly. Solid waste can be placed in a tailings management facility (TMF) to contain the waste elements and limit interactions with the environment. It is important to understand how the chemistry of the tailings evolves throughout the lifetime of the operations that feed the TMF and after the site has been decommissioned. The objective of our collaboration with Orano Canada was to study how the tailings from the TMF located at McClean Lake, Saskatchewan change over time. This manuscript discusses our use of X-ray absorption spectroscopy (XAS) and X-ray microprobe to study the fate of Mo and Ca in the tailings. Mo is considered an element of concern (EOC) and it is necessary to determine if a stable solid Mo-bearing species forms. Thermodynamic modeling suggested that aqueous Mo would precipitate over time as powellite (CaMoO4). Comparing Mo K-edge XAS spectra from the solid tailings to the aqueous Mo concentration in the pore water showed that powellite did form and that this did result in a decrease in the aqueous Mo concentration over time. Further, it has been proposed that Ca2+(aq) can react with bicarbonate ions in the pore water and precipitate as calcium carbonate (e.g., CaCO3). This reaction would limit the aqueous bicarbonate present in the tailings that could react with uranyl ions to form soluble uranyl-carbonate complexes. We have identified several trace Ca-bearing species, including carbonates, in the tailings using XAS and X-ray microprobe.

Jan 1, 2020

By John P. Turner, Benjamin J. Turner

"This report describes a research project for evaluating the applicability of the widely accepted 80 percent criterion for elongation of ground anchors to anchors with unbonded lengths exceeding 100 feet. This issue is driven by several recent projects involving ground anchors for landslide stabilization in which a significant percentage of the anchors did not meet the criterion that requires measured elongation during proof load testing of at least 80 percent of the theoretical elastic elongation. The projects involved anchor unbonded lengths in the range of 85 to 220 feet, which is outside the range traditionally used in practice, although anchors of this length are being used more frequently for landslide stabilization. The principal objective of this research is to address whether the widely accepted criterion of 80 percent elongation is applicable for such applications, and whether other factors affect the ability of anchors to meet the criterion.Analytical methods for predicting transfer of load along the length of steel strand due to friction loss are used routinely in the prestressed concrete industry. These analytical expressions provide a rational framework for quantifying changes in load due to friction along the length of a ground anchor in terms of a ‘wobble coefficient’ (K) as defined in Aalami (2004). Values of the wobble coefficient for ground anchors can only be determined by back-calculating from load tests, i.e., fit the value of K to the appropriate analytical expression based on the known test load and measured percent elongation. The analytical basis is first developed and shown to provide a tool for evaluating results of anchor load tests to determine the magnitude of expected elongation as a function of unbonded length. Next, a database of anchor load tests is used to back-calculate values of K for anchors with unbonded lengths in the range typically used in geotechnical applications (< 100 feet). These values of K are then used to calculate expected friction loss for anchors with high unbonded lengths (100 to 250 feet) to evaluate whether the 80 percent criterion is reasonable."

Jan 1, 2017

By J Silva Castro, W C. Wedding, B T. Lusk, J Calnan, E G. Morris

The emergence of electronic detonators for use in production mine blasting has enabled mining professionals to rethink the traditional blast design methodologies that pertain to timing. In many ways, electronic detonators can allow great advances in productivity, cost effectiveness, fragmentation, and safety. This paper reports on an independent study quantifying the accuracy of two electronic and two non-electric systems in which 674 detonators were tested. This research aimed to determine the accuracy of commercially available electronic detonators as compared to non-electric shocktube systems. Each system was tested over the viable ranges of delays available. Statistical models were then applied to quantify the scatter present in each system. Suggestions for the use of electronic detonators are made from the findings of this work. This work was made possible through funding from the United States Department of the Interior Office of Surface Mining Reclamation and Enforcement.

Jan 1, 2012

By B. Soundara, A. Suganya, S. Selvakumar

"Expansive soils have a potential for shrinkage or swelling under changing moisture content. Attempts were made to reduce the swelling potential of expansive soils with conventional additives such as lime, cement, etc. and non-conventional additives such as industrial wastes. In this research an attempt is made to study the feasibility of using granulated waste expanded polystyrene (EPS) as an additive to expansive soil to control swelling. To investigate the effect of mixing waste EPS granules with expansive clays, three expansive soils with different plasticity index were manufactured in the laboratory by mixing sand with sodium bentonite of various proportions. A series of standard proctor test, California bearing ratio (CBR) test, one dimensional free swell and swell pressure tests were performed on these soils. Test results show that the inclusion of EPS granules significantly reduces the percent swell and swelling pressure when subjected to one-dimensional free swell conditions. The dry density and CBR values decrease with increase in EPS content and increased plasticity of the soil.INTRODUCTIONExpansive soils cover an area of about 257 Million hectares on the earth’s surface (Dudal et al. 1965). In India, the area covered by expansive soils is nearly 20 percent of the total area (Mohan et al. 1961). Movement is usually in an uneven pattern and of such a magnitude as to cause extensive damage to various structures, especially lightly loaded structures or pavements (Chen 1975). Stabilization is one of the methods of treating the expansive soils to make them fit for civil engineering purposes. The variety of stabilizers may be broadly divided into three groups (Petry et al. 2002): (a) traditional stabilizers (lime, cement etc.), (b) by-product stabilizers (fly ash, quarry dust, phosphor-gypsum, slag etc.) and (c) non-traditional stabilizers (sulfonated oils, potassium compounds, polymer, enzymes, ammonium chlorides etc.). Apart from these, a number of other ground improvement techniques such as sand cushion technique (Satyanarayana 1966); cohesive nonswelling (CNS) layer technique (Katti 1978) were adopted for the stabilization of expansive soils. Expanded polystyrene (EPS) is a polymeric foam normally available in white colour and is a wellknown packaging material. The geotechnical specialists recognize EPS as the most commonly used geofoam material, a type of cellular geosynthetic which has been in consistent use in geotechnical applications since the early 1960s (Horvath 1995). EPS has very low thermal conductivity and nearly 98% of the volume is air (Lye et al. 2002). EPS has many exceptional properties such as being lightweight, thermal insulating, shock-absorbing and having low-water pick-up, etc. EPS find its applications in geotechnical engineering as light weight fills in the form of blocks (Refsdal 1985, Karpurapu et al. 1992, Zou 2001, Ikizler et al. 2008). EPS can be used as compressible inclusion and as a vibration damper (Horvath, 1994&1995). EPS is also used in lightweight concrete owing to its lightweight, excellent heat preservation and sound insulation properties (Ravindrarajah et al. 1994; Miledet al. 2004 and Babu et al. 2005). Waste EPS granules have been used in with horticultural soils to improve a number of soil characteristics like improving drainage, lightening heavy soils and improving water uptake capacity of soils (Scheirs 1998). Furthermore, it was also used as sub-base materials for pavements and railway track beds (Hanna 1978; Duskov1996), construction materials for floating marine structures and fenders in offshore oil platforms (Bagon et al. 1976), sea beds and sea fences; as an energy absorbing material for buried military structures, (Perry et al. 1991)."

Jan 1, 2017

By J. Dong

"Xanthate is a sulfide collector that has been widely used in flotation for almost a century. It is inexpensive, easy to synthesize and apply, and produces good metallurgy in the right applications. However, a major drawback of xanthate is that it decomposes easily and generates CS2 gas in transportation, storage and operation, which can be harmful to human health. Also, excessive xanthate in tailings pond leads to toxicity of the process water and potential damages to aqua-life systems. New regulations in Ontario require that the TWA (time-weighted-average) value of CS2 in the work place is below 1 ppm, which is 1/10 of the previous limit. The stringent regulation may eventually sweep other regions of Canada with the increased awareness of healthy working conditions and environment protection. Therefore, it becomes very important to find xanthate replacements which will be “green”, i.e., environmentally friendly.In this research work, a systematic procedure is used for collector evaluation using the Sudbury nickel sulfide ores from Vale’s Ontario operations, starting with the collector properties (MSDS) evaluation, followed by batch flotation tests, miniplant tests, plant trials and economic evaluation. It is found that the most promising xanthate replacement is dithiocarbamate.INTRODUCTIONSulfide mineral flotation has been practiced since the early 20th century. Its industrial importance is well recognized as mineral concentrates from flotation can be economically smelted and refined to provide primary metals. Collectors play a vital role in froth flotation. There are reagents possessing both a polar group that binds them to the mineral surface and a nonpolar group that is oriented away from the surface to attach air bubbles. The introduction of xanthate as a sulfide collector in 1925 was a remarkable development in froth flotation (Keller, 1925). It is low cost, easy to synthesize, water soluble, simple to control in application. Most importantly, it has strong capability and usually good selectivity for sulfide mineral flotation, which have been keeping its application prominent for almost a century."

Jan 1, 2011

By Johanna Alegría-Ortega

Cr/CrN bilayer coating was deposited on AISI 440C by Cathodic Arc. The composition and structure of the Cr/CrN coating were investigated by scanning Electron Microscope, X-Ray Diffraction and X-ray Photoelectron Spectroscopy. The results show that crystal structure obtained was CrN phase with preferred [220] orientation. The hardness and adhesion of coating also were studied. The evaluation of erosion-corrosion (EC) on 440C bare and coated with Cr/CrN was performed by carrying out wear tests using a slurry jet with impingement angle 90° at 4 and 8 m/s. Corrosion, erosion and synergism wear rate were evaluated following the procedure described in ASTM G-119-09. This study presents that the synergism wear rate exceeds 40% of the total mass loss for coating and 60% of mass loss for the 440C, being the most aggressive wear component. The increase in impact velocity generated a rise in mass loss for both 440C bare and coated. The Cr/CrN coating offers better corrosion and erosion–corrosion resistance under all the tested conditions.

Aug 8, 2018

By Dennis A. Beiter, Kenneth G. Fields, Richard T. Stoltz

Section 56.5001 Title 30, [Code of Federal Regulations1], establishes requirements for respirable dust exposure in Metal and Nonmetal Mines based on the Threshold Limit Values (TLV&apos;s) adopted by the American Conference of Governmental Industrial Hygienists. Respirable dust samples collected by Mine Safety and Health Administration (MSHA) inspectors at a sandstone quarry showed certain workers were exposed to excessive concentrations during development of a "coyote tunnel" that was ventilated with a blowing system. Because exhausting face ventilation systems are known to control dust more effectively than blowing face systems, a change was proposed to improve worker respirable dust exposures. This paper describes the evaluation of the proposed exhausting ventilation system in the quarry&apos;s "coyote tunnel" and compares the respirable dust exposures with those measured by the MSHA inspectors with the blowing system. Results showed the proposed exhausting ventilation system reduced respirable dust exposures to less than 20 percent of those measured by MSHA inspectors when the blowing system was used.

Jan 1, 1993

By Ramin Motamed, Fahim M. Bhuiyan, Raj V. Siddharthan, Joseph Toth

The difficulty in material characterization and the erratic response of cemented soil layers, such as caliche in the Las Vegas valley, creates challenges for practicing engineers to reliably predict the response of deep foundations. The focus of this paper is the numerical prediction of axial response in drilled shaft foundations, which are commonly used in infrastructure projects (i.e., bridges and tall buildings) in Las Vegas, NV. The prevalence of hard caliche layers with variation in the degree of cementation add to the complication in numerical modeling. In this study, the applicability of two existing t-z models, developed for Florida limestone and soft rock, was evaluated based on numerical simulations of three bi-directional load tests conducted at caliche-dominant sites. The corresponding top-down load tests were also simulated for further assessment. A MATLAB-based finite-difference program, NVShaft, has been used to implement the mentioned t-z models in axial load analysis. Complexity originating from drilled shaft construction and the interaction with caliche during one axial load test resulted in a stiffer predicted response compared to measure data. For the other two load tests, both t-z models produced comparable load-displacement responses. It was observed that the t-z model for Florida limestone predicted relatively stiffer responses and higher drilled shaft capacity.

Sep 8, 2021

By T. Gerritsen, R. MacRosty, R. Pula

For several years Hatch has been installing fibre optic temperature sensors on the copper cooling elements of smelting furnaces to improve monitoring capabilities in critical locations. The metal/matte tapblock is a key area to monitor in the furnace as it undergoes severe wear from the molten material repeatedly drained through it. The high wear rate around the tapblock means downtime is necessary to perform refractory repairs. A good understanding of the tapblock condition allows the operation to maximize safety and production; consequently the metal/matte tapblocks have been the focus of this study. Fibre optic technology allows the installation of numerous sensors in locations that are very sensitive to refractory thickness, thereby providing information previously unavailable with traditional measurements. The transient nature of the thermal response to tapping and the three-dimensional geometry of the tapblock confound the interpretation of refractory thickness from temperature measurements. This paper focuses on the analysis of both plant data and thermal modelling simulations and details the progress made in relating the temperature measurements to the refractory thickness in front of the copper tapblock.

Jan 1, 2014

By M. Yavuz, M. Aksoy, G. Once, M. Iphar

This paper is concerned with a study on the floor heaving in the transport road of the GLI Omerler Colliery in Tuncbilek-Turkey. This gallery has been opened at the depth of 200 m through the formation of marl in 4.6 m width and 3.5 m height in cross section. Floor heaving occurred up to 70 cm in height in maximum and caused severe problems in railway and band-conveyor transportation in the main road. In addition; after the current panel mined out, the shield support units could not be transferred to the new panel because of the deformation of roadway cross-section. The I-profile steel arch supports also sank into the weak floor rock. This situation has been studied by numerical analysis using the FLAC3Dfinite difference program in order to investigate the rock mass behaviour around the opening. The obtained outputs of the numerical model have showed consistency with the amount of floor heaving in the gallery at 200 m depth. A new gallery has been driven at the depth of 115 m and M4 longwall panel has just been taken to production. So as not to encounter with the same problems at 200 m depth, especially longwall face moving problem, various numerical models have been studied in order to keep the floor heaving in the acceptable limits required to move shield support units. Keywords: Floor heave, Numerical modelling, FLAC3D, Failure criteria, RocLab

Jan 1, 2003

By L. St-Georges

In aerospace and transportation industries, severe problems are related to fatigue failure. Aluminium is frequently used in these industries to optimize the solidity and minimise the weight of the structures. Nevertheless, the fatigue life of aluminium alloys is limited and specific efforts have to be made to reduce the vibratory stresses in the mechanical parts. When riveted, the life of the sheet metal structures can be increased compared to welded structures, due to the energy dissipated by the friction between the rivets and the sheet metal and the sheets themselves. In the past decade, a new tool was developed to assemble aluminium structures; the friction stir welding. With this new technique, fatigue life of the aluminium welded joints can be increased by a factor from two to ten. However, less energy can be damped by the friction between the components and increased vibratory stresses may occur. In this investigation, the potential of the friction stir welding to create damped aluminium sheet metal structures is evaluated.

Jan 1, 2006

By Ali S. Al-Watban

"In this paper, the room temperature friction and deformation properties of various polycrystalline diamonds; i.e. aggregates of diamond crystals with a ""binder"" phase of cobalt and a polycrystalline coating produced by a chemical vapour deposition processes (CVD) were studied when softer metallic and ceramic sliders were used. The experiments were conducted· at relatively low sliding speeds (10 mm/min), in a vacuum of 10-5 mbr after having cleaned the specimen surfaces by out-gassing them for about 30 min at 800 °C. As a result of increasing the number of traversals significant wear of the coated diamond by softer metallic sliders (aluminium and mild steel) was observed. With ceramic sliders, it is shown that the multiple traversals result in the formation of wear groove. With diamond silicon carbide, high friction and adhesion lead to significant metal transfer which then pre-empts cumulative deformation of the harder materials. With the diamond-cobalt composite, the friction is surprisingly low, there accumulation of wear debris on the tip of the slider but no permanent transfer of metal and the harder specimen is not damaged even after 5000 traversal.IntroductionPolycrystalline diamond is mainly produced as tool materials for the machining of hard metals and composites. Thus, the sliding friction and wear resistance are amongst the most important properties relevant to those applications.During cutting by PCD the wear mechanism is mostly influenced by the chemical affinity between the tool material and the workpiece. For example, diamond based materials are not recommended for machining ferrous materials because carbon is highly solubie in iron: This leads to the graphitisation of diamond particles and hence a high rate of diffusion wear is observed (Brookes and Lambert, 1982)."

Jan 1, 2000

By Lana Alagha, Keitumetse Cathrine Monyake

The abstract discusses the synthesis and investigation of polyacrylamide functionalized chitosan polymers (CS-PAMs) as selective depressants for pyrite in the flotation of galena and chalcopyrite from complex sulfide ore. The study employed response surface methodology (RSM) to model and optimize the flotation process, varying parameters like the degree of deacetylation of chitosan, weight ratio of chitosan to acrylamide, and CS-PAM dosage. The developed RSM models effectively predicted iron and lead grades and recoveries, while optimization showed optimal pyrite separation from galena and chalcopyrite using CS-PAM synthesized from chitosan with a high degree of deacetylation and a specific chitosan:acrylamide weight ratio.

Apr 9, 2022