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By Frederic Becket

IN a recent article,1 which described the softening effect of columbium in plain high-chromium steels, the authors stated that their investi-gations had shown columbium to be also a particularly valuable inhibitor of intergranular corrosion in steels of the 18 per cent chromium, 8 per cent nickel type. It is the purpose of the present paper to record some of the results obtained through the introduction of columbium to the austenitic chromium-nickel steels. The damaging effects of this type of corrosion have become so widely known as to restrict considerably the applications of the steels under consideration, and therefore there is little question of the importance of the goal to be attained. Numerous contributions concerning the susceptibility of the aus-tenitic chromium-nickel steels to intergranular corrosion have appeared during the past few years, and among others who have dealt construc-tively with the subject are such well-known authors as Strauss and Houdremont of Germany, Hatfield of England, and Bain in the United States. Different theories have been propounded as to the cause of intergranular corrosion, and various remedial measures have been proposed, the majority of which involve the use of addition agents. Titanium is the addition agent at present most generally employed, as suggested by Houdremont and modified as described by Bain, Aborn and Rutherford.2 Little has been published on the effects of holding these steels for long periods at the relatively lower temperatures in the presence of

Jan 1, 1934

Cyanide is reactive to copper minerals and is not suitable to extract the gold from the copper bearing ores. Ammoniacal thiosulfate is considered an excellent alternative lixiviant for leaching copper bearing gold ores. Unfortunately the results of high reagent consumption and poor gold ex-traction were found by thiosulfate leaching of synthetic gold ores containing chalcopyrite, chalcocite or bornite and a mild refractory copper-bearing sulfidic gold ore. In this investigation, several processes have been applied to reduce the impacts of these minerals on gold leaching. The process included: the pre-oxidation of copper sulphide minerals in water or ammonia solution, the reduction of dissolved oxygen in the lixiviant (0.3 ppm DO or 0.7% oxygen), adding phosphate anion in the leach or pre-leach stage, and the addition of a strong copper ligand (e.g., EDA and DETA). The results indicated that the gold extraction could be improved to 93% with the thiosulfate consumption being reduced to less than 8 kg/t. The dissolution of copper minerals was found to be the major reason for increased consumption of thiosulfate and the highly reductive leached surfaces are responsible for the reduced gold extractions.

Jan 1, 2014

Effects of DA as a Grinding Aid on Selective Grinding of Low-Grade Bauxite Effects of DA (a copolymer of acrylic acid and acrylamide) as a grinding aid on selective grinding of low-grade bauxite were investigated in this study. The addition of DA into the grinding system enhanced the selectivity of grinding and increased the A/S ratio in the coarse fraction of ground product, leading to improved throughput of grinding mills and alumina recovery. The results showed that DA decreased the viscosity of slurry significantly and hence improved grinding efficiency due to low viscosity at a high slurry concentration. Both the hydrogen bond formation and chemical adsorption existed between DA and the surface of bauxite particles. The adsorption of DA on the surface of bauxite could decrease stress needed for crack initiation and extending during grinding, prevent new-born crack surfaces from rejoining, and promote the expansion of the cracks.

Sep 13, 2010

By Rodney D. Lamond

The need for blast vibration monitoring can be attributed to a combination of three factors: Structural damage, Blast design and Human annoyance. Traditionally, vibration damage criteria are prescribed in terms of peak particle velocity (PPV), as measured or predicted in the ground surrounding a blast. The PPV in the vicinity of a blasthole is strongly influenced by the quantity of the explosive per delay. In general, the existing prediction models give reliable results but fall short of addressing the change in PPV when the charge is decoupled and/or distributed.

Jan 1, 1995

By Bao K. Le, Khang T. Truong, Masaki Kitazume, Toru Kobayshi, Long P. Le, Tanaka Hitoshi, Makoto Kamimura, Hoang-Hung Tran-Nguyen

"Earth levees constructed using dredged materials taken from a river along an earth levee have annually damaged in the Mekong Delta due to high void spacing in earth levees and floodwater. Sliding and internal erosion due to floodwater or piping are two key factors causing earth levees’ failures. This study proposed to apply Deep Mixing Method (DMM) to reinforce earth levees in the Mekong Delta, Vietnam. The DMM creates a soil cement wall or soilcrete wall having better engineering properties such as higher strength and low hydraulic conductivity than those of the in-situ soils. The DMM can be applied to reinforce earth levees with limit additional materials that provinces in the Mekong Delta are difficult to supply. The study investigates capacity of the DMM to reinforce earth levees in the Mekong Delta, Vietnam against annual floods. Seepage and slope stability analyses under various conditions were performed with various scenarios of earth levee’s body. The analysis results indicate that the DMM can create a wall that cuts off piping across earth levee significantly and can improve stability against deep sliding due to rapid drawdown of the floodwater.INTRODUCTIONThe Mekong Delta produces agriculture products of 50% of the whole country even though the Mekong Delta has an agriculture area of 30% of the country (Wikipedia 2014). Rice is the main product for the domestic demand and export. This is the main reason why the local people want to cultivate rice 3 times per year to increase the total rice product for export. To do that, the local provinces have constructed earth levees surrounding each area of 100-200-hectare against annual floods to protect rice fields, and farmers can grow rice in the whole year. There are thousands of kilometers long earth levees in the Mekong Delta, and the local governments have spent millions of US dollars to repair and to maintain their earth levees yearly (reports of Dong Thap province 2012; 2014).Earth levees in the Mekong Delta have often failed in flood seasons (e.g., from August to December), especially in Dong Thap and An Giang provinces – the two provinces confronting directly the annual floods from the Mekong River when the floods reach the Vietnam land. The main failure of earth levees is piping, and then causing collapse of some section of an earth levee. An earth levee was usually constructed by piling up dredged materials along a river with minimum compaction. Subsequently, floodwater flows through connected void spacing and washes out soil particles in the body of an earth levee slowly to create piping. Annual wet-dry cycles make the top clay layer swelling and shrinking to form cracks that can store rainwater to trigger sliding (whitlow 2001; Ton That Vinh 2003)."

Jan 1, 2015

By A. B. Walker

The effects of the injection of dry limestone additives into boilers for the sorption of sulphur dioxide have been studied in pilot and full-scale systems. The effects of such injections on boiler mass particulate emissions as well as collectability characteristics of the fly ash and reaction products are presented. Implications of the effects on the design and economics of particulate collectors, in particular electrostatic precipitators, are discussed.

Jan 1, 1971

By Aleksandar D. Bugarski

Three types of uncatalyzed diesel particulate filter (DPF) systems, three types of high-temperature disposable filter elements (DFEs), and one diesel oxidation catalytic converter (DOC) were evaluated in underground mine conditions for their effects on the concentrations and size distributions of diesel aerosols. Those effects were compared with the effects of a standard muffler. The experimental work was conducted directly in an underground environment using a unique diesel laboratory developed in an underground experimental mine. The DPF systems reduced total mass of aerosols in the mine air approximately 10-fold for light-load and 20-fold or more for high-load test conditions. The DFEs offered similar reductions in aerosol mass concentrations. The efficiency of the new DFEs significantly increased with accumulation of operating time and buildup of diesel particulate matter in the porous structure of the filter elements. A single laundering process did not exhibit substantial effects on performance of the filter element. The effectiveness of DPFs and DFEs in removing aerosols by number was strongly influenced by engine operating mode. The concentrations of nucleation mode aerosols in the mine air were found to be substantially higher for both DPFs and DFEs when the engine was operated at high-load modes than at low-load modes. The effects of the DOC on mass and number concentrations of aerosols in mine air were relatively minor when compared to those of the DPF and DFE systems.

Jan 1, 2009

By Ove Rehnberg

Catalytic purifiers are widely used as exhaust treatment devices on diesel equipment in confined spaces. The paper summarizes some studies carried out at the University of Lulea on diesel exhaust purifiers. The main purpose has been to elucidate important chemical activities of catalysts useful for the improvement of their effect. The effects of platinum catalysts on exhaust constituents such as carbon monoxide, nitrogen oxides, unburned gaseous hydrocarbons, and polynuclear aromatic hydrocarbons are discussed. Also pointed out are the great differences in catalyst activity and advantages/disadvantages associated with the catalysts.

Jan 1, 1982

By N. K. Mendiratta

Diethylenetriamine (DETA) is known to be an effective pyrrhotite depressant in pentlandite flotation. It has been reported recently that its performance becomes more consistent when the reagent is used in conjunction with sulfur dioxide (SO2). In the present investigation, the effects of DETA and SO32- ions on the changes in the hydrophobicity of pyrrhotite electrode have been studied at pH 6.8. The results show that both DETA and SO32- can reduce the water contact angles of pyrrhotite; however, the contact angles can be reduced to zero only in the presence of the SO32- ions. This finding may be attributed to the ability of the SO32- ions to reduce the polysulfides formed on pyrrhotite by superficial oxidation, which may in turn provides an explanation for the robust performance of DETA/SO2 combination.

Jan 1, 2001

By K. Lapakko

Kinetic tests results are influenced by methodological variables, including test duration and mine waste particle size. Some samples tested produced neutral drainage in kinetic tests for more than two years prior to drainage acidification. The potential for long "lag times" can be assessed based on the mine waste mineralogy. The lag time duration can be estimated using this mineralogy in conjunction with dissolution rates observed in the kinetic tests. The influence of particle size on the drainage quality is dependent on the variation of the availability of acid-producing and acid-neutralizing minerals with particle size.

Jan 1, 1998

By J. Stachulak

In recent years more emphasis has been placed on the control of nitrogen dioxide (NO2) emissions from mining diesel equipment. Worldwide, diesel engine regulations to control emission and protect the environment are also driving the development of the diesel engine technology to reduce oxides of nitrogen NOx (Nitric oxide, NO + NO2). NOx are toxic gases produced in mines during the operation of diesel equipment. Most of the diesel equipment used in underground operations are equipped with Diesel Oxidization Catalysts (DOCs) designed to reduce carbon monoxide (CO) and hydrocarbons (HC). The effects of DOCs on NO2 production from diesel powered equipment is not well understood. DOCs do not alter NOx concentration, but may promote the oxidization of engine exhaust NO to the more toxic NO2, thus increasing the undesirable NO2 exposure of workers in the mine environment. In 2012, the ACGIH reduced the NO2 TLV concentration value from 3 ppm to 0.2 ppm. Vale and CanmetMINING have been involved in several research projects to reduce diesel emissions exposure to workers. One aspect of the current program is to determine the effects of in-use DOCs on NO2 production. Several in-use DOCs taken from mining equipment were selected for testing in the laboratory using ISO 8178-C1 and mine LHD transient test cycles. The paper presents the laboratory test results and effects of DOCs on NO2 production. The results indicate significant reductions in CO concentration, by over 77%, while increases in NO2 varied from 46% to 315% based on the ISO 8178-C1 8-mode steady state test cycle. The mine LHD transient test cycle showed the same pattern, although the magnitude of CO reduction was less. Consequently, it is recommended the use of only those DOCs that have been properly evaluated and shown not to significantly increase NO2 emission in the environment be used on mine equipment.

Aug 1, 2013

By Jacob L. Brinkman, Catherine E. Johnson

Unmanned aerial vehicles (UAVs) are being explored by researchers to measure concentrations of gas emissions in situations where such measurements are otherwise extremely difficult to obtain, such as NO and NO2 (NOx) emissions from surface mine blasting. Recently, countries have imposed or are planning to impose surface blasting gas pollution regulations, which creates a need for an improved understanding of UAV-based gas measuring systems. The experiments detailed in this paper were performed to determine if airflow generated by the rotors, also known as downwash, unnaturally alters concentration measurements. Downwash turbulence could create locations of varying pressure, which could affect concentration. A UAV fitted with gas sensors was attached to a stand in a controlled environment containing a mixture of NOx. The gas sensor measuring points were placed at various distances on and from the UAV body to evaluate downwash effects on gas concentration. Results show that the presence of downwash turbulence causes no statistically significant changes to concentration measurements at any distance or direction from the UAV. Based on these results, it is possible to use a UAV-mounted gas monitor to measure concentrations without concern for downwash interference, provided the UAV and measuring point are entirely contained within the gas cloud.

May 20, 2021

By B. Tiryaki, O. Z. Hekimoglu

Shearer drums are a critical component in the overall performance of coal shearers, with the cutting performance depending very much on the disposition of cutter tools on the drums (the tool-lacing arrangement). A series of practical and theoretical studies has been undertaken to investigate aspects of shearer drum vibration in terms of circumferential pick spacing. A number of commercially available drums were redesigned and the lacing patterns compared with those of the original drums under near-uniform conditions. Mine trials were carried out at the Middle Anatolian lignite mine in Turkey with drums fitted on Eickhoff type EDW-230 double-ranging drum shearers. It was found that the performance of drums could be improved if the concept of circumferential pick spacing was taken into account in CAD packages along with the existing design parameters such as cutting rate, reduced dust, low pick consumption and low down-time

Jun 19, 1905

Gangue-cemented paste backfill (GCPB), is a well-established green mining technology and significantly improves the recovery rate of mineral resources, prevents mine dynamic disasters, reduces surface subsidence, and consumes a considerable amount of solid waste. The addition of an early strength agent as an additive in cement-based materials provides several security, technical, and economic advantages. In this study, the early strength agent on the early age (3, 7 and 28 days) strength of GCPB is evaluated experimentally. The GCPB specimens have an initial sodium sulfate early strength agent concentration of 0%, 1%, 2%, 3%, and 4%, and the obtained samples were analyzed by testing for uniaxial compressive strength (UCS) and scanning electron microscopy (SEM). The test results show that the UCS of the GCPB specimens with sodium sulfate is much higher than that of the blank specimens. When cured for 3 days and 7 days, the strength of GCPB with 2% sodium sulfate increased the most, by 131% and 116% respectively. When cured for 28 days, the strength of GCPB with 1% sodium sulfate increased by 135%. Scanning electron microscopy (SEM) results showed that the GCPB with 1% and 2% sodium sulfate had better internal structure compactness, thicker acicular crystals, and more flocs. As a kind of early strength agent, sodium sulfate can react with calcium hydroxide to generate calcium dihydrate sulfate and then react with calcium aluminate; the hydration product (C3A) quickly generates calcium sulfoaluminate hydrate (AFt) needle-shaped crystals, forming an early skeleton and improving the early strength.

Jan 7, 2020

By Charles Zdazinsky

Over-break is undesirable in underground civil construction because it excessively damages rock along the perimeter of the tunnel, which directly influences the cycle times of advancement. A quicker cycle time for each process is required to optimize the operation and therefore minimizing over-break is essential for operational success.

Jan 1, 2015

By M. Oguz Ozkazanc, Gulsev Uyar Aldas

Because of its safety, being easy to handle, relatively inexpensive and containing a lot of energy, ANFO is the most popular and widely used explosive in Turkey as well as other countries in the world. According to change dated May 14th 1999 on the regulation 87/12028 related with explosives, blasters are not allowed to mix ammonium nitrate and fuel oil in the tield to make ANFO. Instead of this, they have been forced to use the ready ANFO prepared by explosive producer firms. As a result of this obligation, the use of technical nitrate for agricultural purpose and mixing AN and fuel oil in unsuitable conditions have been prevented. Indeed, wrong mixture means waste of energy and money.

Jan 1, 2001

By S. Noh, T. K. Kim, B. O. Lee

Future nuclear reactor systems such as a sodium-cooled fast reactor are being designed under severe conditions in terms of operating temperature and irradiation fluence compared to current commercial reactors. For realization of such systems, it is necessary to develop an advanced structural material having both high strength and irradiation resistance at high temperatures. Oxide dispersion strengthened (ODS) steel is considered as one of the most promising structural material because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density. Up to now, ODS steels have been intensively studied and developed to apply these materials to the in-core structural component of future nuclear systems. Several advanced ODS steels were designed and fabricated by a mechanical alloying, hot isostatic pressing and hot extrusion processes. This study focuses on the effects of heat treatment parameters during the fabrication process parameters on the microstructures of ODS steels for future nuclear system applications.

Jan 1, 2015

By S. E. Vanderslice, J. A. Hummer

"The results of laboratory evaluations were used to compare the potential of two alternative, biomass-derived fuels as a control strategy to reduce the exposure of underground miners to aerosols and gases emitted by diesel-powered equipment. The effects of fatty acid methyl ester (FAME) biodiesel and hydrotreated vegetable oil renewable diesel (HVORD) on criteria aerosol and gaseous emissions from an older-technology, naturally aspirated, mechanically controlled engine equipped with a diesel oxidation catalytic converter were compared with those of widely used petroleum-derived, ultralow-sulfur diesels (ULSDs). The emissions were characterized for four selected steady-state conditions. When fueled with FAME biodiesel and HVORD, the engine emitted less aerosols by total particulate mass, total carbon mass, elemental carbon mass and total number than when it was fueled with ULSDs. Compared with ULSDs, FAME biodiesel and HVORD produced aerosols that were characterized by single modal distributions, smaller count median diameters, and lower total and peak concentrations. For the majority of test cases, FAME biodiesel and HVORD favorably affected nitric oxide (NO) and adversely affected nitrogen dioxide (NO2) generation. Therefore, the use of these alternative fuels appears to be a viable tool for the underground mining industry to address the issues related to emissions from diesel engines, and to transition toward more universal solutions provided by advanced engines with integrated exhaust aftertreatment technologies. IntroductionDiesel engines have been the workhorses of modern society for industrial and transportation enterprises. Diesel engines of all generations are extensively used in a variety of light-, medium- and heavy-duty applications in underground mining operations around the world. Fuels obtained from various sources and with wide-ranging chemistries have been combusted in diesel engines. However, the bulk of the currently used fuel can still be traced to nonrenewable petroleum sources. The petroleum-derived diesel fuels are primarily made up of saturated acyclic hydrocarbons (parafins or alkanes), aromatic hydrocarbons (arenes or aryl hydrocarbon), and unsaturated hydrocarbons with double bonds (olefins and alkenes). Improvements in the quality of petroleum-based diesel fuels was identified in federal regulations as an important piece in resolving the puzzle of diesel engine emissions (Environmental Protection Agency, 2001, 2004). The reduction of U.S. diesel fuel sulfur content below 15 ppm had the effect of lowering sulfate emissions and enabling the development and implementation of catalyzed emissions control technology across a wide spectrum of applications."

Jan 12, 2017

By C Samuelsson, Q Shu, A Lennartsson, F Gyakwaa, A Andersson, J Isaksson

The physico-chemical property, viscosity, is essential for pyrometallurgical processes and influences the settling rate of valuable metal droplets in slag, affecting the metal recovery. The copper slag from smelting furnaces typically contains between 1 and 2 wt per cent Cu, which equals to or is higher than in most sulfidic copper ores mined today, meaning the slag is a valuable resource for copper extraction. A low viscosity is desirable for slag-cleaning through a settling furnace where entrained droplets settle under gravity. One approach to control the viscosity is through the slag composition. The literature has limited data on the correlation between viscosity, slag structure, and optical basicity of iron silicate slag with FeO/SiO2, CaO, and Al2O3 as factors. Therefore, the present study evaluated the influence of these factors on viscosity and correlations with slag structure and optical basicity. The FeO/SiO2 ratio (at%/at%) and the CaO and Al2O3 content were altered in two levels, resulting in a two-level full factorial design with three factors. The study was done by synthesising FeO–SiO2–Al2O3–CaO–MgO–Cr2O3 melts, followed by water granulation. The melt structure of the samples was analysed with the help of Raman Spectroscopy. The viscosity was then estimated with a high-temperature rheometer using a Mo spindle and crucible. The results showed a correlation between the optical basicity, FeO/SiO2 ratio, and viscosity, where a high optical basicity and FeO/SiO2 ratio were beneficial for achieving a low melt viscosity.

Jun 19, 2024

By K. Gharibi, A. Dehghani, S. Farrokhpay, M. Aghajanloo, M. Ostadrahimi

The effect of flotation operational parameters on froth stability and froth recovery was studied. Froth stability was measured using a special column. To determine the froth recovery, the froth height change model and froth height exponential model were used. It was found that since the interactions between the pulp and froth zones affect the time of froth formation, the exponential model is more suitable than the froth height change method for determining the froth recovery. The results showed that superficial air velocity and collector dosage have, respectively, the highest and lowest effect on the froth recovery, while froth recovery decreases sharply with increasing froth height.

Jan 1, 2021