Search Documents

By Junwei Han, Wenhua Li, Wenqing Qin, Fen Jiao, Wei Liu, Jiaqi Xu

"A novel technology was developed to study the process of recycling copper from waste printed circuit boards (WPCBs), which are the main source of metal production in the next decades. The chemical compositions of the WPCBs were investigated. The results indicated that the PCB powder was mainly composed of copper (38.5 wt.%), iron, aluminum, and non-metallic materials. Copper is mainly in the form of Cu and is the most valuable metal for the recycle of WPCBs. The concentrated WPCBs powder, obtained by the mechanical process, were pressed as the anode, which was directly electrolyzed to produce copper. The effects of H2SO4 concentration, Cu2+ concentration, current density, pole pitch, and liquid-to-solid ratio on the voltage, current efficiency, and copper extraction were investigated. The results indicated that the optimum conditions were liquid-to-solid ratio of 30 mL/g, current density of 571 A/m2, sulfuric acid concentration of 180 g/L, 50 g/L of copper ion, polar distance of 3 cm. Under the conditions, a desired current efficiency could be achieved. Meanwhile, about 95.62% Cu was recovered from the WPCBs. The experimental studies also revealed that the purity of copper obtained at the highest current efficiency was higher to 99.98%. Produced copper sheet were characterized by X-ray diffraction (XRD). XRD analysis indicated that the copper was the main phase. INTRODUCTION With the rapid development of electronic industry, more and more waste electronic and electrical equipments (WEEE) are generated every year (Fogarasi et al., 2012; Liang et al., 2013). The production of printed circuit boards (PCBs) is the base of electronic industry, because it is the essential part of all electrical and electronic equipments (Schlummer et al., 2007). As a result, a considerable amount of waste PCBs containing plenty of heavy metals have to be treated. In general, PCBs contain about 28% metals that are abundant non-ferrous metals such as Cu, Pb, and Sn. Printed circuit boards can be considered as a secondary resource for recycling rather than wasting. The contents of gold and silver respectively reach 80 g/t and 3300 g/t, which are much higher than that of primary ores. Copper is the main metal of PCB and its content is as high as 26.8% ( Zhang et al., 2009)."

Jan 1, 2018

By Ren G. Dong, Thomas W. McDowell, John Z. Wu, Chris Warren, Dan E. Welcome, Chun L. Dong

Hand forces are important factors for risk assessment of hand-arm vibration syndrome (HAVS).1 Grip force is one of the most important force components in the operation of powered hand tools. A considerable number of studies on grip force have been reported. It is well known that the grip force applied on a cylindrical handle is not uniformly distributed on each axis across the center of the handle cross-section.2 Therefore, maximum and minimum orientations of grip force exist around the handle. Such orientations have not been clearly identified. In a recently proposed international standard (ISO/CD 15230, 2005),3 it is stated that “the direction of the main gripping force is generally parallel to the z-axis defined in ISO 8727.” 4 This assertion is questionable, and further examinations are required. The objective of this study was to establish a fundamental theory on the distribution of the grip force around cylindrical handles. Methods As shown in Fig. 1, the grip force is defined as a vector composed of normal and shear components (FN & FT) in this study. Fig. 2 shows the hand coordinate system defined in this study, together with the ISO systems.1,4 Based on this novel grip force definition, we derived four fundamental properties and a theorem. More significantly, we formulated a novel hypothesis: similar to Mohr’s circle of stress, the normal and shear components can be represented approximately using an ellipse on the plane of the two force coordinates, as shown in Fig. 3. The maximum and minimum grip normal forces are termed as the first principal grip force (F1) and the second principal grip normal force (F2), respectively. Their corresponding orientations are termed as the first principal grip angle (a1) and the second principal grip angle (a2). A series of experiments were conducted to test this hypothesis. Twelve

Jan 6, 2006

By Naixiang Feng, Shaohu Tao, Zhihui Wang, Yuezhong Di

"A novel vacuum aluminothermic reduction lithium process was developed in present work which used lithium carbonate, alumina and calcium oxide as raw material. The process mainly contained three steps. The first step is that LiA102 clinker is prepared in ambient environment, then metal lithium is vacuum extracted from LiAl02 clinker with aluminum power as reducing agent, and the last step is that alumina is leached from the reduction residue with a mixture of sodium hydroxide and sodium carbonate. The results show that the lithium reduction ratio can be over 95% under the conditions of reduction temperature 1423K, reduction time 3h, and aluminum excess 20%. The main components of reduction residue are CaO· Al203 and 12Ca0·7Alz03. The alumina leaching rate of calcium aluminate in residue is over 80%. High-whiteness aluminum hydroxide can be obtained by carbonation precipitation of the reduction slag leaching solution.IntroductionWith a density about half of water, lithium is with the lowest density of all solids, mere 0.5 g/cm3 at 20 °C [l]. Lithium is widely used in aerospace, aviation, nuclear-generated power and electric battery industry. Nowadays, over 90 % of the world's primary lithium is produced by molten salt electrolysis [2-4]. But the development of molten salt electrolysis will be effected by some factors: cost, environment, and so on. Vacuum thermal reduction may be used extensively in future because of its low-energy consumption, high-purity and short-cycle."

Jan 1, 2013

By Jochen Petersen, Steven Bradshaw, Guven Akdogan, Ngoie Mpinga, James Mwase, Jacques Eksteen, Cornelius Snyders

"The platinum group metals (PGMs) and associated minerals are particularly refractory to most traditional direct leach processes. However, the remoteness of many new ore deposits, socio-political risks, the scarcity of skilled labor and constraints on the availability of water and electrical power makes it increasingly more difficult to implement the conventional mill-float-smelt-refine process routes to extract and refine PGMs in remote areas. This paper discusses a process to extract PGM’s from low grade ore and concentrate using a sequential stage heap leach process entailing heap bioleaching and high temperature cyanide leaching, and evaluates the feasibility of implementing a carbon-in-pulp process to recover the PGMs from the pregnant leach solution. The heap bioleaching extracts the base metals in an acidic sulfate medium using a mixed culture of thermophiles. After heap bioleaching the heap is reclaimed, rinsed, agglomerated and restacked for high temperature cyanide leaching where the cyanide liquor is directly heated via solar energy in panels. Palladium, gold and platinum are recovered during the cyanide leaching stage. The pregnant leach solution was evaluated for potential carbon-in-pulp adsorption and subsequent elution similar to gold processing. The kinetics of adsorption and elution compared well with gold adsorption and elution."

Jan 1, 2014

By M. Karmis

The algorithms for the mathematical modeling to predict productivity of underground room-and-pillar mining systems are well known and documented. These algorithms consider the time-varying relationships between mining equipment for a given geometry of operations as well as other constraints. This paper presents WebConSim, a newly developed, Web-based, user-friendly computer simulation tool for the Windows environment. The simulator is easily customized for use by field engineers, planning engineers, and management and will help mine operators plan the optimum mining sequence for different mine geometries and equipment layouts. Program output includes production data and equipment utilization indices, as well as time driven event chains that can be used for virtual reality presentations.

Jan 1, 2001

By Franklin B. Woodbury

As part of its goal of helping maintain an adequate supply of minerals to meet national economic and strategic needs, the U.S. Department of the Interior's Bureau of Mines is evaluating alternative technologies to treat oxidized taconites. Since process control is an essential element in the application of these process technologies, research was performed with a prototype monitoring system. A Californium-252 neutron source and a thermal neutron capture- gamma ray spectra analysis method was utilized to measure the amount of iron and the percent solids in the process slurries. The concentrate and tailing streams in a 410-kilogram-per-hour (900- pound-per-hour) pilot plant employing a selective flocculation and cationic flotation process were monitored. The results obtained showed that the thermal neutron capture-gamma ray reaction can be used to provide process control parameters.

Jan 1, 1979

By Y. P. Chugh, J. Ma

Higher production, better safety standard, and potential for automation are some of the benefits of longwall mining. Today, longwall face advances at a faster rate exposing many diversified rock layers in a short period of time. It is now a serious challenge to cope with ground control problems such as roof falls, face and floor failure, and excessive shield loading as fast as possible to minimize production and monetary losses. In Illinois coal mines, the existence of weak floor strata blow the coal seam may pose additional problems related to floor heaving, shield base punching, and associated roof and face falls. In this study, the effects of weak floor on longwall ground control are analyzed using two-dimensional finite element models. A two-leg 635.6-ton (700-short-ton) yielding capacity shield is included in the models to evaluate the effects of different thickness and material properties of the weak floor. The study indicates that the thickness and material properties of weak floor have significant effects on shield loading, the distribution and intensity of front abutment stress, failure zones in the surrounding strata, roof-to-floor convergence, and floor punching by the shield base.

Jan 1, 2000

By V. Petr, G. G. W. Mustoe, T. G. Rozgonyi

We introduced a numerical method that is applicable for the analysis of static and dynamic deformations of elastic media. In this numerical study, each elastic body is modeled with a system of several hundred rigid particles that are joined together elastically. Maximum shear stress fields due to external loading are obtained and compared with those obtained by photoelastic experiment. Preliminary results are presented for the stresses generated in circular disk shaped bodies idealized with connected systems of particles. Extension of this simulation method to fragmentation of brittle materials is also illustrated in an example.

Jan 1, 2000

A newly developed damage model was used in the study of rock fragmentation mechanisms involved in crater blasting. Simulations show that at the detonation of the explosive charge, a crushed zone around the explosive charge is formed due to compressive failure and then a strong pressure wave is sent out forming a pressurized ring that propagates at the dilatation wave velocity. As the pressurized ring leaves the crushed zone, two tensile stress components perpendicular to the radial stress are developed in response to the action of the radial pressure, causing tensile failure and forming a damage zone around the charge. The formation of this damage zone is quite independent of the depth of the explosive charge provided there is no interference by the reflection from the free face. When the pressurized ring reaches the free face, it is reflected there and causes rock failure on the ground surface that forms another damage zone. Under the simulation conditions, it is revealed that the depth of charge is a factor controlling the relationship between the two damage zones. At a depth smaller than the optimum, the two damage zones coalesce into one and there is excessive rock breakage; otherwise, the two damage zones tend to isolate from each other with the increase in the depth of charge. Calculations of fragmentation indicate that the average fragment size increases and the uniformity of fragments decreases when the depth of charge increases as observed in practical blasting.

Jan 1, 1998

By A. Mortazavi, H. Nasab

"The storage of petroleum products on surface is associated with difficulties and limitations. Accordingly, a viable alternative is to excavate underground space in rock and provide a safe way for oil storage. Soft rocks such as salt domes provide good conditions from environmental and operational points of view. The potential for high-volume storage and low permeability are encouraging aspects for oil storage in salt domes. The complicated shape of oil storage caverns, the complicated behavior of salt rocks, and boundary conditions associated with large underground openings are important challenges in the design of oil storage caverns. The aim of this paper is to delve into the stability and deformation mechanisms of storage caverns created in salt domes. A parametric study of effect of the cavern size, orientation, and depth is carried out as a function of ground stress regime. The stress field and deformation mechanisms are calculated for each case aiming at providing design guideline.INTRODUCTIONOne of the most popular soft rock that is used for underground oil storage is salt rock (halite). Salt rock has particular characteristics which makes it suitable for oil storage. Salt rock has several advantages for oil storage, these are: high production rate, high degree of availability, short filling period, high level of safety and low permeability [1]. The low permeability is due to the fact that halite deforms in a plastic manner over a wide range of pressures, temperatures and rates of deformations. This property prevents joints or gaps opening up in the formation, thus preventing the escape of liquids and gases. The state of stresses around the cavern in salt domes depends on the depth of the cavern (initial stresses and rock mass temperatures are increasing with depth), the in-situ stress state within the rock mass, and the internal oil pressure in the cavern. Furthermore, the salt creep behavior and the cavern geometry are influencing stress redistributions during loading and unloading phases.Rock mass structure, cavern geometry, material behavior and cavern operation patterns require complex physical models to describe the load-bearing behavior of the geomechanical structure. The determination of stress, strain and deformation in the rock mass due to cavern construction and operation are complex problems which can be evaluated employing numerical tools such as the Finite Element Method (FEM) or Finite Difference Method (FDM). In this study, the finite difference method was used to evaluate the behavior of oil storage cavern in salt rock."

Jan 1, 2015

By M. Nejati, A. Paluszny, R. W. Zimmerman

A numerical method is proposed to propagate multiple discrete fractures leading to primary fragmentation in a mine that is being worked using block caving. Deformation is computed using the finite element method, fractures are represented explicitly, and the mine domain is discretized by an unstructured mesh. Bedding planes are represented by systematically varying the elastic modulus of the rock and by defining horizontal weakness planes. Fractures and matrix are represented using parametric surfaces, and tips are defined by their boundary curves. Tip advance is controlled by a failure criterion, and a criterion for propagation direction and magnitude, based on the evaluation of the modal stress intensity factors. A novel domain integral approach is applied to accurately compute stress intensity factors (K) ahead of fracture tips in three dimensions. The method does not require a structured volumetric mesh structure around the crack tip, as integration is performed over a series of virtual surface domains along the crack front. The method is efficient, as it makes direct use of automatically generated, arbitrary tetrahedral meshes, and approximates stress intensity factors (KI, KII, KIII) along each crack front using Interaction-integrals. As opposed to the JIntegral, the method does not decompose K a-posteriori, but instead uses an auxiliary field to directly compute modal K. When using this method, numerical approximations of K do not exhibit dependence on the mesh layout, and require meshes that can generally be ten times coarser than are required by displacement- and stress-based methods. Volumetric meshing requires only, on average, 17% of each computation step. Thus, cracks do not follow any pre-existing mesh structure, and the method is well suited for high-density fracture datasets. The method is demonstrated for primary fragmentation of a mine area covering 110 initial draw points, immediately beneath a 2m high undercut. Displacement is constrained at all boundaries except the surface of the undercut. The growth of the fractures is investigated at the onset of the undercut. Ninety initial disc-shaped fractures are taken into account, each having an initial radius of 10 m. Fractures grow around the undercut, intersect the bedding plane boundaries, and the domain is fragmented as a result.

Jan 1, 2015

By P Lindsay

A numerical model has been developed to simulate the effectiveness and costs of a number of conceptual remedial measures aimed at reducing acidity and metal concentrations in the Ngakawau River and its tributaries near the Stockton Coal Mine, situated on the West Coast of New Zealand. The Stockton Coal Mine has been in operation over the past 100 years. During that time, seepage from waste rock dumps has contributed to elevated acidity and metal concentrations in the Ngakawau River and some of its tributaries. The yearly mean rainfall at the mine site is 6000 mm. The model, developed using GoldSim software, simulates rainfall, run-off and stream discharge for 26 tributaries. It then calculates acidity and metal concentrations in the mine impacted tributaries and the dilution downstream from the mine. The model has been calibrated to measured flow and acidity and metal concentrations in the Ngakawau River and some of its tributaries. Acidity and metal loads are removed from the system in accordance with specified efficiencies and capacities of the respective conceptual remedial measures. The user can compare specific remedial measures, or a combination of conceptual remedial measures. The model predicts the acidity and metal concentrations at a number of monitoring stations for any remedial strategy selected by the user. It also calculates the capital and operational costs for that particular remedial strategy. This paper presents the development of the numerical model and describes how the end-user can use it to compare the efficiency and costs of various remedial strategies by running different æwhat ifÆ scenarios.

Jan 1, 2006

By S. K. Sharma, ANKUSH GALAV, G. S. P. Singh

Providing a suitable protective water barrier pillar (PWBP) is common to reduce inundation hazards in underground coal mines. The imperative factors influencing its performance include the water head acting on the pillar, cover depth, pillar width, strength properties, and permeability characteristics. The mechanical failure of such pillar is a stress-controlled phenomenon, whereas the hydraulic failure is a strain-based phenomenon. A finite-difference numerical modeling approach was developed to study the hydro-mechanical coupled behavior of protective water barrier pillars. The mechanical stability was evaluated in terms of the percentage of failed (ZoF) and intact zones. The influence of the strain-controlled weakening on the permeability of the flow medium was studied through the coupling of the mechanical and hydraulic effects. The coupled steady-state model was used to estimate the outflow rate and its hydraulic stability. The adequacy of the protective pillar was also investigated by assessing mechanical stability and capability to resist hydraulic pressure against the maximum expected water head. A seepage rate-based classification system has also been proposed to evaluate the seepage potential and assess the hydraulic stability. The model has been validated for two case studies at the cover depth of 136–189.5 m and the existing pillar width of 16–42 m against the water head of 25–141 m.

Aug 18, 2022

By Gang Mei, Nengxiong Xu, Yanlin Zhang

After open-pit mining finishes, an iron mine with steeply inclined ore-bodies will generally transform to underground mining. Non-pillar sublevel caving method, with horizontal slice mining from up to down, is commonly used for mining deep ore-bodies under the open-pit bottom. As horizontal slice mining proceeds, a gradually enlarging goaf will be formed under the open-pit bottom, the rocks surrounding the handing and heading sides of the goaf will collapse continuously, and then these results in rock-mass failure with large deformation and displacement in the open-pit slope. Based on FLAC3D, a modeling approach to predict pit slope deformation and failure induced by transitioning open-pit to underground mining is proposed in this paper. This method mainly consists of three procedures of modeling, i.e., mining modeling, landslide modeling, and filling modeling, of which landslide modeling is the core of the proposed approach. In the procedures of modeling with FLAC3D, iteration non-convergence is taken as a local failure criterion of pit slope. When iteration calculation cannot converge, the sliding modeling will start by deleting some elements with large displacements, and finish until convergence. Before modeling landslide, several displacement contours of rock-masses in the pit slope are searched out, and each contour is an approximate possible sliding surface of the open-pit slope. From these contours, the most proper one is selected as the slope sliding surface by using the iteration calculation convergence and minimum element deletion as the judgment condition. Landslide modeling is then realized by removing the elements outside the slope sliding surface. Finally, to demonstrate the effectiveness, the proposed approach is used to simulate the process of open-pit to underground mining at Yanqianshan Iron Mine, and to predict the deformation and failure characteristics of open-pit slope during underground mining. The case study results show that: the prediction of the slope stability determined by using our method is consistent with that calculated by using the limit equilibrium methods.

Jan 1, 2015

By Dale S. Preece

The computer program. DMC Qistinct Motion &de), which w&s developed for simulating the rock motion associated with blasting, has been used to study the intluence of row delay timing On rock mOtiOn. The munerical simulations correspond with field observations in that vmy short delays (< 5Oms) and vety long delays(> 3oOms) produce a lower percent-cast thao a medium delay (100 to ZOO ms). The DMC predicted relatio&lp between row delay timing and percent-cast is more complex than expected with a dip in the auve where the optimum timing might be expected. More study is required to gain a full undasranding of this phenomenoo.

Jan 1, 1994

By Hyu-Soung Shin

This study is concerned with the characteristics of the behavior of steel-concrete composite drilled shafts, a material that is used for large bridge foundations, and especially for weak submerged ground conditions. Depending on the loading or boundary conditions considered, the behavior of foundation will vary. The bearing capacity of steel-concrete composite drilled shaft is influenced by initiation and propagation of fractures along the interface between steel casing and filled concrete. The interface effect is taken into account with the following two simplified cases: (1) detached model with free interface (no shear stiffness of interface) between concrete core and steel casing, (2) confined model by an upper steel cap with free interface. In the confined model, it is intended to have an unified behavior of composite shaft between concrete core and steel casing but there is interface between them. Intensive numerical studies have been undertaken to investigate detailed behavior of the composite shaft. In this study, 3-D finite element analysis is employed. Ground conditions typical of those encountered for the design of drilled shaft under water are considered affecting the behavior. Also, an attempt is made to generate possible combinations of the loads which have been considered in fields. Detailed characteristics of the stress and displacement distributions are evaluated to understand the mechanisms of composite shafts.

Jan 1, 2007

By Emile Scheepers, Chris Aldrich, Jacques J. Eksteen

The pneumatic injection of CaC2 powder into molten iron has become a very reliable and effective way to carry out desulphurisation. The key variables that influence the kinetics of this process are the condition and composition of the top slag, the oxygen activity in the hot metal and the injection conditions. Notable injection parameters include carrier gas flowrate, reagent flowrate, lance depth and initial sulphur concentration. A one-dimensional, steady-state model for momentum, heat- and mass transfer in rising gasliquid- powder plumes was developed for conditions relevant to the CaC2 refining process at Saldanha Steel?, South Africa. Combined with a model that predicts the contribution of the topslag to the process, the overall rate of desulphurisation as a function of time was determined, thereby quantitatively demonstrating the influence of the above-mentioned injection parameters on the kinetics of the desulphurisation process.

Jan 1, 2003

By R. C. FLEMING

G OLD MINING is enjoying a real revival in the West, and a considerable portion of the production is coming from small properties. The large mining companies of the world get most of the publicity, but in the last year the small gold property has often proved a more attractive field for the mining engineer looking for something to do. Old mines have been re- opened, prospects have been more closely examined, and many properties that were out of the running with the high commodity and labor costs of two or three years ago, have recently been making money for their operators. An interesting phase of this activity is the operation of so-called one-man mines. The west is dotted with these small properties, without the resources or reserves to warrant large-scale operation, but which return a living and often something over to one or two men who under- stand mining and simple methods of treatment.

Jan 1, 1932

By Ana E. Bohé, Georgina De Micco, Juan P. Gaviría, FEDERICO J. POMIRO, Gastón G. Fouga

Chlorination and carbochlorination processes have industrial applications in metallurgical activity for extraction and purification of uncommon metals such as rare earth elements (REE). This study reviews the chlorination and carbochlorination reactions of light REE (LREE) oxides with chlorine considering the thermodynamic, stoichiometric, and kinetic aspects of the reactions. Lanthanides between lanthanum to gadolinium were considered as LREE, in agreement with previous literature, and the results were detailed in this review. LREE were analyzed taking into account their oxidation states and were divided into three groups accordingly. The results presented show that, although the LREE are chemically similar, their behaviors during the reactions with Cl2 and Cl2–C, and the different LREE-O–Cl compounds formed, have particularities. It was observed that gadolinium, in both thermodynamic calculations and experimental results, presents some differences, and it can be considered intermediate between light and heavy REE; i.e., reactions between LREE2O3 and Cl2(g) begin at approximately 250 °C, except for Gd2O3 that begins at 327 °C. The present work will contribute to a better understanding of the chemistry of LREE oxides and Cl2 under different conditions and the products obtained in the LREE–O––Cl2(g) and LREE–O–C–Cl2(g) systems.

Oct 15, 2021

By Andrew Bamber

A fast and objective spreadsheet-based model for the financial evaluation of innovative mining and processing strategies such as pre-concentration vs. a conventional base case is presented. The size and grade of the deposit must be chosen, from which a mining rate is selected. Expected operational data for the deposit as well as any mill testwork and results from the pre-concentration testwork are entered as input variables on the sheet, and cost and revenue impacts are calculated in the ?Output? sheet. A capital sum and operating costs for the initial mine and mill development as well as the pre-concentration facility are calculated. The net changes in capital and operating costs are calculated, and impacts on revenue through changes in metal recovery are also calculated. These outputs are used to calculate the overall impact on the cutoff grade and thus the size of the mineral reserve using a generic grade-tonnage model. The NPV and NPV profile of the two scenarios is calculated, with variations in basic parameters such as operating cost, capital requirements, metal price or grade as well as discount rate. Cost and revenue impacts are evaluated and compared to the baseline to establish a positive or negative impact overall. Different scenarios of grade, tonnage, mining rate, process performance, capital and operating cost structure can be explored using the model. Outcomes projected by the model for case studies conducted thus far have been calibrated against internal estimates by the sponsoring organizations and found to be accurate to within 30%, confirming the utility of the model in practice.

Oct 1, 2009