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By George P. Demopoulos, Yan Zeng, Zhibao Li

Precipitated silica is marketed with a rising demand as reinforcing filler in the rubber industry and as a potential raw material for the synthesis of lithium-ion battery electrodes. Due to an awareness of the environmental impact of the existing processes for the production of precipitated silica, a green and sustainable process was proposed by using sodium bicarbonate (NaHCO3) as an alternative to sulfuric or hydrochloric acid in the precipitation reaction with sodium silicates. The use of NaHCO3 allows for better control of the supersaturation and pH to form silica with desired quality. Additionally, Na2CO3 solution as the process by-product is recyclable because it could be recovered to produce NaHCO3 by absorbing CO2. The solubility of sodium metasilicate nonahydrate (Na2SiO3·9H2O) in the Na-CO3-HCO3-OH-H2O system was measured using a dynamic method in the temperature range from 288.15 to 308.15 K. It is found that the solubility of Na2SiO3·9H2O decreases with increasing concentration of either Na2CO3 or NaOH over the investigated concentration range. With the aid of the OLI platform, a chemical model for the Na2SiO3-Na-CO3-HCO3-OH system was established with newly obtained interaction parameters of the Bromley-Zemaitis model by regression of experimental solubility data. The new model predicted the solubility of Na2SiO3·9H2O in multi-component systems with good agreement and was used to conduct a preliminary feasibility study of the new process.

Jan 1, 2015

By P. M. Soupios

The study of soft soil (wastes above the rock bed) an issue of great importance in civil engineering, is usually addressed by drilling boreholes. This method is rather expensive and time-consuming and although the information obtained is usually accurate, on the other hand it is much localized. Recently published researches have demonstrated the ability of the combination of geophysical exploration methods to estimate the thickness of deposited wastes, which provides the layered structure of the study area and certain, method depended, mechanical parameters as well. By theory, the frequency of resonance of an upper layer is a function of its thickness and the average shear velocity in it. Furthermore, the application of H/V spectral ratios of micro-tremors is a fast, straight forward and cost effective methodology, yielding the determination of the main resonant frequency of the soil. Based on this framework, 20 microtremor measurements have been carried out in a Landfill in Heraklion-Crete. Some of these measurements were deliberately close to drilled sites, where the basement had been reached. Three electrical resistivity tomographies were also used, in order to define the landfill structure such as, thickness, determination of different wastes distribution in the study area and other parameters. In addition, estimation of predictive Vs using empirical relationship between shear velocity and penetration resistance (SPT?s) were also conducted. Knowing the thickness and the resonant frequency, we estimated the shear (Vs) velocity of the waste cover. The final Vs model was confirmed using the results from the Vs-SPT correlation. The combinative implementation of the above mentioned geophysical and geotechnical methods have successfully defined geometrical and geotechnical/geophysical characteristics of the area under investigation in a fast and cost effective way.

Jan 1, 2005

By Joachim Ulrich

The spreading and splashing behaviour of single tin, lead, copper, aluminium and steel droplets impacting on a solid surface were experimentally examined. The droplet impact was observed using a high speed video imaging technique. The onset of splashing and the mass of the secondary droplets of impacting tin and lead droplets was quantified by the weight difference of the droplets before melting and the splat after the impact. The spread factor and the mass of the secondary droplets in dependence of the impact velocity is shown for different droplet materials, initial droplet diameters, target temperatures in ambient air and inert gas atmosphere. An empirical found correlation predicting the transition from spreading to splashing is presented by means of dimensionless numbers.

Jan 1, 1999

By B. C. Jena

Activities of carbon, cobalt and nickel were evaluated in the ternary systems iron-carbon-cobalt and iron-carbon-nickel for the temperature range 1300-1600°C for cobalt and 1300-1700°C for nickel. The carbon activities were determined from the knowledge of activities (1) in the binary system iron-carbon, (2) in the dilute ternary systems and (3) from the knowledge of carbon saturation data. The activities were mathematically expressed with the Taylor series expansion of Wagner's interaction parameter formalism modified to suit concentrated solutions. The cobalt and nickel activities were determined from the knowledge of carbon activities by applying the Gibbs-Schuhmann integration and from cobalt and nickel activities in the binary systems iron-cobalt and iron-nickel. Partial molar enthalpies of mixing were determined based on the temperature behaviour of the activity coefficients.

Jan 1, 1992

By Karl E. Burgher

Since World War II, the need for the use of explosives with testing, construction, demolition, mining and quarrying near urban areas has increased dramatically. Once remote, testing areas have been encroached upon by commercial and residential areas. Evidence has been found that overpressure levels near these areas can be estimated using meteorological conditions. This paper reviews a study where 205 test shots were fired, meteorological conditions recorded, and over-pressure levels estimated using multiple regression techniques.

Jan 1, 1988

By François Robert, Steve Green, Tyson Birkett, Dan Richardson

Abstract -Detailed sampling using a portable diamond drill, and interlaboratory comparison of selected samples have been combined with statistical studies of truncated populations to establish the gold content of several outcrops in the Val d'Or area. The outcrops chosen are non-mineralized. The background gold concentration in the rocks of the region is 5 ppb or Jess. Gold is distributed relatively homogeneously within the outcrops studied except for slightly increased concentrations within quartz-tourmaline veinlets. Three samples, of which 20 grams of powder are analyzed for each, can adequately determine the gold concentration of a structurally simple outcrop in the Val d'Or area.

Jan 1, 1992

By Tyson Birketi, Françoi Robert, Steve Green, Dan Richardson

Detailed sampling using a portable diamond drill, and inter laboratory comparison of selected samples have been combined with statistical studies of truncated populations to establish the gold content of several outcrops in the Val d'Or area. The outcrops chosen are non-mineralized. The background gold concentration in the rocks of the region is 5 ppb or less. Gold is distributed relatively homogeneously within the outcrops studied except for slightly increased concentrations within quartz-tourmaline veinlets. Three samples, of which 20 grams of powder are analyzed for each, can adequately determine the gold concentration of a structurally simple outcrop in the Val d'Or area.

Jan 1, 1992

By Anthony T. C. Goh

"For deep excavations in soft clay, it is common to use jet grouting piles (JGP) prior to excavation to minimize wall deflections and ground settlement, and to prevent basal heave instability. In this paper, finite element analyses were carried out to assess the basal heave factor of safety for excavations in soft clay supported by JGP. Comparison of the factor of safety from the finite element analyses with limit equilibrium methods was then performed. Subsequently, to account for the uncertainties in the soil and JGP properties, a simplified reliability analysis procedure is proposed to estimate the probability of basal heave failure for deep excavations supported by JGP.INTRODUCTIONJet grout piles (JGP) are often used to prevent basal heave instability and to minimize excessive wall and ground movements associated with deep excavations in soft clay deposits (Shirlaw 2003; Wen 2005; Ou 2006). The jet grouting process which is carried out prior to any excavation works produces a series of short overlapping grout columns resulting in a “continuous” base slab (commonly termed as jet grout pile or JGP) below the final excavation level that spans across the entire excavation (Gaba 1990; Hsieh et al. 2003; Ho and Hu 2006). Typically, the JGP thickness ranges from 2 m to 4 m.The focus of this paper is on the assessment of basal heave instability for deep excavations in clay stabilized with JGP. Finite element analyses were first conducted to determine the basal heave factor of safety for deep excavations in clay with JGP. Comparisons were then carried out with factors of safety based on conventional limit equilibrium methods. Since the conventional factor of safety approach does not explicitly reflect the uncertainties of the soil and JGP properties, it is demonstrated in this paper that a simple reliability based approach (Hasofer and Lind 1974) can be used to assess the probability of basal heave failure.LIMIT EQUILIBRIUM METHODFor excavations is clay, the Terzaghi (1943), Bjerrum and Eide (1956) and Eide et al. (1972) methods which are based on bearing capacity theory, are commonly used to determine the basal heave factor of safety. Another commonly adopted method in Japan and Taiwan is the slip circle method which involves taking moments about the lowest strut level (JSA 1988; Hsieh et al. 2008; Luo et al. 2012). The slip circle method has also been applied for excavations with a JGP at the base by incorporating the undrained shear strength of the JGP. In the slip circle method, the basal heave factor of safety FSslip is assessed by taking moments about the lowest strut level (Fig. 1)"

Jan 1, 1900

By Theophili CN, Kapenis AP

Seismic tomographic imaging has been applied to determine the blast induced damage zones in bauxite pillars in underground mining. At the retreating stage, when pillar dimensions are reduced from 8 x 8 m to approximately 5 x 5 m, the' seismic tomographies reveal, through measurements of the P-wave velocities which is a measure of the degree of fracturation of the pillar rock mass, the presence of three zones within each pillar. In the external zone, where velocities recorded are below 750 m/s. extensive pillar damage occurs which is attributed to both the growth and coalescence of pre-existing cracks and even the creation of new cracks in the rock mass. This effect is in agreement with literature, when considering the peak particle velocity as a criterion for rock failure in tunnels. In the intermediate zone, where velocities range between 7S0-1000 m/s, damage to a much lesser extent occurs which is due mostly to growth of pre-existing cracks and widening of their apertures. The inner zone, where velocities exceed 1000 m/s, is considered to be unaffected by blasting. Simple remedial measures of low cost, which are based on blasting mechanics are proposed to minimise the blast induced damage zone and consequently the transition zone.

Jan 1, 1995

By Adrian Moore, Alan Richards, Andrew Brodbeck

Structural blast vibration limits should be based on the strength of the structure, the stress induced by blasting, and a responsible factor of safety. In this paper a methodology that uses direct strain measurements to determine the stress induced by blasting is described. The methodology has been used to measure strain resulting from blasting, and establish appropriate blast vibration limits on a brick sewer tunnel, an underground mine heading, brick veneer houses, a water pipeline, and transmission tower foundations. An outline is given of the use of the methodology to establish limits for the main entry heading of an underground coal mine, and transmission tower footings. The methodology that is described has reduced uncertainty factors, and permitted the specification of higher blast vibration limits than had been previously used.

By Frank W. Cole, Sharanjit S. Dhillonn

A new method has been developed for calculating flowing bottom hole pressure in a gas well, using as a basis the general energy equation. Fundamentally, the method shows that a plot of flowing pressure versus depth for a gas well can be represented as a series of incremental .straight lines, with the accuracy in-creasing as the number of increments increase. It is shown mathematically that for most cases the slope of the flowing pressure versus depth curve is essentially constant, in which case a single calculation based on surface conditions will yield acceptable results. In all cases studied no more than two iterations were required for very good accuracy, and in most cases only one iteration was necessary. Several example calculations are shown and the results are compared to other commonly used methods of calculating bottom hole pressures These examples show that the method provides answers which are at least as accurate as other methods usually used, and results in a considerable reduction in computation time.

Jan 1, 1960

By R M. Arellano, D M. W Harney, M Makhuvha

Mineral resource and ore reserve estimates are founded on two sources of data: tonnage and grade. The tonnage is a product of volume and density; both of which are estimates. Density impacts numerous operational factors, which include, but are not limited to, mine design, mine planning, equipment selection and operational performance. Hence, density is a significant parameter and its determination requires similar care as the measurement of grade. Selecting an appropriate method to determine density, and ensuring its rigorous application, thus reduces risk and can improve operational performance, which in turn increases profit margin.Different Anglo American sites use a variety of practices and protocols to determine density, which is highly dependent on the physical characteristics of the orebody, local conditions and historical practices. Also, individual sites sometimes execute the same method in a slightly different way, which may also affect the outcome of the measurements. In order to gain a better understanding of how density is determined at Anglo American projects and operations, a review of these techniques was undertaken. The objective of the study was to identify and share good practices across the company, as well as to look for improvement opportunities, where applicable. Ten different methods of measuring density, applied to nine different commodities, were identified and described. An additional technique was recently developed by Anglo American Technical Solutions. The core pycnometer is a large gas displacement pycnometer capable of measuring density at high accuracy on full pieces of intact core.This paper provides an overview of methods used to determine density within the Anglo American Group, including quality control and quality assurance aspects. It is not the purpose of this paper to identify a preferred method, but to highlight the importance of choosing the best suited practice for a project or mine site. In addition, a case study comparing two different density determination methods applied to the same rock samples from the Los Bronces Copper mine was undertaken and the results of that study are presented here.Selecting the most appropriate method to determine density and comparing results from two or more techniques against each other, together with other suitable quality control procedures, is considered to be of utmost importance for all mining operations and exploration projects.CITATION:Makhuvha, M, Arellano, R M and Harney, D M W, 2014. Determination of bulk density in Anglo American plc, methods and impacts, with a case study from Los Bronces Mine, in Proceedings Ninth International Mining Geology Conference 2014 , pp 85–96 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By Erdal Unal

In underground mining today, safety and economical aspects demand a better understanding of the rock-mass conditions, particularly for design of underground mine openings excavated in weak and stratified rock mass. The rock mass classification systems, in essence, are empirical approaches utilized during preliminary design stage. These systems have been developed for specific purposes and rock mass types, therefore, direct utilization of the classification systems in their original form, for characterization of complex rock-mass conditions is not always possible. This is probably one of the main reasons why designers continue to originate new systems, or modify and extend the ones already existing. RMR and Q systems, for example, although widely used in mining and tunnelling, can not fully describe the specifications of the weak, stratified and flay bearing rock mass. Consequently, the engineering applications that would be carried out based on original RMR and Q ratings could be inadequate for making design decisions even during the preliminary design stage.

Jan 1, 1990

By Sumit Kumar Biswas, Moyukh De, Sibapriya Mukherjee

"The piles often are also subjected to lateral (horizontal) forces and moments. In fact, there are some structures where the primary function of piles is to transfer lateral loads to the ground. Proper analysis of laterally loaded piles is very important to the geotechnical and civil engineering profession.In the present investigation an experimental study has been carried out with free head short model cast iron hollow piles of outer diameter of 24 mm and L/d ratios of 8, 10, and 15. The experimental results have been supplemented by numerical techniques using PLAXIS-3D Foundation version 2.1 software. The results have been found to agree reasonably well with the experimental results. Further finite difference approach has been adoptedto reduce the computational time and to calculate the coefficient of modulus of subgrade reaction (?h) from the load- deflection data obtained from PLAXIS output at different pile depths. The parametric study has been extended for the non-dimensional form defined as flexibility ratio (F.R.),where ?h, L, Ep and Ip are the coefficient of modulus of sub-grade reaction, the embeddedlength of model pile, elastic modulus of pile material and the moment of inertia of model pile about the central axis respectively).The variation of coefficient of horizontal modulus of sub-grade reaction (?h) has been studied with respect to the following parameters for homogeneous soil system: relative density andL/d ratio. It has been found that the logarithm of flexibility ratio increases with increase inrelative density and increase inL/d Ratio. The values of ?h obtained by the proposed method have been, found to be close to the numerical results.As output of this research, graphs have been generated in respect of different parametric variations to gain an insight into behavior of piles under lateral load for short piles."

Jan 1, 2015

By Fookes R. A, Bunch K, Gravitis V. L, Watt J. S

The combustible volatile matter in coal mine roadway dusts (CVM) has been determined using x-ray backscatter techniques. The correlation between x-ray and chemical techniques is reasonably good for the 92 samples from collieries on the Bulli seam, and the maximum error expected at the maximum level of 11· 5 weight per cent CVM permitted in the N.S.W. Coal Mines Regulation Act, 1912, as amended, is about ± 2·5 weight per cent. This x-ray technique can be used only when the combustible volatile content of the coal matter (cvm) varies within a limited range, and a separate calibration is required for each coal seam.Portable equipment based on a radioisotope x-ray source ahd digital ratemeter makes possible simple and rapid analysis, and with adaptation to use in coal mines should lead to much more comprehensive testing- ofroadways and hence improved overall prevention of coal dust explosions.

Jan 1, 1977

By G. Brackebusch, S. J. Jung

Backfilling techniques are widely used in large-scale underground mines. Massive pillars, which have been left in place for stability, limit mining activity. Backfilling allows safe recovery of the ore remaining in pillars and assures long term stability. In deep mines expected high stress can be relieved with the backfill. Initially, waste rock was used to fill the openings with mixed results. The need to improve safety and reduce costs has prompted the industry to investigate alternatives. Hydraulic filling with Portland cement added has shown considerable promise, but little has been done to define the parameters of design effective system. The purpose of this study is to determine the relationship between backfill and mining components that can be used to effectively design a best-case hydraulic backfill.

Jan 1, 2000

By Cesimiro Fabian

The crystallite size of copper electrodeposits was determined by X-Ray powder diffraction analysis using a General Area Detector Diffraction Solution (GADDS) diffractometer. Crystallite size was calculated for copper thin films which were deposited on a 316 stainless steel rotating cylinder electrode (RCE) in the presence and absence of additive ?A?. The crystallite size was calculated from a corrected full width at half maximum (FWHM) of the [110] peak profile using the Scherrer equation. The test of significant difference on crystallite size was derived using Kruskal-Wallis method. It was found that in the absence of the additive the median crystallite size was 426, which decreased to 364 in the presence of the additive. As the additive degraded, the crystallite size increased to a size similar to that observed in the absence of additive.

Jan 1, 2003

By K E. Mudzanani, T A. M Msagati, D T. Maiga, T T. Phadi, M R. Letsoal, B M. Chabalala, S W. Limani

This paper addresses critical environmental, health, regulatory and scientific concerns related to gold mining activities in the specific area of Barberton, Mpumalanga, South Africa. The paper thus calls for informed decisions to be made by the authorities to safeguard both the environment and people’s health. The novelty of this study is based on its comprehensive nature of the simultaneous assessment of both cyanide and potential toxic elements (PTEs) in tailings, while taking into account their composition variability over time. By combining these aspects, it is then possible to provide a holistic understanding of the contamination risks associated with mining tailings and thus justify the need for regular monitoring and supervision to ensure compliance against regulatory limits. Additionally, this paper considered investigating the dynamic nature of tailings, which are subject to changes in their chemical composition due to exposure to weathering by various agents. In this study, the determination of weak acid dissociable (WAD) and free cyanide in tailings was performed using a validated method employing the South African Council for Mineral Technology (MINTEK) Laboratory Cynoprobe. The PTEs in tailings were determined by an inductively coupled plasma optical emission spectrometer (ICP-OES). The results revealed that the tailings contained primarily substantial amounts of PTEs, including Fe (87 566 to 37 800 mg/L), Cu (271 to 110 mg/L), Mn (2100 to 680 mg/L), Ni (400 to 390 mg/L), Zn (180 to 68 mg/L), Cr (645 to 510 mg/L), As (450 to 128 mg/L), and Pb (up to 35 mg/L). The cyanide concentrations in tailings varied between 0.20 mg/L and 0.26 mg/L for free CN (with a mean of 0.23 mg/L in water leaching), 0.23 mg/L to 0.28 mg/L for free CN (with a mean of 0.25 mg/L in alkali leaching), 0.24 mg/L to 0.35 mg/L for WAD CN (with a mean of 0.28 mg/L in water leaching), and 0.31 mg/L to 0.39 mg/L for WAD CN (with a mean of 0.35 mg/L in alkali leaching). The measured concentration of cyanide and the PTEs was compared to the minimum permissible levels enforced by the South African Department of Water and Sanitation (DWS) and the Water Research Commission (WRC) regulations that govern the disposal of hazardous constituents into the environment. Additionally, it was observed that the concentrations of contaminants in the tailings exceeded the acceptable minimum limits for hazardous waste exposure, posing risks to the environment and human health.

Apr 16, 2024

By Juan M. Antorena

A pile driving and testing program was undertaken to evaluate installation procedures, assess capacity, particularly in uplift, of 360- and 460-mm (14- and 18-inch) square prestressed concrete piles and provide foundation design parameters for the New Mid-Point Bridge project in Fort Myers, Florida. Nine piles were dynamically monitored during installation, and six piles were monitored during restrike driving to evaluate pile drivability and uplift and bearing capacity including time related capacity increases due to soil "set-up". In addition, two static load tests (tension and compression) were performed to calibrated the results obtain during the dynamic testing. This paper presents descriptions of the pile driving testing program along with findings regarding pile uplift and compression capacities from the static load testing, pile capacities from dynamic testing (CAPWAP® analyses), soil-pile adhesion values, wave equation factors, soil strength vs. time dependency, foundation design (anticipated pile tip elevation) and pile driving recommendations.

Jan 1, 1995

By A. V. Bogdanovich

In diamond ores processing, final waste tailings size, rejected to dump, is one of the most important parameters. On one side, it is necessary to minimize losses of diamonds, whose size exceeds 1 mm, on the other side ? to provide for the plant high throughput and sufficiently low capital and energy costs, which is in greater part connected with disintegration process. Extensive laboratory, pilot-scale and commercial-scale dressability studies of different types of diamond ores have been performed at JSC ?Mekhanobr Engineering? in recent years. With that, special consideration was given to determination of the required ores? disintegration size that would provide for a high recovery of diamonds. In diamond ores processing, in order to exclude breaking of large diamonds, stage disintegration is used with regrinding of light fractions and heavy fraction X-ray fluorescent separation tailings. On account of rather weak bonds of diamonds with enclosing minerals, in crushing and grinding of diamond ores, selective disintegration takes place, with aggregates? breakup along plane surfaces of least bonding, which facilitates liberation of diamonds and their transition to free state. Heavy components losses with different sizes of final dump tailings were studied in processing of large samples. It was established, that in order to almost completely exclude losses of heavy components over 1 mm size, light fractions had to be ground to 2.5-3 mm size, while X-ray fluorescent separation heavy tailings of -15+3 mm size do not contain diamonds larger 1 mm in aggregates, and their regrinding does not increase total recovery of diamonds. On the basis of the conducted studies, relationships regarding heavy components and diamonds losses with respect to diamond ores final disintegration size were obtained, providing for more rational organization of the ores disintegration and processing flow sheet. Keywords: diamond, waste tailings size, disintegration process, recovery of diamonds

Sep 1, 2012