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By Caroline Gomes de Oliveira

As fibras lignocelulósicas representam vantagens econômicas, técnicas e ambientais em comparação com as fibras sintéticas, como fibra de vidro por exemplo, quando se considera as alternativas de reforço aos compósitos. A fibra natural usada no presente trabalho é a fibra de eucalipto, que é largamente cultivada em território brasileiro. Este trabalho tem como objetivo avaliar uma análise estatística da correlação entre o diâmetro e a densidade da fibra de eucalipto. Para isso, foi aplicado o método de Weibull. O diâmetro foi obtido por meio de medições em projetor de perfil, enquanto a densidade utilizou determinações precisas da massa e do volume de fibras. Os resultados revelaram uma dependência inversa entre o diâmetro da fibra de eucalipto e sua densidade

Aug 17, 2017

By Catia Casagrande

O processo de pelotização foi desenvolvido com a finalidade de aproveitar as partículas finas e ultrafinas geradas nas operações de exploração e tratamento do minério de ferro. Os principais minérios que alimentam as usinas de Pelotização de Tubarão/Vitória/ES são provenientes das minas Brucutu, Fábrica Nova, Alegria, Conceição e Cauê. Os estudos de caracterização mineralógica e testes tecnológicos são realizados para auxiliar o processamento de minérios. Entretanto, alguns minérios possuem grande variabilidade de participação de minerais em sua composição, gerando necessidade de ajustes no processamento dos mesmos. Ter a previsibilidade mineralógica dos minérios é muito importante para atuar no processo com antecedência, realizando ajustes operacionais caso necessário, a fim de ganhar qualidade e reduzir custos. O método de cálculo normativo mineralógico é uma técnica nova que utiliza os resultados de análise química como base para quantificar minerais presentes no minério de ferro. O objetivo principal deste trabalho foi avaliar a aplicabilidade da metodologia de cálculo mineralógico normativo por meio de correlação com a microscopia ótica. As amostras analisadas foram pellet feed das minas de Fábrica Nova, Alegria e Brucutu. O estudo mostrou que existem diferenças entre as técnicas, entretanto os resultados foram promissores e satisfatórios.

Aug 17, 2017

The captions to Figs. 1 and 2 of the paper by B. J. Parry entitled 'High-strength cold-rolled steels' should read as follows:

Jan 1, 1984

By Tobin GJ

Testwork carried out in the cooling water circuit at the Yabulu treatment plant of the Greenvale Joint Venturers (Metals Exploration Queensland Pty. Ltd. and Freeport Queensland Nickel Incorporated) since 1980 has resulted in significant improvements to both fouling and corrosion control. At the same time corrosion inhibitor costs have been reduced.Acrylate-type silt dispersants were identified as the most effective means of sediment control in the circuit. An increase in the cathodic component of the corrosion inhibitor coupled with a relatively minor adjustment to water pH has yielded a two to three fold reduction in corrosion rate. It has been established that these lower corrosion rates can be sustained in the face of a 20% reduction in corrosion inhibitor addition rate. Further improvements are indicated with a change of raw water algicide.

Jan 1, 1985

By N. O. Taylor

THE failure, by swelling, of several cast aluminum-zinc, spiral, pump rods, used to circulate water in a constant-temperature bath, brought up the question as to whether the presence of tin in varying quantities would have any appreciable influence in controlling this action. Previous workers had found the same difficulty with aluminum-zinc alloys, due to their swelling in water or solutions of electrolyte^.^ It was known that pure aluminum was practically insoluble in concentrated sulfuric and nitric acids, presumably due to the formation of an oxidized film on the surface. Concentrated sulfuric acid had little or no effect on pure zinc and tin and concentrated hydrochloric acid would attack all three metals. These facts aroused curiosity as to the probable reaction of the ternary alloys of these metals, and tests were made to determine their resistivity to the action of common laboratory reagents. Samples, covering the entire range of the ternary series of aluminum, zinc and tin alloys, were made up from good grades of the commercial metals.2 The materials were melted, at as low temperatures as possible, in graphite crucibles in a gas-fired crucible furnace. Graphite crucibles were used in preference to clay, to prevent the absorption of silicon by the aluminum, as found by previous workers. The melted materials were stirred thoroughly with pine sticks in order to ensure complete mixing and the greatest possible freedom from oxidation, and were cast in sectional, iron molds giving bars % in. in diameter and 5 in. long.

Jan 1, 1927

By Anja Pfennig, Axel Kranzmann, Phillip Zastrow

"Properties of pipe steels for CCS technology require resistance against the geothermal corrosive environment (heat, pressure, salinity of the aquifer, CO2-partial pressure). To predict the reliability of two different injection pipe steels with 13% chromium and 0.46% carbon (1.4034, X46Cr13) as well as 0.20% carbon (1.4021, X20Cr13) steel coupons were heat treated by comparable routines prior to long term corrosion experiment (60°C, 100 bar, artificial brine close to a CCS-site in the Northern German Basin, Germany). In general higher carbon content exhibits better corrosion resistance with respect to corrosion rate, amount of pits and maximum intrusion depth in the case of local corrosion. At 100 bar hardened steels with martensitic microstructure have the lowest corrosion rates with an average of 0.003 mm/a after 2000 h exposure time. At ambient pressure normalized steels show the lowest corrosion rates, indicating that the corrosion is driven by grain boundaries.IntroductionEngineering a geological on-shore saline aquifer CCS-site (CCS Carbon Capture and Storage [1-3]) corrosion of injection pipe steels may become an issue when emission gasses, e.g. from combustion processes of power plants, are compressed into deep geological layers [4-8]. Typically 42CrMo4 (1.7225, AISI 4140) is used for casing, and for injection pipe the steel X46Cr13 (1.4034, AISI 420 C) or X20Cr13 (1.4021, AISI 420 J) is used. Saline formations are the most favorable storage sites in Germany [9], because of their large potential storage volume and their common occurrence. Leakage of CO2 back into the atmosphere may be a problem in saline aquifer storage, especially around the water level within the borehole. Carbon dioxide corrosion may cause failure of pipelines and wells as known from the oil and gas industry [4,6,10,11, 12].From thermal energy production it is known, that the CO2-corrosion is sensitively dependent on alloy composition, contamination of alloy and media, environmental conditions like temperature, CO2 partial pressure, flow conditions and protective corrosion scales [6-8,13- 20]. Considering different environments, aquifer waters and pressures, the analyzed temperature regime between 40 °C to 60 °C is a critical temperature region well known for corrosion processes as shown by Pfennig et al. [21-23] and various other authors [10,24-28] (figure 1). Here a maximum around 4.7 mm/year was found for the pit intrusion depth of 13% Cr steel X46Cr13. Still this may be predicted by the rather conservative Norsok-Model used in the oil and gas industry to calculate surface corrosion rates of carbon steels [29]."

Jan 1, 2014

By Ham. Y. M.

The corrosion behaviour of Al-B4C metal matrix composites immersed in 2500 ppm boron-containing H3B03, 0.5 M K2SO4, and 3.5% NaC1 solutions was investigated. Effects of B4C particle volume fraction on the corrosion behaviour of composites were studied using potentiodynamic polarization and electrochemical impedance spectroscopy techniques. Scanning electron microscopy was employed to study the surface morphology of the material before and after corrosion. Results show that all materials investigated are more corrosion resistant in 2500 ppm boron-containing H3B03 than in other solutions. No appreciable corrosion was observed in boric acid and sulfate solutions in contrast to an obvious pitting in NaC1 solution for both base alloy and composites. The preferential pitting sites are the interfaces of Al/Fe intermetallics for the base alloy, and the A1/B4C interfaces for the composites. Increasing the volume fraction of B4C particles in the composite decreases its corrosion resistance of Al-B4C composites.

Jan 1, 2011

By M A. Rhamdhani, R Z. Mukhlis

Removing the ledge formation in the Hall-Heroult cell during the electrolysis process may significantly reduce the energy requirement of the aluminium production process. In the absence of the ledge, however, the sidewall-material types become heavily restricted since the cryolite is very corrosive at the electrolysis temperatures. This paper study the corrosion behaviour of sintered nickel ferrite, nickel aluminate, and magnesium aluminate refractories (as possible candidates for sidewall material) in molten aluminium and cryolite melts with various alumina content at 980°C. Immersion tests of refractories with various porosity were conducted to assess the suitability of the refractories in the corrosive environment of the electrolysis cells. Microstructural change of the refractory after immersion were analysed using secondary scanning electron microscopy (SEM). Sampling of the melts were taken at 0, 10 min, 30 min, and each hour up to 6 hrs, and subsequently analysed by Inductively Coupled Plasma (ICP) spectroscopy. Based on the projected concentration of the refractories constituents in the melts, it was predicted that the corrosion rate of NiFe2O4, NiAl2O4 and MgAl2O4 in cryolite with 11 wt per cent Al2O3 were 461 × 103, 1.03 × 103, and 798 × 103 cm/a, respectively. Much lower corrosion rate of 2.3 cm/a for NiFe2O4, 2.6 cm/a for NiAl2O4 and 0.3 cm/a for MgAl2O4 were predicted if the refractories in contact with aluminium melts. Erosion played an important role in the corrosion as the concentration of the refractory constituents in the melts were beyond its solubility limit. It is therefore crucial to increase the densities of the refractory and improve its wetting characteristics.

Aug 21, 2024

By F. Charette

The paper reviews recent investigations of the impact of corrosion on the performance of both plain and coated Swellex rock bolts. It addresses the problems associated with estimating and predicting corrosion rates of friction bolts, and based on field data it suggests an empirical relationship to predict corrosion rates. A review of the necessary qualities for a protective coating leads to recent experience with coated Swellex bolts that suggest that they can contribute to extending the useful life of Swellex bolts in potentially corrosive environments.

May 1, 2004

By W. Dingley, G. R. Hoey

"AbstractWear of six types of grinding balls was compared with and without corrosion inhibition in grinding Ni-Cu sulphide and hematite ores in laboratory ball mills. Forged steel balls (Rc 60 to 65) and three types of white cast iron balls (Rc 50 to 65) were susceptible to corrosive wear and two types of stainless steel balls [AISI Type 440C (Rc 65) and AISI Type 302 is; 35)] were relatively immune. The relative wear rates of the five types of hard balls (Rc 50 to 65) were dependent on the corrosivity of the ore. Ranking of the hard balls with respect to wear resistance was consistent for the sulphide and hematite ores in the presence of corrosion inhibition, whereas their ranking was different for the two ores in the absence of inhibition.The electrochemical potential of the grinding balls was measured during grinding and was found to be a useful measurement for assessing the susceptibility of an alloy to corrosive wear. Reduction of ball wear for forged steel and white cast irons with corrosion inhibition was concomitant with a shift of ball potential to less active values. Ball potentials in the presence of inhibition were indicative of non-corroding metal surfaces.IntroductionA PREVIOUS STUDY by the authors (1) showed that corrosion inhibitors - sodium nitrite, sodium chromate and sodium metasilicate - reduced wear of forged steel grinding balls by up to 49% in grinding Ni-Cu sulphide ore. Although the mechanism of wear reduction was not elucidated, it was concluded that corrosion must play a significant role in the wear of grinding media. Remark and Wick (2) of Battelle Pacific Northwest Laboratories have also evaluated corrosion inhibitors for the reduction of metal wear using abrasive and n on- abrasive te sting procedures. Their research was sponsored by 16 companies throughout the world. Preliminary results indicated that anodic inhibitors prevent from one-fourth to one-half of the loss due to corrosion."

Jan 1, 1977

By D. Zim

Mining activity in South America is a growing enterprise. One of difficulties found in many areas of the South American continent, especially in north Chile and south Peru, is the shortage of water supply. In order to overcome this difficulty some mining companies proposed to transport the water from Pacific Ocean up to the mountains. This can be accomplished by the use of stainless steel pipelines, but this is a cost prohibitive solution and is also subject to severe pitting corrosion in a saline environment. The use of mild steel may be a lower cost solution than stainless steel as the material of construction for pipelines but it is subject to corrosion anyway. The corrosion in this case can be internal or external corrosion although cathodic protection as well preventive maintenance usually is enough to mitigate external corrosion without the need to shut down the pipeline. The same is not true about the prevention of internal corrosion. It is not practical, sometimes not even possible, shutdown a pipeline to carry out an inspection and fix sections where potential failures are detected. It is possible avoid corrosion caused by sea water within the mild steel pipelines by applying a proper chemical program designed to virtually eliminate dissolved oxygen in the water commonly called deaeration.1 This type of treatment obviously involves additional capital investment since it requires the construction of one deaerator with the first pumping station and additional equipment at each point where the water can come into contact with oxygen. Deaerators will increase operational costs and subsequent injection of chemicals will be required in the case of multiple degasification facilities thus increasing the consumption of chemicals. grams based on oxygen scavengers, the objective of the present study is to develop a new water treatment capable of preventing mild steel corrosion in aerated sea water. The new treatment must be able to prevent both generalized and localized (pitting) corrosion and overcome the necessity to construct and operate deaerators.

Feb 23, 2014

By W. Dingley, G. R. Hoey

"Thirteen Canadian sulphide ore mines were surveyed for corrosion control. The mines visited were a small, yet representative, proportion of this segment of the Canadian mining and metallurgical industry. Information on metallic corrosion and methods used to control it in underground workings and mills was gathered (a) by discussing corrosion problems with company personnel, (b) by examining equipment and structures during under-ground and mill tours, (c) by photographing corrosion sites, and (d) by collecting and analyzing mine water samples.The corrosion survey, which is summarized in the re-port, leads to the following general conclusions. Mine environments are corrosive, particularly when the mine w1a-ter is acidic. Because of a lack of good corrosion control measures, excessive deterioration of equipment due to corrosion occurs in mines. Mill environments are also corrosive, but in some cases good preventive measures are being taken to effectively control corrosion losses.Ways to reduce corrosion losses in sulphide ore mines and mills are discussed. The main areas for more corrosion research and development are selection of materials of construction, protective coatings, cathodic protection, inhibitors, equipment design, and mining and milling practices."

Jan 1, 1971

By Anja Pfennig, Thomas Böllinghaus, Marcus Wolf

During CCS components are exposed to a corrosive environment and mechanical stress which results in corrosion fatigue and is inevitably followed by the lifetime reduction of these components. The lifetime reduction of the cyclically loaded high alloyed stainless injectionpipe steel AISI 420C (X46Cr13, 1.4034) constantly exposed to highly corrosive CO2- saturated hot thermal water is demonstrated in in-situ-laboratory experiments (T = 60 °C, brine: Stuttgart Aquifer, flow rate: 30 l/h, CO2) in an environment similar to the on-shore CCS-site in the Northern German Bassin. In-situ tension-compression experiments were established simultaneously along with electrochemical measurements using a newly designed corrosion chamber in a resonant testing machine at a frequency as low as 30 – 40 Hz. In addition technical CO2 was introduced into the closed system at a rate close to 9 L/h. S-N plots, micrographic analysis and surface analysis of the fracture surface are demonstrated. X46Cr13 (surface roughness Rz = 4) reached the maximum number of cycles (12.5 x 106) at stress amplitude of 173 MPa producing a low scatter range of 1:3.5. Hydroxide and siderite layers were found on pits and crack surfaces. No typical fatigue limit exists. Pit corrosion prior to crack initiation may be identified as failure cause.

Jan 1, 2016

By V. Brabie, S. Jansson, L. Bohlin

The rate of dissolution of solid MgO-C and doloma into liquid in CaO-Al2O3-SiO2-MgO slag at different temperatures was studied under conditions of forced convection by rotating cylindrical refractory specimens in a stationary crucible containing the molten slag. The corrosion rate was calculated from the change in diameter of the cylindrical specimens. Refractory specimens were 13 mm in diameter and 70 mm long. The specimens were rotated for15 to 120 minutes at speeds of 100 to 400 rpm in the molten slag. The rate of corrosion increased with temperature and with the rotating speed of the rod, and decreased when the slag was nearly saturated with MgO. The experimental results confirm the assumption that the diffusion of magnesium oxide through the slag phase boundary layer controls the corrosion process. The corrosion mechanism seems to be the dissolution of the refractory materials into the slag, followed by penetration of pores and grain boundaries and dispersion of the grains in the slag. Keywords: MgO-C refractory, doloma refractory, molten slag, corrosion rate, corrosion mechanism

Jan 1, 2004

By Liyuan Chai

The corrosion mechanism of A3 steel induced by chloride ions in the purified water had been investigated with the A C Impedance technique. The results showed that there were another two factors which determined its electrochemical corrosive rate: the electrode potential and coverage ratio of chloride ions on the surface of A3 Steel. The corrosion mechanism of A3 steel in the solution with chloride ions emendation was two steps of electrode process with the rate-determining step of 0,32kFeClFeCle+--¾¾®++.

Jan 1, 2009

By Guangshi Li, Xionggang Lu, Xueliang Xie, Xingli Zou, Yuyang Bian, Hongwei Cheng, Kai Zheng, Changyuan Lu

The corrosion resistance and corroded microstructure of MgO-C refractory in molten slag are investigated by immersion test in muffle furnace at 1600 °C . The microstructure and chemical compositions of the specimens after erosion experiment are characterized by scanning electron microscope (SEM) and energy dispersive X-ray (EDX). The results confirm that the oxidation of graphite is the most important degradation mode of MgO-C refractory. The structure of the refractory material is damaged due to the decrease of graphite, as a result, the periclase substrate reacts with the molten slag directly. The corrosion process is controlled by the dissolution of the refractory materials into slag, low melting point oxides are therefore generated which lead to the damage of MgO-C refractory finally.

Jan 1, 2015

By P. Hubert, J. P. Ildefonse, F. Qafssaoui, J. Poirier

Corrosion tests by corrosive alumina-lime slags were carried out on commercial high alumina bricks used in steel ladle linings and model refractories (with different raw materials : bauxite, andalusite, and different microstructures). Using (SEM) scanning electron microscope and (EDS) energy dispersive spectroscopy, microstructures of slag-corroded refractory interfaces were studied in detail. The monomineral and glassy phases, the composition of reaction products and chemical profiles were determined. A thermochemical analysis based on phase equilibrium diagrams has permitted to estimate the proportion and the composition of the high temperature intergranular liquid phase. These data were compared to the experimental microanalysis results. The viscosity of the high temperature liquids were calculated according to Urbain 's model and the relationship between the viscosity and the penetration of liquid phases were discussed. These theorical and experimental results were used to understand the complex phenomena of slag penetration and corrosion of andalusite and bauxite refractories at high temperature and to propose new ways of improvements for the formulation of high alumina refractories.

Jan 1, 2004

By G. J. Biefer

"Fatigue and corrosion fatigue measurements were carried out on five commercially available metals -four steels and an aluminum alloy -which are used as structural materials in mine shaft conveyances. In the corrosion fatigue measurements, drain waters collected in the shafts of three different Canadian mines were used as corrodents. The mine waters had been selected on the basis of their relatively large differences in acidity and/ or composition.It was found that the corrosion fatigue strengths of the four steels were similar, despite their differences in tensile properties, and that the type of water used in the tests had little effect on the results. Mild steel showed the highest and most consistent values of the damage ratio (ratio between the corrosion fatigue and the plain fatigue strengths at 107 cycles). The corrosion fatigue behaviour of the aluminum alloy (ASTM Type 6061-T6) was found to differ markedly in the three mine waters. A high damage ratio (i.e., superior performance) was shown in a mine water in which the corrosion attack was uniform; much lower damage ratios were shown in waters which produced localized corrosion attack. Corrosion rates were too low to be deter-mined conveniently by conventional weight-loss methods, but calculations from polarization curves provided a rapid demonstration that corrosion rates were distinctly lower in the mine water which produced high damage ratios."

Jan 1, 1967

By F. L. Wolf

THE catenary system of line construction possesses so many desirable characteristics from the operating standpoint that it has wide application for all types of electric traction. Many steam roads are electrifying sections of their lines, and in most cases are operating both steam and electric locomotives over the same track. This' means that the overhead catenary system is subjected to the severe corrosive action of locomotive smoke, and data concerning the resistance of various alloys to this form of corrosion are very desirable from every point of view. Reliable and specific information and data on the subject of corrosion due to steam and smoke from locomotives are extremely meager and, on this account, extensive service tests, together with accelerated tests, have been made on a number of commercial metals and alloys. The observations and data recorded in this paper are the result of a, preliminary test which was started in 1923 and which has been carried on to the present time. The recognition of the need for even more detailed and accurate data has resulted in the undertaking of another test which has been in progress for about a year. The result of this test will be published in due course. Some years ago The Ohio Brass Co. was asked by one of the large steam railroad companies to furnish data on construction details for a catenary system which it was considering for one of its divisions. The selection of, materials which would give the necessary physical characteristics as well as withstand the severe corrosive action of locomotive gases caused electrical railroad engineers considerable concern. At that time, there were available no specific or authentic data on these important questions: no systematic investigation of the problem appeared to have been made, even though its importance was generally recognized. Such observations as had been made were crude in that they had been limited largely to visual inspection which too frequently is most misleading. However, the scattered information which was collected gave important clues as to how best to start an investigation.

Jan 1, 1930

By John Wulff, J. H. Hollomon

THE opinion has been widely held that the corrosion of alpha brass occurs by the selective solution of zinc. As late as 1939, Fink1 and Evans2 suggested that in the initial stage of the corrosion the selective solution of zinc produces copper-rich areas, which subsequently act as cathodes that facilitate the deposition of copper. Previously Abrams3 had shown that most of the copper found on corroded brass was redeposited and not residual, although he did not consider the nature of the initiation of the corrosion process. Enough data exist to indicate that any metal surface is sufficiently heterogeneous to provide the anodes and cathodes necessary for the initiation of corrosion.4,5 Thus, for alpha brass we need postulate not an initial selective solution of zinc, but only the existence of local differences in electrochemical potential. The heterogeneity responsible for potential differences may arise from oxide and other films as well as from alloy concentration gradients. Even though selective corrosion may be possible in some alloy systems, previous data on alpha brass as well as the experimental work reported in this paper do not require this supposition. Bengough and May,6 in a discussion of Abrams' paper, first suggested the addition of small amounts of arsenic (0.03 per cent) to alpha brass to prevent the redeposition of copper (dezincification). This suggestion was later substantiated by Nixon.7 In their studies of the inhibiting influence of arsenic, Evans and Fink were led to the selective-solution hypothesis in order to explain the initial corrosion of such alloys. They believed that an arsenic film covered anode areas and prevented the formation of copper-rich spots capable of acting as cathodes for the deposition of copper. They did not consider, however, the mechanism by which the arsenical film was formed. Bengough and May,8 in another publication, suggested that the commonly found gray or black arsenical film may act to: (I) carry oxygen to the brass surface, (2) increase the discharge potential of copper on brass, (3) precipitate cuprous chloride from colloidal suspension in chloride solutions. Masing9 assumed that the film found upon arsenical brass was metallic arsenic. His measurements of hydrogen overvoltage of bulk arsenic led him to believe that the inhibition of dezincification occurs because the overvoltage of a brass surface is lowered by the arsenic film. He reasoned that this film would permit the more rapid reduction of hydrogen at the cathode, which would prevent the redeposition of copper. In a recent paper,10 we have pointed out that the film formed during the corrosion of arsenical brass and copper in stagnant solutions is essentially arsenious oxide (As203),

Jan 1, 1942