Search Documents

By A. S. W. Kurny, M. Z. Huq

Bangladesh ilmenite is partially altered, containing pseudorutile, rutile and haematite as well as the predominant ilmenite phase. A typical analysis is 39.45% TiO2, 24.19% FeO and 33.0% Fe2O3. Reduction of the ilmenite by charcoal was found to involve two major reactions: conversion of pseudorutile into ilmenite and rutile, and change of ilmenite into metallic iron and rutile. The first, which was much the faster reaction, was responsible for an initial increase in ilmenite content with reduction time at lower temperatures. Apart from these two major reactions, rutile was reduced to lower oxides at 1 100 degrees C with a consequent decrease in its XRD peak height

Jun 19, 1905

By M Haest

This study demonstrates the application of HyLogging™ technologies for mineralogical characterisation of different iron ore types throughout the Hamersley Province (Western Australia), including a channel iron deposit (Murchison Metals Ltd) and bedded iron deposits in the Brockman and Marra Mamba Iron Formations (BHP Billiton Ltd).Drill core from these deposits was analysed using CSIRO’s hyperspectral drill core logging systems (HyLogging systems), which are commercially available at the AMDEL and AMMTEC laboratories in Perth (Western Australia), through a leasing agreement. These HyLogging systems provide high resolution photographs at 0.1 mm pixel resolution as well as visible and infrared spectroscopic refl ectance data at 1 cm spatial resolution. The minerals identified include haematite, goethite and its subtypes (ie vitreous and ochreous goethite), AlOH-clays (kaolinite, Al-smectite and white mica), carbonates, gibbsite, chlorite, amphibole and hydrated silica as well as water content. The abundance and composition of these minerals was established from the spectral data and was validated against XRF analyses.The full potential of HyLogging systems in the iron ore industry is only starting to be unveiled, but some major benefits have already been demonstrated:• HyLogging systems can delineate different ore zones by mapping the vitreous and ochreous goethites. This has a potentially large impact in mine planning and operations, as hard, vitreous goethite and soft, powdery, ochreous goethite have different processing characteristics that can affect plant throughput if not carefully managed.• HyLogging mineralogy can also be used to support stratigraphic interpretations of the host, for example in subdividing the Dales Gorge 1 - 4 submembers of the Brockman Iron Formation.• HyLogging can have a potentially signifi cant impact on waste rock characterisation, as many of the waste materials can be identifi ed and quantifi ed with hyperspectral data (eg clay-type,• hydration state).• HyLogging can provide accurate three-dimensional (3D) mineralogy to iron ore companies that will empower them to improve future exploration and resource planning.• Application of high resolution photography to further improve ore deposit domaining is also to be considered.

Jul 11, 2011

By P. N. Erasmus, M. Heyns, M. J. Pretorius

The characteristic of stope supports plays a vital role in the design of the supports. This paper deals with the characterisation of both cellular lightweight concrete and timber supports since both supports absorb and dissipate the energy in different ways. The behaviour of the support and hence its performance is simulated for different loading conditions by constructing a model consisting of various mechanical components like springs, dampers and blow-off valves. When the force exerted by the stope support increases significantly during deformation of the support, the stresses in the hangingwall could exceed values where failure of the hangingwall may occur. There is a need to understand this phenomena and the work presented in this paper is a first attempt to start with the characterisation of the stope support. Les caractéristiques des supports de taille jouent un rôle vital dans la conception des supports. L’étude présente traite de la caractérisation des supports cellulaires en béton léger et en bois, puisque ces deux types absorbent et dissipent l’énergie de façons différentes. Le comportement du support et par conséquent sa performance est simulée pour des conditions différentes de chargement en construisant un modèle qui consiste en des organes mécaniques variés tels que ressorts, registres et valves d’échappement. Quand la force exercée par le support de taille augmente considérablement pendant la déformation du support, les contraintes dans le toit peuvent dépasser des valeurs qui pourraient entraîner la défaillance du toit. Il est nécessaire de comprendre ce phénomène et l’étude ici présentée constitue un premier essai dans la caractérisation du support de taille. Die Charakteristika der Strossenunterstützung spielt im Design von Unterstützungen eine vitale Rolle. Diese Arbeit befaßt sich mit der Charaketerisierung sowohl der porösen Leichtgewichtbeton- als auch mit der Holzunterstützung, da beide Unterstützungen Energien auf verschiedene Art und Weise absorbieren und auflösen. Das Verhalten der Unterstützung und folglich seine Leistung wird für unterschiedliche Ladezustände simuliert, indem ein Model konstruiert wird, welches verschiedene mechanische Komponenten wie Federn, Dämpfer und Ausblaseventile enthält. Wenn die von Strossenunterstützung während einer Unterstützungsdeformation aufgebotene Kraft signifikant ansteigt, könnten die Spannungen im Bereiche des Stollenfirstes Werte überschreiten wo ein Versagen des Stollenfirstes eintreten kann. Es besteht die Notwendigkeit dieses Phänomen zu verstehen, und die Arbeit, die in diesem Elaborat dargestellt wird, ist ein erster Versuch, mit der Charaketerisierung der Strossenunterstützung zu beginnen.

Jan 1, 2003

By Beamish B. B

In this study, a systematic examination of the scale and variety of micro-structures in coal using Scanning Electron Microscopy (SEM) has been carried out, using coal samples of differing stages of coalification from the Bowen Basin and New Zealand. SEM provides detail of various micro-structural features and shows that a variety of micron-sized fractures and cavities are present in coals. These are differentiated into three pore types: fracture porosity, phyteral porosity and matrix porosity. Fracture porosity is generally associated with bright coals (although it has been shown that micro-fractures are present in maceral fragments from the dull coal layers). Characteristically the macro- and micro- fractures form a continuous structural fabric through the bright coal layers and thus make a significant contribution to overall permeability. The macro- and micro-fractures appear to have been formed during the process of coalification rather than being formed due to shrinkage during methane extraction, as most of them are infilled with secondary minerals. In contrast, phyteral and matrix porosity is associated with the dull coal layers that are composed of plant fragments or a heterogeneous mixture of macerals. Like the macro- and micro-fractures, the continuity of the observed cavities suggest that these too are a significant contribution to overall permeability, and therefore play a major role in the transmissibility of methane at a level between diffusion at the micropore level and laminar flow at the macro-fracture level. Due to different spacing, orientation and persistence of individual fractures and cavities, the rate of methane transmissibility through a coalseam will vary according to coal rank, coal type and the organic precursors from which the coal was derived. This is important as a knowledge of the micro-structure system and its relationship to coal type and coal rank, plays an important consideration in: a) gas drainage modelling, b) enhancing permeability by inducing fractures and c) predicting the occurrence of outbursts.

Jan 1, 1991

By D Nobes, D Trumm, D Manhire, A OÆSullivan, M W. Milke

Coal seam gas (CSG) exploration and development requires the abstraction of significant amounts of water. This is so because gas desorbtion in coal seams takes place only after aquifer pressure has been reduced by prolonged pumping of aquifer water. CSG waters have a specific geochemical signature which is a product of their formation process. These waters have high bicarbonate, high sodium, low calcium, low magnesium, and very low sulphate concentrations. Additionally, chloride concentrations may be high depending on the coal depositional environment. This particular signature is not only useful for exploration purposes, but it also highlights potential environmental issues that can arise as a consequence of CSG water disposal. Since 2002 L&M Coal Seam Gas Ltd and CRL Energy Ltd, have been involved in exploration and development of CSG in New Zealand. Anticipating disposal of CSG waters as a key issue in CSG development, they have been assessing CSG water quality along with exploration work. Coal seam gas water samples from an exploration well in Maramarua closely follow the geochemical signature associated with CSG waters. This has helped to identify CSG potential, while at the same time assessing the chemical characteristics and water generation processes in the aquifer. Neutral pH and high alkalinity suggest that these waters could be easily managed once the sodium and chloride concentrations are reduced to acceptable levels.

Jan 1, 2005

Characterisation of Computer Printed Circuit Boards for Hazardous Properties and Beneficiation Studies

Sep 13, 2010

By R Badreddine, J Rose, L De Windt, P Chaurand, L Raimbault

Municipal solid waste of incineration (MSWI) bottom ashes are recycled as aggregates in civil engineering. These heterogeneous materials are composed of crystalline and glassy solid phases which contain trace metals, presenting a potential risk to the environment. Secondary ion mass spectrometry (SIMS) can provide quantitative chemical information, in particular the localisation of metals at trace level. Unstable glassy phases formed during incineration are present in relatively high proportions. Their analyses suggest a continuum between melilite-bearing glasses and dark glasses enriched in iron with abundant spinel aggregates. These primary glasses are enriched in zinc (~4500 ppm) but depleted in lead (~800 ppm) by comparison with the bulk chemical composition and reference materials. Heterogeneous cementing and encrusting admixtures on coarse grains are studied in a second step. SIMS imaging suggests a superposition of band zones including an intermediate layer enriched in iron oxyhydroxides and a superficial layer with calcium accumulation. A strong spatial association between lead and iron is systematically observed. Extended X-ray absorption fine structure (EXAFS) supports these observations by demonstrating that lead co-precipitation within iron oxyhydroxides, or sorption on their surfaces, may be a main containment process in the cementing and encrusting admixtures, whereas lead speciation is globally more complex in MSWI bottom ash.

Jan 1, 2008

By S C. Dominy

For any gold deposit-based geometallurgical study, the collection and processing of representative samples for gold grade and recovery tests is critical. Sampling protocols should be designed to suit the style of orebody in question. The proportion and size of gold particles has a direct impact on the effectiveness of sampling protocols and metallurgical recovery processes employed. Studies focussing on ore mineralogy and gold particle deportment, size and distribution are required. Key issues are the presence of gold particle clustering (important for sampling optimisation) and proportion of coarse versus fine to refractory gold. X-ray computed tomography (CT) is a radiographic technique that produces high-resolution 3D computerised models of objects based on density distribution. The ‘virtual’ specimens are made up of voxels, the 3D equivalent of pixels each assigned a grey value based on X-ray absorption. This paper presents the results of recent research on the imaging of in situ gold particles in a coarse gold-bearing ore. The technique shows promise as a rapid non-destructive method for preliminary characterisation to facilitate more detailed studies. Early and rapid gold particle determination enables sampling protocol optimisation and metallurgical recovery parameters to be defined prior to detailed feasibility studies

Sep 5, 2011

By I M. Platten, Y Xie

Sampling protocols that are designed to suit the mineralisation style will result in a reduction of the nugget effect and hence resource risk. The a priori need for all sampling programs is the effective characterisation of the mineralisation type(s) to support optimisation. This requires a program of sampling for sampling followed by holistic characterisation. At each end of the coarse-gold to fine-gold spectrum, the samplability of a deposit ranges from relatively simple for fine-grained disseminated gold particles, through to extremely difficult for coarse nuggety mineralisation. Many deposits contain a proportion of both particle size types. The proportion and size of coarse gold particles has a direct impact on the effectiveness of sampling, where coarser particles will require larger samples and more specialised protocols. The nature of mineralisation geology/mineralogy and associated gold particle sizing can only be determined by sampling to facilitate optimised protocols. Mineralogical studies, focusing on particle size, particle clustering and distribution in host minerals, are required as part of wider paragenetic and metallurgical investigations. This paper discusses the role of mineralogical studies in the characterisation of gold ores for sampling optimisation through a series of case studies.

Jan 1, 2008

By F H. Henrfquez, A G. Oroz

Design and operating conditions of large size mechanical flotation cells were evaluated by comparing them with actual operating conditions in a plant. The objective was to determine the time scale-up factor, typically based on empirical rules. Experiments were conducted on the rougher flotation circuit at Minera Escondida Ltd. The circuit consisted of self-aerated mechanical cells of 160 m3, arranged in six parallel banks with nine cells each. The rougher circuit flotation kinetics were evaluated from direct sampling and local mass balances around each cell of the bank. Adjusted overall mass balances were also developed. This information was used to fit different kinetic flotation models, and it was found that the rectangular distribution function was the most appropriate to describe the distributed rate constant for industrial operation. Then, a rougher flotation simulator was developed to describe the actual operation in terms of the operating variables (mass flowrate, solid percentage, feed grade) and the actual volumetric flowrate entering to each cell. In this study feed pulp samples were taken in parallel from the rougher circuit and were simultaneously floated in the laboratory. The kinetic behaviour was then modelled at a laboratory batch scale in order to determine the time scale-up factor between laboratory batch flotation data and industrial size flotation. The time scale-up factor observed for large sized cells, 160 m3, was found to be reasonably similar to those previously determined for self-aerated mechanical cells, but of lower size, operating at similar recoveries. In addition, the relative effect of mixing, between laboratory batch and an industrial flotation bank, was quantified by the parameter, separating the impact that kinetic and mixing changes have on the time scale-up factor. In general, the rougher flotation operation was found to reach the predicted metallurgical target, and the optimal separability criterion was also respected. The diagnostic generates information about the internal state of the process and helps to identify potential improvements for design, operation and control of the circuit.

Jan 1, 2005

By R Salmimies

Choosing a ceramic capillary action filter is often favoured in processes where low energy consumption is important, such as the dewatering of iron ore. In addition, the performance of the filter medium is essential, and the possibility to regenerate the medium is an advantage compared to other types of filter media. Although low, roughly 8 - 9 w-per cent for iron ore concentrate, and even cake moisture is the primary goal of dewatering, the introduction of better filtration processes can result in significant improvements of water economy and material efficiency.As industrial beneficiation processes are often complicated in their chemistry due to impurities originating from the ore itself, from the up-stream processing equipment and from the process water used, the characterisation of the filter media after usage might provide relevant information on what actually takes place during long operating periods. The aim of this study was to obtain new information on the fouling of fi lter media in an iron ore process to enhance and develop the regeneration process of the media in the future.X-ray diffraction and scanning electron microscopy were used to characterise ceramic filter media used in the dewatering of magnetite. Principal component analysis and discriminant analysis were introduced to identify trends in the data. Two types of media blockages were found to play an important role in an acidic iron ore dewatering process: fouling by slurry particles and by in situ crystallisation of a calcium compound, of which the latter originated from the combination of process water and process chemistry.

Jul 11, 2011

By S McKnight, L Koroznikova, J Begelhole

"This paper outlines a simple methodology for iron ore characterisation. Iron ores commonly contain a range of iron oxides with varying iron content along with generally minor quantities of lighter silicate gangue phases, giving rise to density variations. Companies tend to rely on heavy liquid separation (HLS) in the evaluation of samples arising from exploration, mining or metallurgical processes. Heavy suspension separation (HSS), a simple laboratory technique of density fractionation, employing suspensions of fine tungsten carbide (WC) particles in lithium heteropolytungstate (LST) solutions, can be used in the evaluation of iron ore.As part of Arrium Mining’s program to improve its knowledge of ore types being processed in two hematite ore beneficiation plants (OBP), metallurgical evaluation of hematite feed and geometallurgical evaluation for the OBPs has become a major focus.Metallurgical evaluation of the hematite ore ultra-fine size fraction, formally treated as waste but now upgraded by HSS, is a part of Arrium’s program to improve recovery.The HLS method for iron ore characterisation is not generally used as part of routine iron ore feed metallurgical evaluation due to the expense, toxicity and time-consuming nature of the technique. Results show that the HSS method for iron ore characterisation can achieve low-cost, low-toxic separation and can be used on-site to improve turnaround time of results (Begelhole, Jasper and Koroznikova, 2013).Arrium have applied this technique successfully for the past three years to progress process improvement for the two OBP as well as to assist Arrium’s on-site laboratory services, Bureau Veritas in Whyalla.The main objective of this program has been to further develop the HSS procedures using a low-toxicity, high specific gravity (SG) suspension; LST and WC as the dense medium for metallurgical evaluation of ultra-fines.A suspension of a particular density will separate iron ore into two products: a sink fraction (denser iron oxide – hydroxide particles) and float fraction (silicate – iron ore composite particles). A theoretical grade and mass recovery can be calculated, and a grade – mass recovery curve can be constructed for iron.Metallurgical evaluation of the plant feed ultra-fine size fractions are used to improve efficiency of an upgrading plant process. This type of characterisation can be used to prepare feed piles of known processing characteristics, or to benchmark the performance of the process against what can be theoretically achieved.CITATION:Koroznikova, L, Begelhole, J and McKnight, S, 2016. Characterisation of Low-grade Hematite Ore Ultra-fine Size Fraction Particles by Heavy Suspension, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 327–334 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

Characterisation of Manganese Ores

Sep 13, 2010

By J T. Woodcock

This paper discusses characterisation techniques that can be applied to complex waste products from metal production and processing operations with the aim of devising treatment methods for upgrading the metal content for recycling. Two waste streams were selected to illustrate the role of characterisation in adapting mineral processing techniques to provide an effective recycling strategy. Waste products chosen were:aluminium dross, which contains metallic aluminium particles in a coarse matrix of many components; and steel shredder sludge that contains copper wire and other metallics in a matrix of plastic and natural fibres, iron oxides, metallic iron, and other compounds. Characterisation methods discussed include chemical analysis (XRF, ICP-AES, and selected specialised techniques), phase analysis (XRD, SEM, TEM, and optical microscopy), morphology (IFESEM), sizing analysis (screening, Cyclosizing, Infrasizing, Malvern sizing), and general techniques such as particle shape, surface area, and porosity determinations. The applicability of these techniques to the waste products is considered in relation to their advantages and disadvantages, and sampling issues.Treatment techniques considered for the two waste products included comminution, screening, air or water classification, simple water leaching, gravity separation, magnetic separation, flotation, and eddy current separation.Tentative flow sheets were developed for the two wastes. For aluminium dross, it was proposed to use fine crushing followed by water washing to remove soluble chlorides and aluminium nitride, and then desliming followed by flotation of the granular fraction to give a metallic aluminium-rich concentrate. For shredder sludge, it was proposed to use wet screening, water classification, and gravity concentration to produce a copper-rich product and magnetic separation to produce a metallic iron-rich product.

Jan 1, 2004

By J Cortinez, P Vallejos, J Yianatos, M Rodriguez

Nowadays, one of the main problems in current flotation plants and new projects is the significant decrease in feed grades and changes in the mineral composition, which has an important effect on the mineral liberation and associations. Additionally, flotation plants usually operate with feed throughput higher than the original design, which has a significant impact on the feed particle size. All these conditions affect metallurgical performance, and must be evaluated and addressed, by improving control strategies for banks optimisation. For this purpose, the flotation of valuable minerals along the circuits requires better understanding, considering the compromise between performance and selectivity in flotation circuits. This paper presents a characterisation of the different minerals recovered along industrial flotation circuits. Plant sampling campaigns, performed in a copper industrial concentrator in Chile, provided the data for the study. Two rougher flotation banks consisting of cells of 130 m3 and 300 m3 were analysed. All the samples from the industrial surveys were analysed by screening and mineralogy, and the mineral recovery along the circuits was evaluated per particle size class, liberation class, type of associations, and others. Additionally, operating data on froth depth profiles complemented the evaluation of the mineral composition of concentrate streams, along the circuit. The results allowed for identifying and quantifying the main factors that affect the copper recovery and concentrate grade along the flotation banks. It was found that minerals with liberation lower than 50 per cent have a significant impact on the recovery. On the other hand, the decrease in the Cu grade in concentrates along the flotation circuits is mainly due to the relative increase of middling minerals (less liberated), non-valuable floatable minerals, such as free pyrite, and gangue entrainment. The characterisation of the gangue entrainment flow rate along the flotation banks showed a strong relationship with froth depth, which becomes more critical towards the last cells of the banks.

Aug 24, 2022

By P Fullagar

Automated multi-sensor core loggers (MSCL) measure petrophysical properties of diamond drill cores, including gamma density, P-wave velocity, electrical conductivity and magnetic susceptibility. A Geotek MSCL system has been used to record petrophysical data on archival drill core from Cadia East Au-Cu porphyry deposit, New South Wales, Australia, for correlation with metallurgical parameters. P-wave modulus, calculated from density and P-wave velocity, exhibits a correlation with small-scale crushability (A*b) test results, and hence offers a means for æcontinuousÆ characterisation of ore crushability at Cadia East. Magnetic susceptibility has proved to be a good indicator of alteration styles, and is a possible indicator of crushability.

Jan 1, 2009

By Y. Belloa, C. Dorfling

The presence of impurities such as Se and Te in copper sulfate leach solutions can have a detrimental effect on electrowinning efficiency. These elements can be removed from the solution by precipitation; sulfurous acid is commonly used as a precipitation reagent, while studies have also reported improved precipitation with the addition of metallic copper. This paper aimed to determine the effect of conditions used during the solution purification step on the characteristics of the precipitates that formed. Precipitation tests were performed in a batch reactor with copper sulfate leach solutions obtained from the base metal refinery of a platinum group metal producer. The effects of agitation rate (250 and 500 rpm), SO2 flow rate (4.4 and 5.8 mL/min.L), temperature (65 and 95°C) and metallic copper powder addition (0, 1 and 2 g/L) on the characteristics of the precipitates formed during the tests were determined using scanning electron microscopy. The major phases detected in the precipitates formed when using SO2 as the only precipitation reagent were elemental Se and Cu2Se. The introduction of copper powder led to the production of different sulfide phases for the experiments conducted at 65°C irrespective of the values of the other reaction parameters. At 95°C, Cu crystals, Cu2O and tiny inclusions of Cu2(Se,Te) were the prominent phases noticed in the precipitates produced from all the tests conducted with copper powder as precipitation enhancing reagent. Keywords: copper, precipitation, selenium, tellurium

Jan 1, 2020

By R. Asamoah, P. Forson, S. Xu, W. Skinner, M. Zanin

In most auriferous hydrothermal deposits, gold is preferentially associated with pyrite and arsenopyrite minerals, with higher economic gold values noted for the latter and arsenian pyrite minerals. In this paper, surface (Cryo-XPS) and solution (EDTA extraction) analysis were used to characterise pyrite and arsenopyrite minerals under different aqueous conditions involving electrokinetic study and collector interactions to better understand ways of improving the separation of pyrite and arsenopyrite. The evidence showed higher surface oxidation at solution pulp pH values in the range of 4-11 for arsenopyrite relative to pyrite. The observed highest ratio of pyrite to arsenopyrite selectivity was 1.7 at collector concentration of 50 g/t and decreased with an increase in collector concentration. Keywords: EDTA extractable iron, selectivity index, differential flotation, grade engineering

Jan 1, 2020

By M I. Pownceby, S Hapugoda, H Han, E Donskoi, L Lu

Iron ore sinter mineralogy and its associated macro-/micro – structure has a strong impact on sinter quality. At a macroscopic scale, sinter ideally consists of a strong, porous matrix which bonds relict ore nuclei together. Microscopically, the sinter matrix (solidified from the melt part of the initial sinter mix) generally consists of complex calcium ferrites known as SFCA, secondary magnetite and hematite grains (precipitated from the primary sinter melt), glass and silicates. Depending on the conditions under which the sinter structure is formed, two major forms of SFCA with different morphologies are generally recognised, ie fine micro-platy SFCA (usually termed SFCA-I) and coarse columnar/prismatic SFCA. Detailed optical microscope observations of several pot grate and compact sinter samples revealed the presence of a variety of fine, coarse and dense forms of both types of SFCA. The controlled cooling tests revealed that cooling rate has an impact on the form and size of SFCA crystals. In this work, EPMA analysis of SFCA compositions from a variety of pot grate and compact sinter samples are presented. Results show that the SFCA types exhibit a broad range of complex compositions within the system Fe2O3/CaO/SiO2/Al2O3/MgO/TiO2/MnO2. Although SFCA-I and SFCA are known to be crystallographically distinct and with different, well-defined ranges in composition, there was considerable overlap in compositions of the experimental sinter samples. The development of SFCA textures depend on several parameters including the local chemistry and conditions including the maximum temperature attained and the cooling rate, within the sinter bed, thereby suggesting that SFCA identification based on morphology alone may be erroneous.

Nov 8, 2021

By L. Mabiza

Keywords: Pyrometallurgy, furnace, sulphur, SO2, off-gas, Zimplats Zimplats embarked on an off-gas sampling campaign in December 2009 to characterise the concentration of SO2 in the off-gas from their 13 MW furnace. In excess of forty isokinetic samples (US EPA Method 8) were taken over seven days. The aim of the sampling campaign was to increase the understanding of factors that influence sulphur release from sulphide concentrates in an electric furnace. Specifically, detailed monitoring was conducted over various operating conditions to evaluate: ? The relationship between SO2 and feed rate (i.e. furnace power) ? The relationship between SO2 and ingress (i.e. furnace freeboard pressure) ? The impact of concentrate bed thickness on SO2 (i.e. blacktop) ? The effect of events such as tapping and converter slag return on SO2 ? The desulphurization reactions that take place in the blacktop A model was developed to predict the SO2 content in furnace off-gas for a particular set of operating conditions. In order to evaluate the impact of random, uncorrelated changes in concentrate composition, ingress and power (feed rate) on the SO2 content of the off-gas, a Monte Carlo approach was adopted whereby concentrate composition, power, and ingress were allowed to vary randomly around selected set-points. The model is primarily based on the release of ?labile? sulphur from the partial thermal dissociation of sulphide minerals with an over-stoichiometric sulphur content (e.g., Fe7S8 decomposition to FeS and S). The main findings of this work suggest that labile sulphur does not fully account for the measured SO2 content of the off-gas, and that limited oxidation of sulphides during melting also contributes to the SO2 content. Details of sulphide oxidation reactions in the furnace remain unclear, and it is currently not possible to provide a theoretical framework for the relationship between the extent of oxidation and variables such as temperature, gas composition, particle size, and residence time in the furnace black top. Through the use of the Monte Carlo model it was, however, possible to constrain the extent of sulphide oxidation to about 1%. This work has shown in practice what was expected in concept, that SO2 in off-gas is proportional to furnace power and ingress rate. The model that was developed consistently slightly under-predicts the quantity of SO2 generated. It also highlights that more work is required to better understand the analytical methods used to analyse for SO2 in off-gas.

Jan 1, 2011