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By M. Werner

Mining in the Coeur d'Alene Mining District has been going on for over 100 years with a long- term continuation very likely. Mining is presently carried out at depths below the -5000' horizon. As mining continues at ever increasing depths, higher in-situ rock stresses and subsequent rock deformation is encountered making mining costly and hazardous. To provide access for men and materials in such areas, a wooden raise preparation structure is typically built. Although these structures provide adequate support and access, they have proved to be very costly to construct and maintain.

Jan 1, 1986

By Upali Siriwardane, Tushar V. Kudale, Naidu V. Seetala

"Cellulose acetate (CA) membranes with 25% triethyl citrate (TEC) as plasticizer were prepared with varying thickness for CO2 gas separation from water-gas-shift (WGS) reaction products. The AFM analysis of the CA membrane showed that the uniform coating had fewer and smaller pores as the film thickness increased, and corroborated by gas permeability studies. The CO2 permeability has decreased faster than CO permeability with the CA/TEC membrane thickness, and findings support that the CA membrane could be used to entrap CO2. Several CA/TEC membranes were also staked to increase the separation efficiency. Positron Annihilation Lifetime Spectroscopy (PALS) was used to estimate the nano-porosity (pore size and concentration) changes of CA/TEC films. PALS results show a decrease in pore size with increasing CA-TEC concentration in acetone, while the pore concentration increases. The PALS results are correlated with the CO2/CO permeability variations as the CA-TEC concentration change.IntroductionHydrogen is one of the main energy sources available for the future advancement of clean fuel technologies especially for fuel cells. Generation of hydrogen and CO2 from Water Gas Shift (WGS) reaction mixtures of CO and H2O is of interest to many researchers since it allows a large scale production of hydrogen [1, 2]. Once hydrogen is produced using the WGS reaction, the output products contain mixture of CO, CO2, H2, and water vapor. Metallic membranes have been used as hydrogen separation membranes [3-6]. As H2 is separated from the mixture using the metal membranes, we need to separate CO2, and find ways of sequestration of CO2 to avoid environmental problems by greenhouse gasses. Polymeric Membranes have been used for CO2 separation [7]. Plasticizer can control the micro-structural properties such as pore size and concentration of polymer membranes [8], which influence the size/molecular weight dependent diffusion rates of the gas molecules. We have used cellulose acetate with triethyl citrate as plasticizer to separate CO2 from the WGS reaction products. Positron annihilation lifetime spectroscopy (PALS) is very sensitive and able to identify different kinds of defects and their agglomerates such as vacancies, vacancy loops, and voids [9, 10]. PALS has been successful in determining the free volume in polymers that influence the properties of the polymers [11, 12]. Microscopic properties of the free volume obtained from PALS have been correlated to macroscopic properties [13, 14]. We used PALS to study the nanoporosity (pore size and concentration) and fractional free volume changes of CA/TEC films, and used to understand the variations observed in the CO2/CO permeability as the CA-TEC concentration in the membranes change."

Jan 1, 2014

By John A. Ames

Webster's dictionary nearly equates portland cement with its current primary definition of cement. While such equation may be a triumph of common usage, the confusion between the terms cement and concrete unfortunately is very widespread. Full definition of cement properly would extend to many substances, but for purposes of this chapter cement is restricted to "varieties" of portland cement including "portland-pozzolan" cement. Among the usually recited historical notes concerning cement is that it was developed by the Romans. Their use of cement in the great structures of Rome, and even in the far corners of their Empire, such as Hadrian's Wall in the north of England, testifies to the antiquity of a major cement industry. From English sources we know of John Smeaton's carefully proportioned hydraulic cement mixed in 1756 and of Joseph Aspdin's patented cement to which, in 1824, he gave the name portland cement. (He claimed that his cement mortar looked like the famous dimension limestone quarried from the Isle of Portland on England's south coast.) The year 1971 marked the centennial of portland cement manufacture in the United States. A fair historical account of the many real contributors to the cement industry between 1756 and 1972 unfortunately would be too extensive for this chapter. Development of rotary kiln practice and burning at higher temperatures clearly was the major move into today's technology. As part of the 4th edition of Industrial Minerals and Rocks, this chapter on utilization focuses on inferred interests of the anticipated readers. The main period for which statistics are cited generally is that since the 3rd edition (1960) of this same volume. Cement manufacture is the processing of selected and prepared mineral raw materials to produce the synthetic mineral mixture (clinker) that can be ground to a powder having the specified chemical composition and physical properties of cement. Cement making incorporates a number of distinct steps, but it is characterized by the key pyroprocessing (or "burning") step, which brings about the necessary changes in the raw materials. This pyro processing is a chemical process. Conversion of large volumes of mineral raw materials into specification-controlled cement at relatively low cost is the objective. Statistics on the cement industry are of uneven quality. The U.S. Bureau of Mines (USBM) is the principal collector of available data. These statistics can be only as good as the quality of information supplied by the reporting companies. The data perhaps most often questioned relate to productive capacity of the industry. The questions submitted by USBM are valid, nevertheless, and the information gained from them, as good as is available, is what is generally used. The Portland Cement Association also is a source of much quality information. The year 1972 witnessed a test of the adaptability of cement industry statistics. This was the year of conversion from barrels and sacks of cement as the units of measure to tons and hundredweights. The barrels and sacks related to volumetric measures in that a sack was judged to be 1 cu ft (weighing a "standard" 94 lb). A barrel was 4 sacks. Volumes of concrete are stated in cubic yards, and the number of cubic feet of cement in a cubic yard of concrete was a sensible approach to the mensuration involved. However, cements do not weigh the same amount from plant to plant or from type to type, and the buyer was more interested in getting an assured weight for his money than in "buying air." Thus, a sack, in accepted practice, became 94 lb instead of 1 cu ft, and a "barrel" became 376 lb, regard- less of whether it would fit into 4 cu ft of space. With the de facto dealing in weight rather than in volumes, the awkward numbers made little

Jan 1, 1975

By Raymond E. Davis

LET'S imagine we are at the Grand L Coulee Dam, where daily 15,000 barrels of low-heat Portland cement and 27,000 tons of processed aggregate in various sizes are mixed to produce 30,000 tons of concrete. Inspect the autographic records which show for each 4-cu-yd. mixer batch of concrete the weights of its constituent materials including its several sizes of aggregate, cement, and water, and which also show the period of mixing and the consistency of the mix. Watch the inspectors sample and test the aggregate for gradation and moisture content of sand, and sample the concrete for homogeneity. Watch the huge buckets deposit the concrete in the forms. It looks too dry to handle, but the concrete vibrators make it melt away. Just enough vibration fully to com- pact the mass, but not enough to produce segregation of the materials; the inspector says when. See the sprinkler system covering all hardening concrete with a spray so that it may not thirst for water. Watch the cleaning of the top of an old lift preparatory to placing a new lift; the sand blasting; the blow-down; the mop-up; the minute inspection.

Jan 1, 1939

By D. H. Stonehouse

Of the f ive Canadian cement producing regions- Atlantic, Quebec, Ontario, Prairie and Pacific-Ontario has the greatest capacity and normally produces the most cement. However, during the last 5 years the greatest activity within the industry in Canada has been in the Prairie and Pacific regions where major capacity increases have taken place. Most Canadian cement companies produce normal Portland, high-earlystrength Portland and sulphate resisting Portland cements. Some companies also manufacture moderate Portland cement, and low-heat-of-hydration Portland cement. Escalating energy costs highlight the need for technology research into more energy-efficient equipment for the energy-intensive cement industry. The industry is well integrated and plants are well situated to support construction in Canada. Expansion into the United States has become common during the past decade.

Jan 1, 1984

By Edmund J. Cardoza

The paper describes the design, construction and quality control aspects of the installation of a cement-bentonite (CB) cut off wall to impede seepage through a flood control dike. Special emphasis is placed upon the development of a proper specification, distinguishing the CB method from the Soil-Bentonite technique. The importance of the pre-construction laboratory testing program and field quality control procedures is emphasized by the fact that the in-place properties and characteristics of the CB cut off may not be known until after a majority of the work is complete. Sections are included which describe the construction method, the specialty equipment and personnel requirements and the quality control/quality assurance aspects of the project.

Jan 1, 1992

By A. A. Zatout, G. H. Sedahmed, T. M. Zewail, M. H. Abdel-Aziz, B. S. Ibrahim, E-S. Z. El-Ashtoukhy

In this work, the possibility of intensifying the cementation process in stirred vessels was studied by using the perforated baffles as turbulence promoters; the cementation reaction of Cu+2 on Zn was selected as a model. Zn was used in the form of a sheet lining the inner wall of an agitated vessel. Parameters considered are initial concentration of Cu+2, solution temperature, impeller rotation speed, and impeller geometry. Within the present range of parameters studied, the rate of cementation was found to increase with increasing initial concentration of Cu+2, solution temperature, and impeller rotation speed. At the same rotational speed, a flat turbine gave a higher rate of cementation than a 45° pitched turbine. The present suggested that baffles’ geometry gave superior performance in terms of mass transfer of copper cementation compared to the conventional baffle geometry. All parameters that affect the rate of cementation were correlated in the form of dimensionless equations suitable for the design and performance prediction of the agitated vessel. Potential applications of the obtained results in the field of hydrometallurgical processes and wastewater treatment were discussed.

Jan 12, 2021

A rotating disc geometry was used to provide a uniformly accessible surface for a kinetic study of copper cementation with zinc in sulphate solution. For copper concentrations of the order of 10 p.p.m., a porous, adherent deposit is formed on the zinc surface and this has a significant influence on the reaction rate. When the specific mass of deposit is less than about O· 35 mg/cm2 the surface may be considered as smooth and the rate is described by simple convective counter diffusion of zinc and copper ions through a laminar diffusion boundary layer to the deposit-solution interface. In the presence of additional deposit, the diffusional mass transfer rate is increased by increased surface roughness.The rate under these conditions is first order, with the degree of enhancement independent of further increases in the specific deposit mass. The enhancement in rateis, however, directly related to the initial mass flux and the species involved in the reaction.Preliminary work showed the same mechanism to apply to cementation from chloride solution, solutions of high zinc concentration, and cementation of copper with iron..

Jan 1, 1970

By Marcos Antonio Barcelos

O uso de tratamentos termoquímicos assistidos por plasma tem apresentado grande crescimento nos últimos anos em consequência dos excelentes resultados obtidos na modificação de superfícies em materiais de engenharia. Neste estudo será utilizado o aço inoxidável AISI 304 que apresenta boas características de resistência à corrosão, tendo vasto campo de aplicação nas indústrias têxteis e químicas. Será realizado tratamento termoquímico de cementação a plasma com temperatura fixa, variação de tempo e mistura gasosa (CH4).

Aug 7, 2018

By Manca PP, Rossi G, Lipari D, Knissel W, Massacci G, Licheri P, Fioravanti E, Helms W, Lai S

Mining of the massive complex sulphides orebodies of Campo Pisano and San Benedetto (Southern Sardinia, Italy), dates back to before Christ, though their exploitation with modern technology was only resumed in the middle of the last century. The increasingly adverse economic conditions and the weakness of both country rock and mineralization were concurrent in forcing the Company's management to develop suitable high-productivity stoping methods. In the framework of a project fi- nanced in part by the Commission of the European Coranunities, and carried out in cooperation with the Universities of Cagliari (Italy) and Clausthal (Germany), a cemented backfill stoping method was developed. The concrete mix preparation and placement facil- ities, study of the cement mixes and endeavaa-s to optimize the methods are described. The monitoring system for measuring stress evolution within the emplaced backfill is illustrated together with the successful replacement of part of the Portland cement

Jan 1, 1992

By Baogui Yang, Jie Yang, Anthony Iannacchione

"The cemented coal gangue-fly ash backfill technique (CGFB) has commonly been used to control subsidence damage caused by underground coal mining. This paper discusses the CGFB backfilling process used at the Xin-Yang coal mine, Shanxi Province, China. A general description of the components of the CGFB are provided. The reaction of the strata to the backfilling process is simulated with a scaled physical model based on the Xin-Yang conditions and verified with subsidence points on the surface. With the help of the cemented filling materials, the CGFB produces only a slight bend to the overburden roof strata over the longwall panel. Physical models were constructed at the China University of Mining and Technology, Beijing, to simulate actual conditions. The modeling results show minor fracture distribution in the overlying strata and lower abutment pressure development within the backfilling area. The effectiveness of the CGFB technique is verified by a reduction in the vertical surface subsidence measured above the backfilled area.INTRODUCTIONUnderground longwall mining is the most efficient underground means to recover coal resources and is used widely in China, the US, Australia, and Europe. However, this type of mining has introduced some serious environmental impacts. Perhaps the most significant environmental issues are the surface and groundwater impacts associated with the formation of the subsidence basin (Bell and Donnelly, 2006). Backfill technology has been used for years to mitigate subsidence impact. Simply speaking, the backfilling technique places filling materials into the void left from the extraction of coal. When this material is placed within the gob, it is capable of partially supporting the overburden until a new equilibrium is reached. Essentially, the backfill material inhibits crack development and expansion caused by the strata movement and mitigates damaging ground deformations.The cemented gangue-fly ash backfill (CGFB) is one type of novel backfill technology, consisting of cement, coal gangue, fly ash, water, and additives in varying concentrations. The CGFB is mixed on the surface, pumped underground through a pipeline as a slurry, and placed in the void behind the longwall shield under the protection of specially designed hydraulic supports."

Jan 1, 2018

This paper considers three aspects of cemented fill practice and research in Mount Isa. Firstly, an account is given of the use of Portland cemented hydraulic fill, considering mainly the role and specifications of the fill used but including û brief description of fill preparation and placement. Data resulting from a Portland cemented hydraulic fill sampling, curing and testing campaign covering about 18 months of operating practice are presented, analysed and discussed. These yield information indicating the mode of operation of a fully-automated fill preparation station, as well as a means of comparing field and laboratory strength results. A technique with potential for use as a fill quality control without actual strength testing is also described. Results of a fill research program conducted by the author in Mount Isa since early 1968 are presented, involving both Portland cemented hydraulic fill and alternative, cheaper, additives for cementing hydraulic fill.

Jan 1, 1971

This paper considers three aspects of cemented fill practice and research in Mount Isa. Firstly, an account is given of the use of Portland cemented hydraulic fill, considering mainly the role and specifications of the fill used but including brief description of fill preparation and placement. Data resulting from a Portland cemented hydraulic fill sampling, curing and cesting campaign covering about 18 months of operating practice are presented, analysed and discussed. These yield information indicating the mode of operation of a fully-automated fill preparation station, as well as a means of comparing field and laboratory strength results. A technique with potential for use as a fill quality control without actual strength testing is also described. Results of a fill research programme conducted by the author in Mount Isa since early 1968 are presented, involving both Portland cemented hydraulic fill and altei._acive, cheaper, additives for cementing hydraulic Fill.

Jan 1, 1980

The need to schedule ore production to make maximum use of the strength gained by cem- ented fill during curing is discussed, to show how cement content and hence fill cost can be kept down for any particular operation. Results from laboratory testwork on Isa Mine fill conducted by the author while employed by Mount Isa Mines Limited form the basis of the Discussion

Jan 1, 1973

By Greenwood AG

Research into cemented rock fill at Mount Isa Mines Limited since 1992 is described. The key mechanisms controlling segregation during stope filling with cemented rock fill are described and include the gravity flow mechanism which is described in detail. Examples are provided to demonstrate these mechanisms. Comparisons are made between Mount Isa Mines' cemented rock fill and slurry-based cemented rock fills. Recent backfill stability modelling using a three-dimensional finite clement program is described.

Jan 1, 1998

By C. Sun

The Leeville underground mine has been in operation since 2006 and currently produces 3,500 tons of ore per day with an average gold grade of 0.34 opt. The mine has a large horizontal extent of 2,500 feet by 500 feet and a vertical extent of 20 to 200 feet. Based on the characteristics of the ore bodies, a long-hole stope and cut-and-fill mining methods are used at the deposits which are divided into several mining zones. Cemented rock fill (CRF) is used as the backfill in the open stope. CRF design includes the aggregate design, the ratio of cement and fly ash design, and strengths for the long-hole stope and cut-and-fill. In the aggregate design, the particle size distribution is one of the most influential aggregate characteristics in determining how it will perform as a basic backfill material. Gradation helps determine durability, porosity, cement and water requirements, strength, and shrinkage. To cut the backfill cost, fly ash usually is added into the binder to replace some part of cement. However, adding fly ash can affect the strength of the backfill. The reasonable percentage of fly ash is also important for making a good and low cost backfill. Based on the different mining method, the different backfill with different strength is designed. A systematic quality control procedure for aggregate and backfill is followed. After four yeas application, CRF system in Leeville achieved very good results.

Jan 1, 2011

By T. Emery, D. Sweet, J. Bourgeois, B. Seymour, D. Porter

Cemented rockfill (CRF) is being used to backfill primary and secondary stopes at the Eagle Mine, an underground nickel and copper mine operated by Lundin Mining. National Institute for Occupational Safety and Health (NIOSH) researchers from the Spokane Mining Research Division (SMRD) are conducting cooperative research with the mine staff to determine if the size of a CRF sample affects its measured strength properties. Based on previous research by NIOSH, cylindrical samples of CRF ranging in size from six to eighteen inches in diameter were cast at the mine and cured underground. The samples were later transported to the SMRD laboratory and the Michigan Technological University where tests were conducted to determine the strength and elastic properties of the CRF. To further analyze the relationship between backfill density and compressive strength, different ASTM International compaction techniques were used to cast the samples. For comparison, tests were also conducted on in-situ core samples that were drilled from a stope which had been backfilled with the same CRF mix. The data collected from this study not only improves our understanding of CRF in-situ properties but also helps optimize Quality Assurance/Quality Control (QA/QC) methods for backfill preparation and testing.

Feb 1, 2023

By J. McCreedy

"The addition of Portland cement to hydraulic sand fill has resulted in the production of stable and self-supporting cemented sand fill. The use of cemented fill in the mines of The International Nickel Company has resulted in substantial economies in timber requirements, de-creased dilution of ore and greater flexibility in mining methods.Coupled with special mining techniques, it has permit-ted mining by both cut-and-fill and shrinkage stoping methods to much greater depths than heretofore. The use of cemented sand fill has permitted revisions to undercut-and-fill mining which have significantly improved the efficiency of this method.Automated mixing systems have been developed for preparing cemented sand fill in surface sand plants on a continuous throughput basis. Control of cement-sand mixtures is obtained by the use of a mass flow measuring system and weighing cement feeders."

Jan 1, 1966

By P. Moran

A promising and increasingly popular tailings management strategy is to place cemented tailings underground as backfill. The placement of cemented tailings results in enhanced geotechnical stability and a purportedly more geochemically stable tailings form with lower leaching potential. Conventional subaerial tailings management can negatively affect water quality if weathering causes acid rock drainage and metal leaching (ARD/ML) to occur, whereas cemented tailings can limit leaching via porosity and permeability reductions and contribute alkalinity to limit the potential for ARD/ML. Cemented tailings backfill appears to be better, but how can this advantage be proven? Currently, cemented tailings backfill is utilized at mining operations internationally, but there is limited guidance on performing geochemical characterization and associated evaluation of the potential impacts to water quality. As a result, various approaches to simulating the leaching behavior of cemented backfill have been utilized, including some methods that are unlikely to represent weathering under site-relevant conditions. American Society for Testing and Materials (ASTM) Standard Test Method C1308-08 is a diffusion testing method initially developed to assess constituent release rates from solid nuclear waste forms. ASTM C1308-08 uses intact cylinders that more closely represent actual backfill than methods that require crushing or size reduction. It is widely believed that leaching from actual cemented tailings is controlled by diffusion through small pores that exhibit limited exposed surface area, making diffusion testing particularly applicable to cemented tailings placement.

Feb 27, 2013

By W. P. Sykes

SEVEN years ago, Dr. S. L. Hoyt1 presented a masterful discussion of the hard metal carbides and cemented tungsten carbide. His lecture summarized most of the data then available in the field; many of the details relating to the production, properties and structure of cemented tungsten carbide had never been previously published, for, in fact, this information was only then being acquired. During the intervening years, the cemented carbides have assumed a place of real importance in the commercial field, with an ever widening variety of applications due to constant improvement in the control of production technique and the unremitting search for new compositions that might better the performance of the alloys in one or another type of service. The most recent summary of production methods, properties and guides for the successful application of the cemented carbides appears in the 1936 edition of the Metals Handbook. Of necessity, much detailed information relating to structures and physical properties is not included in such a summary, and it is with such details that the present discussion is concerned.

Jan 1, 1938