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By Daniele Perondi

Diferentes resíduos são gerados pelas indústrias siderúrgicas, dentre eles o resíduo dos trituradores de sucatas (RTS). O RTS gerado pelas siderúrgicas brasileiras se difere dos demais países devido aos materiais que são alimentados no triturador. Assim, o objetivo deste trabalho foi avaliar as características do RTS gerado por uma siderúrgica brasileira. As seguintes técnicas foram utilizadas: identificação e quantificação dos principais constituintes, análise termogravimétrica, imediata, elementar, poder calorífico superior e teor de cloro e metais. Os principais polímeros presentes no RTS foram o poliestireno e o polietileno. A partir dos resultados de análise imediata, elementar e de poder calorífico superior do RTS, verificou-se uma elevada quantidade de matéria volátil (76,22% ± 6,90). Os altos teores de carbono (72,92%) e hidrogênio (9,86%), foram atribuídos à elevada quantidade de polímeros e borrachas presentes no resíduo. O teor de enxofre (0,21%) pode ser atribuído a presença de borracha no resíduo, enquanto o teor de cloro (1,33% ± 0,13) pode ser atribuído a presença do PVC no resíduo. O poder calorífico superior do RTS foi de 30,01 ± 1,22 MJ/kg, de forma que uma avaliação termoquímica mostra-se como uma técnica atrativa para a sua destinação final.

Oct 30, 2017

By Mike Treffy

El presente texto describe las características geoquímicas de las rocas ígneas del tipo HHPG (High Heat Producing Granites) en los Andes peruanos. Dichas rocas tienen diferentes edades geológicas y están relacionadas a los depósitos minerales como estaño, plata, cobre, zinc, plomo, uranio, etc y están ubicadas al extremo sur de la Cordillera Oriental y norte del Batolito de la Cordillera Blanca. Asímismo, en base al procesamiento geoquímico de la de ANDESDATA, se demuestra que estos granitos y rocas volcánicas félsicas corresponden a diferentes series magmáticas y que este tipo de rocas pueden relacionarse a altas concentraciones de plata, oro, cobre, zinc, molibdeno, uranio, favoreciendo la circulación de fluidos hidrotermales a grandes distancias de las intrusiones y rocas volcánicas bastante diferenciadas.

Sep 21, 2013

By Tiago Nunes Lima

Novas ligas de Ti estão sendo desenvolvidas como uma alternativa para aplicação em implantes cirúrgicos e em componentes estruturais por possuírem propriedades atraentes em comparação à liga Ti6Al4V, com destaque ao menor módulo de elasticidade, menor citotoxicidade, maior resistência à corrosão e propriedades mecânicas similares, alta resiliência e elevada formabilidade. Este estudo tem como objetivo observar as características mecânicas de ligas Ti35Nb2Sn deformadas a frio e seguidas de envelhecimento. A liga foi laminada a frio com 80% de redução e envelhecida a 400 ºC por 48 horas. Foram realizados ensaios de tração, dureza, metalografia e análise das superfícies de fratura. A liga laminada apresentou uma maior relação de resistência à tração pelo módulo de elasticidade e maior ductilidade do que a liga envelhecida.

Aug 16, 2017

By Jean-François Dorion

La corrosivité des environnements miniers souterrains est un phénomène peu étudié au Canada. En plus de détériorer les systèmes de soutènement, la corrosion s?attaque aussi à divers installations et équipements souterrains. Cette étude, débutée en janvier 2007, est l?établissement d?une banque de données afin de caractériser les environnements miniers souterrains selon leur potentiel de corrosivité pour les systèmes de support de terrains. Pour ce faire, cinq (5) mines ont été sélectionnées afin de comparer les environnements : Laronde, Géant-Dormant, Niobec, Mouska et Doyon. À chacune des mines, trois (3) endroits ont été étudiés. Les résultats préliminaires démontrent une grande variabilité des conditions d?une mine à l?autre ainsi qu?à l?intérieur même d?une mine. La minéralogie des roches et du gisement influence la composition des eaux souterraines et la présence des sulfures joue un rôle important sur l?agressivité de l?eau et de l?air des mines de l?étude. Afin de déterminer le potentiel de corrosivité, plusieurs paramètres doivent être considérés et la mine doit être zonée selon l?agressivité des endroits.

Feb 1, 2008

By Réal Tanguay, Mathieu Piché, Jacques Carignan, Charles Beaudry, André Bonenfant

"Le gisement Isle-Dieu est situé sur le flanc sud de l'anticlinal de Galinée. La stratigraphie locale comprend, de bas en haut, la rhyolite du Groupe du Lac Watson surmontée par le basalte du Groupe de Wabassee. Un horizon repère, siliceux et sulfure, d'origine sédimentaire, appelé ""Tuffite Clef', est présent au sommet du Groupe du Lac Watson et pend à 45° vers le sud.Le gisement Isle-Dieu est constitué par une lentille qui recoupe, en partie, la ""Tuffite Clef"". Elle est séparée en deux trorçons par un dyke de tonalite. Les données obtenues à partir des forages effectues à travers la rhyolite sous-jacente permettent de définir les zonations chimiques et pétrographiques de la cheminée d’altération.Ces transformation minéralogiques et chimiques sont caractérisées par un enrichissement en MgO, Fe2O3, MnO et un appauvrissement en CaO, SiO2 et Na2O. La zonation spatiale de ces altérations permet de mettre en évidence la géométrie et l'extension des conduits hydrothermaux. L'épaisseur maximale des sulfures massifs au sein de la lentille est en étroite relation avec l’importance des zones d'altération. Les patrons de variations chimiques dénotent une orientation préférentielle WNW des conduits hydrothermaux. Les parties les plus altérées et les plus déformées présentent localement de fortes variations positives en Zr, Nb, et terres-rares; ces concentrations sont vraisemblablement imputables a /' enrichissement résultant de la diminution du volume lors de l'altération.L'étude pétrographique montre que la porosité et la perméabilité du milieu ont joué un rôle important dans la circulation des fluides car les roches de la cheminée présentent des phénomènes de dévitrification, de bréchification et de microfracturation très prononces. La nature magnésienne de certaines chlorites et la perméabilité accrue du milieu semblent en accord avec le modelé propose par Roberts et Reardon, ( 1978 )"

Jan 1, 1990

By Mark Cadzow, Rodney Lamb

CARBAD is a recently developed Australian process for the recovery of gold and platinum group metals (PGM). The process relies on the selective agglomeration phenomena of the gold and PGM to capture the mineral in a carbon-hydrocarbon media. The precious minerals are then extracted from the loaded media by a solvent gold room process producing a relatively pure concentrate. The media is then reformed and recycled. The process development from batch test work to a 5 t/h commercial scale CARBAD plant is discussed. The operation and results of processing a variety of ore types at several alluvial and hardrock gold mines is examined. The operating and capital costs for the CARBAD process shows that it is significantly less than that the conventional CIP/CIL. The environmental safety of the process is a major feature where precious metal deposits are located within urban environments or within wilderness areas.

Jan 1, 1989

By Maria José Santos Lima

A pesquisa e o desenvolvimento de Materiais nanoestruturados vêm crescendo significativamente nos últimos anos. Estes materiais apresentam propriedades significativamente modificadas em comparação às dos materiais convencionais, devido às dimensões extremamente reduzidas dos cristalitos. O carbeto de Tântalo (TaC) é um material extremamente duro, apresentando elevada dureza, elevado ponto de fusão, elevada estabilidade química, boa resistência ao ataque químico e choque térmico e excelente resistência à oxidação e corrosão. Desta forma este trabalho teve como objetivo a obtenção de TaC nanoestruturado a partir do precursor tris(oxalato)oxitantalato de amônio hidratado, através de reação gás-sólido a baixa temperatura (1.000°C) e curto tempo de reação. Os materiais obtidos foram caracterizados através de difração de Raios-X (DRX), Refinamento Rietveld, Microscopia Eletrônica de Varredura (MEV), Espectroscopia de Infravermelho (espectroscopia IV), Termogravimétrica (TG). Através das analises de DRX e do refinamento Reitiveld para o TaC com S = 1,1584 observou-se a formação do carbeto de tântalo puro com estrutura cúbica e tamanho médio de cristalitos na ordem de 12,5 nanômetros.

Aug 7, 2018

By Sander Mul, Michael Brandner, Armin Paar

Graphitic HSS roll grades such as ESW’s brand VANIMO can be considered as the latest developments for the last finishing stands in hot strip mills. These roll grades are developed on the basis of the alloying concept of (Carbide Enhanced) Indefinite Chill work roll materials. During the development of VANIMO, the amounts and types of carbide forming elements were increased and adjusted into the direction of cast HSS roll grades. The microstructure of graphitic HSS roll grades therefore consists of tempered martensite, cementite and several different carbide types as well as a well-defined amount of free graphite. The main purpose of graphitic HSS roll grades is to combine the high surface quality of Indefinite Chill alloys as well as the high wear resistance of HSS roll grades. Several systematic steps were taken to increase the wear performance from Carbide-Enhanced Indefinite Chill grades to the more advanced VANIC grade and further on to the highest alloyed roll grade VANIMO. In every development step, the surface quality of the roll grades was carefully monitored. The decision to invest in new testing equipment at ESW’s plant was driven by the wish to see microstructural effects of different alloys in a macroscopic dimension. Usually samples are taken from cast rolls and investigation is done in comparably small areas compared to the total surface of a roll. Rolling of strip is done with the entire barrel, so effects of alloy and microstructure can appear anywhere on the barrel surface. To ensure better understanding and deeper knowledge about influences of alloying trials we decided to install the last version of LRI (Lismar Roll Inspection). LRI includes the latest technology of Eddy Current with an enormous resolution. Depending on the formation of carbide precipitations, carbide network as well as matrix and free graphite, the EC test can detect smallest differences. The possibility to analyze the different results of EC and UT surface wave inspection will be discussed. A few examples of surface effects in the mill application will be discussed and improvement strategies explained.

Oct 1, 2019

. F. W. SPERR, JR.,* Pittsburgh, Pa.--Mr. Malcolmson states that the Carbocoal process produces ammonium sulfate in excess of that normally recovered in the ordinary byproduct coke process. Table 3 indicates that 20,000 to 25,000 lb. of sulfate of ammonia are obtained in carbonizing 1000 tons of Clinchfield coal. This is a high-grade coal and yields from 26 to 28 lb. of ammonium sulfate per ton in a modern byproduct coke oven. On the next page, 21 lb. is stated as the yield of ammonium sulfate per short ton of raw coal; this is less than the average production from any well operated byproduct coke-oven plant treating coal of the character usually coked, in Pennsylvania and Ohio. The statement as to the comparative yields of light oil is somewhat misleading in view of the results obtained during the past year or two by the more modern byproduct coke plants. The plants put in operation by the H. Koppers Co., during the past two years, are producing about 3.5 gal. of light oil per short ton of coal, and several of these plants are producing more than 4 gal. per ton. The yield of pure toluene runs from 0.45 gal. to 0.55 gal. per ton. .The quality of the light oil .obtained from the Carbocoal process is of much greater importance than would be inferred by one not closely familiar with the subject. The presence of paraffins in the benzol and toluol fractions seriously detracts from their commercial value; the benzol and toluol fractions derived fro in the Carbocoal process contain about 50 per cent, of paraffins. It should be thoroughly understood what these paraffins are. They are simply hydrocarbons that go to make up ordinary petroleum, and if a successful method for the removal of paraffins from benzol and toluol has been developed, this can at once be applied to several well known processes by which benzol and toluol can be made directly from petroleum, which have as yet been total failures on account of the contamination of these products by paraffins.

Jan 11, 1918

By B. Pesic

This is an extension of the work on recovery of silver and manganese from Ag-Mn ores, and recovery of silver and gallium from flue dust from phosphate industry. Carbon adsorption was considered as the most adequate method for recovery of silver from thiourea leach solutions. For this reason it was decided to examine the characteristics of adsorption of silver on activated carbon. Coconut hard shell activated carbon was used for this study. Ag(TU)2C1 complex was dissolved into thiourea solution to give 2 gpl stock solution. Thy studied parameters were: loading isotherms at 25°C, 35°C, and 45°C, initial kinetics as a function of thiourea concentration, temperature, pH, N2, and O2. It was found that the loading capacity of carbon for silver and thiourea was 137-150 mg/g and 514 mg/g, respectively, at 25 °C.

Jan 1, 1986

Table 1.-Salient statistics of carbon black produced from natural gas and liquid hydrocarbons in the United States [ ]

Jan 1, 1967

By Donald S. Colby

CARBON-BLACK shipments, which had declined in the latter art of 1953, remained low in 1954 until after settlement of the labor strike that occurred in the rubber industry in July and August. The production of new model automobiles in the last quarter of the year spurred the demand for rubber tires and consequently the demand for carbon black. Total shipments of 1,498 million pounds for the year were 4 percent below 1953.

Jan 1, 1958

By Ivan F. Avery

DOMESTIC production of carbon black increased 4 percent in 1962 to 2,056 million pounds. Furnace black output was 8 percent, or 132 million pounds, above that in 1961 and accounted for 90 percent of total carbon black production. Channel black output continued to decline and was 55 million pounds less than in 1961. Carbon black shipments during the year totaled 2,082 million pounds and were 5 percent above those of 1961. About one-fifth of these shipments were exported; the balance were sold domestically. An increase of 180 million pounds in domestic sales was partially offset by a decline of 80 million pounds in exports. Total value of carbon black production in 1962 was $145 million. The average value per pound of 7.06 cents was 0.24 cent per pound less than in 1961. Producers' stocks declined 26 million pounds during the year.

Jan 1, 1963

By William B. Harper

Domestic sales of carbon black sustained the upward movement for the 4th consecutive year, reflecting the increased sales of motor vehicles during the same period. Sales of carbon black in the domestic market topped 2 billion pounds for the first time during 1965 and have more than doubled the output of 20 years earlier. By far the largest user of carbon black is the rubber industry. That use accounted for more than 94 percent of the carbon black consumption with the bulk of it being used in tire casings and tubes. Thus demand for carbon black is naturally sensitive to trends in the sales of passenger cars and other motor vehicles, Manufacturers of inks, paints, plastics, paper chemicals, and food are also important users of carbon black.

Jan 1, 1967

By Carl W. Kelley

PRODUCTION in the United States of carbon black has increased from 20 million pounds per year in 1920 to over 2 billion pounds in 1964 valued at $156 million, mostly for consumption by the rubber-tire industry, which uses over 90 percent of total production. Production of over 2 billion pounds in 1964 is a 7.8-percent increase over 1963 and is the first time furnace black production has topped 2 billion pounds. Although 1964 channel black production dropped 6 percent below 1963, carbon black produced by the furnace process, which ac-counted for 92 percent of total production, increased 9 percent to 2,053 million pounds. Total shipments during 1964 amounted to 2,245 mil-lion pounds, a 7 percent increase. This growth parallels the expansion of the automotive and petroleum industries. Along with this expansion have been many advances, both in methods of manufacture and in the quality and variety of blacks available to industry. There are several kinds of carbon black, thermal, channel, furnace, lamp, and oil blacks. Until recently, channel has been the important black in rubber compounding. Following the introduction of the synthetic GR-S, and more recently of "cold rubber," it has been found that certain furnace blacks with particle size larger than that of the standard channel black give superior reinforcement. A great advantage of furnace black is that its yield per unit of gas feedstock is higher than that of channel black. The 184-million-pound increase in domestic carbon black sales was partially offset by a 37-million-pound decrease in exports. Decrease in exports especially to Europe, is expected to continue. In Europe, as in the United States, the major end use for carbon black is in the manufacture of automobile and truck tires. Although the number of automobiles in Europe is predicted to grow by about 7.5 percent per year, compounded until 1975, the increased demand will be met by a 20 percent increase in existing capacity and by the new plants being built in Europe by U.S. companies. Also) aromatic oils for producing furnace blacks are plentiful now that western Europe's chemical industry is switching to a petroleum base.

Jan 1, 1965

By Ivan F. Avery

DOMEST1C production of carbon black in 1963, remained at about the same level as in 1962. Carbon black produced by the furnace process increased 2 percent to 1,880 million pounds in 1963 and accounted for 91 percent of the total output. Channel black production continued to decline and was 14 percent less than a year ago. Shipments during 1963 totaled 2,098 million pounds, a 1 percent increase for the year. An increase of 88 million pounds in domestic sales was partially offset by a decrease of 72 million pounds in carbon black exports. Total value of carbon black production in 1963 was $148 million. The average value per pound was 7.18 cents or 0.12 cent per pound more than in 1962.

Jan 1, 1964

By B. P. Faulkner, M. Weinecke

Svedala started a development program in 1997 to develop a process to convert waste tires into valuable commodities. A review of numerous approaches revealed short-comings in the various approaches either process, mechanical, combination of factors, or trying to emphasis the production of low value products. A market study revealed that a process that could produce a good grade of carbon black would be economically feasible. This paper discusses the laboratory and pilot plant development and commercial plant design.

Jan 1, 2001

By Ahmad Ghahreman, Denver Cowan, Yeonuk Choi

"Testwork was conducted in order to compare the effectiveness of carbon based catalysts while oxidizing a gold-bearing pyrite concentrate under atmospheric conditions. Without the use of a catalyst the oxidation of pyrite was incomplete after 96 hours, resulting in roughly 60% pyrite oxidation. Furthermore the resulting sulphate yield from unassisted pyrite oxidation ranged between 72 and 84%. It is evident that atmospheric oxidation of pyrite is not viable due to slow oxidation kinetics and high sulphuric acid production when using a ferric sulphate media without a catalyst. The effect of two different carbon based catalysts, one Lewatit® AF 5 a new microporous carbonaceous bead, and the second a granular coconut shell based activated carbon, were tested under the same oxidation conditions as the unassisted pyrite tests. After 96 hours, Lewatit® AF 5 assisted oxidation showed approximately 96% pyrite oxidation with a sulphate yield ranging between 26 and 35%, while the activated carbon assisted oxidation reached approximately 100% pyrite oxidation with a sulphate yield between 36 and 37%. Testwork indicated that not only does the addition of a carbon based catalyst greatly improve the oxidation kinetics and lead to almost complete oxidation, the sulphate yield is also drastically reduced, resulting in very high elemental sulphur yields.INTRODUCTION Pyrite is an important sulphide mineral due to its ability to contain invisible gold concentrations up to 132 g/t (Chryssoulis & Cabri, 1990). As a result, ores composed of only a small amount of pyrite still have the ability to contain high gold grades. This refractory gold cannot be accessed via conventional gold leaching processes, such as cyanidation, and additional oxidative pre-treatment is required to liberate the gold, making it more amenable to extraction (Marsden & House, 2006). Current oxidative pre-treatments do exist consisting of both pyrometallurgical and hydrometallurgical processes including high temperature and high pressure leaching within autoclaves, biological atmospheric leaching and roasting. Autoclaves are a proven process reaching desirable recoveries within approximately a 1–2 hour retention time, due to the increased temperatures and pressures, allowing for an increase in dissolved oxygen (Marsden & House, 2006). The typical reaction for pyrite oxidation within autoclaves is presented in Equations 1, 2 and 3."

Jan 1, 2017

By D. Thibault, A. Akhiate, M. Brochu, E. Braud

Cast martensitic stainless steels, 13%Cr-4%Ni, having carbon contents between 0.018 wt% and 0.067 wt% were normalized, air quenched, and tempered at two different temperatures (550°C and 610°C). Their microstructures were characterized by optical microscopy and X-ray diffraction (XRD). Macro and microhardness, tensile strengths, and impact resistance were quantified for each material and condition. Results show that the prior-austenite grain size is constant through the materials but the percentage of reformed austenite, contained in the martensitic matrix, depends strongly on the material chemistry and on the tempering temperature and on its duration. It is observed that, independently of tempering conditions, an increase in carbon content increases the material hardness and tensile strengths, whereas the elongation remains constant. In contrast, the results of Charpy type impact toughness tests show a different trend. The material containing the average carbon content (0.034 wt%) is significantly tougher than the two other alloys. Surprisingly, the toughness of the steel containing 0.034 wt% carbon was found independent of the reformed austenite content. It is thus concluded that carbon and reformed austenite contents are not the only parameters affecting the toughness of these steels.

Jan 1, 2014

By D. J. Young

Alloys used at high temperature must resist both creep and corrosion. Design for corrosion resistance is based on the formation of a slow-growing, protective oxide scale by selective oxidation of an appropriate alloy component, usually chromium or aluminium. A successful scale will exclude other corrodents, notably carbon, which can otherwise cause extremely rapid corrosion at high temperatures. Selective oxidation of an alloy component necessarily lowers the concentration of that metal in the alloy subsurface region. Under thermal cycling conditions, mechanical damage to the scale leads to renewed oxide growth and accelerated alloy depletion. Eventually, a point is reached where diffusion of a corrodent into the alloy becomes competitive with the outward diffusion of alloy metal to repair the protective scale. Two examples of alloy failure by carbon attack are considered. In the steam cracking (pyrolysis) process, centrifugally cast tubes of heat-resisting alloy are exposed to a gas stream of hydrocarbon and steam, at a carbon activity of unity. Formation and repair of the surface chromia scale causes alloy depletion, Kirkendall void formation, and subsequent internal precipitation of chromium-rich carbides. Their formation makes chromia scale formation much more difficult, and generates internal stress. Eventually, the tubes fail by creep rupture. In other processes (e.g. steam reforming, heat treatment), synthesis gases are supersaturated with carbon at intermediate temperatures. Once the alloy's protective scale is breached, carbon attacks the depleted substrate. In the case of ferritic alloys, it forms a surface scale of Fe3C. As this scale thickens, the supersaturated carbon precipitates as graphite within its outer regions. The resulting volume expansion causes disintegration of the cementite in a process known as metal dusting. In the case of austenitic alloys, no metal carbide is formed. Instead, carbon dissolves in the depleted metal to diffuse inward and precipitate as graphite within the metal matrix. Again, volume expansion causes disintegration of the alloy, and metal dusting results. Dusting occurs at an extraordinarily rapid rate, and leads to failure by section loss or even penetration.

Jan 1, 2013