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By Joseph C. Mead, James R. Cudworth

THE Birmingham district of Alabama has utilized the slag from its blast furnaces consistently since the earliest development of the slag industry. Today there are producers of slag cement who started business in 1900, and who have, under a progressive policy, expanded the number of their products to meet present demands. There are producers of slag aggregates and other crushed slag products who have been successful for periods of over thirty years. There are at the present two companies, Cheney Lime and Cement Co. and the Southern Cement Co., manufacturing puzzolan cement; two companies, Birmingham Slag Co. and Woodstock Slag Co., making slag aggregates and by-products; one company, Tennessee Coal, Iron and Railway Co., a subsidiary of the U. S. Steel Corporation, producing ground open-hearth basic slag for soil conditioning. Two companies, the Sloss Sheffield Steel and Iron Co. and the Woodstock Slag Co., make slag concrete in ready-mix plants and one company, the Superock Company, manufactures fine and coarse slag aggregates under a new granulation process. No Portland cement is made with slag as an ingredient, because dolomite is used so extensively as a blast-furnace flux that the magnesium content of the slag is excessive. Sources Of Slag In the Birmingham district there are 22 blast furnaces, of which the majority are in blast. The present production is 165,000 tons of pig iron monthly; the production in 1935 was 1,297,960 gross tons1. There are also two blast furnaces at Gadsden and one ferroalloy electric furnace at Anniston. From these two sources is obtained slag to approximately 1.1 tons per ton of pig iron.

Jan 1, 1937

By B. Rai

Aluminum is produced by the Hall-Héroult process, which involves passing a current through a molten mixture of alumina dissolved in cryolite (Na3AlF6) to reduce the alumina to aluminum. This process occurs in an electrolytic cell comprising a steel shell lined with a carbon cathode and refractory bricks. After a certain period of operation, the carbon cathode deteriorates and is removed from the cell along with the refractory bricks. These removed materials are referred to as spent pot lining or ?SPL?. Typically, 30 Kg of SPL waste is generated for every ton of Aluminum produced. Globally aluminum smelters produce more than 500,000 tons of SPL each year. Even though SPL has a high fuel value (8000 to 9000 BTU/lb) and contains valuable metals, it is classified as a hazardous material due to its cyanide content and leachable fluorides. Various disposal/recycle techniques have been developed over the years for SPL but none of them is satisfactory. Thus, large quantities of SPL are still being dumped in landfills. In some countries, even the land filling of SPL is not permitted. The safe disposal of SPL thus remains a challenging problem to the aluminum industry and the search continues to find methods of converting SPL into a non-hazardous waste and/or recovering the valuable materials contained in the SPL. We have developed a process to produce hydraulic setting cements (eco-cement) containing a novel fluoride rich cementitious phase, from SPL by an energy efficient, low temperature clinkering route. A raw mix blend of SPL, lime/limestone, calcium sulfate and tailings sands based on a set of design criteria developed by us, is clinkered in a two stage process; 2 hours soak at 800 °C followed by clinkering at 1000 °C for another 2 hours, to produce a soft clinker. The SPL eco-cement is made by grinding the clinker to a fineness of 5000 cm2/g Blaine with 1% by weight borax as a set retarder. A good quality cement having as high as 20 % by weight of SPL in the raw mix (28 % by weight in the cement clinker) is thus produced. The physical properties of the SPL cements are found to be comparable to the Indian standard (IS) specifications for Ordinary Portland Cements (OPC). We have produced the cement in a few Kg batches and tested the reproducibility of results from batch to batch for further scale up. Once commercialized, this process has a potential of converting SPL into value-added cement products. Keywords: cement, spent pot lining, clinkering, fluoride, aluminum, ordinary portland cements

Sep 1, 2012

By S. Shrivastava, R. G. Reddy

Spent potliner is generated in the electrolytic process of reducing alumina to make aluminum metal using molten fluoride electrolytes. Spent potliner (SPL), obtained at the end of the pots life contains a small amount of cyanide and fluoride which present environmental problems. SPL became a listed hazardous waste under RCRA (KO88) in July, 1990. One of the possible uses of spent potliner is as a substitute for Calcium Fluoride (CaF2) as a fluidizer in iron- and steelmaking and in the glass industry. A low viscosity and a low melting point are prime requirements for accomplishing the above. In the present study, viscosity measurements were performed. Effect of various additives, such as sand, limestone, dicalcium silicate dust, and MgO baghouse dust on the viscosity of SPL was studied. The results showed that with the addition of sand and limestone, very high fluidity of SPL melt can be obtained at significantly low temperatures. The results suggest that spent potliner mixed with additives could potentially be used as a substitute fluidizer.

Jan 1, 1999

By R. G. Reddy

Spent potliner is generated in the electrolytic process of reducing alumina to make aluminum metal using molten fluoride electrolytes. Spent potliner (SPL), obtained at the end of the pots life contains a small amount of cyanide and fluoride which present environmental problems. SPL became a listed hazardous waste under RCRA (K088) in July, 1990. One of the possible uses of spent potliner is as a substitute for Calcium Fluoride (CaF2) as a fluidizer in iron-and steel making and in the glass industry. A low viscosity and a low melting point are prime requirements for accomplishing the above. In the present study, viscosity measurements were performed. Effect of various additives, such as sand, limestone, dicalcium silicate dust, and MgO baghouse dust on the viscosity of SPL was studied. The results showed that with the addition of sand and limestone, very high fluidity of SPL melt can be obtained at significantly low temperatures. The results suggest that spent potliner mixed with additives could potentially be used as a substitute fluidizer.

Jan 1, 1999

By R. G. Reddy

Spent potliner is generated in the electrolytic process of reducing alumina to make aluminum metal using molten fluoride electrolytes. Spent potliner (SPL), obtained at the end of the pots life contains a small amount of cyanide and fluoride which present environmental problems. SPL became a listed hazardous waste under RCRA (K088) in July, 1990. One of the possible uses of spent potliner is as a substitute for Calcium Fluoride (CaF2) as a fluidizer in iron-and steel making and in the glass industry. A low viscosity and a low melting point are prime requirements for accomplishing the above. In the present study, viscosity measurements were performed. Effect of various additives, such as sand, limestone, dicalcium silicate dust, and MgO baghouse dust on the viscosity of SPL was studied. The results showed that with the addition of sand and limestone, very high fluidity of SPL melt can be obtained at significantly low temperatures. The results suggest that spent potliner mixed with additives could potentially be used as a substitute fluidizer.

Jan 1, 1999

By Jorge Armstrong, Sean Warren, JOSEF BOURGEOIS

The application of statistical analysis software programs has proven useful for the investigation of rockfall runout distance along a designed slope. Rockfall modeling programs are continually being upgraded with more sophisticated analysis tools, such as the use of the rigid body versus lump mass models. Engineers at mine sites utilizing the software may have varied experience related to these models, their associated input parameters, and how to interpret the generated results. To address this concern, researchers at the Spokane Mining Research Division (SMRD) of the US National Institute for Occupational Safety and Health (NIOSH) investigated the influence of slope height, slope angle, slope material, and rock size for both rigid body and lump mass models in a 2-D statistical analysis program. Based on a literature search and industry input, specific ranges common to that of an open pit mining environment were chosen for each of the input parameters to determine 90% rock runout distance as well as their sensitivity to change. Data collected from this numerical analysis and simulation will be compared to empirical rockfall data gathered through the duration of the Highwall Safety project conducted by NIOSH from 2022–2026.

Jun 18, 2023

By J. Armstrong, J. Bourgeois, S. Warren

The application of statistical analysis software programs has proven useful for investigation of rockfall runout distance along a designed slope. Rockfall modeling programs are continually being upgraded with more sophisticated analysis tools, such as the use of the rigid body versus lump mass models. Engineers at mine sites utilizing the software may have varied experience related to these models, their associated input parameters, and how to interpret the generated results. To address this concern, researchers at the Spokane Mining Research Division (SMRD) of the U.S. National Institute for Occupational Safety and Health (NIOSH) investigated the influence of slope height, slope angle, slope material, and rock size for both rigid body and lump mass models in a 2-D statistical analysis program. Based on a literature search and industry input, specific ranges common to that of an open pit mining environment were chosen for each of the input parameters to determine 90% rock runout distance as well as their sensitivity to change. Data collected from this numerical analysis and simulation will be compared to empirical rockfall data gathered through the duration of the Highwall Safety project conducted by NIOSH from 2022–2026.

Mar 2, 2022

By Brad Murray

Evaluating the performance of a shielded tunnel boring machine (TBM) can be difficult because the ground cannot be observed directly and in relation to the TBM attitude within the excavation. It is difficult to determine whether performance problems are caused by ground loading, steering issues, fine muck packing against the shield, or migration of annular grout around the shield. The Arrowhead Tunnels Project in Southern California uses strain gauges on its shielded hard rock TBMs to detect shield strains early and correlate them with tunneling conditions, thereby increasing the chances that problems will be correctly diagnosed and addressed to optimize TBM performance. The frequent automatic measurement of shield strain has also been valuable by confirming whether remedial methods used to free the machine after stoppages are effective. This paper discusses the qualitative interpretation of characteristic strain patterns on the Arrowhead Tunnels TBM shields and discusses installation details and special considerations for setting up a strain measurement system.

Jan 1, 2008

By A. T. Robles, L. Buckingham

"When certain gold ores containing pyrite, graphite, humates and fumates or other organic compounds which are possibly adsorbed on clay minerals are treated with aqueous solution of alkali metal cyanide, the aurocyanide complex which forms is adsorbed by these ""pregrobbing"" species in the ore. Dissolution of gold proceeds until chemical equilibrium is attained between the cyanide complex adsorbed by the ore and in solution.Sodium lauryl sulfate (SLS) may be used to decrease the adsorptive activity of the prerobbing species in the ore. It has successfully improved recovery at Holt-McDermott Mine and is highly biodegradable.INTRODUCTION Precious metal-bearing ores containing preg-robbing species are poorly amenable to standard cyanidation techniques. The ""preg-robbing"" impurities with which they are associated tend to adsorb the gold cyanide complexes and carry them through the circuit to the tailings. Also, gold may be associated with these impurities in the ore and not be leached by the cyanide complexing agents used in conventional cyanidation techniques.Methods for dealing with the problem of preg-robbinq impurities in gold ores are:Carbon-in-Leach (CIL), in which granular activated carbon is added to compete with preg-robbing species for the gold cyanide complexes. This process can improve gold recovery in mildly preg-robbing ores especially when fine carbons with very high activities are used. However, with severely graphitic ore, the carbon associated with the rock may outperform the granular activated charcoal.Chemical Oxidation, in which the ore is subjected to preliminary chemical oxidation techniques to oxidize carbonaceous materials using such diverse reagents including ozone, sodium hypochlorite, calcium hypochlorite, chlorine gas, permanganates, perchlorates, chlorates and oxygen prior to subjecting the oxidized ore to standard cyanidation treatment to extract gold. This is generally a costly method and will not prove economical on a low-grade ore."

Jan 1, 1992

By F. Cihangir, A. Kesimal, K. Karaman, B. Ercikdi

Uniaxial compressive strength (UCS) and shear strength parameters(cohesion and angle of internal friction, Cand F) of rocks are important parameters needed for various engineering projects such as tunnelling and slope stability. However, direct determination of these parameters is difficult and requires high-quality core samples for tests. Therefore, this study aimed to explore the applicability of the Brazilian test (BT) - a simple, less sophisticated and inexpensive method for both specimen preparation and testing - to estimate the UCS and shear strength parameters of rocks. Thirty-seven rock types were sampled and tested, 24of which were volcanic, 8 were metamorphic, and 5 were sedimentary. Statistical equations were derived to estimate the UCS and shear strength parameters of rocks using the BT. The validity of the statistically derived equations was confirmed using predictive analytics software (PASW Statistics 18). A strong linear relation was found between BT and UCS values. BT and UCS values exhibited prominent linear correlations withthe cohesion values of rocks. The Mohr envelope was also used to determine the cohesion and friction angle of rocks using BT and UCS values. It is deduced from the current study that the BT values can be used to estimate the UCS and cohesion. However, no relation was observed between the angle of internal friction values and the UCS and BT for all rock types. Therefore, different approaches are suggested for the estimation of the internal angle of friction for application in the preliminary design of projects.

Jan 1, 2015

By Bill Stormes

This paper will discuss implementation of the Hilti OneStep rock anchor technology to improve face bolting operations during the May 2008 longwall move; increase rock anchor installation capacity; and improve safety by reducing employee exposure periods by utilizing the Hilti OneStep rock anchors.

Jan 1, 2008

By Tom Blevins, Roland Walker, Jinsheng Chen

"The Dywidag-Systems International DSI Tandem Anchor bolt, with an improved expansion shell-washer design, can substantially reduce potential entry roof falls caused by twisted or deformed expansion shells of the traditional mechanical anchor bolts during installation. In addition, the improved anchorage system can also ensure that a consistent and high installed load is achieved, which is critical for effective beam building under thinly laminated or layered roof conditions. This paper discusses the genesis and anchorage performance of the Tandem Anchor bolt, and analyzes the tension/torque relationship of different mechanical shell anchors using data obtained from both lab and field tests. It also discusses roof bolting mechanisms, roof bolting systems, and factors influencing effective beam building. Finally, numerical modeling was used to analyze the effect of bolt pretension magnitude on entry roof stability.INTRODUCTIONThroughout the history of underground mining, keeping the roof from uncontrollable collapse has been the greatest concern of the miner. Tremendous strides have been made in better understanding, predicting, and supporting the mine roof. This conference has spent the last twenty-eight years sharing information and distributing it to the mining community. A paraphrased statement from former Secretary of Defense Donald Rumsfeld adequately describes the challenges to the mining engineer as it pertains to roof control: it is a study of known knowns, known unknowns, and unknown unknowns. It is the hope of the authors to address some of these unknowns.The paper discusses the development of bolt anchorage systems from dry shells to shells with resin-assisted anchorage. It looks at some of the issues faced with the anchorage shells being used when introducing the insertion pressures caused by resin cartridges. The rationale behind the shell design changes was to compensate for this resin induced stresses.An improved expansion shell assembly (a slotted expansion shell base, a tapered cramming plug, and a novel support nut with tapered top) for mine roof bolts makes up the Tandem Anchor (U.S. Pat. No. 6742966); this minimizes the possibility of twisting seen with traditional mechanical shells and thus prevents springy bolts and shell leaves from breaking. A fully grouted Tandem Anchor bolting system has the advantages of both the pure mechanical point-anchor and the non-pretention fully grouted bolting systems. Once installed, the installed load or pretension will be locked in and never bleed off. Compared with the fully-grouted (2-speed resin) tension rebar bolting system, the fully-grouted Tandem Anchor bolting system can (a) reduce bolting cycle time (about 15 seconds per bolt), boosting coal production and productivity; (b) provide a greater installed load or pretention; and (c) achieve a consistent tension/torque ratio, which gives better bolting quality control. Therefore, a fully grouted Tandem Anchor bolting system is the most effective means to reinforce a weak rock mass intrinsically by the theory of beam building. For thinly laminated or layered roof conditions, a higher installed load or pretention (50% or more of the bolt's yield strength) can make a roof bolting system much stiffer, which results in less roof movement. Numerical modeling results show that the magnitude of the roof's tensile stress and relaxation zone can be substantially reduced under a higher installed load or pretention."

Jan 1, 2010

By J. A. Heskett

NEW ZEALAND is dependent on the outside world for its ferro goods, yet it can boast of at least two well-defined iron-ore deposits; namely, Para Para limonite, 3 Fe203 + 21120 also found as lower hydrated oxides, and Taranaki iron-sand, a combined magnetite and ilmenite, 2FeO + 2Fe203 + FeO + Ti02. The former is of massive variety and the FIG. 1.-VIEW OF WORKS SHOWING IRON-SAND DEPOSITS, ALSO WHARF AND BREAK¬WATER IN THE DISTANCE. latter granular and mixed with various proportions of fine shell and siliceous sand well water-worn. This latter deposit forms the greater portion of the beach sands of the west coast of the North Island of New Zealand. It is so fine that the whole of a sample passed through a sieve of 40 meshes to the inch. The ilmenite cannot be detected by the microscope, as in the titaniferous ores of the Adirondacks, nor can it be magnetically separated, as in the titaniferous ore of Natashkwan, Canada. To all appearances it is a chemical compound of the double oxides of iron and titanium and not a mechanical mixture, as is the ore of the Adirondack deposits.

Jan 8, 1920

By J. A. Every-Brown

Case studies are presented of three derelict sites in Kent and Essex that provide a good cross-section of opportunities for second-generation commercial uses of former chalk, limestone, clay and gravel workings. A 240 ha abandoned chalk quarry at Grays in Essex, now known as Chafford Hundred, is undergoing mixed development to include leisure facilities, a range of housing and commercial areas and an enhanced environment. The 120 ha of Stone Marshes now comprises the Crossways business park and the Dartford international ferry terminal. Reclamation and servicing required more work than had been anticipated and the fact that the area was within the green belt added to the delays, but Blue Circle was eventually able to provide a comprehensive development of the entire area to a high environmental standard. Stone Pit 1 landfill, at Dartford in Kent, is a former chalk quarry 40 ha in area and with an original average depth of 35 m. Landfilling commenced in 1976 and during the period 1979-1984 the site operator designed, developed and installed a gas collection and flaring system. From 1986 a gas plant supplied up to 5 000 000 therm/yr of landfill gas to a local cement works and in 1989 a 1 MW power generation scheme, later expanded to 3 MW, was commissioned. Gas is currently also supplied to a metal refining company for use in internal combustion engines

Aug 1, 1994

By M. E. Tyrrell, Alan H. Goode

The application of a simple, two-dimensional computer technique for evaluating rock burst potential in cut-and-fill stopes was investigated. The principal purpose of the study was to compare the effectiveness of high-modulus fill and destressing as aids in the control of rock bursts. Two conclusions that are probably of general applicability are drawn. First, high-modulus fill is ineffective as a means of increasing the mine stiffness and acts to control rock bursts only if it supports enough load to reduce substantially the stresses on the unmined vein material. Second, destressing is most effective if it is performed when the vein material is near the point of failure.

Jan 1, 1975

By J. C. Ashby

Electric utility response to certain amendments of the Clean Air Act has resulted in a production of several types of alkaline coal combustion byproducts. Alkaline combustion byproducts are gaining increasing usage for acid mine drainage mitigation as research leads to a better understanding of their beneficial applications. Since January of 1997, Mettiki Coal Corporation has been injecting alkaline flue gas desulfurization material from Virginia Power's Mt. Storm Unit #3 wet limestone scrubber into abandoned portions of the active Mettiki mine. This paper provides an overview of the key design, transportation, regulatory, and environmental issues faced in the project.

Jan 1, 1998

By Ricardo dos Santos Oliveira

Este trabalho foi realizado a partir da identificação do problema da alta geração de resíduos cafeeiros e de emissão de gases poluentes pelas indústrias siderúrgicas. Ao analisar as emissões nacionais de sistemas de energia, observou-se que o segmento da indústria de aço tem uma importante participação devido ao alto consumo de carvão metalúrgico e coque no balanço energético. O projeto teve como objetivo utilizar duas biomassas, a casca de café e o carvão vegetal, como uma fonte de energia no processo de redução do minério de ferro, através da injeção de finos pulverizados pelas ventaneiras de altos-fornos. O cafeeiro e a planta de eucalipto são fontes renováveis, ao contrário do carvão mineral, e através da fotossíntese capturam o gás CO2 da atmosfera, reduzindo parte da poluição causada pelos altos-fornos à coque. Para simular a possibilidade de injetar as biomassas estudadas, um simulador de injeção de materiais pulverizados foi utilizado. Foram utilizadas, também, técnicas para caracterizar os materiais, como classificação granulométrica, combustão, calorimetria, análise de gás, superfície específica, microscópica e química. Através do estudo, esta pesquisa mostra que a casca de café pode ser injetada em altos-fornos substituindo parcialmente a moinha de carvão vegetal.

Aug 17, 2017

By Thompson Júnior Ávila Reis

Neste trabalho, a microscopia de força atômica foi empregada para estudo da evolução da fragilização a 475ºC em um aço inoxidável lean duplex. Para tal, amostras deste aço foram submetidas a tratamentos isotérmicos com duração variando entre 1 e 100 horas na temperatura de 475ºC. Ensaios de tenacidade ao impacto e de dureza foram realizados para confirmar a ocorrência da decomposição da fase a. Posteriormente foram realizadas análises no microscópio de força atômica. Os ensaios de tenacidade ao impacto e de dureza indicaram que ocorreu decomposição espinodal da fase a. Medições da diferença da dissolução das fases a e ?, conduzidas no microscópio de força atômica, indicaram que a resistência à dissolução da fase a diminui com o tempo de envelhecimento de forma similar a redução da tenacidade. Os resultados indicam que a microscopia de força atômica é uma ferramenta eficiente para avaliar o grau de evolução da fragilização a 475ºC.

Aug 16, 2017

By Wemerson Junio Gandra

Para a redução do minério de ferro no alto-forno é necessária a utilização de uma fonte de carbono, que pode ser encontrada no carvão mineral e/ou carvão vegetal. Diante do cenário atual, a busca constante por maior competitividade, associada ao atendimento da qualidade e aos requisitos ambientais, exige a implementação de várias ações alternativas no processo de fabricação de gusa. Dentre elas, destaca-se a utilização de combustíveis alternativos no sistema de injeção dos altos-fornos, como por exemplo, a substituição parcial do carvão mineral pelo carvão vegetal. Do ponto de vista ambiental, é altamente favorável a utilização de uma fonte renovável de carbono. O objetivo desse trabalho é apresentar a adequação do processo, desde o recebimento do material até sua injeção nos altos-fornos, bem como os resultados já alcançados e os desafios futuros. A utilização do carvão vegetal na mistura de carvão pulverizado resulta em flexibilidade na utilização de matérias primas e contribui para preservação do meio ambiente.

Oct 30, 2017

By Francisco Diego Araruna da Silva

necessidade de elevados patamares de competitividade na indústria do aço tem levado à utilização cada vez mais frequente, por parte daqueles que utilizam lingotamento contínuo, de ferramentas de modelagem matemática da solidificação. A construção dessas ferramentas, por sua vez, possui uma etapa importante de validação, onde devem ser comparados os resultados simulados com dados reais do processo sendo estudado. Dessa forma, o presente trabalho tem como objetivo utilizar critérios metalúrgicos de qualidade e processo no lingotamento contínuo para auxiliar na construção e validação de um modelo matemático da solidificação de tarugos de aço. Uma vez que há na literatura diversas formulações para os coeficientes de transferência de calor na refrigeração primária (molde) e secundária (zona de sprays), foram realizadas análises – a luz dos critérios metalúrgicos – dos resultados simulados com nove combinações dessas formulações, sendo possível, ao final, determinar qual combinação melhor modela o processo (ou máquina) em estudo.

Aug 17, 2017