Search Documents

By Higuchi K

Intorducing the hypothesis that the cause ,òi spontaneous combustion of coal is depending un the accumulation of heat produced by its oxidation, the authors derived the equation expressing the temperature change in a heap i fine coal. To solve the equation, thermal conductivity, specific heat and rate of heat ,eneration of fine coal (-48 mesh) were measured at various temperatures in the range _'0-65¦C. The equation was solved numerically and the volume of fine coal which would ignite spontaneously was estimated as the function of ambient temperature. Using 170 Kg of fine coal, everal experiments for confirmation were conducted. At the ambient temperatures of 60¦C nd 50¦C, coal began to fire spontaneously brut 00 and 110 hours later respectively. Iii addition to this, the measured t,,rp,i,itures in the coal heap agreed with the ,aLulated ones comparatively well, If more volume of fine coal were used, experi;:ontul ;,eneration of spontaneous combustion from ...,n-, , 1-1 I'd Sill al r..

Jan 1, 1981

By R. V. Ramani, R. Bhaskar

"IntroductionThe behavior of dust clouds in mine atmospheres has been a subject of longstanding interest due to both health and safety reasons. Pioneering studies in Germany and SMRE focussed on ambient dust concentration, principally aimed at determining optimum velocities for effective dilution. A summary of studies related to this area is provided by Hall,(l) Efforts to understand dust deposition from the explosion hazard point of view led to experiments in return airways (2-4) followed by experiments in longwalls.(5) Concerted efforts, either experimental or theoretical, were not made until recently to relate ambient concentration with dust deposition in mines. In 1974 Hwang et a1 (6) developed a computer model to predict dust concentration which considered deposition-concentration relationships. Also, experimental studies involving concurrent dust deposition and ambient concentration were conducted in the U.S. by Courtney et al (7 ) in operating mines. Efforts to relate theory with experimental results have been made by Owen (8) and Hwang et al (6 ) for dust deposition. There has been limited work, however, to determine the application of the theories and assumptions from aerosol sciences for modeling dust flows in mine atmospheres. (9 ) This is the objective of the work currently underway in the Generic Technology Center on Respirable Dust since· 1983 under a project titled, ""Prediction of Ambient Dust Concentration in Mine Atmospheres."" The scope of the project activities include:1. Development of a mathematical model to predict dust deposition and concentration in mine atmospheres.2. Experimental studies on dust transport and deposition in mine airways.3. Comparison of the model results with the experimental data."

Mar 1, 1989

By R. T. Dec

A review is undertaken of existing mathematical models of compaction process in roll press. The example of plane-strain, plane-stress model is presented together with comparisons between computed and experimentally recorded pressure distribution in roll nip region. Next, the discrepancies between predicted and measured values are discussed and practical method based on experimental optimization of compaction process using laboratory roll press is proposed. Examples of the selection of optimum roll press operating parameters for calcium oxide fines, sodium chloride and iron oxide dust are presented to illustrate advantages of the method. Finally scale up procedure is discussed for estimating the performance of commercial size roll press based on the data collected on laboratory size equipment.

Jan 1, 2000

By F. Vagnon, A. M. Ferrero, M. Pirulli, A. Segalini

"The topic of this study is the design of flexible fences to mitigate the risk due to debris flow phenomena by means of theoretical and experimental studies analysed in framework of the Rock Engineering System (RES).The study of the interaction between debris flows and flexible barriers is a major challenge since many different aspects concerning both the slope characteristics and the structure features are involved. Debris flows are often triggered by the mobilization of debris deposits that are generated by rock fall of adjacent rock walls. The rock debris deposits are difficult to be characterized by the physical and mechanical point of view due to their large variability in volume distribution and, moreover, when dealing with high mountains environment, they are also strongly affected by the presence of water at different phases (solid or liquid) depending on the temperature. The debris deposit turns unstable in relation with the geotechnical and environmental features of the areas and the instability evolution in high mountain steep valley is often a debris flow. Debris flow destructive potential is very high and protections are often needed to reduce the debris flow risk.This complexity determines the needs of comprehensive study able to include the global basin dynamic and the environmental conditions. An a-priori analysis of the influence of the different aspects can be useful to focus on the real driving aspects of the problem. Due to the complexity of the system the application of the RES methodology is recommended in order to clearly define the different assumptions needed, their influence on the simulations and a comparison among them.RES allows investigating triggering criteria, flow and depositional processes and interaction of flows with protection fences in a rational way. For this purpose, an interaction matrix is created: it summarizes the key geotechnical parameters that influence debris flows, their interactions and debris/engineering protection opera behaviour. The goal is to quantify the diagonal-off terms to assess the residual risk after barrier construction, using back analysis from real debris flow event and data collection from literature.This methodology is applied to analyze a debris flow event in the Italian Western Alps where numerical analyses are carried on to assess flow characteristics to be used for fence design through the application of an analytical and numerical model developed by the authors (Brighenti et al, 2013). In particular, the velocity and deposition heights have been estimated using the numerical code RASH3D (Pirulli, 2010), which is a single-phase model based on depth-averaged Saint Venant equations. Pathways of different lengths are studied to assess the input data necessary to design the protection barrier and to determine the associated risk. Simulation of the barrier at different places along the valley will also allow to determine optimal barrier location in terms of minimum residual risks by comparing the velocity, the volume and the energy of the debris after the barrier impact.The work will produce a possible design scheme to be adopted in this environment."

Jan 1, 2015

After a short theoretical comparison of various typical large bell tops with the bell-less top for segregation and other ,ffects on the material flowing through the equipment proper, a comparative analysis between classical and the new burdening in the furnace is given, showing the theoretical effects of distribution and segregation on the horizontal pressure variations, temperature values and gas composition in the stack. Then some typical theoretical charging patterns of the bell-less top for wall and centre temperature adjusting, pressure drop corrections, dissymmetric local action for blow-in and scaffolding are described. Finally the available practical results on furnaces equipped with the bell-less top are compared with the theoretical statements made before and conclusions indicate that the new approach to burdening blast furnaces is a real improvement.

Jan 1, 1975

By Roshan B. Bhappu

Although the economic importance of recovering copper by leaching of mine work dumps from open-pit operations has been realized for some time, serious attempts to understand and to improve such operations through scientific research has been made only in recent years. This progress report covers the results of chemical, physical, and biological studies pertaining to the dump leaching process and discusses salient features and parameters that may be helpful in improving such operations.

Jan 1, 1968

By Tatyana A. Ivanova, Tamara N. Matveyeva, Anatoliy A. Fedorov, Tatyana V. Nedosekina, Valentin A. Chanturiya

An ingenious methodology purposively developed by the authors for comprehensive assessment of flotation properties, electrophysical characteristics and. crystal chemistry features of natural gold-bearing sulfide minerals of different origin has been used in this study. Examination of the elemental composition of the minerals, ion-molecular components of the liquid phase in suspensions, surface properties of sulfides and different flotation reagents sorption forms was performed using the methods of X-ray phase and spectral analysis, potentiometry, UV and IR spectrometry, computer image analysis, and computer simulation techniques. The role of isomorphous impurities in the formation of hydrophobic sulfhydric collector layers on mineral surfaces in complex ore processing has been elucidated. The parameters characterizing the variability of the Fe:S ratio in pyrite of different origin have been determined based on non-stoichiometry characteristics of natural gold-bearing sulfide crystals. An ingenious method of formatting and linear approximation of experimental data was used to find out the quantitative relationships between the impurity content, electrophysical characteristics, non-stoichiometry and floatability of pyrite from a number of different deposits. The effect of the impurity species present in sulfides on the characteristic pH value marking the floatability peaks as such and their trend of shift towards higher alkalinity has been revealed. A theoretical substantiation has been given to prognostic assessment criteria for processing characteristics of gold-bearing sulfide minerals with varying composition. New flotation reagents and advanced reagent systems which help to increase the contrast of processing characteristics for different gold-bearing sulfides, resulting in improved selectivity, have been developed. The mechanism of selective flotation of precious metal-bearing Fe and As sulfides achieved by using short-chain dithiocarbamates and a mixture of cyclic trithiocarbonate with oxyalkylsulfides has been analyzed.

Jan 1, 2003

By C. Guan

Since it was patented in 1942, the Crago process with fatty acid rougher flotation followed by deoiling and amine cleaner flotation has become the standard for phosphate flotation in Florida and North Carolina. This paper outlines the basic fundamentals involved in this proven technology. Included are the mineralogy of the flotation feed, the solution chemistry and the interfacial phenomena. The process variables affecting the performance of this technology are also discussed.

Jan 1, 2009

By Janne P. Isohaka, Anssi M. Laaksonen

"Abstract In Scandinavia the use of steel pipe piles in bridge foundations started in the mid-1980s and has increased steadily since. As the piles driven in soft soils are slender, they can fail by buckling. Buckling usually requires taking into account the second order effect in structural and geotechnical design.The purpose of this paper is to derive formulas for demonstrating the theory behind the formulas given in literature for the second order effect of initially bent piles.IntroductionIn Scandinavian countries solid bedrock usually lies at moderate depth. If the bridge site is in an area where the soil above the bedrock is soft, the bridge is usually founded on end-bearing piles resting on the bedrock.The main purpose of the piles is to transfer axial forces into bearing soil. Like columns, piles can lose their stability by buckling when surrounded by soft soil. When axial compression on a slender, initially straight, pile reaches a particular value called the critical load, the pile is subjected to lateral deflection and loses stability. The soil around the pile suffers a corresponding deformation. This soilstructure interaction increases the critical load compared to a pile without surrounding soil.It is very unlikely that piles are ideally straight. Initial curvature along with curvature and deviation caused by the installation of piles causes bending moments to the pile when normal force is applied. These lateral displacements increase when normal force increases. This increase of moment is called asecond order effect.Eurocode and literatureEurocode 7 includes guidelines for the design of piles (Eurocode 3, section 5 includes design of steel piles). However, there are no clear guidelines for considering the second order effects related to piles surrounded by soil. Eurocodes advise doing structural design of piles the same way as in the case of columns. With columns, the second order effect is taken into consideration by multiplying the first order moment with the factor shown below (SFS EN-1992-1-1, 2005):"

Jan 1, 2014

By Robert F. Mehl

EXTENSION of physical and chemical methods of research in the study of metallic behavior continues rapidly, particularly in the correlation of behavior with crystal structure, and in the analysis of elastic and plastic properties. The growth of the science of metals during 1933 calls for special comment; the need for special reviews and for textbooks and monographs is now acute, as might he supposed from the number of references appended to this article, a list which is much abbreviated.

Jan 1, 1934

By Charles S. Barrett, Robert F. Mehl

A study of the structures arising from the decomposition of the ß solid solutions in the Cu-Zn and the Cu-A1 systems is of peculiar interest in the study of the mechanism of precipitation from solid solutions. It is possible in these alloys, by varying the composition within the ß field, to precipitate from the same basic lattice phases having different lattice structures. It has been rather generally assumed heretofore that the type of structure originating from the decomposition of a solid solution— the Widmanstätten structure—-is determined by the lattice structure of the parent solid solution alone. In the first paper of this series1 evidence was advanced which threw doubt upon this hypothesis; but definite proof of the correctness or incorrectness of the hypothesis should be forthcoming from a study of these alloys, for if the structures originating, for example, from the precipitation of the a phase from ß and of the ? phase from the ß in the Cu-Zn system should be shown to be crystallographically different, the hypothesis would necessarily be held as definitely disproved. Furthermore, the newer proposal enunciated in the first paper of this series—that the origin of the Widmanstätten structure lies in a cooperation between the lattice of the parent solid solution and that of the precipitate-—which at present seems the only a1ternative hypothesis, would in such an event be given added weight. The work here reported shows that the Widmanstätten structures originating in the precipitation of the a phase from the ß and in the precipit'at.ion of the y phase from the y in the Cu-Zn system are indeed crystallographically different; and incidentally presents some new descriptive information on the Widmanstätten structure from a more general point, of view.

Jan 1, 1931

By Oluwasegun Samuel Odebiyi, Shaona Wang, Feng Gao, Biao Liu, Hao Du

Recovering vanadium from vanadium titanium-magnetite (VTM) ore using ( NH4)2C2O4 is a clean hydrometallurgical process, but the drawback is the low recovery and slow kinetics due to the formation of inhibitor. A novel energy-efficient mathematical model was derived for green leaching of VTM in which the mechanical activation (MA) removed the inhibitor “δ” (formation of impermeable product layer of CaC2O4) covering the reacting core of the CaV2O6 leaching process in ( NH4)2C2O4 solution. Before the MA processing, the formation of the CaC2O4 layer affects the kinetics (slow) and NH4VO3 leachability (low recovery). The dissolution rate enhancement and economic importance (in terms of leaching kinetic/recovery) of mechanical activation (MA) pretreatment in hydrometallurgical processing cannot be overemphasized. It is shown from the experimental and developed mathematical model results that the rotating speed of the ball mill (ωb) has a significant effect on the NH4VO3 recovery. At 360 rpm, the experimental result gave an 82% optimum recovery rate and a reaction rate constant of 0.01889s−1 with close correlation with the present models at 82.8% and 81% for liquid-to-solid layer diffusion and chemical reaction controls, respectively, with a reaction rate constant of 0.018883s−1. The close correlation between the experimental recovery rate results and the diffusion recovery rate model result justifies that the leaching process is diffusion control shrinking core kinetic with experimentally measured activation energy (Ea) value of 19.502 kJ/mol . This present model proved that MA enhances the dissolution rate regardless of the formation of a passivation layer on the material and best describes the kinetics of the MA hydrometallurgical processes compared to the shrinking core model.

Nov 3, 2023

By D. Van Dooren

The final goal of the research project is to develop a 3D FEM model that is able to predict the kinetics and micro-structural evolution during the bainitic transformation. The input parameters consist of thermodynamic and atomic mobility data obtained from the ThermoCalc and mCTRA databases combined with structural mechanics data extracted from the stress-strain curves of the fcc and bee phases. In this paper the general principles of the model are outlined and some interesting preliminary results are shown and commented. The full implementation of the model has presently not been achieved yet. In the model the bainitic transformation is considered as a sequence of martensitic (re)nucleation and growth of a ferritic subunit followed by the carbon rejection into the surrounding austenite. The (re)nucleation of the subunits will be described through a non-classical martensitic nucleation criterion. Once a nucleus has been activated at a specific location in the material, a full-sized subunit is instantaneously formed through a displacive mechanism. The stress state in the system that arises due to the transformation strain can be calculated by a 3D FEM programming code. Immediately after the formation of the subunit, another 3D FEM programming code calculates the carbon diffusion from the supersaturated ferrite into the surrounding austenite. The resulting stress state and carbon profiles will be used to determine where and when a new subunit will nucleate based on a renucleation criterion. Keywords: Bainitic Transformation, Modeling, Eshelby, Carbon Diffusion

Jan 1, 2003

By Lj. D. Andric

Development of modern devices for mechanical and mechanochemical materials activation has been dated since the beginning of last century. Rapid development of high-energy mills that are different in type, size, design and performances, has been occurred during the last four decades. Because of complete understanding of mechanical processing, entire knowledge of theoretical principles of high-energy mills is necessary. These principles are main causales of process that are happened in materials during the mechanical activation. This paper is occupied by theoretical principles of operation of high-energy mills. Conventional high energy mills with balls, high-energy planetary mills and high-energy vibrational mills are particularly considered in the paper.

Jan 1, 2014

By G. Y. Liu

The structure-activity relationships for four thionocarbamate collectors are discussed in this pa-per. These collector classes are alkyl alkyl thionocarbamates, allyl alkyl thionocarbamates, acyl al-kyl thionocarbamates and alkoxylcarbonyl alkyl thionocarbamates. The main emphasis will be to highlight the differences between collectors and their affinities for copper and iron sulfide minerals on the basis of data on electronic-structure properties obtained by vacuum and solution density functional calculations, flotation experiments and analysis measurements. The mechanism of interaction of these collectors with sulfide minerals is also discussed with perturbation theory. The theoretical study results indicate that acyl alkyl thionocarbamates and alkoxylcarbonyl alkyl thionocarbamates have best performance in these agents as flotation collectors with improved collecting power for copper sulfide minerals and excellent selectivity against iron sulfide minerals, which are consistent with the experimental data reported in the literature.

Jan 1, 2014

Many industries base their decisions on the assaying of tiny analytical sub-samples. The problem is that most of the time several sampling and sub-sampling stages are required before the laboratory provides its ultimate assays using advanced chemical and physical methods of analysis. As long as each sampling and sub-sampling stage is the object of due diligence using the theory of sampling it is likely that the integrity of the sought after information has not been altered and the generated database is still capable to fulfil its informative mission. Unfortunately, more often than not, unawareness of the basic properties of heterogeneous materials combined with the unawareness of stringent requirements listed in the theory of sampling, lead to the conclusion that massive discrepancies may be observed between the expensive outcome of along chain of sampling and analytical custody, and reality. There are no areas that are more vulnerable to such misfortune than sampling and assaying for trace amounts of constituents of interest in the environment, in high purity materials, in precious metals exploration, food chain, chemicals, and pharmaceutical products. Without the preventive suggestions of the theory of sampling serious difficulties may arise when making Gaussian approximations or even lognormal manipulations in the subsequent interpretations. A complementary understanding of Poisson processes injected in the theory of sampling may greatly help the practitioner understand structural sampling problems and prevent unfortunate mistakes from being repeated over and over until a crisis is reached. This paper presents an overview of the theoretical, practical and economic difficulties often vastly underestimated in the search for quantifying trace amounts of valuable or unwelcome components.

Jan 1, 2010

By Xianguo C, Baoqi S, Shaozhong Z, Huiling Z, Zhengbing C

Acidless and fluoless flotation is a new method for separating feldspar from quartz at the natural pH value of tap water in the absence of any acid and fluoride and other inorganic reagents. The paper introduces the production application of this method in plants and research results on the mechanism involved in the flotation method.

Jan 1, 1993

A general analytical solution of the effect of an inclined contact separating two media of differing electrical properties on a normally incident plane electromagnetic field has been given (Geyer, 1972). These solutions for the electromagnetic response at any observation point P(r, [u]) are given in the form of inverse Lebedev-Kontorovich transforms. Two modes of excitation are considered: (1) case where current density flows across strike of the contact separating the media of differing electrical properties (only Er , E [u] , and Hx differ from zero) and (2) case where current density flows along-strike (only Hr , H [u] , and Ex differ from zero). The electromagnetic fields in the frequency range of interest and for the rock conductivities under consideration are quasi-static in nature so that to a first-order approximation the horizontal magnetic field at the surface of the earth is constant and continuous across the discrete discontinuity in resistivity for case (1) above, and so that the tangential derivative of the horizontal electric field at the surface of the earth is constant and continuous across the discrete discontinuity for case (2) above. Of course, it is well known that where large horizontal gradients in conductivity exist, there also exists large anomalous components of the vertical magnetic field (Weaver, 1963). The recognition of such anomalous components and their magnitudes due to the presence of lateral resistivity changes in the overburden becomes very important in any wavetilt type measurement which may be used to locate a miner. When the lateral change in resistivity becomes quite large, the integral solutions (expressed as Lebedev-Kontorovich transforms) simplify considerably and allow ready numerical evaluation. Examples of the amplitude and phase responses of the radial electric, horizontal electric, and vertical magnetic field in the vicinity of the contrast in resistivity are shown in Figures 2, 3, and 4. Of particular significance is the fact that the anomalous vertical magnetic field is three orders of magnitude larger near the contact than far from the contact. This fact implies that where large resistivity contrasts do occur in the rocks overlying mine workings, that significant errors may be present in wavetilt measurements as used above for location criteria! Another observation insofar as the anomalous vertical magnetic field is concerned is the linear variation of phase as one proceeds away from strike in induction number (increased distance or frequency). For a pulse-excited communications system this phenomena would have a bearing on where the zero crossings would occur (i.e., 'pulse breadth') in the transient coupling between any given source-receiver configuration and at any given receiver site.

Jan 1, 1973

By W. E. Forsythe

WHEN measuring ordinary temperatures, the instrument is generally placed in very close contact with the body the temperature of which is desired. However, if the temperature of the source is continually raised, a point is soon reached where no known substance will, in general, remain constant in any of its temperature-measuring properties if placed in direct contact with the source. Also, it is occasionally necessary to measure the temperature of a source that 'is so small or so situated that it would be very hard to bring the measuring instrument into direct contact with the source. When these conditions exist, advantage is taken of the well-known fact that all bodies, when at sufficiently high temperatures, send out radiation in amounts readily measurable. This radiation has been found to be related to the temperature. The temperatures of very hot bodies have probably always been judged by the color, or the brightness, of the light given off. With practice, one can estimate probably within 50° to 100° C. of the correct value. However, if judgment is left to the eye alone, very much larger errors are sometimes made, due to

Jan 9, 1919

By Y. Jin

Magnesia ramming materials have been widely used in China instead of magnesia bricks as furnace lining materials of ferroalloy refining furnace. The paper introduces the development of the ramming material, recounts its chemical composition, physical property and application characteristics. Because of its high MgO contents and fine sintering property, the ramming furnace bottom has the properties of good refractory, monolithic construction and thermal shock resistance. The changes in mineral composition and furnace tearout characterization show the reasons for the bottom?s long service life. The obvious benefits are widely achieved, the annual saving cost in refractory is about 2 millions US dollars.

Jan 1, 2004