Search Documents

By E. Shelobolina, S. M. Pickering, J. E. Kogel

A long history of weathering and bacterial alteration processes have transformed Georgia’s Coastal Plain kaolins from dark organic muds to recrystallized white pigment-grade industrial clays. A sequence of six stages in development of these valuable mineral deposits is outlined over their Late Cretaceous and Tertiary deposition and alteration history. Anaerobic and aerobic iron oxidizing and iron-reducing bacteria are present in the Georgia kaolins. These bacteria may have had a major role in iron and organic matter removal during several of the alteration stages that occurred over the past 60+ million years. Iron was likely solubilized by both iron-reducing and iron-oxidizing bacteria, depending on availability of Fe(II), Fe(III), and NO3. Thus, over long periods bacterial activity slowly led to nearly complete groundwater removal of iron from the kaolin deposits. Further bacterial iron removal on an industrial process scale may eventually prove feasible. “Without the multitude of living reactions as channels for energy and electrons and without the enormous capability of life to transfer with and against chemical gradients, there would be practically no or at least a very reduced geochemical rock cycle on this planet.” (Krumbein and Dyer, 1985, p. 157)

Jan 1, 2002

By J. M. D. Wilson

The literature relating to binders in iron ore pelletizing is reviewed from the point of view of their established or proposed bonding mechanisms in green and dry pellets.

Jan 1, 1981

By Vladislava A. Ignatkina, Victor D. Samyguin

"Within the limits of two-phase approach, considering mass transfer with pulp and air streams was shown that each bubble appears to be an elementary carrier, transporting particles from the collection zone into the froth. The kinetics of flotation was described by the exponential equation in which first order flotation speed constant has to be replaced with two-phased coefficient of a mass transfer. Criteria of selectivity of two ore fractions separation, based on determination of optimum time at which maximum difference between extractions and components content in separated fractions were offered. An interrelation between optimum time of pulp residence in a flowing chamber of a flotation machine, time of bubbles mineralization and an optimum airflow has been ascertained. Cumulative criterion of mass transfer efficiency of flotation process has been ascertained to be a form of the spectrum and its position on axis of three-phase coefficient of a mass transfer.INTRODUCTIONRegularities of a mass transfer of three bearing streams: pulp stream, air stream and froth stream underlie theory of mineral complexes flotation (Samygin, Filippov, & Shekhirev, 2003)However, only description of mass transfer in pulp stream by means of kinetic equations that were simple and convenient for practical use, has gained a full distribution (Tykhonov, 2009;Rubinstein&Filippov, 1980; Saleh, 2010).Within the limits of a single-phase approach, the role of gas stream in increase of speed and selectivity of flotation, was associated with an improvement of hydrodynamic mode. An influence of particles and bubbles sizes (Rubinstein&Filippov, 1980; Rubinstein&Samygin, 1998, Samygin et al., 2003; Dai, Fornasiero,& Ralston, 2000), of pulpflow and airflow (Finch& Dobby, 1990) and turbulent energy intensity (Shubert, 1979; Massinaei, 2007) on the flotation process has been studied. It was stated that flotation selectivity is increasing by means of gradual airflow increase from first to final cameras of the impeller flotation machine (Aslan&Boz,2010; Finch, 2011) and by means of using a multizone flotation machine (Samyguin, Filippov, Matinin, Lekhatinov, &Tertyshnikov, 2013)."

Jan 1, 2016

By Giuli M, Barnaba P, Sacerdote R, Tammaro F

Following a theoretical consideration of the effect of flooding, fluidisation and softening on blast furnace blowing limits, results are presented which show the effect of these parameters on operation. Industrial trials on Oscar Sinigaglia No. 4 BF are reported and results compared with those obtained theoretically and in the laboratory. It is shown that in these trials the furnace operated at levels of fluidisation very much (80-90%) below those theoretically calculated whereas in some cases (high proportion of sinter) actual hot metal output was near the calculated flooding limit. However, it was observed that as the sinter percentage decreases also actual productivity becomes lower than the one caused by flooding. This gap, which increases as other ferrous components (essentially acidic) replace the basic sinter was explained by the softening of the burden under bosh conditions. Softening indices measured on the individual materials yield support to this explanation. Coke rates data show that for approximately every one percent increase in the basic sinter in place of blended sized ore, a coke rate decrease of 1.1 kg/thm results. For acidic pellets this value is 0.6 kg/thm. Results of breakdown and reduction characteristics are also given and their indices compared with actual pt oduction. Measures to improve operations are proposed.

Jan 1, 1975

By J. S. Ross

The significance and role of industrial minerals in Canada differ from those in the United States, The smaller Canadian industry has recently become well diversified and self-sufficient in most commodities, However, it depends on exports, principally to the United States, for much of its market, Imports are small, but imports of several basic products manufactured from industrial minerals are large. This nation is a leading world producer of asbestos, gypsum, sulphur, nepheline syenite, titania slag, potash and barite. It has reserves in asbestos for at least 30 years enough potash to supply the current world's needs for 2,000 years and sulphur reserves for 40 years of current world demand, One of the ilmenite deposits contains enough titania to supply the current world demand for at least, 25 years.

Jan 1, 1964

By N. Sahin, K. Baris, A. Ozarslan

This paper aims to assess the current and future role of coal in energy strategy of Turkey and evaluates the compatibility of the policies to the EU energy policy and strategy. The Turkish government set targets to utilize more coal reserves of the country in next decades. However, the country is also in the process of becoming an EU Member State, hence, it is expected that the energy policies have to comply with the EU. Moreover, Turkey ratified Kyoto Protocol, thus the country should limit greenhouse gas emissions. Clean Coal, Carbon Capture and Storage (CCS) technologies are expected to become an important instrument for the mid-term reduction of CO2 emissions from coal-fired power plants. An alternative technique to the conventional CCS methods is CO2 sequestration by mineral carbonation. Turkey has significant resources of magnesium silicate minerals (olivine, serpentine) deposits which can be utilised in CO2 sequestration by mineral carbonation method.

Jan 1, 2011

By N. V. Mel'nikov

This paper discusses the reserves of oil, natural gas and coal in the USSR, with particular attention to the future role to be played by coal in supplying the energy fuel resources of the country.

Jan 1, 1972

By Natalie J. Shackleton, Deryck de Vaux, Cyril T. O’Connor, Vratislav Malysiak

"The major losses of PGM and base metals in the beneficiation of platinum group deposits occur during the separation of gangue from the value minerals by selective flotation. A number of studies have shown that this negative impact on flotation is due to surface passivation, caused by various ions that may originate from the external water supply or, as is likely in the majority of cases, from the oxidation of the mineral surfaces and the grinding media. The objective of the study was to investigate the effect surface passivation and inadvertent activation have on flotation and how this can be managed so as to increase the separation of pentlandite and pyroxene. The aim was to minimise the percentage pyroxene reporting to the concentrate and simultaneously maximise the pentlandite recovery. The testwork incorporates the addition of an activator (copper sulphate), a complexing agent, such as DETA (diethylenetriamine) and a dispersant (polyphosphate) at pH 6 and pH 9 in an attempt to alleviate the surface passivation of pentlandite and inadvertent activation of pyroxene. Both synthetic minerals and plant ores were studied in order to determine the effect surface passivation and inadvertent activation have on mineral surface alteration and floatability. Zeta potential determinations, microflotation, ToF-SIMS (Time of Flight Secondary Ion Mass Spectrometry) analyses, laboratory batch flotation tests and continuous flotation testwork were used as tools to study the surface alteration and/or floatability.Zeta potential determinations and ToF-SIMS analyses showed that copper adsorption is non-selective. Both pentlandite and pyroxene become copper (II)-activated in the presence of copper sulphate and subsequently, in the presence of xanthate, adsorption of the collector will occur onto copper activated mineral surfaces. Zeta potential determinations also showed an alteration of the surface charge in the presence of polyphosphate, thereby inhibiting surface passivation of sulphides by slime coatings due to surface repulsion."

Jan 1, 2003

The effect of conditioning energy input on the metallurgical results of an emulsion flotation process has beenattributed by previous authors to a detergency process.This paper shows that such a process does not explain the data and that an attrition mechanism is more appropriate.

Jan 1, 1970

By T. K. Dichmann, J. A. Finch

"Microflotation, laboratory batch, and in-plant minicell continuous tests were conducted to determine if copper ions not only activate sphalerite but also depress pyrite when the minerals are together. Microflotation tests showed that pyrite recovery increased with addition of copper ions in the pH range of 5-10 when alone, but decreased when sphalerite was also present. Batch flotation tests (Red Dog ore) showed that upon addition of copper, pyrite recovery decreased significantly. The continuous tests (Louvicourt Mine) confirmed this and indicated that with excess copper pyrite recovery can increase. The results suggest there is competition for copper and xanthate in favour of sphalerite. To take advantage of this competition it may be necessary to control the sequence and rate of copper, collector, and lime addition. INTRODUCTIONFlotation, in common with all physical separations, is an imperfect process that results in misplacement of minerals. One source of this imperfection is accidental activation by contaminating metal ions. An important practical example is the misplacement of pyrite to zinc concentrates. Flotation of sphalerite generally requires activation by copper ions, added as copper sulphate. Copper ions are also used to activate pyrite [l] hence there is the suspicion that accidental activation contributes to the recovery of pyrite (Py) with the sphalerite (Sp). However, recent literature has shown that copper ions may make Py less floatable if Sp is also present. Xu et al. [2] conducted continuous minicell tests in-plant at Kidd Creek Operations (division of Falconbridge Ltd.) and showed that while the addition of copper sulphate improved zinc/iron selectivity, it did so as much by reducing the recovery of pyrite as increasing zinc recovery (Figure 1)."

Jan 1, 2000

The objective of a mine planning exercise is to plan a safe mine that maximises net present value (NPV) for the project. Two primary elements are key to design of a mine plan optimised to maximise profit: selection of an optimised production rate and selection of an optimised equipment fleet. Both depend upon accurate estimations of capital and operating costs for the equipment and for the life cycle of the mining operation. Once a trial production rate is determined, a primary equipment fleet, ie excavators, haulers, and blasthole drills, can be determined based on material characteristics and haulage distances and gradients. An auxiliary fleet, dozers, road maintainers, service trucks, etc can be determined using less rigid productivity criteria. With an equipment fleet determined, operating and support personnel can be assigned based on shift requirements and equipment operating needs; and material and supply requirements can be estimated. Knowing the areal dimensions of the major equipment items, road widths and repair shop dimensions can be determined. Personnel numbers and supply requirements determine the square metre sizes of offices, change rooms, and storage facilities. Reliable sources of capital and operating unit prices and costs for all these items are referenced in the paper. Once preliminary capital and operating cost estimates are calculated by applying unit costs to equipment, personnel, material and supply needs, potential profit can be tested using DCF techniques. An optimised mine plan can then be determined by testing the potential profitability of multiple mine production rates. Because of the economies of scale, full capital and operating cost estimates must be completed for each production rate in order to produce meaningful comparisons.

Dec 6, 2010

By Lorenzen L, Van Der P F

It is the aim of this paper to review recent research in understanding the role of cyanide in the elution of gold. Under conditions of severe pre-treatment (high temperatures and levels of cyanide), the dynamics of elution are determined mainly by the adsorption equilibrium and the flow conditions in the column. When conditions are less favourable for desorption, transport phenomena are rate controlling. The most important sub-processes of elution are the changes in cyanide, potassium and gold concentrations, as well as the change in passivation of the carbon surface. Mathematical models to simulate the various sub-processes are described briefly.The presence of an irreversibly adsorbed species such as AuCN on the carbon is determined mainly by the pH, temperature and the type of carbon. Cyanide in the pre-treatment step will convert the AuCN to reversibly adsorbed Au(CN)2. Competition between cyanide and Au(CN)z for adsorption sites will enhance the elution of gold, but plays a minor role at elevated temperatures. The most important effect of cyanide is its reaction with the functional groups on the carbon to passivate the surface for the adsorption of anionic metal cyanides and thereby promote the elution of gold. This passivation, caused by the degradation of cyanide, is strongly temperature dependent. Free cyanide in the elution step of an AARL elution is of lesser importance than the cyanide in the pre-treatment step. Elution without cyanide is possible only after cold acid washing, and has been proven on plant scale.

Jan 1, 1992

By R. A. Spitz, R. Leiby, M. Bricker

Electrochemistry plays a significant role in minimizing wastes at East Penn's secondary lead smelter. East Penn has been recovering spent battery acid for reuse in new batteries since 1992. East Penn also produces a fertilizer feedstock from sulfur dioxide in the smelter stack gases. The success of these processes is, in large part, due to the installation of electrochemical cells. The cells in the acid recovery plant allow the waste from this process to be concentrated into less that 10% of the original spent acid. The cells in the fertilizer plant treat the solution to remove dissolved metals prior to sale to fertilizer manufacturers.

Jan 1, 2000

By Versiane Albis Leão

This work aims at the selection of an appropriate eluant for cyanide recycling using ion exchange resins. Based on a literature review as well as on experimental results, the elution of resins loaded with copper and minor amounts of iron and nickel is discussed. The resins Imac HP 555s, Amberlite IRA 900 (Rohm&Hass) and Purolite A860S (Purolite Co) were eluted using either NaCI, zinc and nickel cyanides, hydrochloric acid, sulfuric acid or acid thiourea solutions. The results indicate that saline solutions are effective only with polyacrylic resins (Purolite A860S), failing to desorb the metals, specially the nickel cyanocomplex, loaded on polystyrene-based resins. Cyanide solutions of both zinc and nickel are capable of eluting over 90% of the loaded metals. In contact with pure acid' solutions, iron precipitates onto the resin beads, as Cu(II) ferrous cyanideCu2Fe(CN)6.xH20. Thiourea is able to elute all the three metal cyanocomplexes owing to the increased solubility of copper cyanocomplexes in the presence of this complexing agent. The results demonstrate that a universal eluant is not available and the selection of the most appropriate resin-elution procedure should be based on the specific features of the system under consideration

Jan 1, 1998

By Ian E. Efford

The paper gives an assessment of Canada's energy supply-and-demand position, the current situation and projections into the future, as well as a review of some alternative energy futures for Canada. The main elements of Canada's energy strategy for the period 1977-1990, with particular reference to the role of energy conservation, are discussed, leading in to the development of the national energy conservation program.

Jan 1, 1977

By David A. Newman

Severe roof control problems have plagued a West Virginia underground mine since its initial development in the late 1970's. Adverse roof conditions in the Eastern portion of the reserve result from a combination of mining: - perpendicular to the major principal horizontal stress direction, - near lineament intersections, - in areas where the ratio of horizontal stress to vertical stress exceeds 2.00 to 4.00, and - where laminated strata are present in the immediate roof. The focus of this study is to identify the engineering (mine orientation, roof safety factor) and geological parameters (lineament and horizontal stress orientation, horizontal to vertical stress ratio, and immediate roof lithology) causing poor roof conditions and to quantify their influence on projected mining conditions in the Western portion of the reserve Rose diagrams were used to illustrate the correlation between the orientation of eight hundred thirty-six (836) roof falls with that of forty-four (44) lineaments and the principal horizontal stress Similarly a composite map was used to demonstrate the relationship between roof falls and the ratio of horizontal stress to vertical stress The immediate roof strata across the property were categorized as either laminated or non-laminated based upon a thorough examination of one hundred sixty-two core logs. The presence or absence of fireclay, a rider coal, and carbonaceous shale was also noted because of the historic correlation with poor roof conditions. Rock strength and physical property tests were conducted on selected immediate roof strata recovered from coreholes drilled along the mains projected to the Western portion of the reserve Potential roof control problems in the Western reserve were quantified based upon the correlations developed by analyzing engineering and geological data The main conclusion is that laminated roof strata, the rider seam, and its associated fireclay will have the greatest influence on mining conditions. Roof problems attributable to horizontal stresses will not be as severe in the West due to an increase in overburden depth and corresponding decrease in the stress ratio. Recommendations are provided for mining orientation, the layout of mains and submains, panel location, and roof support based on intended service life.

Jan 1, 1999

Increasing use has been made of engineer ing geology and hydrogeology in the development of the infrastructure for mining projects. The Geological Survey of the Department of Mines, the Department of Main Roads, the Irrigation and Water Supply Commission and private consulting organisations and mining companies, employ spec- ialist staff to carry out engineering geological and/or hydrogeological investigations. Such in- vestigations have been of assistance in recent mining developments in northern Queensland, in- cluding those in the Cloncurry - Mount lsa, Weipa, Greenvale and northern Borten Basin areas.

Jan 1, 1974

Ferric (Fe3+) ions are omnipresent in flotation circuits. Depending on pH and the nature of the ore body, Fe3+ ions may play a role in the adsorption of thiol collectors on sulfide minerals. To investigate this possibility, a two-compartment galvanic coupling cell was designed. This cell was used to monitor changes in contact angle of a sulfide mineral in one compartment, while varying concentrations of the Fe3+ ions in the other. The results showed that Fe3+ ions promote xanthate adsorption as indicated by the increase in contact angle. Implications of this finding in sulfide mineral flotation in general will be discussed.

Jan 1, 1998

By J McQuie

The concentrator at WMCÆs Leinster Nickel Operation has operated with flash flotation in the grinding circuit since the early 1990s. There has always been a positive correlation between flash flotation Ni recovery and overall Ni recovery û however this relationship could be explained by differences in the ore, rather than by the action of the Flash flotation cell in reducing overgrinding of Ni. In July 2003, refurbishment within the plant made it necessary to operate the concentrator for a period with the flash flotation cells off. The resulting data set provided evidence that flash flotation in the grinding circuit changes the size distribution of Ni to reduce the amount of slow-floating fine (-7 ¦m) Ni produced. Ni recoveries in the finer size fractions were similar with flash flotation on or off û but because less fine Ni is produced when the flash flotation cells are operated, overall Ni recovery improved.

Jan 1, 2005

By D Prior

The Australian mining industry is a significant contributor to the nation’s greenhouse gas (GHG) emissions, and like any industry, it must make efforts to reduce these. Medium- and long-term strategies will include the replacement of diesel engines with alternative energy sources, but what can be done in the short-term to reduce diesel consumption and hence CO2 emissions? Haul trucks are identified as the major contributors of CO2 emissions in the mining fleet and this paper focuses on firstly identifying what drives haul truck emissions and secondly, discussing what is the role of the Fleet Management System (FMS) in reducing these. A key enabler of this is having a robust fuel consumption model within the FMS, and I describe how this may be done. Besides novel approaches to incorporating fuel consumption (CO2) management into truck assignment algorithms, this paper also describes how the FMS can be used to implement and manage procedures and policies to reduce haul truck emissions.

Jun 22, 2022