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By E. W. Mountjoy

THE Exshaw formation is a thin but very persistent black shale unit generally well exposed along the easterly scarp faces of the fault blocks comprising tl1e front ranges of the Rocky mountains. It is over lain by the Mississippian Banff shales and silty shales and underlain by the massive Palliser Limestone formation of late Devonian age. The Exshaw continues eastward under the plains of Alberta and on into Saskatchewan, with little change until it reaches the surface of the Palaeozoic-Mesozoic unconformity. During the summer of 1953, the writer was working- with a field party under Dr. J. L. Usher in the front ranges of the Alberta Rocky mountains. This party, sent out by the Mobiloil Company, conducted a geological survey of Devonian rocks between the towns of Banff and Jasper. The writer helped to describe and map these Devonian rocks and obtained first-hand information concerning the Exshaw shale and its relationship to the underlying and overlying sediments. Additional information was obtained from reference material and from a number of geologists whom the writer has consulted. Grateful acknowledgment is offered to them, to the Mobiloil Company for releasing field information, and to F. W. Beales and W. P. Hancock who helped edit the original paper for publication. Information from areas north and smith of that studied and from bore holes on the prairies is referred to. Localities mentioned may be found in Figure 1.

Jan 1, 1956

By Penny C. Stewart

Narrow vein underground stope design engineers in Australia have expressed significant interest in the requirements and methodology for developing site-specific stability charts. This is largely due to a concern that existing stope stability charts inadequately take into account factors influencing narrow vein stope stability, such as the effect of backfill abutments and the effect of in stope pillars. This paper presents conclusions from a comprehensive statistical examination of case history requirements for a site specific stability chart and critiques literature arguments for site-specific charts. A new statistical analysis technique and a large comprehensive stability database enabled the authors to quantify case history requirements and any site-specific effects the model exhibits. The analyses indicated that a reliable stable-failure boundary requires at least 150 case histories, of which a minimum of 10 percent should be unstable stope surfaces. Marginal site-specific effects were observed for the operating conditions captured within the database. The authors conclude that the apparent site-specific effects noted in previous literature are attributable to operating conditions inadequately represented in the database. Such operating conditions could induce erroneous stability predictions at any site, and are therefore not truly site-specific. Following from these conclusions, a strategy for taking into account operating conditions particularly relevant to narrow vein mining has been proposed. In particular, the development of a chart that accounts for the effect of backfill abutments on stope stability. Backfill abutment effects are particularly relevant to mechanised narrow vein mining methods such as modified Avoca. Collaboration from at least five sites is required to obtain access to relevant data and underground drives for geotechnical mapping. Preliminary estimations indicate that approximately three months fieldwork is required to meet case history requirements. CMS data in conjunction with 3-dimensional design software will be used to calculate equivalent linear overbreak/slough (ELOS). In contrast to stable, failure, major failure and caving categorical variables, ELOS is an objective and continuous stability variable and is therefore, more conducive to mathematical modelling.

Oct 1, 2001

By D. Doungdeethaveeratana

The extraction kinetics in a novel solvent extraction process have been investigated. In this process, the liquid-liquid emulsion is generated by bottom gas injection into countercurrently flowing aqueous and organic phases. This process has a number of advantages over the mixer-settler unit or the spray column in terms of simple equipment configuration, without any mechanical moving parts, and the ease of cleaning and process control, while providing a sufficiently large interfacial area for rapid mass transfer. The overall rate increased with increasing gas injection rate and height of the aqueous phase but decreased with increasing injector diameter at the same gas injection rate. The variation of the overall rate constant was correlated against a set of dimensionless numbers, representing the operating conditions. Extraction rates and efficiencies comparable to those in a mechanically generated emulsion were attained in this new process.

Jan 1, 1998

The passage of chloroform vapour in a carrier of oxygen through two nickel sulphide ores heated to 380°C converted the nickel to the water soluble chloride form. In one ore the nickel (2·75 per cent) was presentas violarite ((Ni, Fe)3S4) whereas in the second it was present as pentlandite, ((Fe, Ni)9S8) (4·9 per cent Ni).A similar technique was utilized to convert nickel in nickeliferous laterites (1·6 per cent Ni) into a soluble chloride using town gas instead of oxygen as a carrier.With both techniques greater than 90 per cent extraction was achieved.

Jan 1, 1972

This paper describes the extraction of gold, as the anionic aurocyanide complex, from solution by strong- and weakbase anion-exchange resins. The effects, on the rate of extraction and the loading capacity for gold, of parameters such as pH, temperature, ionic strength, agitation, and the presence of competing anions are reported. The elution and regeneration of strong- and weak-base resins will be examined in a second paper. A third paper in this series will present the results of several smallscale pilot-plant investigations carried out with strong- and weakbase resins In cyanide pulps from various South African gold mines, and will compare the metallurgical performance of resin-In-pulp with that of the carbon-in-pulp process.

Jan 1, 1984

The extraction and recovery of gold from copper electrorefining slimes by leaching and solvent extraction using dibutyl carbitol (DBC) has been practiced for several decades. Yet, the deportment of some common elements in this process has not been reported. The focus of this paper is to report the behavior of copper, bismuth, silver and selenium during the processing of industrial solutions by batch and continuous extraction on the laboratory scale. It was found that DBC, while an excellent extractor of gold from a highly oxidative chloride leach solution, also loads significant quantities of Cu, Bi, and Se. Silver was not present in significant quantities in the leach solution nor did it load appreciably. The deportment of gold and impurities are reported for batch and continuous operations of a two-stage extraction process using distribution ratios and separation factors.

Jan 1, 2010

By L. D. van Dyk, G. S. Tshofu

Iron ore fines are by-products of iron ore mining operations. Unlike iron ore lumps, fines cannot directly be used in conventional iron making processes, and consequently large quantities accumulate around the world. Pelletizing and sintering can be used to convert iron ore fines into agglomerates or briquettes for processing with lump ore, but these techniques are energy intensive and produce greenhouse gases. This research investigated the extraction of iron from iron ore fines using acetylacetone (a ß-diketone) as an environmentally friendly alternative process for fines utilization. A 2k factorial experiment design was used to identify the significant extraction variables. It was found that the reaction temperature and solid to liquid ratio had significant effects on the extraction process. The extraction kinetics were studied at different temperatures and the highest iron extraction (97 %) was obtained after 48 hours at 413 K and 0.025:1 (g:mL) solid to liquid ratio for a particle size range of +106 to -150 µm. The extraction products were easily separated from the unreacted acetylacetone by flash distillation and iron(III) acetylacetonate crystals were recovered. An economic evaluation showed that selling the crystals was profitable. Alternatively, the crystals can be reduced with hydrogen to iron particles and acetylacetone (for reuse).

Jan 1, 2015

By Ry Stone

To maintain longwall continuity, NRE Wongawilli Colliery extracted the approximately 20-year-old Thompson Mains and in doing so, 20 roadways were holed into during longwall retreat. The orientation of these roadways with regard to the longwall face varied between (i) a parallel alignment where the entire roadway was simultaneously subjected to a significant increase in vertical stress on holing and (ii) a more favorable high angle of alignment, meaning that only a portion of the roadway was subjected to an increase in vertical stress on holing. In addition, the longwall holed into and was recovered in one of the existing roadways. The geotechnical environment presented several additional challenges during longwall retreat. The orientation of the stress field resulted in a major horizontal stress notch on the maingate and an elevation in the major horizontal stress in front of the longwall face during the retreat up to an adjacent goaf edge. The presence of geological structure zones also resulted in both swings in the major horizontal stress direction and increased levels of roof deformation. The gate road support designs were based on commonly accepted strata management techniques and principles. The support designs in the hole-through roadways were based on empirical design models generated from (i) aconceptual geomechanical model of pre-driven hole-throughand recovery roads and (ii) a worldwide database on pre-driven hole-throughand recovery roads. Imperative to the success of extracting the panel was a sitespecific strata management process. In this regard, consideration was given to the following: roof displacement monitoring in the gate roads (in particular, Longwall (LW) Acceleration Position), roof-to-floor convergence monitoring in the hole-through roadways, the ability of the mine to limit downtime prior to and during holing by utilizing an Authority to Mine (ATM) type process, and the use of Trigger Action Response Plans (TARP).

Jan 1, 2012

Spectrum Resources commenced operations as a public listed mining company in August, 1983, with a variety of precious metal projects in New Zealand. At that time the outlook for most mineral commodities, with the notable exception of precious metals, was decidedly gloomy. Metal prices were depressed and demand forecasts were universally gloomy. Against this background the company reviewed the non-traditional metals sector to try and identify a 'new' metal with an above average demand growth and market value. Lithium, a commodity with exciting new applications in storage batteries and alloys, met both criteria. Annual world consumption of lithium is around 7000 tonnes; current prices are around $NZ40/lb for lithium metal and demand growth is projected at five to seven per cent per annum. Geothermal fluids at Wairakei and elsewhere contain anomalous amounts of lithium and in May, 1984, the Chemistry Division of DSIR was commissioned to carry out a literature survey on the possible recovery of lithium and other minerals from geothermal waters. The survey results were encouraging and the company subsequently negotiated exclusive access rights, for research purposes, to geothermal discharge fluids from the Wairakei and Kawerau geothermal fluids. Most of the subsequent investigations reported here were carried out by Chemistry Division, DSIR, under contract to the company with some assistance from the Industrial Processing Division, DSIR.

Jan 1, 1986

By J. Wallace Gwynn

Salt from Great Salt Lake was probably used by the Native Americans prior to the Jim Bridger Expedition to the lake in 1824-25, and was used by the region's early explorers and trappers after that time. From the arrival of the Mormon pioneers in 1847, salt has been produced from Great Salt Lake, starting first with the collection of crude salt from along its shores, and later by boiling down the lake's brine to obtain crystalline salt. Since these early beginnings, salt production from the lake has become a substantial commercial enterprise. Since the early 1960s, research and development have led to the economic production of potassium sulfate, magnesium metal, chlorine gas, magnesium chloride products, and nutritional supplements. Many of the salt-production techniques and equipment that were developed prior to 1964 are still being used today. Sodium sulfate has been produced, but is no longer marketed. Morton Salt, Cargill Salt, and IMC Salt currently extract sodium chloride, which is precipitated during the early stages of evaporation when the brine concentration reaches saturation, or about 26 to 27 percent total dissolved solids. Magnesium Corporation of America produces magnesium metal and chlorine gas, and IMC Kalium Ogden Corporation produces potassium sulfate, as well as magnesium chloride brine and flake products. These salt, gaseous, and metallic products are processed from the sodium-chloride-saturated, high-magnesium-chloride brines, and from the potassium and magnesium salts that are precipitated from the lake brine after it has been further concentrated. One obstacle to salt production is the fluctuating level of Great Salt Lake. In 1983, the lake level began a dramatic rise from an elevation of 4,200 feet (1,280.16 m) to its historic high of 4.211.85 feet (1,283.77 m) in 1986-87 (uncorrected USGS provisional lake-level records). The State of Utah employed flood-control measures, including breaching the Southern Pacific Railroad causeway in 1984, and pumping lake water to a shallow basin west of the lake in 1987. During the high-water years, the lake's mineral-extraction industries faced many challenges including the need to raise dikes to prevent flooding of facilities, broken dikes which resulted in the inundation of solar ponds, and dealing with the lake's greatly reduced brine salinities which resulted in lower annual salt and concentrated-brine production. The years following the record-high lake levels have been a time of adaptation, innovation, and change for Great Salt Lake industries. After its solar ponds were flooded in 1986, AMAX, Inc. built a new solar-pond complex near Knolls, and used the concentrated brines from the West Pond, generated by the State's West Desert Pumping Project. Great Salt Lake Minerals built a 21-mile-long (33.8 km) open, underwater canal, called the Behrens Trench, to convey concentrated brines from a new, remote solar pond on the west side of the lake to the east side of the lake, to help increase its production of sulfate-of-potash. There were also numerous changes in corporate ownership and production-facility locations.

Jan 1, 2001

By T. G. Legare

It is now well documented that trace amounts of silver, gold, and platinum group metals occur in certain geothermal brine deposits. A significant body of literature has been generated over the last twenty years which describes attempts to quantify the frequency and levels of these precious metals in the brines. This literature is often confusing and contradictory. For example Barnea 1 states that the Salton Sea geothermal field carries 2 ppm gold, yet more recent data by workers at Lawrence Livermore National Laboratory2 (LLNL) concludes that the gold level in Salton Sea brine is <0.07 ppb. They report a platinum level in one well of 55 ppb. This apparent contradiction may be explained by sampling source and technique, but is most probably explained by difference in analytical technique. Analytical techniques and problems will be discussed in the next section.

Jan 1, 1985

By Z. B. Karshigina, Ye. G. Bochevskaya, E. A. Sargelova, Z. S. Abisheva

At the present time of depletion of reserves of high grade rare earth deposits, it has become necessary to involve low grade raw materials in the production. Among the rare-earth deposits in Kazakhstan, the most advanced one is Kundybai. The mineralogical composition of ore is represented by the minerals: a-quartz SiO2, kaolinite Al2(Si2O5)(OH)4, muscovite KAl2(AlSi3)O10(OH, F)2, albite Na(AlSi3O8), rutile TiO2, and hematite Fe2O3. It contains: 59.1–68.5% SiO2, 19.1–28.4% Al2O3, 7.2–10.3% Fe2O3, 0.51–0.84% TiO2, 0.10–2.32% CaO, 0.39–2.10% MgO, and some other elements. Rare earths are located in the clay part (kaolinite, goethite) in the ion-adsorbing form, and they are represented by the main ore mineral churchite - YPO4·2H2O. In the ore the amount of rare-earth elements (total REEs) varies from 210 to 600 ppm. Elements of the cerium group predominate (La, Nd, Ce, Sm, Pr) and the yttrium group is represented by Y, Gd and Dy. Extremely thin intergrowth and accumulation of REEs in clay minerals cause difficulties in their recovery using flotation and gravitation beneficiating methods. The purpose of this work is the development of an extraction method for the main mineral components of ore with transfer of the total REEs into the solution with high extractive efficiency. Results of the experimental work into high-temperature processing (hereinafter referred to as sulphatization) of ore by sulphuric acid with subsequent dual-mode water leaching of the sulphate product (sinter) are presented in this manuscript. The influence on the ore sulphatization process of some physical and chemical parameters: liquid-to-solid (L/S) ratio (0.36–0.86 cm3/g), temperature (100 – 500°?), concentration of sulphuric acid (3.0–18.62 mol/L) and duration (0.5–2.5 h) was studied. Optimal technological parameters of the process were determined to be: L/S ratio 0.36–0.46 cm3/g; temperature 500°?; concentration of H2SO4 9.0 mol/L; soaking time 1.5 h. Under these conditions it is possible to obtain extractions of ~ 85% REE, as well as 58% aluminium and 10% iron. XRD and IR-spectroscopy analyses were used to determine the material constitution of sulphated cakes obtained under optimal conditions. It was found that the primary minerals are quartz and muscovite; however different sodium aluminium silicates and albite minerals are present as well. In the future, it is proposed that the leach residue cakes are processed into precipitated silica (“white soot”).

Jan 1, 2016

By Xiaolong Bi, Shaohua Luo, Longjiao Chang, Shiyuan Cao, Jianan Liu

The abstract discusses the extraction of silica from nickel laterite ore using a hydrothermal process with sodium hydroxide. The effects of reaction temperature, time, and NaOH-to-ore ratio on silica extraction were investigated. The optimal conditions were determined, achieving over 98% silica extraction. The mechanism involves the reaction of Si in lizardite and quartz with sodium hydroxide, forming sodium silicate solution. Other metals like Mg, Fe, and Ni are enriched in the residue.

Apr 21, 2022

By Cordner G. D

Titanium is not yet being produced on a commercial scale despite the facts that it has some impressive properties, and that it occurs very abundantly in easily-mined, highgrade oxide ores. One important reason for this is that the excellent mechanical properties of the metal were not widely recognised and appreciated until about twenty years ago.Another factor which has tended to retard progress in titanium metallurgy has been the realization that the oxide minerals of titanium are very stable; in other words, considerable energy has to be expended to reduce the oxide to metal. Table 1 presents the minimum energies which would have to be expended to produce one ton of each of the metals, aluminium, magnesium, titanium and iron from their respective oxides under theoretically ideal conditions at normal temperature and pressure. At higher temperatures, the minimum energy requirements are different, but the values for the various metals still fall in the same order as indicated in Table 1.In actual fact, the energy consumption in the case of any particular metal is higher than the ideal value by an amount which can be determined only by&apos; the results of plant practice. The only general conclusion that can be drawn from the data in Table 1 is that it might eventually prove...

Jan 1, 1950

By Lingzhi Yang, Feng Chen, Yufeng Guo, Tao Jiang, Zeqiang Xie

Zinc ferrite (ZnFe2O4), one of the major forms of zinc in Electric Arc Furnace (EAF) dust and zinc leaching residue, is very difficult to chemically dissolve in either acidic or alkaline solutions. In spite of the zinc resources in the Electric Arc Furnace (EAF) dust and zinc leaching residue are abundant, there is no mature utilization technology. This situation not only causes the waste of resources, but also produces the harm to the environment. In the paper, the basic principle of this process has been established by revealing the phase equilibria in the CaO–Fe2O3–ZnO system, where Ca2Fe2O5 can be in equilibrium with ZnO rather than ZnFe2O4 at higher CaO region. It has also been demonstrated that the formed ZnO can be solved by ammonia-leaching and Ca2Fe2O5 keep in solid residue, which can be used as a flux for steel refining.

Mar 1, 2017

By William Hawker, James Vaughan, Jeff Chen, Antony van der Ent

"Nickel agromining utilizes hyperaccumulator plants (“metal crops”) to extract nickel from low-grade soils, a process that yields high-grade nickel bio-ore. This feedstock is further processed into a range of nickel products. The bio-ore is relatively free of impurities that complicate the traditional processing of laterite nickel ores. In this paper, current primary nickel processing routes and proposed nickel bio-ore processing options are summarised. A novel pyro-hydrometallurgical route demonstrated at the laboratory scale is described. This process produces a precipitated nickel hydroxide product and takes advantage of the water-soluble basic compounds in the ash to minimise reagent requirements, thereby making it suitable for small-scale implementation in close proximity to the nickel farm. In this process, nickel is precipitated from the leach solution using the basic ash wash liquor. Leaching nickel from ash generated from open air burning requires strong acid and long residence times to obtain high recoveries due to its complex nature and distribution of nickel in multiple phases. This process can be improved by optimising the ashing process with respect to nickel leachability.INTRODUCTIONHyperaccumulator plants have the unique capacity to ‘biopurify’ and concentrate certain trace elements (e.g. nickel) from the soil into their biomass (Reeves 2003; van der Ent et al., 2015). Cultivating these plants as ‘metal crops’ by periodically harvesting and incinerating their biomass generates a high-grade bio-ore (Chaney et al. 1998; Li et al. 2003). This process is called phytomining or ‘agromining’ which is an emerging technology for extracting nickel from sub-economic resources (van der Ent et al., 2015). Potential near-term applications of the technology include implementation on land ahead of processing of the underlying ore-body (Willis 2015), as a mine-site rehabilitation strategy or as an alternative crop for farmers on land that is not suitable for normal food crops. In the longer term, nickel agromining could provide a significant supplement to the nickel supply chain. Critical to the success of agromining is effective bio-ore processing. Due to the unique chemical composition of this feedstock material, existing processes are not very efficient. Our current research efforts aim to develop new process options that overcome limitations of previously trialled routes. In this paper we summarise conventional nickel process routes and proposed new options for producing agromined nickel."

Jan 1, 2016

By H. G. Warrington

Abstract As part of the active development programme pursued by Dominion Magnesium Limited since 1945, a modern extrusion plant was erected and has been in operation for about twelve months. The only source of nigh purity magnesium in the world, Canadian metal is produced by metallurgical processes within the frame-work of the mining industry, which gives a different viewpoint to every phase of production from other world suppliers of commercial grade metal whose operations are based on chemical industries and techniques. The superior properties of corrosion resistance and grain refinement have aided a programme of standardization, reducing the number of alloys supplied in extruded form from seven to four as an aid to economic production. The first big step was the development of a general purpose alloy known as AZ?21x covering all decorative and medium stressed applications, which will supersede two older alloys. Sales approaching a million feet in this alloy show that it bids fair to become the &apos;mild steel&apos; of the magnesium industry, its applications ranging from terrazzo floor strip to textile machinery and television mast components. In the high stressed field, metallurgical features preclude low-cost extrusion of the older high-strength alloys, but recent development of a magnesium alloy containing zirconium promises an easily workable metal. Hitherto produced by expensive chemical additions, research now shows that the alloy can be produced by metallurgical means, which may make this alloy available for a wide range of commercial applications. Thus the future development programme for extruded products in the form of tube, bars, shapes, and structural angles and channels may evolve two alloys to cover all applications for strengths up to 52,000 lb. per sq. in. Such standardization is the result of taking advantage of the physical and metallurgical properties of high-purity magnesium instead of accepting techniques based on metal produced by older processes.

Jan 1, 1951

By Donald Barton

THE theory of gravitation is based on Newton&apos;s law that any two bodies exert a mutual attraction which is proportional to the product of their masses and inversely proportional to the square of the distance between them; i. e., A =KRM/R2 (1) where K is a constant, M and m are the respective masses of the two bodies, and R the distance between them. In the earth&apos;s gravitational system, the earth is one of the bodies; the other may be any body within or without the earth. In theoretical dis¬cussions and calculations in regard to gravity, that other body usually is taken as a unit of mass: in the C. G. S. system, a body of one gram in mass. GRAVITY AND LEVEL SURFACES Gravity is defined in geophysics as the force of attraction exerted by the earth, towards itself, on a body of unit mass. The intensity of gravity is usually expressed in dynes of force or in centimeters of acceleration. In geophysical work in America, most commonly it is expressed in dynes (per gram) with the "per gram" understood and not directly expressed. In geophysical work in Europe, most commonly it is expressed in centimeters per second per second (cm./sec.2) and less commonly merely as centimeter-gram-second units (C. G. S.). At sea level, the intensity of gravity amounts very nearly to 980 dynes. The vertical is the direction along which the attraction of gravity is exerted at any point. . In most cases, it is very nearly, but not quite, per¬pendicular to the earth&apos;s surface. The path that would be taken by a body falling freely through space toward the earth is vertical at each point and may be spoken of also as "the vertical," or as the line of the vertical, or as a line of force of gravity. At the earth&apos;s surface it com¬monly is very nearly, but not quite, a straight line.

Jan 1, 1928

By M. G. Senyur

This study aims at investigating the structural characteristics of backfilling material. In this regard, spatial arrangement of solid particles and associated voids in a unit mass of coal mine refuse as backfilling material were tested. The materials were produced from coal mine refuse of Zonguldak Colliery, Turkey. The experimental procedures were developed to determine their void ratio (or its equivalent porosity), bulk density and the shape properties of constituent particles. The orientation fabric and the co-ordination number were the other two fabric elements determined. The filling materials were sieved and their particle size distributions were found. The results obtained by experiments were related to the particle size distribution parameters, namely, the coefficient of uniformity and the effective size. It was concluded that mean value of void ratio is correlated with coefficient of uniformity. The standard deviation of porosity as an index of fabric heterogeneity is clearly correlated to effective size. By an original experiment, the frequency distribution of coordination number was observed as binomial in uniformly graded materials. Also, the co-ordination numbers of test mixtures were calculated by the Marsal method and results obtained showed a good correlation between the minimum particle size and number of contacts per unit area.

Jan 1, 1998

By E. C. W. Perryman

BEFORE describing the methods used for fabricating uranium into various shapes and sizes it is necessary to illustrate briefly the unusual conditions under which uranium has to operate when used as a fuel element in a reactor. During reactor operation, for every fission that occurs two atoms of intensely radioactive fission products are produced together with two or three neutrons. The neutrons that are ejected possess several m.e.v. of energy and when one of them strikes an atomic nucleus, that atom acquires up to 105 e.v. of kinetic energy. This is large enough to displace the atom from its lattice position and send it shooting through the crystal, displacing other atoms out of their lattice positions. The net result is that a large number of vacancies and interstitial atoms are formed within the crystal lattice which sometimes have profound effects on the physical and mechanical properties of the material in question.

Jan 1, 1957