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Samples weighing O· 2 g are digested with 2 ml of 72 per cent perchloric acid for 2 hr at 180°C, and then diluted to 10 ml. with water. After settling, an aliquot of clear solution is reduced with ascorbic-citric acid, and then a zinc dithiol solution is added to form a coloured molybdenum complex which is extracted with petroleum spirit for comparison with standards.Concentrations down to 2 p.p.m. may be analysed at rates up to 150 determinations per day.

Jan 1, 1970

Samples weighing 0·5 g are decomposed with hydrofluoric and other acids. Most elements are extracted ftom the acid, aqueous solution by Alamine 336 (tricaprylyl tertiary amine) and thorium is determined in an aliquot taken from the aqueous phase by means of its reaction with arsenazo III. Concentrations down to 4 p.p,m. may be determined at a rate of 100 samples per man-day of 8 hr.

Jan 1, 1971

By F. K. Crundwell

The rate of dissolution of sulphide minerals is frequently interpreted in terms of the passivating behaviour of a layer of material on the surface. This interpretation has driven research to identify and possibly remove this layer from the surface, and thus yield higher rates of dissolution. The identification of such layers has proved difficult, with different researchers claiming different compositions for possible layers. An alternative framework has been pursued by the author and co-workers, who have argued that the rate of dissolution is governed by the electronic structure of the minerals which give rise to their semiconducting properties. Researchers sceptical of this approach have argued that semiconducting properties are only important in highly pure substances. In this paper, we review the electronic and semiconducting properties and discuss how they impact dissolution behaviour. These properties affect their colour and dissolution properties even though the minerals are not high purity substances. Keywords: Dissolution, leaching, passivation, semiconductor, chalcopyrite

Jan 1, 2020

By Thomas T., Read

TWO American students entered the Ecole des Mines in 1856, Joseph Lesley of Philadelphia and Thomas Egleston of New York. Lesley remained there only one year, but Egleston completed the whole 'curriculum and received, in 1860, the certificate given to foreign students .in lieu of the official appointment and degree. awarded French students. Returning home he received, in 1861, an appointment by Secretary Henry of the Smithsonian Institution to sort, label, and arrange the collections of mineralogical and geological specimens which had been brought to Washington by the various government exploring expeditions in the West. Thomas Egleston, born in New York City on Dec. 9, 1832, was the son of Thomas Jefferson Egleston, who came to New York from Massachusetts some time before 1829. The first American ancestor of the family had settled near Dorchester. in 1630. T. J. Egleston and Joseph Battell established an iron-merchandizing business* at 166 South St., New, York, which prospered exceedingly; so much so that when Thomas J. Egleston died, July 12, 1861, his estate had a book value of over $500,000. Since an older brother was expected eventually to take over this business, Thomas, who had a liking for science, went to Yale,, where he completed the regular four-year course in 1854, and then remained another year for advanced work in chemistry under Silliman. I One biographer says he went to Europe, . early in 1-856, on account of his health. It was the custom at that time for wealthy young men to make a tour of Europe after completing their academic education. Whatever the precise reason, he began scientific work at the Jardin des Plantes in Paris but soon trans* It still operating as Egleston Bros. Inc., though no direct descendants of its founder are now living.

Jan 1, 1941

By Jorgensen FRA, Moyle FJ, Turner TM

Laminar flow furnace techniques and thermal analysis were used to study the combustion of Kambalda nickel concentrate and Collie coal. The study was made to ascertain the suitability of the latter as a replacement for the fuel oil currently burnt in a flash furnace at the Kal- goorlie Nickel Smelter. The coal was found to ignite at temperatures between 500-600¦C which was the same as that required for the most reac- tive component of the concentrate, namely py- rite. The rates of reaction of both the coal and concentrate were dependent on oxygen con- centration. Sulfur dioxide hindered the combus- tion of concentrate and of coal, the effect on the concentrate being the more pronounced. The effects of moisture content and the tendency for spontaneous combustion of the coal were also noted.

Jan 1, 1982

By B. S. Hulvey

Thin support liners are becoming more accepted and being developed with improved properties because the mining industry as a whole has been offering underground safe test trial sites. This is because of the huge potential for such products. Recent developments tend to indicate that the technology is “coming of age” and these are discussed in this paper.

Jan 1, 2003

By David T. Bunney

In .December of 1987, International Mill Service, Inc. signed an exclusive licensing agreement with Tetronics Research & Development Co. Limited of Faringdon, Oxfordshire., England to commercialize plasma technology which had been demonstrated in an EAF dust processing application. The intent of the process is to reduce and volatize the zinc, lead and cadmium oxides inherent in EAF dust and collect these elements as metals in an ISP (Imperial Smelting Process) zinc splash condenser, and to render the resultant slag an inert, non-hazardous material. With these objectives in mind, IMS started commissioning facilities in 1989 at Florida Steel in Jackson, Tennessee and Nucor-Yamato Steel in Armorel, Arkansas. This paper will address the commercial development and progress of the technology at these two installations. Process Description In the EAF steelmaking process typically the off gas stream is cleaned by some form of baghouse. The particulate collected is known as Electric Arc Furnace dust and has been designated by the U.S. EPA as hazardous waste number K061, once it leaves the collection system. This designation was given to the material due to the high toxic concentrations of lead and cadmium (nickel and chromium for stainless EAF dusts) inherent in the dust. IMS' method of operation is to locate the facilities on the client mill's property adjacent to the baghouse. The dust is transported directly to IMS via a closed conveyance system. This method enables the technology to be an additional processing step in the steelmaking process. Once the dust has been transported to the IMS facility, it is fed, metered and mixed mechanically in the feed conveyance system with a carbon reductant (typically coke breeze). The carbon reductant is approximately 10% of the dust feed rate. This mixture passes through the feed system and enters the furnace

Jan 1, 1992

By Marius R. Campbell

Does mine-sampling show the commercial value of a coal, and if so, how should it be done? This question is often asked, but seldom answered. During the past summer, while engaged in securing coal for the Government coal-testing plant at St. Louis, I had an excellent opportunity to obtain information on this subject, and the results seem to furnish an answer to the questions propounded above. Sampling for the Geological Survey Coal-Testing Plant. In organizing the work of the testing-plant, it was decided that coal in car-load lots only would be accepted for testing, also that this coal should be loaded under the immediate supervision of a representative of the plant, so as to be certain that the car-load sample would be representative. As an additional check on the work, two mine-samples were to be collected from each mine visited, and these samples, as well as the sam¬ple from the car when it was received at the testing-plant, were to be carefully analyzed at the chemical laboratory, which was established in connection with the plant and operated under the direction of Prof. N. W. Lord, of the Ohio State University, Columbus, Ohio. Mine-Sanmhling:-Mine-samples were collected with great care by me and my assistants, Messrs. J. Shober Burrows, John W. Groves and Frank W. De Wolf. The dominant idea in the regulations which were adopted for mine-sampling was that it should be done in such a manner that the sample would have the same composition as the commercial output of the mine. .

Sep 1, 1905

By H. A. Guess

A Discussion of the Paper by Mr. H. A. Guess, read at the Atlantic City meeting, February, 1904. MR. JOSEPH P. GAZZAM, Germiston, Transvaal, So. Africa (communication to the Secretary*) :-About fourteen years ago, in southeastern Missouri, I used a method for the wet determination of lead which closely resembles the modified sulphate-chromate method described by Mr. Guess. The principal difference, however, is, that after dissolving the lead chromate in hydrochloric acid, the chromic acid is determined by means of a standard solution of ferrous sulphate. The method, which I believe is still in use in southeastern Missouri, was found to be convenient and accurate for the determination of lead in the ores and various products of the mills and furnaces in that district, but it was never used for complex ores. A number of determinations of lead in mill-tailings were made in the year 1891; a few of these results are given in Table I.

Mar 1, 1905

Taknar polymetal (Cu-Zn-Au-Ag-Pb) deposit and concentration flotation plant are located in the northeast of Iran. The flotation feed contains Chalcopyrite, sphalerite and pyrite with 4, 4 and 8 percent respectively. Cu and Zn contents are 1.26 and 3.5 present. Pyrite decreases the quality of base metal concentrates and increases the amount of sulfur compounds produced in the base metal extraction processes. Therefore, depression of pyrite is essential in the concentration of base metal sulfides by flotation. For flotation tests, 4 mixed collector systems, MIBC (20g/t), lime and tow depression systems (sodium cyanide (60g/t)-zinc sulphate and dextrin (300g/t)-zinc sulphate) were used as collector, frother, pH regulator and pyrite-sphalerite depressants in the chalcopyrite flotation stage, respectively, and SIPX, MIBC, lime and copper sulphate (as activator) were used in sphalerite flotation from first stage tailings. The results have shown that, sodium cyanide is a suitable depressant for pyrite and sphalerite in the first stage of flotation. Compared to dextrin as depressant, chalcopyrite recovery was decreased approximately 1.83%. In addition, when sodium cyanide was used as pyrite depressant, copper sulphate consumption raised approximately 90 g/t for activation of sphalerite. From Environment and HSE points of view, dextrin is natural, biodegradable, and non-toxic while cyanide is very high toxic. Keywords: sequential flotation, Cu-Zn massive sulphide, pyrite depressant, dextrin, cyanide

Sep 1, 2012

By Pratt V

The economic, social and political environment of the mining and minerals industries is, as we all know, volatile and affected by constantly changing international forces. In addition, the outcome of negotiations with overseas customers is often uncertain for long periods, or even unfavourable. The industries and companies represented at this Conference are in an arena of high competition, risk taking and enormous capital outlay. They are industries which our overseas markets (rightly or wrongly) have criticised for industrial relations problems, unreliable production and uncertain deliveries. They are industries which have an urgent need to be cost effective and competitive at all levels of activity.A critical factor in the mining and metallurgy industries is, therefore, its human resources and its human resource management. It requires the full use of available talent, innovation, skills and qualifications within its workforce, and the appropriate management of these resources.

Jan 1, 1985

By A. Tsekov, Stefan Neufeind, T. Angelov, G. Savov

"A complementary ion exchange/solvent extraction process for the recovery of copper from low-grade ores developed by Iontech Engineering Ltd. is described. It has successfully been implemented on a full-scale plant level at the Buchim Copper Mine in Macedonia, yielding a maximum copper cathode production of 2400 tonnes per year. Technical and economic aspects of three years of operational experience are comprehensively compared with the Asarel Medet copper plant in Bulgaria, which is utilizing conventional solvent extraction in the enrichment/purification step. INTRODUCTION The concentration and separation of copper from primary leachates is one of the key operations in the hydrometallurgical processing of oxide ores (Langner, 2011). Conventionally, this basic operation is conducted by submitting the pregnant leach solution (PLS), with a 1–5 g/L Cu content, from the initial sulfuric acid leach to a solvent-extraction (SX) process in which copper reports to the organic phase (see Figure 1). After phase separation, the metal is stripped from the extractant/diluent mixture employing sulfuric acid to furnish a concentrated metal solution, usually containing 40–50 g Cu/L. The final products of the overall process are copper cathodes, which are obtained from a terminal electrowinning step.Although considered as “technology of choice”, SX to date is still suffering from several drawbacks, such as the risk of poor phase disengagement and the high capital costs of solvent-extraction plants. Especially, the processing of leachates with lower copper tenors (< 1 g/L) is often economically less attractive. As a result, tremendous efforts have been dedicated to the evaluation of alternative technologies to address these challenges."

Jan 1, 2015

By J R. Leeming

Mining law has developed in Great Britain (GB) over centuries, mainly in response to lessons learned after disasters and other major incidents. This has led to a culture of preventing repeat accidents, rather than predicting and controlling unsafe acts or conditions.This paper explains how, initially in response to a government drive to reduce the burden on industry, the opportunity was taken to review and reform all 48 sets of GB mining-specific law into a single document. The philosophy adopted, the procedure followed and the significant changes that resulted are explained.CITATION:Leeming, J R, 2017. The complete renewal of Great Britain’s mining laws for the 21st century, in Proceedings Australian Mine Vent Conference 2017, pp 3–8 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 28, 2017

By H. D. B. Wilson, D. T. Anderson

"Canadian sulphide deposits generally have characteristic compositions. Metal associations in ore deposits and in igneous rocks are similar.Nickel: sulphur ratios, copper-nickel ratios, and nickel :cobalt ratios in copper-nickel sulphide ores are characteristic for most orebodies. Nickel, as sulphide, is highest in ores associated with ultrabasic rocks, whereas copper is highest in ores associated with gabbros. Cobalt is relatively constant. The metal ratios in copper-nickel ores are due, first, to the composition of the related igneous rock or magma; second, to the partition ratios of the metals into the sulphides when separating from the silicate rock or magma; and third, to the conditions at the time of deposition. Each factor is discussed and the evidence indicates the Frood orebody is a magmatic segregation in place and Falconbridge is an injected sulphide melt. Many Canadian orebodies containing copper, zinc, or lead also have relatively constant compositions. •Copper and zinc are concentrated in gabbro and diorite, and copper-zinc ores in northwestern Quebec are spatially related to gabbros and diorites. The same three factors con-trolling metal ratios in. copper-nickel deposits should control the metal ratios in copper-zinc deposits if the metals come from the gabbro-diorite intrusions.The ratios of base metals in common sedimentary rocks are not similar to the ratios in orebodies. Base metal elements are mobilized during high-grade metamorphism, but much fundamental research is needed before the relation between metamorphism and ore deposits can be established on a sound basis. The distribution of elements in sulphide orebodies suggests that cop-per, zinc, and lead are deposited simultaneously .in relatively constant proportions rather than successively in a paragenetic sequence. Zoning may be due to different ratios of metals being deposited under changing temperature, pressure, and chemical environment, or may be the result of other processes."

Jan 1, 1959

In an earlier paper (Stanton, 1953) a brief account was given of the geological environment and structure of the Lloyd Copper Mine orebody, Burraga, N.S.W. The present paper is concerned with the chemical and mineralogical features of the ore from this mine.Investigation has been made difficult because of inaccessibility of the workings, which have been fallen in for many years. The exact positions within the orebody of the specimens described in this paper are known in only a few cases. The specimens examined are from the collections of the Mining and Australian Museums, Sydney, and from material collected by the writer from the upper parts of the mine and from various dumps about the old workings.However, no significant variations in the nature (as distinct from grade) of the ore have been mentioned in the old reports, or by Carne (1908) or Kenny (1928), so it is likely that the specimens examined are reasonably representative of the orebody as a whole.CHEMICAL CONSTITUTIONThe ore is of simple and apparently very uniform composition.It is essentially a copper ore, with minor amounts of zinc and very minor amounts of lead. Plotting of copper against zinc shows a more or less sympathetic relationship between these at least as far as 20 per cent. copper - the highest grade assayed during the present investigation. The trend of the plots indicates a Cu/Zn ratio of about 15/1 to this point. Lead is very low and extremely sporadic, showing no clear relationships with the other metals.MINERAL COMPOSITIONThe principal non-opaque minerals are quartz and sericite, and these are accompanied by smaller quantities of muscovite, calcite and biotite. Quartz is the most abundant mineral, occurring both as a C&apos;onstituent of the country rock a quartz-sericite schist-and as veins. All quartz aggre...

Jan 1, 1955

INDEX OF CONTENTSBlast Furnace SlagsForehearth AccretionsConverter SlagsConclusionsIllustrationsCOMPOSITION OF SOME COPPER SLAGS FROM PORT KEMBLASamples of copper slags from the Port Kembla Smelter of the Electrolytic Refining and Smelting Co. of Australia, Pty. Ltd., have been submitted for mineragraphic examination, with reference to the mode of occurrence of copper in them. The samples included (I) blast furnace slags, (H) a forehearth accretion, and (IH) converter slags. 1. BLAST FURNACE SLAGS Four series of samples of blast furnace slag have been submitted. The. chemical compositions of the several slags are shown in Table 1. Analyses Nos. 1 and 2 are of samples of slowly or normally cooled slag, taken from the slag dump, Analyses Nos. 3 and 4 are of samples comprising slowly or normally cooled slag, together with granulated slag from the same melt.

Jan 1, 1949

The ores described in this paper are from the two principal orebodies at Wiseman&apos;s Creek, a small village about 22 miles south-east of Bathurst in central-western New South Wales.The first official reference to mining at Wiseman&apos;s Creek is in &quot;Mineral Statistics of New South Wales&quot; of 1875, which reported that the Wiseman&apos;s Creek Copper Mining Company had proved a lode-later known as &quot;North Wiseman&apos;s&quot;-to a depth of 120 ft., where it was found to be 20 ft. wide. By 1876 the erection of a mill and smelting works had commenced, and the sulphide ore found to contain copper lead, zinc, silver and gold. Some oxidised ore was also being worked. Operations were, however, generally unsuccessful, and sporadic work up until 1907 produced only about 5,000 tons of ore. The other more important orebody of the locality-the Phoenix-was not opened until about 1895. By 1908, as reported by J. E. Carne, the shaft had been sunk 340 ft., with the extraction of both oxidised and primary ore. At the time of the slump in copper, pric&apos;es in 1907 approximately 3,000 tons of, ore had been produced.Several smaller orebodies were discovered and worked during the same period as the North Wiseman&apos;s and Phoenix, but their output was more or less insignficant. THE OREBODIES AND THEIR GEOLOGICAL SETTINGIt is now impossible to examine the orebodies underground, but they appear to have formed a series of flat lenses, whose major axes were parallel to ,the foliation of the enclosing quartz-chlorite-muscovite schists. The largest ,of these lenses was worked as the North Wiseman&apos;s orebody, which was reported by Carne to vary in width from 1 ft. to 20 ft., and which probably extended discontinuously over a strike length of about 1,000 ft. The Phoenix orebody is stated to have varied from 1 ft. 6 in. to 3 ft. in width...

Jan 1, 1955

By Baker G

The detailed mineral composition of the lead-zinc ores at Captain&apos;s Flat was first studied in 1942 (Edwards, 1943).At that time the workings did not extend far below the 750ft. level. Since then development has been extended to the 1,390ft. level, and -at the request of the management of Lake George Mines Ltd., an examination of the ore from the deeper levels has been made as part of the research programme of the Mineragraphic Section of the Commonwealth Scientific and Industrial Research Organization.This account is. based on that examination (Mineragraphic Rept. No. ,537, C.S.I.R.O.)GENERAL GEOLOGYThe geology of the Lake George Mines has been described briefly in The Geology of Australian Ore Deposits (1953), and in much greater detail in an unpublished report by K. Glasson (1952). The area consists of fossiliferous Upper Ordovician sediments overlain by volcanics (Kohinoor VoJcanics), and by fossiliferous Silurian sediments. The volcanies comprise a series of&#183; flows ranging in&apos; composition from dacite to rhyolite, with interbedded tuft&apos;s and shale lenses.The region has been strongly folded. The regional strike is from 340&#176; to 355&#176;, and dips are from 75&#176;W. to 75&#176;E, A major syncline, pitching 200 N., occupies the centre of the area. The Kohinoor Volcanic&apos;l outcrop as two bands which represent the east and west limbs of this syncline.The Volcanks in the western limb, with whIch the orebodies are associated, are more strongly sheared than those in the eastern limb.

Jan 1, 1953

The following observations on the mineral composition of the lead-zinc ores at Captain&apos;s Flat, New South Wales, are based upon the examination of a collection of specimens made during a brief visit to the mine in January, 1942, in conjunction with earlier studies of specimens and mill products, which have &apos;been the subject of various Mineragraphic Reports, Captain&apos;s Flat is about 35 miles south of Canberra, and is connected with the main line from Goulburn to Bombala by a branch line to Bungendore, 23 miles away from the mine.The geology of the mine has been described by Kenny and Mulholland2 and by Harper.3 The country consists of Silurian sediments, which have been invaded by a composite sill of quartz-felspar-porphyry. Both sediments and sill have been folded gently, the axial lines of the folds trending north and south. In the vicinity of the orebodies the folds are steeper, and thru,st faults are associated with the anticlines. The intense compression and shearing that accompanied the faulting has converted the adjacent porphyry to schist. The Captain&apos;s Flat orebodies occur along such a zone of shearing and faulting, on the eastern limb of a steep, north-pitching anticline. At their southern end the orebodies are enclosed in the slates underlying the porphyry, but the northerly pitch of the fold carries the slate to greater depth in the northern part of the mine, where the orebody lies beween schistose porphyry on the hanging wall and massive porphyry in the footwall.THE OREBODIESThe orebodies occur along a N.-S. strike length of 4,200 ft., and from the point of view of mining, fall into three sections: the Elliot&apos;s Section to the north, the Central Section, and the Keating&apos;s Section to the south. The Keating&apos;s Section is separated from the Central Section by 500-600 ft. of mineralised ground of so low a grade as&apos; to be called barren, and is offset about 125 ft. to the &apos;east of the Central body by an oblique fault striking N.300E. Elliot&apos;s Section and the Central Section are connected by persistent veins and stringers of lead-zinc ore, but although these are...

Jan 1, 1943

The Peko copper orebody is associated with a body of magnetite rock which it has partly replaced. The primary ore averages about 9 per cent. copper and 4 dwt. gold per ton and locally IS much richer. It consists essentially of chalcopyrite and unreplaced magnetite, with lesser amounts of pyrite, marcasite, pyrrhotite, cobaltite, bismuthinite, native bismuth and native gold. The earliest formed mineral is wolfram, and the latest formed is goethite, so that the temperature of deposition ranged from about 5000 C. to 1650 C. or lower.Oxidation extends to 270 ft., which is 100 ft. below the present water level. The oxidized ore consists of cuprite and native copper, and has replaced more or less massive chalcocite of a former zone of secondary sulphide enrichment. The present zone of secondary sulphide enrichment extends from about 270 ft. to 310 ft. depth.INTRODUCTIONThe Peko mine is about 6 miles south-west of Tennant Creek township in the Northern Territory, adjacent to a small outcrop of hematite rock that projects above an otherwise featureless &quot;bull-dust&quot; fiat.The copper-gold orebody being developed in this mine did not outcrop. It was first detected in 1950 by a surface diamond-drill hole (DDH.1), which intersected primary copper ore at a depth of 400 to 425 ft. This ore contained from 4 to 11 per cent. copper and 1 to 25 dwt. gold per ton. Since then a shaft has been sunk, and crosscuts and development drives have been opened on the 210..ft., 300-ft. and 400-ft. levels, which are also connected by winzes. Two diamond drill holes sunk from the 400-ft. level have intersected theorebody at about 450 to 460 ft., and a winze from the 400-ft. level intersected the lode from 445 to 500 ft. At this point it is 54 ft. wide, and averages 9 per cent. copper. More recently an inclined surface drill hole (Peko No. 1) has cut the lode at 856 ft. to 921 ft., equivalent to a vertical depth...

Jan 1, 1955