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By Matthias Pulsfort, Jiarui Du, Torsten Wichtmann, Achim v. Blumenthal, Diethard König, Rowena Verst

The influence of the interaction between support fluid and soil, e.g., filter cake formation, on the shear stress transfer in the soil-concrete interface of diaphragm walls and bored piles is still controversially discussed. Actual research on the soil-concrete interface using bentonite suspensions indicates that shear stress transfer is underestimated by existing standards. Investigations on the soil-concrete interface using polymer solutions are rare. Therefore, complementary field investigations and systematic laboratory studies were conducted to analyse the soil-concrete interface using both bentonite suspensions and polymer solutions. Thickness and composition of real-scale filter cakes were investigated on several slurry wall construction sites, where bentonite suspensions were used. Direct shear tests (60 mm x 60 mm) were executed for soilbentonite mixtures with varying amounts of bentonite and different granular fines representing a realistic bandwidth of in-situ filter cake compositions. Larger direct shear tests (300 mm x 300 mm) with preceding horizontal penetration, subsequent vertical tremie concrete placement, and filter cake consolidation were performed using both bentonite suspensions and polymer solutions. The results support the view that shear stress transfer in the soil-concrete interface can be described by a wall friction angle in a range of 25° to 30° for bentonite suspensions and between 35° and 40° for polymer solutions in non-cohesive soils.

May 1, 2022

By Jochen Petersen

Design and operation of heap leach processes are still largely based on,operator experience and rule of thumb. Although considered a low-cost, low-tech route for mineral extraction, the underlying physical, chemical and biological processes are actually rather complex. Numerous heap leach models have been devised over time, but the majority of these tend to simplify the true process and are of limited use in practise. The modelling approach presented here combines the more conventional reaction-diffusion model with models accounting for equilibrium reactions in solution, bacterial growth kinetics, complex reactions schemes, gas flow, heat conservation, etc. One particular model application is discussed in the context of developing a novel high temperature heap leach processes using thermophile micro-organisms. The complexity of processes such as this can only be appreciated with the aid of a systematic model. For the designing engineer an accessible, personal computer based model should be an indispensable tool for the design and optimisation of efficient heap leach operations.

Jan 1, 2002

One of the important directions of further increase of quality and efficiency of control of mining companies and branches is the creation of the operation and development monitoring systems of such facilities. The main purpose of these systems is to provide managers with reliable and timely information on the current state and typical tendencies of operation of the facilities under control. However until the present time no scientific and methodical ground for system monitoring of the mining companies and branches has been created. Therefore, the authors of the report have aimed to assess the current situation with regard to the researches in this field and to do analysis of the most important aspects and ways of solution of the issue under consideration.

Dec 6, 2010

By Frank F. Rahne

Butler Taconite, operated by the Hanna Mining Company, is an Iron ore pelletizing operation that is located on the Western end of the Mesabi Iron Range in Northeastern Minnesota. The operation mines low-grade taconite ore and through primary crushing, two stage grinding, magnetic separation, agglomerating and indurating, produces 2.6 million annual tons of high quality, 66% iron pellets. Mining and stripping is done with 13 - M100 trucks and 5 - 12 cu. yd. shovels. The operating processes in the concentrator and pellet plant are primarily con¬trolled through a centralized control room and monitored by a PDP l140 computer. During 1969 and 1970, a re-organization of the Company took place. Through this re-organization, each mine unit was analyzed and studied to determine the proper staffing of the internal departments. At this time, it was decided to continue with further detailed studies of the Maintenance Department with the intent to reduce maintenance costs. Maintenance costs at the time of the re-organization were 38.6% of the total mine operating cost. The preliminary study indicated that the Maintenance Department had a system of maintenance, as a matter of fact, it had a separate system in each sub-maintenance division and in some of the sub-divisions each foreman had a system of his own. Therefore, from the data collected, it was decided to develop one system of maintenance that could be utilized throughout the entire operation. To determine the type of system suitable to all phases of the operation, detailed time and method studies were conducted. All types of maintenance tasks performed at the operation were studied. The data collected was analyzed and the recommended improved methods were reviewed with the Maintenance Superintendent and his staff. The new improved methods that were accepted as feasible, were introduced into the system immediately.

Jan 1, 1975

By Teresa Sikora

For over 40 years the Institute of Innovative Technology EMAG has specialized in the development of systems and equipment for laboratory and on-line monitoring of coal quality parameters, as well as the implementation of these systems and devices in mines and power stations. Some of these systems, based on advanced radiation detection techniques such as ?-ray backscattering (ALFA-06 and ALFA -06/T systems) or dual energy ?-ray transmission measurement (ALFA-06/2E ash meter), and also the ALFA-06/3E system applying microwave technology for the measurement of moisture, have had numerous applications in Poland. At present, over 100 systems and devices are used in Polish hard and brown coal mines. For over 10 years, EMAG has been specializing in the development of systems and devices, based on natural gamma measurement technology. An on-line ash meter, RODOS and RODOS Ex, based on measurement of natural gamma radioactivity of coal, has been developed and put into operation. This technique has been also used in developing the portable ash meter WALKER and laboratory analyzer GAMMA NATURA. The paper briefly presents features of the above-mentioned devices, their limits and their obtained accuracy, but in particular refers to the laboratory analyzer, GAMMA NATURA, as the first such device in the world, and presents the results of ash and moisture content measurement in hard, brown coals and potassium salts. The possible applications and advantages of the device in coal mines are discussed. The paper also presents the implementation results of the portable ash meter, WALKER, and the on-line ash meter, RODOS, that is used underground in coal mines.

Aug 1, 2013

By G R. Howard, G Back

Management of information systems for data collection is essential to maintain data integrity and continuity, and manage loss control on a large world-class mine such as Telfer Gold Mine. This paper aims to describe the individual systems and protocols of geological data capture at Telfer, then focus on Quality Assurance Quality Control data as an example of loss control in practice. Loss control systems are required to provide capacity, flexibility, structure and management tools to enhance data interrogation. The data that have been collected can then provide geological, financial, environmental, and contractual information to optimise management of business best practice. Telfer Gold Mine is a wholly owned and operated subsidiary of Newcrest Mining Limited. The mine is located in a remote area of NW Western Australia, and has been operating for 20 years. Geological data have been collected at Telfer since 1973. The data include drilling, assay, geological, survey, structural and geophysical data. Data management has evolved through many systems with data stored on many different hardware and software platforms. Commencing in 1995, collation, standardisation and validation of the historic data was completed. This has resulted in the first Access based drill hole database incorporating all available drilling data. This drill hole database, now hosted in SQL Server, is the hub for all geology related data management systems. The Telfer Gold Mine Geology Department has developed a series of inter-related database systems in order to manage the core geology business issues. Databases relating to drill hole planning, drill contract management, geological logging, accounting (standard costing, forecasting, invoice reconciliation), quality control (QAQC), and environment rehabilitation have all been developed to manage loss control. Management effort to provide adequate data systems and protocols has driven the system from concept to utilisation. The improved productivity, data integrity and data analysis capabilities provided by the new database systems at Telfer have allowed for greater confidence in decision making. Systems such as the drill hole and QAQC databases, when utilised in the proper manner provide up-to-date data analysis for resource audits and contract negotiations. The loss control systems are essential to maintain confidence in data integrity and hence directly effect the future of mining at Telfer.

Jan 1, 2000

By Donald E. Scheck

Blasting practices based on sound engineering principles are well established but the successful application of these practices requires accurate information about the overburden geology and close supervision of the drilling and blasting operations. Good design alone is not sufficient to insure good results, but the process may be difficult to control unless steps are taken to measure the variables and to provide management and the operators with the information they need to establish and maintain control. Satisfactory blasting can be defined as loosening and fragmenting the rock so that it can be handled by the excavating equipment, while at the same time, governmental regulations on air blast and ground vibrations are not violated. Optimum practices achieve these objectives at the lowest combined cost of the drilling and loading operations and the blasting materials. Total system optimization, that is, taking into consideration the effect of fragmentation on the cost of operating and maintaining excavating equipment as well as drilling and blasting costs, probably is not a reasonable goal at the present time.

Jan 1, 1984

By R. Mishra

The validity of the concept of mine resistance in ventilation systems is examined. Mine resistance is the proportionality constant relating the head generated by a fan and the quantity flowing through it when the fan is connected to a mine circuit. It is the total effect of all branches in the mine ventilation circuit. Its importance lies in the fact that for new mine projections, and in the extensions of existing mines, ventilation calculations are usually based upon adjustments of the mine resistance. In ventilation circuits with regulation, and/or with multi-fans, simple adjustments of the mine resistance curve do not lead to correct solutions. A ventilation system consists of several interconnected subsystems where one subsystem behavior affects that of the others, and the total system. Through a series of simple but realistic examples, the authors will demonstrate the importance of the systems concept in mine ventilation, and its practical application to coal mine ventilation planning.

Jan 1, 1977

By Bahadir Ergener, Angel Maria Tobar Escudero, Sandra Nowosad

Modern mining companies are increasingly turning to integrate digital technologies and circular economy (CE) principles to increase the sustainability of their operations. The so-called “mine of the future” is envisioned as a smart, integrated system where technologies such as automation, artificial intelligence, digital twins, and real-time data analytics work in harmony with human decision-making and environmental responsibility. Already in 2018, McKinsey and Co. identified that the three drivers that would define a technology-enabled change in mining would be technology, including digital, analytics and automation, management systems able to identify the potential and value of the new technologies, and the culture and capabilities of the organisation, leaning to more agile and responsive organisations. From the three drivers, in the last five years most developments have been centred in the first one. Yet despite rapid advances, the adoption of new technologies across the industry today remains uneven and often slower than expected. Furthermore, it has been identified that the problem on the technology uptake often relay on the lack of operational readiness, process incompatibility or misalignment, and resistance to change within the mining operation. At the same time, leading companies like Rio Tinto, BHP, and Anglo American have each launched major digital transformation programs. Rio Tinto, for instance, operates one of the world’s largest autonomous mining fleets and has integrated digital technologies across nearly all its operations (Rio Tinto, 2025). BHP is actively investing in information and communication technology (ICT) development as artificial intelligence, big data analytics and robotics, and has partnered with battery companies to pursue circular economy initiatives. Only in 2024, their ICT spending reached US$ 438.3 million (Global Data, 2024). Anglo American has rolled out its FutureSmart Mining™ framework, explicitly aligning innovation with circularity and sustainability goals (Anglo American, 2025). The accelerating pace of change across leading mining companies along with the uneven adoption in the technology uptake clearly state how digital transformation is no longer just about implementing new tools, instead it requires a fundamental shift in how people, processes, and culture are aligned. Addressing only the technical layer, while neglecting the human and organizational dimensions, leaves transformation efforts fragile and unsustainable. As the industry must act decisively to close this gap, the true test of transformation is today centred in changing behaviours, mindsets, and systems. Even at the listed leading companies, initiatives have encountered cultural and structural resistance that are relatable to the industry in large: siloed departments fail to collaborate, procurement teams focus on upfront costs rather than lifecycle value, and operators are often excluded from early-stage planning, reducing buy-in. In many cases, a lack of communication or failure to link technology to real operational bottlenecks leads to disengagement at the ground level. This friction reveals a broader issue: mining organizations have historically treated technology and culture as separate domains, when in fact they are deeply interdependent. To address this, the authors propose a systems engineering approach focusing on the mining operations as a complex socio-technical system composed of people, processes, and technologies. Systems engineering offers tools and frameworks for mapping interactions, aligning incentives, designing for feedback and adaptation, and integrating change across organizational boundaries. Specifically, besides technical requirements, it demands treating culture not as an afterthought or side-effect, but as a design variable that must be intentionally shaped alongside infrastructure and workflows. This paper explores how this approach can be applied in practice, by analysing a real-world case scenario where resistance to innovation was overcome not by technical capabilities alone, but through alignment of stakeholder incentives, thoughtful communication, and cultural integration. A particular focus is set on the adoption journey of the Powerbit X, a drill bit technology with significant potential for operational and environmental gains.

Feb 22, 2026

By M. C. Holton

South Africa has the world?s largest in situ deposits of platinum group metals, but economically exploitable resources are shrinking due to escalating costs and technical challenges. The South African National Research and Development Strategy comments that an increase in the knowledge intensity of the resource-based sectors is required to turn these resources to account. Highly trained human resources, continuous improvement, technological innovation, and smart acquisition of know-how will become the major differentiators in the global mining market. Mechanization and, ultimately, automation in mining have the potential to reverse the negative mining trend and resolve safety and other challenges. However, the adoption rate of mechanized mining in platinum (and hard-rock gold) has been slow for various reasons. Changing systems from conventional drill?and-blast to continuous mechanized mining is a big step-change endeavour. The problem of transformation is discussed, and the discipline of systems engineering is examined because of its successful application in aerospace and defence.

Jan 1, 2012

By Thomas Zukovich, Robert Morhard, Thomas Gelormino

The ExploTrack Explosives Tracking System is a sophisticated integration platform designed to track explosive products in both fixed locations and mobile environments globally, in real-time, on a 24/7 basis. The system utilizes active and passive RFID (Radio Frequency Identification Devices) installed within or applied upon explosives materials and explosives articles and incorporated within explosives packaging and logistic transport mechanisms. The system is designed for real-time inventory on an enterprise level and also across the globe providing explosives tracking, monitoring and explosives security from manufacturing throughout the logistics supply chain through use. The system can also track and monitor all known persons coming into contact with RFID enabled explosives materials and articles at the production level, at the magazine level, at the logistics level and to final use enabling a complete and real-time auditable chain-of-custody.

Jan 1, 2007

By C Hedemann, N Silveste, H Davis, C J. Moran

For nearly two decades water scientists have been debating the need to use appropriate models for the questions being asked and the data available. This paper puts forward a rationale for a hierarchical framework for water balance modelling as it applies to mine sites. The hierarchy is based on the complexity of models and their data requirements. Scientific models are the most complex and require the most data; next is engineering models, then systems models and the simplest representations are given by conceptual models. A position is put forward that systems models have a range of uses that the others do not provide. A systems model, called SiteMiser, is described and its calibration illustrated. The model is applied to seven coal mines from the Northern Bowen Basin in Central Queensland. Currently, there is little relationship between total water use and coal production. This relationship is not any stronger when fresh (raw) water is compared to reused water. Leading practice water use levels are simulated for all sites. The simulation results demonstrate that there is considerable opportunity to reduce water consumption and, in particular, to import less fresh (raw) water to the sites.

Jan 1, 2006

By Stanislaw Trenczek

Natural hazards such as rock bumps, methane, coal dust explosions, airborne respirable dust, outbursts of gas and rocks, water, radiation caused by natural radioactive materials, spontaneous fires, and climatic hazards, occurring in the Polish hard coal mines, should be controlled. These hazards are characterized by different scale levels numbered from 2?5. To recognize the amount and levels of hazards, research works were carried out in 109 mining districts of mines belonging to Jastrzebska Spólka Weglowa, Katowicki Holding Weglowy and Kompania Weglowa. These are 86 % of all mines and could be regarded as representative of the majority of Polish mining. The hazards have been classified as regards the frequency of their occurrence as: commonly occurring ? with a frequency of 100 % (like airborne respirable dust and fire hazards), high occurrence frequency ? frequency from 60 to below 100 % (methane hazard ? 83.5 %, coal dust explosion hazard ? 92.0 %, and water hazard ? 99.1 %), medium occurrence frequency ? from 30 to below 60 % (rock-bump hazard ? 52.3 % and climatic hazards ? 51.4 %), and episodic occurrence frequency ? below 30 % (outburst of gas and rocks and radioactive hazards). The dynamics of effects of growth in hazard levels to their intolerable values is diverse. Some of them are passive in nature, which allows for longer observation of changes and appropriate early response (as for climatic and spontaneous fire hazards). However the majority of them take on the character of disasters, like methane or coal dust explosions and damage of the excavation structure ? as occurs after a rock-bump or rock outburst; and creation of an atmosphere unfit for breathing ? during open or spontaneous fires, or after gas outbursts containing methane. There are also latent hazards whose effects do not influence indeed a process of production; however they are detrimental to health when a worker is exposed for a long time to airborne respirable dust and radiation. For other types of hazards a level of danger may be only estimated. Since the systems monitoring allows a wider range of control, therefore, aside from rock-bump and methane hazards, there are monitored also fire hazards including measurements of other air parameters (velocity, pressure, humidity, temperature, O2, CO2 concentration). A few types of monitoring systems are used in Polish mines, like the monitoring systems for environmental parameters such as SMP-NT, SMP-NT/A, the telemetric systems CST-40, CST/A, including the computer-aided system for methanometry control officer SWµP, the computer-aided measuring systems KSP-1, KSP-2, KSP-2C, or the production and safety control system VENTURON. The underground part of the systems monitoring of natural hazards contains measuring devices and equipment for automatic control (power-off) of machines and electric devices in case of increased methane hazard. The surface part of the monitoring system allows the measuring data to be visualized and pre-alarm (warning) and alarm states to be displayed. Furthermore it makes it possible to archive and report the data and to control the underground supply and signalling devices. The EMAG Institute developed monitoring methods to extend a measuring range of monitored parameters (such as methane and fire hazards) as well as to monitor so far unmonitored hazards like dust hazards (by continuous monitoring of dust levels in mine air) and climatic hazards (by online monitoring climatic parameters of mine air).

Aug 1, 2013

By K. M. Li, Y. D. Zhang

The selection of stripping dragline is a complicated problem. Several factors, such as the deposit buried conditions, the demand of mine production rate, cast blasting result, the mining/stripping operation method and parameters, etc. may comprehensively influence the optimal selection of technical specifications of the dragline. Under these circumstances, the basic thinking and procedures for dragline selection are put forward as follows. •Step 1—Initially estimate the dragline annual stripping rate and stripping bench height according to the annual coal production rate and advancing speed of mining front. Then the feasible alternatives of dragline sizes can be calculated and selected from the existing dragline series. •Step 2—A computer simulation model is developed to simulate the dragline stripping operation, to obtain a series of working face parameters, then to select the best dragline alternative. This step can be interactively iterated until the satisfactory results are obtained. •Step 3— Sensitivity analysis can be done with the systems simulation model by changing the stripping bench parameters, e.g. stripping bench height and cut width, etc. to verify and modify the selection results if necessary. The mathematical model for dragline stripping simulation has been set up. The flowchart of the model is shown. A case study for a large surface coal mine with annual production rate of 16 Mt/a is followed. The dragline bucket capacity and operation radius, stripping bench height and cut width as well as other parameters are comprehensively optimized and selected. Keywords: Open cast, dragline, specification, selection, cast blasting

Jan 1, 2003

By Brian Clifford

A wide range of different cablebolt systems are available and in use in hard rock and coal mines around the world. The birdcaged cablebolt was initially used in UK coal mines in conjunction with rockbolts in the late 1980's. More recently other cablebolt configurations have been used. Innovations in cablebolt design in the UK have been driven by a demand to find a system as effective as the birdcaged cable, but which can be installed more rapidly and offer immediate support. A laboratory short encapsulation pull test (LSEPT) has been developed for both rockbolt and tendon systems which measures bond strength and stiffness in rock and assesses the full range of potential failure modes. This test is now used along with conventional 'gun barrel' and shear tests to provide full assessment of bolt and tendon performance. This test may be incorporated into a new performance based British Standard for rockbolts and long tendon systems. This paper describes the performance of some of these systems as being applied to UK and South African coal mines.

Jan 1, 2001

By A. Coulombe

"RésuméL’analyse des séquences d’exploitation, actuellement en usage pour les gisements très inclinés, a démontré qu’elles ne sont pas toujours optimales du point de vue du contrôle des terrains et de la concentration des travaux d’abattage (nombre de chantiers simultanément en opération). Effectivement plusieurs séquences sont très propices à la création des nombreuses zones de hautes contraintes, qui sont à l’origine des effets de pilier. L’étude de cas de la mine Lac Shortt a démontré que certaines séquences d’exploitation, actuellement en usage, ne sont surtout pas adéquates dans le cas d’un état élevé des contraintes naturelles. En effet la mine a eu de sérieuses problèmes avec le contrôle des terrains (coups de terrains et les effondrements des épontes). Ces effondrements étaient responsables de la dilution excessive et des pertes importantes des réserves minières. Les deux nouvelles séquences proposées, visent la meilleure redistribution des contraintes d’exploitation en vue d’éliminer la création des effets de pilier. En plus elles permettent une concentration plus élevée des travaux d’abattage.À notre avis les séquences proposées pourraient améliorer substantiellement la stabilité des chantiers d’abattage et par la suite les performances technique et économique des opérations souterraines. ABSTRACTThe planning of underground mining sequences represents an important aspect of the mining operation. The analysis of mining sequences actually in use for very steep orebodies has demonstrated that they are not always optimal, considering ground control and the number of stopes simultaneously in extraction. These sequences are conducive to the creation in the rockmass of several stressed zones caused by pillar effects. The case study of Lac Shortt mine showed that the sequences of exploitation currently in use are not adequate especially in the case of a high state of the natural constraints. Indeed, the mine had serious problems with ground control (rock bursts and collapse of walls). These collapses were responsible for excessive dilution and significant losses of mining reserves. The two new sequences suggested aim for the best redistribution of exploitation constraints in order to eliminate creation of pillar effects. Moreover, they allow a higher number of stopes to be extracted simultaneously. In the opinion of the authors, the sequences suggested could substantially improve the stability of working areas and, thereafter, technical and economical performances of the underground operations."

Jan 1, 1998

"El presente texto señala las formas en que se presenta el sílice libre y las principales rocas constituyentes del material generador de la silicosis. En ese sentido, el ""sílice libre"" se presenta a través de tres formas: cristalizada, criptocristalina y amoría. Sus diversas variedades en forma de cuarzo son el cristal de roca, el cuarzo amatista, cuarzo rosado, amarillo, ahumado, lechoso, ferruginoso, etc. De otro lado, la presencia del cuarzo en las rocas ígneas sirve de base para su clasificación en ácidas, intermedias, básicas y ultrabásicas. Las rocas ácidas son las que contienen más de 10% de cuarzo, las intermedias menos de 10% de cuarzo y las básicas y ultrabásicas, carecen de este mineral en su esencia. Asimismo para determinar el grado de peligrosidad del polvo es necesario revisar la concentración de partículas de polvo, a través de una muestra y cuenta de los mismos. El muestreo se basa siguiendo diferentes técnicas basadas en principios fiísicos como filtración, estrellamiento, precipitación electrostática y térmica. Mientras que la cuenta de partículas se efectúa mediante un microscopio provisto de un sistema óptico standarizado y diferentes tipos de celdas (Dunn, hemacitómetro y la celda Hatch). Cabe aclarar que no es posible la comparación de peligrosidad de dos polvos, basándonos solo en el componenente sílice, sino que el tamaño de las partículas y la concentración en el ambiente, son factores a considerar para su evaluación. Entre los métodos importantes de determinación cuantitativa de sílice libre tenemos: químicos y físicos. Los primeros, utilizan la descomposición de todos los componentes de la muestra -con excepción del sílice libre-a través de un tratamiento ácido, mientras que los segundos son más precisos respecto de los polvos industriales y se realizan a través de análisis petrográfico, difracción de rayos y el método de fusión. Posteriormente, la Asociación Americana de Higienistas industriales revisa los datos encontrados en África del Sur, Australia, Inglaterra y Estados Unidos, y hace un esbozo sobre los límites de tolerancia permisibles de polvo, revelando que el polvo contenido con más de- 50% de SiO2 es equivalente a 5 MPPPC, los que tienen de 5 a 50% de SiO2 tienen 20 MPPPC, y aquellos que contienen hasta 5% deSiO2 equivale a 50 MPPPC, a diferencia de otros métodos propuestos."

Jul 20, 1957

By Rubens Lincoln Santana Blazutti Marçal

O objetivo deste trabalho foi avaliar o comportamento do niobato de alumínio (AlNbO4) como aditivo na sinterização de alumina (Al2O3). O composto AlNbO4 foi sintetizado através de reação no estado sólido dos compostos Al2O3 (0,5 Mol) e Nb2O5 (0,5 Mol). A técnica de difração de raios X foi utilizada para comprovar o sucesso da síntese. Para o estudo da sinterização, o composto sintetizado (AlNbO4) foi adicionado à alumina nas concentrações de 0, 1, 2 e 3 % em peso e prensados unixialmente à 60MPa. A sinterização foi conduzida à 1400 ºC. Os corpos sinterizados foram caracterizados quanto a densificação, pelo método de Arquimedes, e microdureza superficial Vickers. Os resultados demonstraram clara influência do composto AlNbO4 na sinterização da alumina elevando os valores de densificação e microdureza quando comparados à alumina sem adição.

Oct 30, 2017

By Felipe Sombra dos Santos

Este trabalho tem por objetivo principal sintetizar e caracterizar nanopartículas de ferro de valência zero (nFVZ) para degradação de substâncias recalcitrantes, através de Processos Oxidativos Avançados. A primeira etapa consiste na sintetização nFVZ, através da reação utilizando reagentes ferrosos, com o agente redutor borohidreto de sódio, em condições controladas (pH, temperatura e velocidade de agitação do sistema). Agentes complexantes e dispersantes, como o ácido cítrico e o etilenoglicol, respectivamente, foram utilizados durante a sinterização para avaliar a variação da formação do tamanho das partículas obtidas. A caracterização foi realizada através dos ensaios de distribuição de tamanho de partículas, microscopia óptica interfacial e microscopia eletrônica de transmissão (MET). Foi observado que a concentração de ácido cítrico de 0,009 mols e o volume de 100 mL de etilenoglicol, mostraram-se como os melhores valores obtidos. Todavia o ácido se tornou um interferente na reação ao ser utilizado com o SDS. Os resultados da microscopia eletrônica de transmissão comprovam que as partículas obtidas estão na escala nanométrica.

Aug 16, 2017

By Camila Ferreira da Silva

O presente trabalho descreve a síntese de um vidro de constituição inovadora, elaborado com adição de escória de distribuidor em sua composição. Suas propriedades ópticas foram determinadas através da realização da caracterização elipsométrica. Em virtude da vasta gama de composições vítreas possíveis e visando o reaproveitamento de um coproduto siderúrgico, propõe-se a utilização de escória de distribuidor para a composição de um novo vidro. Efetuou-se a análise superficial via microscopia confocal. Posteriormente ao preparo da superfície, as propriedades ópticas foram obtidas através da medida dos parâmetros elipsométricos tan(?), cos(?) e por conseguinte a obtenção preliminar do índice de refração e do coeficiente de extinção.

Oct 30, 2017