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By Lucas Sanches Magalhães

A utilização de resíduos industriais é dificultada, na maioria das vezes, pela presença de determinados elementos, como por exemplo, o ferro, justificando assim a sua remoção. Dentro deste contexto, o objetivo deste trabalho foi estudar a sulfatação de um resíduo proveniente da flotação de um minério de ferro e subsequente lixiviação deste resíduo sulfatado. A composição mineralógica da amostra inicial foi obtida por DRX e MEV sendo possível identificar quartzo (SiO2), hematita (Fe2O3) e muscovita (KAl2Si3AlO10(OH,F)2). De acordo com a análise química, os teores dos elementos principais foram: Fe (12,65%), S (4,02%), e Al (0,62%). Na sulfatação, realizada à 250ºC durante 4 horas, foi estudada a influência da relação ácido sulfúrico/amostra (0,1:1; 0,2:1; 0,7:1; 0,8:1; 0,9:1 e 1:1) na extração do ferro. A lixiviação foi conduzida com 5% de sólidos do material sulfatado, sendo avaliada a interferência da temperatura de lixiviação (25°C e 90°C) e do tempo de duração dos ensaios (15min, 30min, 60min, 120min, 180min e 240min). Pelos resultados obtidos observou-se que o tempo de lixiviação foi um parâmetro insignificante. A máxima extração de ferro foi encontrada sulfatando o resíduo na relação ácido/amostra 1:1 e posteriormente realizando a lixiviação deste resíduo sulfatado a 90°C por 30 minutos, alcançando 85,64% de extração do Fe.

Aug 17, 2017

By J. Wagner, P. Eger

Although lifetime estimates for sulfate reduction based on total substrate carbon typically range from 20 to 30 years, field and laboratory experiments showed that rates of sulfate reduction decreased over time as readily available organic material was consumed. When the rate of acid input exceeded the rate of sulfate reduction, alkalinity was removed from the substrate, pH decreased and metals increased. Output pH increased from 4 to over 6 after the system was shut down for several weeks and the rate of acid input was reduced. Successful long term treatment requires a design based on the input pH and the long-term organic decomposition rate.

Jan 1, 2001

By Tracey Bodnarchuk, Philipp Mirzoev

Sulfate balance control is a common problem for zinc plants. Roast-leach-electrowin plants are mostly concerned with the over-generation of sulfates while for the HudBay direct leach plant both extremes are possible including potential necessity to buy sulfuric acid to replenish a sulfate-depleted circuit, which makes the problem doubly important. Quantitative methods were applied at the HudBay plant to analyze sulfate generation/depletion based on a local sulfur balance and sulfate extraction calculation in the leach circuit, using a Pb-tie method. Main factors were established influencing sulfate generation/depletion, including the critical role of Pb and pyrite. Regression analysis proved to be effective and allowed the quantitative prediction of Pb concentrations necessary to reach the equilibrium for the sulfate balance. This in turn provided a firm basis for a sulfate-control strategy realized through concentrate blend correction, which allowed the plant to fine-tune sulfate generation/depletion effectively reducing economic consequences of excessive/deficient sulfate generation.

Jan 1, 2015

By A. H. Kaksonen

Numerous reactor designs for biological sulfate reduction have been reported. Fluidized-bed bioreactors (FBR) can efficiently retain biomass and allow high mass transfer and reaction rates. This work reviews the development of various sulfate-reducing FBR processes for treating acidic metal- and sulfate-containing waters and recovering metals from bioleaching liquors. The FBR process performance was evaluated with continuous flow experiments under various operational conditions: fluidization rates, influent pH values, metal, sulfate and salt concentrations, hydraulic retention times, electron and carbon sources, and temperatures. Substrate utilization and sulfide inhibition kinetics were determined with batch FBR-kinetic experiments. An artificial neural network (ANN) model was used to predict the performance of the FBR. Sulfate-reducing bacteria (SRB) were characterized in FBRs with molecular and culture-based approaches with the aim to gain a better understating of the bioprocesses. Based on the studies, FBRs are well suited for the combined removal of metals, acidity and sulfate from water.

Jan 1, 2010

By Steve Lloyd, Ryan J. Foy, Brandon Steinborn, Jerome P. Downey

Research was performed to evaluate copper and silver extraction from samples of bornite flotation concentrate. Sulfation roasting experiments were performed in a rotary tube furnace, a fluidized bed reactor, and a static bed muffle furnace. Roasting was plagued with rapid, lowtemperature calcine sintering, apparently related to the presence of organic matter in the concentrate. Calcine entered a weak acid leaching process to remove copper, and silver was extracted from the weak acid leach residue in a ferric chloride and hydrochloric acid solution. Copper extraction efficiencies in excess of 90% were attained in the weak acid leach while 90% silver extraction was achieved in the ferric chloride leach, along with copper and lead extractions as high as 93% and 99% respectively. The two-stage leaching process resulted in overall extraction efficiencies of 99% copper and 90% silver.

Jan 1, 2015

By F. H. A. Abdalla

A process is described for the recovery of valuable nonferrous metals from steelmaking dust by suiphatizing roasting using ammonium sulphate. Maximum recoveries of soluble metal sulphates achieved at optimum conditions were> 99.0 %. Selective metal separation of the soluble sulphates in the leached liquors were performed either by controlling the roasting temperature or by adjustment the pH values of the leached liquor ranging from 3.6-6.2. Either pure zinc oxide orland tin oxide could be obtained at optimum conditions, and the products were evaluated chemically and by X-ray analyses. The residues rich in iron oxide can be removed and recycled. The mechanism of sulphatizing roasting process was considered. A general flow-sheet for the overall process of treatment the steel making dust to recover its valuable nonferrous metals was suggested, which ca be applied for other nonferrous bearing materials.

Jan 1, 1996

By R. Padilla

The reaction of chalcopyrite with gaseous sulfur has been investigated in the range 350-450 °C in order to transform this mineral into a more acid soluble copper sulfide and insoluble iron sulfide. The results of thermodynamic analysis of this system as well as the X-ray diffraction analysis of the reaction products showed that in the temperature range 350 400°C the sulfidation reaction proceeded without formation of intermediate copper-iron sulfides according to: The effects of temperature and time on the conversion of chalcopyrite were studied. Conversion of chalcopyrite reached about 80% very rapidly with increase in temperature up to about 400°C. The recovery of copper from the sulfidized samples was determined by leaching in oxygenated 1.2M H2S04, 2M NaCI solution. Copper recoveries over 90 % were obtained from samples sulfidized for 30 min at temperatures lower than 400°C.

Jan 1, 2001

By Omar A. Muhtadi

Brohm Mining Corporation, in conjunction with Geobiotics, Inc. has nearly completed a pilot heap biooxidation test on sulfidic ore from the Gilt Edge Mine near Rapid City, South Dakota. Some results from the pilot testing have shown the correlation between the extent of biooxidation and the increase in cyanide gold recovery seen in the laboratory. Bench scale testing showed approximately a 1: 1 correspondence between percent biooxidation and percentage increase in gold recovery. The economics of large scale biooxidation were also evaluated in terms of increased gold recovery versus the time and cost of biooxidation. In the pilot test, the rate of biooxidation became limited by the acid water neutralization system. Later in the test, measures were taken to overcome this problem. Results from bench scale column bioleach testing showed that the Gilt Edge sulfide ore is quite amenable to biooxidation with a substantial increase in gold recovery with just partial biooxidation. Direct cyanide gold recovery of 51 % on ore crushed to -3/8" was enhanced to 82-85% after oxidation of37% of the sulfide as measured by iron. Laboratory experiments also showed that the slow rate of biooxidation of this ore could be accelerated by removal of metal sulfate build up from the leach liquor. The combination of these normally non-toxic metals became inhibitory to biooxidation if not removed by the neutralization circuit.

Jan 1, 1995

By John W. Shield

Oxide gold reserves are being rapidly depleted, especially in regions with long histories of gold mining, such as the Black Hills of South Dakota. However, these districts often have substantial additional deposits, where gold is refractory. It is not amenable to traditional cyanide extraction due to the presence of sulfide minerals that encapsulate or otherwise preclude the economic extraction of the gold. Several technologies have been developed to render refractory sulfide deposits amenable to traditional cyanide processing. These include roasting and pressure autoclaving. Unfortunately, these oxidation processes require substantial capital investment and incur significant operating costs. Microorganisms that obtain energy for their life processes by the oxidation of iron sulfides can be used to treat gold-bearing refractory sulfide minerals. As the bacteria convert the sulfide to sulfate, they expose any gold associated with the sulfide matrix. This makes the gold amenable to cyanide extraction.

Jan 1, 1996

Changes in mining technology have led to an increase in the number of underground sulfide dust explosions reported in Australian and overseas mines. Samples collected at the Elura mine consisting primarily of pyrite, pyrrhotite, arsenopyrite, sphalerite and galena, were tested in 8 litre explosion chamber. The dusts were found to be capable of producing dangerous dust explosions with maximum explosion pressures of 440 kPa and rates of pressure rise of 5200 kPa/s. The hazards of a sulfide dust explosion are associated with the pressure wave and flame front of the explosion and the toxic gases remaining after the explosion.

Jan 1, 1984

By Grano S. R, Kilgariff B

The Renisun Tin concentrator treats an ore containing I's per cent till as cassiterite and 22 per cent sulphur in a range of sulphide minerals. predominantly pyrrhotite. The sulphide minerals are removed by flotation using copper sulphate (CuS

Jan 1, 1997

By D. S. Kimbal

The McCoy/Cove mine is located 48 km (30 miles) south of Battle Mountain, Nevada, USA, in the Fish Creek Mountains at an elevation of 1548 m (5080 ft), see Figure 1. Joseph H. McCoy first discovered gold at this location in 1914. This discovery led to the Gold Dome Mine which produced the first gold from this area in 1928. After the Gold Dome era, the land remained relatively dormant until Houston oil and Minerals Corporation purchased the claims from the Summa corporation and defined an ore body at the present day McCoy pit. In 1986 Tenneco Minerals (formerly Houston oil and Minerals corporation), sold the McCoy mine and adjoining claims to Echo Bay Minerals corporation. The Cove ore body was discovered soon after the sale to Echo Bay. Echo Bay expanded the heap leach operation and built the present mill which began processing ore in the fall of 1989.

Jan 1, 1993

By Volker Vogt, Wolfgang Sand, Eberhard Gock

"It was discovered that the selective activity of bacteria during the extraction of raw material concentrates by means of flotation could also be achieved with extracellular polymeric substances (EPS) excreted by bacteria. EPS, which is extracted by means of centrifuging bacterial cultures, can help to significantly reduce the use of cyanides, approximately 200,000 t/a of which are used for ore dressing today.The bacterium used was Acidithiobacillus ferrooxidans. In order to identify the bandwidth of the oxidation activity, 20 bacterial strains of the strain collection of the University of Hamburg were attracted to iron(II) sulfate and pyrite under defined conditions. All strains oxidized iron(II) sulfate ten times faster than pyrite.EPS has so far been derived from four strains. In general, EPS extracts are divided into a hydrophilic and a hydrophobic fraction. The hydrophilic fraction is composed of e.g. fucose, rhamnose and glucose; fatty acids such as dodecanoic acid, hexadecanoic acid, octadecanoic acid and nonadecanoic acid were found in the hydrophobic fraction.Pure mineral phases and mineral mixtures were used for the flotation tests. As opposed to current knowledge, the results were reproducible with technical flotation machines."

Jan 1, 2003

By Volker Vogt, Wolfgang Sand, Eberhard Gock

"For about 20 years, the use of bacteria to control the flotation process for the production of raw material concentrates has been the subject of worldwide scientific and engineering efforts. The objective is to reduce the consumption of biologically non-degradable toxic reagents. The principle idea is to use the activity of bacteria in natural leaching processes – known since the middle of the last century – for controlling flotation processes.It was discovered that the selective activity of bacteria during the extraction of raw material concentrates by means of flotation could also be achieved with extracellular polymeric substances (EPS), excreted by bacteria. EPS, which is extracted by means of centrifuging bacterial cultures, can help to significantly reduce the use of cyanides, approximately 200,000 t/a are used for ore dressing today.The bacterium used was Acidithiobacillus ferrooxidans. In order to identify the bandwidth of the oxidation activity, 21 bacterial strains of the strain collection of the University of Hamburg were attracted to iron(II) sulfate and pyrite under defined conditions. All strains oxidized iron(II) sulfate ten times faster than pyrite.EPS has so far been derived from four strains. In general, EPS extracts are divided into a hydrophilic and a hydrophobic fraction. The hydrophilic fraction is composed of e.g. fucose, rhamnose and glucose; fatty acids such as dodecanoic acid, hexadecanoic acid, octadecanoic acid and nonadecanoic acid were found in the hydrophobic fraction. Pure mineral phases and mineral mixtures were used for the flotation tests. The outcome was reproducible results with technical flotation machines. The research results known so far are mainly based on investigations with micro flotation devices, which are usually used for the characterization of reagents and which do not allow a direct translation to the technical scale."

Jan 1, 2003

By Richard W. Hutchinson, Christopher Osterman

Abstract -The Selebi-Phikwe deposits are hosted by amphibolite to granulite facies gneisses of the Limpopo belt. The sulfide orebodies are generally stratiform and conformable to the foliation of the wallrock gneiss. Sulfide remobilization has occurred during metamorphism and has produced discordant sulfide veins, called piercement structures, which project into the hanging wall and foot­ wall gneisses. These piercement structures are compositionally similar to the stratiform sulfides, consisting mainly of pyrrhotite, pentlandite and chalcopyrite. However, texturally the piercement sulfides are coarse grained and inclusion-free, whereas the stratiform sulfides are fine grained and packed with tectonically produced wallrock inclusions. The piercement structure sulfides and adjacent stratabound sulfides were sampled and analyzed for major base metals and PGE's for comparative purposes. Most of the piercement structures were enriched in Cu, Ag and Au, whereas they were generally depleted in Ni, Co, Fe and PGE's. Changing elemental associations were observed from the stratabound sulfides and along the length of the piercement structures. This and the degree of depletion or enrichment of various major and minor elements in the sulfide piercement structures may reflect the relative mobilities of metals under metamorphic conditions. The similarities between sulfide piercement structures and the footwall Cu-POE veins in some Sudbury deposits are reviewed.

Jan 1, 1994

By Alvear G. R. F. Flores

It is now 35 years since the organization of the first sulfide smelting conference in 1983. Since then, the smelting base metals industry has experienced several changes driven by the necessity to improve economic, operational and environmental performances and resource efficiency and meet the increasing market demand for metals. In this continuously challenging environment, it is relevant to recognize which are the main challenges that the industry will face in the coming years and critically address our preparedness to respond to them. This analysis have to consider not only the effort required from the fundamental research and technology aspects but also how these pillars interact with the drivers behind the base metals industry. This paper discusses some relevant aspects required to continue developing the base metal industry focusing on copper. Aspects such as the need to supporting the generation of fundamental metallurgical knowledge, acquisition and proper use of data with advanced analytics methods, technological innovation to develop sustainable process flowsheet are discussed with emphasis on efforts conducted by Aurubis.

By Lana Alagha, Fardis Nakhaei, Jose L. Corchado-Albelo, Noelia Munoz-Garcia, Michèle Heitz

Sulfide tailings from past and present mining activities are important hosts of critical elements and precious metals. This review paper presented a literature survey on the recovery practices of some critical minerals containing Te from sulfide tailings with a special focus on the physical beneficiation and hydrometallurgical separation methods. Finally, a conceptual framework and possible processing flowsheets were proposed. The findings of this review will be useful for the researchers in the field of geochemistry, mineral processing, and metallurgy to evaluate the separation processes for reprocessing of mine tailings for the recovery of critical minerals.

Feb 1, 2024

By E. Keskinkilic

In this study, sulfide-type inclusion morphologies of a Ca-treated hot-rolled wheel steel, Grade-X, were investigated. The specimens taken from the hot-rolled products of Grade-X heats were studied. The size and distribution of elongated sulfide inclusions were examined for the heats of different S levels. Elongated sulfide inclusions were either not observed or rarely encountered when ladle analysis S content was below 50 ppm. The size and relative abundance of sulfide inclusions were reported to increase markedly when the S composition was greater than or equal to 70 ppm and the Ca/S ratio was less than 0.50. The effect of Ti addition (0.010?0.020% Ti) on sulfide-type inclusion morphologies was then investigated for heats having a sulfur content higher than 50 ppm. Addition of Ti was found to have a partial effect on decreasing the size of sulfide-type inclusions under real steelmaking conditions. Keywords Sulfide inclusions, Ca-treatment, titanium.

Jan 1, 2011

By M I. Pownceby

High temperature roasting studies on chrome-spinel contaminated ilmenite concentrates showed that sulfur, introduced through a sulfidising roast treatment, selectively reacted with the chromium in the spinels. The roast treatments were carried out in a laboratory scale rotating drum kiln using a standard Becher-style heating profile (10 h, 1075ºC), char as the reductant, and variable amounts of added elemental sulfur (0 - 3 wt per cent).After roasting, bronze-coloured grains were visible representing chrome-spinels that had undergone selective sulfidisation. SEM imaging of the products showed that sulfur was preferentially concentrated in ~5 - 15 µm thick rims fully enclosing the chrome-spinel grains. The sulfur-rich rims became a sink for manganese (Mn) from the ilmenite resulting in the rims being rich in Cr-Mn-Fe-sulfides. Quantitative electron probe microanalysis of phases present within the rims identified two sulfide phases. The first sulfur-phase (S-phase) was low in Mn (1 - 3 wt per cent) and high in Fe, Cr and S, while the second S-phase was considerably higher in Mn (30 - 35 wt per cent Mn) and lower in Fe and Cr. The dramatic change in the composition of the chrome spinels after sulfidisation is likely to significantly alter their physical properties (eg hydrophobicity, conductivity, etc). This should make their physical separation from the ilmenite potentially easier than roasting/magnetic separation methods.

Oct 5, 2011

Sulfidisation Promotion Effect of Ammonium Sulfate on the Flotation of Copper Oxide Ores

Sep 13, 2010