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Study on the Reasonable Mineral Processing Technology of a Cu-Mo Ore

Sep 13, 2010

By L. Alagha, M. Khodakarami

"This work focuses on the extraction of rare earth metals (REE) from aqueous solutions using stimuli-responsive polymers. Various parameters affecting the adsorption capacity of the polymer, including pH, polymer concentration and REE concentration were studied. The interfacial behavior of REE in aqueous phase before and after polymer addition and the mechanism of the formation of metal-polymer complexes and their properties were investigated using UV/VIS spectroscopy. Results obtained would help to test the feasibility of employing stimuli responsive polymers in pre-concentration of rare earth elements associated with other elements in mineral aqueous streams prior to solvent extraction. The pre-concentration step would reduce the amount of organic solvents used for extraction and striping compared to conventional extraction processes. INTRODUCTION Rare earth elements (REEs) have become the foundation for several technologies and have been used extensively in many industries such as modern electronics, green energy, health care and transportation and defense [1-4]. As these industry sectors are growing, the global consumption of REEs is going to increase dramatically. The current global REEs demand is estimated to be 105,000 tons of rare earth oxides per annum with an expected annual growth of 5.6% [5-6]. Rare earth elements are produced from different sources (primary and secondary). China is considered as the largest producer of REE in the world, providing about 90% of the world’s mine production while the United States is second with 4% of the mine production [7]. High global demand for rare earth materials results in shortage of such materials in the near future. It should be considered that the term ‘‘rare’’ earth is not an accurate term, since they are abundant in some extent in the Earth’s crust, but are typically finely dispersed. Thus, nowadays looking for more efficient and cheaper methods for extraction, separation and purification of low concentrated REE ores and exploring secondary sources are essential. Rare earth materials are found in raw condition and require treatment that involves several processes, which can consume money and time. Recent improvements in extraction and recycling technology have made the extraction of rare earth elements from rare earth sources more feasible in terms of cost and time [8-10]. Physical and pyrometallurgical methods require high-energy and thus high costs. Moreover, due to environmental problems, environmental protection systems are required, and they are not as adaptable as chemical processes [11, 12]."

Jan 1, 2016

By Z. He

Based on full investigation of the characteristic of sphalerite in the residue obtained from cyanidation leaching process and the study of the mechanism of the interaction between flotation reagents and sphalerite with the aid of electrochemical analysis, the reagent named YO was developed for eliminating the depression effect of CN- on sphalerite and reducing the dosage of CuSO4. The achievements have been used in commercial production for the treatment of the cyanidation residue to recover the zinc minerals, obtaining a zinc concentrate with grade of 56.49% Zn and recovery of 86.63% Zn.

Jan 1, 2014

Based on X-ray phase analysis and exploratory experiments, a new technology was developed to recycle multiple valuable elements in spent Al2O3-based catalyst. The experimental results showed that after roasting at 750°C for 30 minutes at an Na2O:Al2O3 mol ratio of 1.2, the leaching recoveries of alumina, vanadium and molybdenum from the spent catalyst were 97.2%, 95.8% and 98.9%, respectively. Vanadium and molybdenum in sodium aluminate solution can be recovered by barium hydroxide and barium aluminate. The precipitation recovery of vanadium and molybdenum was 94.8% and 92.6%, respectively. Al(OH)3 is prepared from sodium aluminate solution using the carbonation decomposition process. The purity of Al2O3 is 99.9% after calcinations, and the recovery of alumina can reach 90.6% in the whole process. The Ni-Co concentrate was leached with sulfuric acid, and a nickel recovery of 98.2% and a cobalt recovery of more than 98.5% were obtained under the experimental condition of 30% (w/w) H2SO4, 80°C, a liquid: solid ratio of 8:1 (by weight), a reaction time of 4 hours and a stirring rate of 800 rpm.

Jan 1, 2007

By Sun Chuanyao, Jia Muxin

Generally, if the bond valence (BV) between metal ion and oxygen of the mineral is greater than 0.8, only surface species –Me-O-H or –Me-O exposures on the mineral interface, if the BV is between 0.2-0.8, the metal ion exposures on the interface, and if the BV is less than 0.2 the metal ion dissolves into water. The PZCs of oxide minerals and island silicate minerals are determined by the bond valence of the bond in the mineral crystals, the higher the bond valence the lower the PZC of the mineral. So the PZC sequence of Al2SiO5 minerals is kyanite> andalusite> sillimanite. The general rule for framework silicate minerals is as: The higher the Al content, the lower the PZC of the mineral, when the ratio of Al to Si in the tetrahedron skeleton is below 1:3. The higher the Al content, the higher the PZC of the mineral, when the ratio of Al to Si in the skeleton is between 1:3 and 1:1. The general rule for layer silicate minerals is summarized as: the three-layer silicate minerals have much lower PZCs than that of the two-layer silicate minerals. The threelayer silicate mineral with the octahedron layer occupied by lower charged cations has lower PZC than that of the three-layer silicate mineral with the octahedron layer occupied by higher charged cations. The twolayer silicate mineral with the octahedron layer occupied by lower charged cations has higher PZC than that of the two-layer silicate mineral with the octahedron layer occupied by higher charged cations. The layer silicate mineral with Al substitution in the tetrahedron layer has lower PZC than that of the layer silicate mineral without Al substitution in the tetrahedron layer. Such pyroxene minerals whose M1 is occupied by a trivalence cation and the M2 is occupied by a monovalence cation has lower PZCs than those both M1 and M2 are all occupied by bivalence cations. Such hornblende minerals whose M2 is occupied by a trivalence cation and the M4 is occupied by a monovalence cation has lower PZCs than those both M2 and M4 are all occupied by bivalence cations. There is no Si4+ or 4 coordinated Al3+ exposures on the surface of framework silicate minerals, the metal ions of three layer or chain silicate minerals are compact between tetrahedron layersor chains, they hinder the metal ions to interact with oleate acid radical, the metal ion octahedron layer exposures on the surface of a two layer silicate mineral, but the the oleate acid radical can not attach to a metal ion by replacing a –OH- that connects three metal cations in the same time, So the floatability of such silicate mineral is bad. The metal octahedron chain style of an island silicate mineral affects it floatability, the mineral exposures octahedron chain metals with two dangling bonds in two directions floats better than the mineral exposures octahedron chain metals with two dangling bonds in one direction.

Jan 1, 2003

By Yuanpei LAN, Minren XU, Deliang NIU, Zhu WANG, Qingcai Liu, Shan Ren

Removal of gas is the major function of RH degasser. To optimize the RH refining craft in Chongqing Iron and Steel Co. Ltd, the degassing effect of RH degasser at different degrees of vacuum was investigated using a vacuum induction furnace. In addition, the effect of processing time on the gas content dissolved in molten steel was also studied. The results showed that degree of vacuum was one of the important factors that determined the degassing efficiency in RH refining process. High vacuum degree is helpful in the removal of gas, especially in the removal of [H] dissolved in molten steel. The processing time could be reduced from 25-30 min to 15 minutes and gas content could also meet the demand of RH refining

Jan 1, 2015

By Liu Yong

A complex rare metal ore, containing various valuable elements is used in this study. The mineralogy results indicate that the mineral composition of the raw ore is complex, and there are more than thirty-eight kinds of minerals in the raw ore, and the elements, such as Nb, Ti, Fe, REO, Be etc, always form isomorphism relationship. The REO content of the raw ore is 0.45%, and the contents of other rare metals Nb, Ta, Ti and Zr are 0.33%, 0.02%, 0.93% and 2.00% respectively, and the main gangue elements are Si and Al, and their contents are 71.84% and 8.5% respectively. The beneficiation-metallurgy combination process of ?preconcentration-reduction and magnetic separation-acidification and leaching-precipitation? is used to treat the raw ore. The preconcentration of raw ore is realized through high intensity magnetic separation, and the magnetic field intensity is 1.0T, and the rough concentrate with 2.88% REO and 1.95% Nbresidue can be obtained, and the iron recovery is 92.83%, and the REO recovery is 95.87%, and the Nbresidue is treated by hydrometallurgy process of ?acidification-leaching-precipitation?, then the rare earth oxide, niobium concentrate and zircon-bearing residue can be obtained, and the REO recovery is 80.10% and the Nbresidue and the gangue obtained from the high intensity magnetic separation process is separated by gravity separation, and then the zirconium concentrate can be obtained. The indexes of the beneficiation-metallurgy combination process used to treat the complex rare metal ore are as follows. The REO content of the rare earth oxide is 92.58% and the recovery is 58.44%. The Nb2O5 and 27.42% TFe can be obtained. Iron in rough concentrates is removed after reduction and low intensity magnetic separation, then the iron powder with Fe content over 88% and nonmagnetic rare-metal 2O5 recovery is 94.77%. The rare-metal 2O5 recovery is 80.04%. The mixture of the zircon-bearing 2O5 content of niobium concentrate is 28.34% and the recovery is 54.02%. The ZrO2 content of zirconium concentrate is 28.43% and the recovery is 52.35%. The TFe of iron powder is 89.53% and the recovery is 78.13%. Keywords: rare metal ore, separation and extraction, beneficiation-metallurgy combination, comprehensive utilization

Sep 1, 2012

By W. Z. Yin

With increasing of mining depth, many iron ores in Liaoning Province contain carbonates such as siderite and ankerite. The emergence of these carbonates in ores creates a fatal impact on the running producing process of anionic reverse flotation in Dong Anshan Sintering Plant, which leads to ?concentrate and tailing no separated?. And its reason is still unknown. Moreover, siderite, despite that its ferric theoretic grade is only 48.2%, however, do not affect the blast furnace utilization factor, therefore, can be used as raw materials in ironmaking. In order to solve the separate problem of iron ore containing carbonates, five pure minerals, martite, magnetite, quartz, siderite and ankerite, were selected for a series single flotation experiment. The aim was to discover the flotation difference of these minerals, furthermore, to explore a new flow sheet for the iron ore containing carbonates. The results of single mineral flotation experiment reveal that the combination regulators, starch and CaCl2, in different pH extent, can make these minerals taking on obvious flotation difference, which make it possible to process the iron ore containing carbonates. A new flow sheet, step-flotation, to process iron ore containing carbonates is explored, that is, first step, direct-flotation processing, is to eliminate the bad effect that the carbonates bring in flotation system by collecting carbonates under neutral condition; the second step, reverse?flotation processing, is to get qualified iron concentrate by collecting quartz under alkaline condition. Manual mixed ore sample were processed successfully through this new flowsheet under proper reagent system, which has absolute advantage compared with routine flowsheet. Actual ore sample of compound magnetic separation concentrate were processed successfully both open and closed circuit experiment through this new flowsheet. SEM and EDS were used to probe the reason why carbonates affect the regular processing. It is analyzed that moderate floatability of siderite and its coating on the surface of hematite and quartz make the phenomenon ?concentrate and tailing no separated?. This research provides a reasonable processing scheme for iron ores containing carbonates and can be used for reference in processing other complicated, refractory iron ore.

Jan 1, 2014

By X. J. Lu

Purified Na-montmorillonite samples were used as the starting materials to prepare organically modified montmorillonites (OM), and a series of OM samples were prepared by intercalation of al-kyl quaternary ammoniums with different alkyl chain length. The interlayer spacing (d001) of the OM was determined by small angle X-ray diffraction and its gelating performance was characterized by measuring the viscosity of OM/dimethylbenzene mixture. The effects of alkyl chain length, dosage of alkyl ammonium, intercalation duration and layer charge of the starting material on the OM structure and gelating properties were investigated. According to the results, the adsorption quantity of the alkyl ammonium is dependent on the hydrocarbon chain length, the dosage of the alkyl ammonium and the retention time. The adsorption quantity of the alkyl ammonium increases with the chain length and the dosage, and extra adsorption more than the CEC of the montmorillonite sample was observed under the dosages of more than 1.3 CEC. The interlayer spacing (d001) of the OM shows a dynamic variation with the dosage and the retention time, and super interlayer spacings greater than the length of the alkyl ammonium were observed under larger dosages and shorter retention times. However, the gelating performance of OM does not follow the variations of the adsorption quantity of alkyl ammonium, an optimum viscosity value of OM/ dimethylbenzene gel was observed with the moderate adsorption of the alkyl ammoniums. Furthermore, the layer charge plays an important role on the gelating performance of OM. The OM synthesized by the starting material with lower layer charge shows better gelating performance in the dimethylbenzene solution.

Jan 1, 2014

By S. Q. Zhu

Coal Water Mixtures (CWMs) are densed suspensions of coal particles in water. Viscosity is one of the most important rheological properties of CWMs and it is desired to be as low as possible. The slurry viscosity was influenced significantly by additive formation, the particle size distribution and the ash content of the coal. However, the influence of dispersants is most obvious. At present, there are several kinds of dispersants such as polymeric styrene sulfuric sodium, lignin sulfonate, humate, polycarboxy salt, ethylene epoxide surfactant. In this paper, a newly synthesized CWM dispersant has been reported, which is an efficient anionic surfactants of polycarboxylic acid type. The synthesis process includes three steps. At the beginning, the polyglycol acetate ester has been performed by acetic acid and polyethylene glycol (PEO) on the condition of acetic-acid/PEO ratio 1:1.1, at 368~373K for 30 minutes. Then the macro-monomer is prepared through the esterification of 85.71% acrylic and 14.29% polyglycol acetate ester, at 368~373K for 10 minutes. After that, the polycarboxylic acid CWM dispersant is polymerized using proper proportion macro-monomer, acrylic (AA) and sulfonic styrol sodium, at 368~373K for 1 hour. This new dispersants are used in the coal water mixtures formulation. Four kinds of coal used in the experiment are Shuang Yashan, Tunliu, Luning, Changcun samples. ? The highest concentration for shuanyashan coal is 70% when the dosage of dispersant is 0.4%, and the content of -200 meshes particles is 75.53%. As the dosage of dispersant de-creases to 0.25%, the Shangyashan CWM concentration is 67%. ? For Tunliu coal CWM concentrations are in the range of 76% to 75% when dosage of the dispersant changes from 0.4% to 0.25% at the same particle size distribution of 83.5% minus 200 meshes. ? The highest concentration for Luning coal is 69% when dosage of the dispersant is 0.4%, and the content of -200 meshes particles is 88.86%. ? For Changcun sample, the coal concentration of CWM is 73%~75% when dosage range of the dispersant is 0.35%~0.5%. The experiments show that the synthesied dispersant is quite promising for some coals CWM preparation, but a little bit coal-dependent. The Proximate and Ultimate analysis, surface characteristic measurement have been made to investigate the interactions between coal and additives.

Jan 1, 2014

By Wenbing Guo, Yi Tan, Erhu Bai

"It is important to study the mining technology under structures for raising the coal resources recovery ratio. Based on the geological and mining conditions, the top coal caving harmonic mining technique in thick coal seam beneath the earth dam was put forward and studied. The 5 factors such as the panel mining direction, panel size, panel location, panel mining sequence and panel advance velocity were taken into account in this technique. The dam movement and deformation were predicted after the thick coal seam mining and the effects of mining on the dam were studied. By setting up the surveying stations on the dam, the movement and deformation of the dam were observed during mining. By taking some protective measures on the dam, the top coal caving mining technique in thick coal seam beneath the earth dam was carried out successfully. The study demonstrates that harmonic mining in thick coal seam is feasible under the dam. The safety of the earth dam after mining was ensured and the coal resources recovery ratio was improved.The surface movement and deformation caused by coal mining not only influence the ecology environment in the mining area, but damage the surface structures such as buildings, railroads, highways, water bodies and damsr1-31_ The movement of strata and surface caused by mining had disturbed various aspects of industrial and agriculture productions in the mining arear41. The earth dam is a very important water retaining structures, so it must makes sure the safety of dam if mining under it. Therefore, to study the effect of mining on dam and control measures to ensure safety of mining under the dam are important factors for improving the mining recovery ratio, reliving the mining continuity, preventing or reducing damage to the dam.By means of the harmonic mining technologyrs1, theoretical analysis and field observation, the mining method under an earth dam and the mining influences were studied and analyzed in this paper. The mining of a thick coal seam under the dam was carried out safely and successfully."

Jan 1, 2016

By Lichao Ding, Jingbiao Fan, Yunnen Chen

"With the development of industrial production, more and more wastewater containing high concentration ammonia nitrogen was discharge into the environmemt, which caused serious harm to the environmemt. Treating the wastewater has great significance to protect water resources. Using air-stripping combined with oxidation to uptake high concentration of ammonia nitrogen wastewater. The influence of operating parameters was investigated. Experimental results revealed that pH of solution, aeration time and aeration strength showed heavy influence on ammonia nitrogen removal. Air-stripping combined with oxidation can be considered as an alternative approach for the removal of high concentration of ammonia nitrogen from practical metallurgical wastewater. When pH was 11, aeration time 20 min, aeration strength 1040 Lh-1, and oxidation with 10 % NaClO solution 10 min, the initial ammonia nitrogen 2130 mgr1 could reduce to 12 mgr1. Other items could also be removed to meet the ""Integrated wastewater discharge standard (GB8978-88)"".1. IntroductionThe rapid development of human activities has caused a worldwide increase of nitrogen in rivers, lakes and coastal waters. It leads to considerable eutrophication and an increase in the frequency of toxic algae blooms [1,2]. The concentrations of nitrogen in the water of China are pervading high [3]. The discharge of wastewater containing high concentration of ammonia nitrogen is one of the most important factors. Great efforts have been devoted to the removal of ammonia nitrogen from wastewater. Traditional methods include biological denitrication [ 4 ], chemical precipitation with magnesium ammonium phosphate [5], electrochemical conversion [6], air-stripping [7] and so on. Biological denitrication is the most common process in the treatment of ammonia nitrogen wastewater. But the process is only suitable for the removal of relatively low ammonia concentration due to the requirement of appropriate C/N ratio [8]. Chemical precipitation needs additional reagents, which may introduce new pollutants to water body. Electrochemical method often uses expensive metal or metal oxide as electrodes, and also consumes large quantity of energy [6].Although air-stripping makes use of stripping tower and consumes energy, it is very suitable for the removal of relatively high ammonia concentration. Different air-stripping conditions would appear different removal efficiency. And only air-stripping the effluent can not be attained the ""Integrated wastewater discharge standard (GB8978-88)"". In this study, we use air-stripping and oxidation to removal high concentration of ammonia nitrogen from simulated and real ammonia nitrogen wastewater."

Jan 1, 2011

By Yang Song, Li Shaokang, Wang Zhiqiang, Wang Jinjun, Li Guofeng, Su Meixuan

CaCO3, as a component widely existing in natural minerals, is a common impurity. In recent years, triboelectric separation has been applied to the separation of minerals containing CaCO3. However, the CaCO3’ s tribocharging mechanism is still unclear and the charging effect of CaCO3 is not obvious. In order to study the effect of triboelectric charging of CaCO3 particles under different conditions, according to the single particle frictional collision charge-mass ratio formula derived from the condenser model, an experimental platform for particle tribocharging was built in this paper. Then, the formula of charge-to-mass ratio (Q/m) was derived based on the analysis of the particle force. Particle image velocimetry (PIV) was used to record particle motion trajectories to calculate the Q/m of one particle by this formula. In the experiment, the airflow velocity, tribocharge material, and moving distance of the particles were varied to investigate the variation of the particle charge-mass ratio results. The results show that CaCO3 was negatively charged when tribocharging with mental. The particle’s Q/m is positively correlated with the airspeed. When the metal is triboelectrically charged with the insulator, the metal with a smaller work function leads to the insulator particle with a larger Q/m. As the moving distance of the particles increases beyond 230 mm, the particle charge ratio decreases. The particle charge-mass ratio is consistent with the trend of the charge-mass ratio deduced from the capacitance model.

Jun 3, 2023

By Yong-neng Feng, Xiao-ping Chen, Wei Guo

"While the uniaxial compressive strength of rock has been extensively investigated, the relation between the saturation and natural compressive strength is relatively unexplored. This paper studies on 1865 statistical data of Chongqing Rail Transit Line 1 and Line 6, which located in the Middle Jurassic of Shaximiao formation. The research focuses on the relation between the saturation and natural compressive strength. The statistical data are categorized and quantified in order to ascertain the softening properties of sandstone and sandy mudstone. The findings suggest that the saturation compressive strength is significant effected by its natural compressive strength, and an empirical formula is introduced to explain the relation. These findings have implications for researchers and engineer who concerned with Chongqing rail transit construction.INTRODUCTIONIn the engineering construction and surrounding rock classification, the uniaxial compressive strength index (Ministry of Water Conservancy, 1995; Ministry of Railways, 1999) is one of the essential parameters of rock mass. Usually, there are two types of the uniaxial compressive strength index, natural and saturation compressive strength, and the ratio of them is the softening coefficient. Most of the previous studies on rock strength had focused on the influence factors (Liu et al., 2008; Liu et al., 1998; Liu et al., 2013; Wang, 2013; Zhang et al., 2008; Zhang et al., 2010; Zeng & Lin, 2003) with experiment and in-situ tests. But few publications that reports a long and formal research project on the relationship between natural and saturation compressive strength. In order to figure out this issue, this study investigated the distribution of Solidity Classification of Rock Mass and softening coefficient based on the statistical data of Chongqing Rail Transit Line 1 and Line 6. Based on the analysis, an empirical formula was proposed to explain the relationship."

Jan 1, 2015

By Zhengen Zhou, Dachun Liu, Baoqiang Xu, Bin Yang, Yong Deng, Heng Xiong, Jia Yang

The thermogravimetric method was selected for investigating the evaporation of Sb2S3 in the pressure range of 50–300 Pa and in the temperature range of 823–1123 K, the gas phase diffusion was the rate-determining step for Sb2S3. The volatilization rate was related to the temperature and pressure, that the logarithm of volatilization rate yielded a line with the reciprocal of temperature and pressure. The volatilization rate for Sb 2S3 was between 0–0.023 g/C1 cm−2/C1 s. The apparent activation energy was between 65.8 and 60.6 kJ/mol.

Mar 1, 2018

By QIE Jun-mao, DONG Fang, DENG Hao-hua

The DIL402C thermal dilatometer and STA449C thermal analyzer were employed to test the linear expansion and contraction coefficient，CP and DSC curve of 304 stainless steel. The result showed that the linear expansion coefficient range was 20.9700×10-6～21.5712×10-6 and the linear contraction coefficient range was 21.2528×10-6～21.9471×10-6.The linear expansion and contraction coefficient were higher than other steel grade，so the 304 stainless steel belonged to the crack sensitive steel. Because of the crystal phase transformation occurred during the 1000~1400 ℃,the curve of CP fluctuated obviously and the defects of casting blank occurred easily. Chosen 1414℃ as the liquidus temperature of 304 stainless steel based on the analysis results of DSC. The curve of DSC was unsmooth during 1450～1100℃，the crystal phase transformation occurs and thermal stability of slab was inferior.When the initial solidified shell formed in this temperature range,the thickness of the shell would be nonuniform and the surface defects occurred more easily.

Jan 1, 2015

By Yuanbo Zhang

Keywords: Complex Iron Ores, Roasting, Tin, Zinc, Pellets, Comprehensive Recovery. The complex iron ores containing tin, zinc are typical refractory ores. Large reserves of the ores are found in China and have not been utilized efficiently so far. A new process of tin and zinc recovery and pellet preparation from iron concentrate containing tin and zinc by controlled atmosphere roasting is developed in this investigation. The results of 2573 N/P compression strength of product pellets, the 91.49% and 82.22% volatilization of tin and zinc respectively, are achieved for a concentrate containing 0.39% tin and 0.28% zinc. The strength and chemical compositions of the pellets meet the requirement of blast furnace ironmaking. Volatilization mechanism of tin and zinc are investigated. Thermodynamic study shows that the reduction balance curves of SnO2(s) and SnO(g) are proximate in the presence of carbon, and the standard formation free enthalpy of FeO and SnO2 is also approachable. Therefore, it is difficult to realize the complete volatilization of tin in the form of SnO(g) by selective reduction. But SnO2(s) and SnO(g) will form SnCl4(g) or SnCl2(g) in the presence of chlorides and can be easily volatilized from the ores.

Jan 1, 2005

By X. Tan

In this paper, the application of the metallurgical residue produced from oceanic cobalt-rich crusts leaching process is studied in the area of wastewater treatment. The modification of the sulfuric acid leached residue and the adsorption behavior behaviour of heavy metal ions such as (Pb(II), Cu(II), Zn(II), Cd(II), Ni(II), Mn(II), Co(II), As(III)) in the waste-water on the surface of the residue are investigated. The rate of adsorption efficiency of heavy metal ions in the wastewater on the modified sulfuric acid leached residue is investigated. It is showed that when the initial pH value of wastewater containing heavy metal ions including Pb(II), Cu(II), Co(II), Ni(II), Mn(II), Zn(II), Cd(II) and As(III) range from 1.4 to 1.9, with the use of the modified leached residue, As(III) ion can be selectively separated from wastewater, and the separation efficiency can reach 90%~100%. The adsorption efficiency is affected by pH, reaction time, amount of adsorbent and the initial concentration of heavy metal ions in wastewater. The results showed that the optimum pH was natural pH value and the absorption equilibrium time was 2 hours. The adsorption efficiency of heavy metal ions increases with the addition of adsorbent and de- creases with the increase of the initial concentrations of heavy metal ions in wastewater. The heavy metal ions polluted wastewater, of which concentration is about 22.5~793.6 mg/L, can meet the national disposal standard for industrial wastewaters in China very well, after 2 hours treated by 3.75~7.50 g/L modified adsorbent at room temperature. Standard methods were used to investaged investigate the absorption behaviour between abosorbentabsorbent and metal ions in the wastewater. It is concluded that the adsorption behaviour of Co(II), Mn(II) and As(III) ion fits Freundlich iso-therm, while the adsorption behaviour of Pb(II), Cu(II), Zn(II), Cd(II) and Ni(II) ions fits Langmuir isotherm, and the saturated adsorption amount of the modified adsorbent is about 54.0~336.7mg metal/g?adsorbentabsorbent. It is suggested that the modified sulfuric acid leached residue produced from oceanic cobalt-rich crusts is environmentally attractive and meaningful as absorbent used in heavy metal ions polluted wastewater.

Jan 1, 2014

Study on Treatment of Wastewater Containing Heavy Metal Ions Using Modified Oceanic Cobalt-Rich Crusts

Sep 13, 2010

By J. -H. Wu, S. Nishiyama, Y. Ohnishi

The behaviors and stress distributions of the inclined jointed rock masses with different dip angles obtained from DDA are compared to the results of laboratory tests. By calculating the block stress distributions, it is confirmed that DDA can reproduce the arching around the trap door when lowering the trap door. The shapes of arching change with the angles of inclined layers. In addition, the earth pressures acting on the trap door shows non-symmetrical distributions when the layers are not horizontal. The stress concentration occurs in one side of the rock masses close to the trap door. Furthermore, the surface settlements are also related to the inclined angle, and the loosening zone in rock masses can be different from Terzghi’s theory [1]. Since, simulations have good agreements with the laboratory test , it demonstrates the applicability of DDA to explain the mechanical behaviors of tunnel, such as arching phenomenon, non-symmetrical earth pressure distributions acting on the trap door, and the surface settlement profile in the jointed rock masses. Dans cet article est décrite l’étude numérique du perçage d’un tunnel dans un massif de couches rocheuses jointes inclinées. La simulation à l’aide de l’Analyse de Déformation Discontinue (DDA), en faisant varier l’angle d’inclinaison des couches de roche, nous apporte des résultats en termes de distributions de contraintes et de comportement des couches, résultats qui sont ensuite comparés avec des résultats de tests en laboratoire. Les résultats confirment le fait que la DDA est capable de reproduire le phénomène d’arcage autour de la trappe lorsque la trappe s’abaisse. Les formes d’arcage varient selon l’angle d’inclinaison des couches de roche. Par ailleurs, lorsque les couches ne sont pas horizontales, la distribution de pression agissant sur la trappe est assymmétrique. La concentration de contraintes se produit du coté proche de la trappe. De plus, les tassements de surface dépendent eux aussi de l’angle d’inclinaison. En conséquence, les résultats de simulation sont en accord avec les tests en laboratoire, ce qui prouve que la DDA permet d’expliquer des comportements mécaniques du tunnel tels que l’arcage, les distributions assymmétiques de pression du sol sur la trappe, ainsi que le profil du tassement de surface dans la masse de roches jointes. Dieser Beitrag beschreibt eine numerische Studie über Tunnel im geklüftetem Fels. Das Verhalten und die Druckverteilungen in den unterschiedlich geneigten und geklüfteten Felsenmassen wird mit Hilfe des Discontinuous Deformation Analysis Programms (DDA) simuliert, und mit Laborversuchen verglichen. Die Resultate bestätigen, dass DDA der Gewölbewirkung im „Trapdoor“ Experiment gut reproduzieren kann. Die Form des Gewölbes, ändert sich mit unterschiedlichen Neigungswinkeln der Schichten. Bei geneigten Schichten entstehen unsymmetrische Druckverteilungen. Auch die Oberflächenabsenkung ist von dem Neigungswinkel abhängig. Die gute Übereinstimmung der Simulationen mit den Laborversuchen zeigt, dass die DDA-Methode gut geeignet ist, um das mechanische Verhalten von Tunneln, wie z.B. den Effekt der Gewölbewirkung, die unsymmetrischen Druckverteilungen bei geneigten Schichten, oder die Oberflächenabsenkung in geklüfteten Felsenmassen, zu erklären.

Jan 1, 2003