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By Kamalendu Bhunia

With the progressive depletion of known resources of good quality coal and minerals as well as the increasing demand of these minerals by different user industries, the emphasis has been shifted all over the world from selective mining to bulk mining followed by up- gradation to obtain the required quality of concentrate. The column flotation cell is one of the alternatives to reduce the gangue content of fines because of its inherent characteristics viz. easier to operate, low space required, no moving parts etc. A laboratory flotation column is used to conduct experiment. Present work has been undertaken to observe the effect of process variables (gas flow rate, feed/slurry flow rate, and frother concentration) on gas dispersion parameters (gas holdup, bubble surface area flux) in collection zone and to explore the effect of feed (slurry) inlet orientations and gas flow rate on column?s metallurgical performance. The effects of solid particle concentration, size and type (hydrophobic and hydrophilic) of solid on gas dispersion parameters have also been investigated. Test work has been performed in a continuously operating Perspex column (10 cm in diameter and 168 cm in height) using coal, sphalerite and dolomite as solid. Gas hold-up has been measured by phase separation method and mean bubble sizes are estimated from a drift flux analysis. The influence of operating parameters on bubble surface area flux has been discussed. It is observed that gas holdup in collection zone is affected by air as well as feed flow rates and also solid?s type. It is also found that addition of solid decreases the gas holdup and rate of decrease in gas holdup increases when solid concentration increases and particle size increases. Increase in gas flow rate increases recovery in collection zone due to increase in number of bubbles per unit volume of the column. From the experimental results it is evident that cross-current orientation of feed inlet shows slightly better metallurgical performance compared to other orientations. Keywords: column flotation, gas holdup, drifts flux, bubble size, bubble surface area flux, hydrophobicity, and recovery

Sep 1, 2012

By Z. M. Wang

A large scale a polymetallic mine in north China is a refractory ore containing many useful com-ponents: W, Mo, Cu and Fe. Mineralogical investigation shows that the deposit is a quite complex one due to fine disseminated size and unevenly distribution of valuable, intergroth of sulphide and tungsten minerals, concurrence of scheelite and calcium minerals. Based on ore characteristic, a flowsheet is used by the floatation processing of sulfide minerals superior to scheelite. Bulk sulphide flotation is used in sulphides. Mo and Cu are floated in sequence after sulphides regrinded. Tungsten mineral is floated using combined depressant that is an effective depressant to gangue, and can improve the grade of rough tungsten concentrate. Compound depressant has high effective in removal of collector in gangue and sulphide, and tungsten is activated also. High quality of tungsten concentrate is obtained at satisfactory recovery. The test production obtains Mo concentrate with grade of 48.16%, recovery of 81.43%; W concentrate with grade of 66.47%, recovery of 78.19%; Cu concentrate with grade of 23.14%, recovery of 56.6%; Fe concentrate with grade of 67.33%. The valuable metals are recovered comprehensively and well techno-economic index is obtained. The mine enterprise profit is increased greatly.

Jan 1, 2014

The ore studied occurred in the Three Rivers area in China and was a silver-lead-zinc complex ore containing 400.52 g/t silver, 4.77 % lead and 3.47 % zinc. Silver, lead and zinc were the major valuable elements in the ore and copper, cadmium and tin were the associated elements to be comprehensively recovered, whereas arsenic was the harmful element. The element silver occurred mainly in freibergite with small proportion in dyscrasite and other silver minerals. The carrier minerals for silver were mainly galena and oxidized lead minerals and then sphalerite, arsenopyrite and pyrite. The ore contained numerous minerals with complex mosaic texture and the lead and zinc minerals enclosed each other multiply, which made the separation of the minerals in the ore very difficult. Experimental investigation on the beneficiation of the ore indicated that with flotation separation process it was very hard to obtain single lead concentrate or single zinc concentrate that would meet the requirement of market. In the meantime, during the separation process of lead and zinc, silver tended to be dispersed, resulting in a low recovery of silver. Therefore, a rational utilization technique for the ore should be a combined process of bulk flotation to reduce arsenic? sulphating roasting of silver-lead-zinc bulk concentrate-leaching with diluted sulphuric acid to separate silver, lead and zinc. With this process quality lead concentrate containing silver and high grade zinc product and silver product could be obtained. The recovery of silver, lead and zinc in flotation was 85.10%, 84.48% and 82.48%, respectively. The total recovery of silver, lead and zinc in chemical processing was 97.07%(sum of recovery of silver ingot and lead concentrate), 99.61% and 90.93%, respectively.

Jan 1, 2014

By N. Dashbold, E. Rudnik

"Waste electric and electronic equipment currently comprises the fastest-growing waste stream in the world, but at the same time it is seen as an important source of metals for the recycling industry. E-waste is usually treated pyrometallurgically, with hydrometallurgical methods used to a lesser extent. This paper reports the results of research on the selective recovery of copper from smelted low-value electronic waste. Pyrometallurgical pretreatment of the scrap allowed the removal of plastics and the increase of metal content in the material. The obtained alloy of copper, zinc, tin and silver was a multiphase solid consisting of two brass phases and inclusions rich in iron, lead and silver. Copper alloy was further anodically dissolved in ammoniacal chloride solution. It resulted in high degradation of the material and accumulation of the metals mainly in the slime. The slime was then leached in acid or ammoniacal chloride and sulfate solutions followed by selective copper electrowinning. Hydrochloric acid was the most efficient solvent for the slime, but ammoniacal solutions were more selective for copper. Copper could be leached with 96 to 100 percent and 87 percent efficiency from the slime by the chloride and sulfate solutions, respectively. Copper with 90 to 99 percent purity at current efficiency of 42 to 76 percent was obtained from the acid solutions, while copper with 98 to 99 percent purity at current efficiency of 60 to 86 percent was deposited from the ammoniacal baths. IntroductionObsolete electrical and electronic equipment makes up the fastest-growing waste stream in the world (Baldé et al., 2015), due not only to the introduction of wider ranges of new types and models of a variety of electronic products but also to the shortening of their life-spans, sometimes referred to as planned obsolescence by producers (Keeble, 2013). About 42 million tons of electronic waste, or e-waste, are estimated to have been generated globally in 2014 (Baldé et al., 2015), and it is expected that in the European Union alone the waste electrical and electronic equipment (WEEE) stream will reach more than 12 million tons by 2020 (European Commission, 2015). Accurate evaluation of e-waste generation (Wang et al., 2013) and its global transport (Breivik et al., 2014) is difficult, mainly due to a lack of high-quality data related to its market and socio-economic dynamics.Many countries introduced legislation to control e-waste flow, collection and recycling. For example, Directive 2012/19/EU on waste electrical and electronic equipment (European Parliament and the Council of the European Union, 2012) obliges all E.U. members from 2016 to maintain a minimum collection rate of 45 percent of the total weight of WEEE collected. From 2019, the minimum collection rate to be achieved annually shall be 65 percent of the average weight of electronics placed on the domestic market in the three preceding years, or alternatively 85 percent of WEEE generated in the territory of the particular member."

Jan 1, 2017

By Y. Luo

"It is generally known that spontaneous combustion potential is a function of coal rank, with low-rank coals having high susceptibility to self-ignition and high-rank coals having low potential. To establish this functional relationship and use it as an engineering tool to identify the propensity of coal to self-heat, both rank and spontaneous combustion potential should be quantified. ASTM D388 is normally used to classify coals by rank, but this classification system can only serve a qualitative analysis. To classify coals by their potential for spontaneous combustion, the self-heating temperature (SHT) method originally developed by the U.S. Bureau of Mines (USBM) was used by Litton and Page (1994) to correlate coal rank with spontaneous combustion potential. In that method, the SHTs of coal determined by an adiabatic experiment are linked with proximate analysis results through a proposed concept known as the “moist fuel ratio.” This ratio is a function of moisture, volatile matter and fixed carbon, all of which have widely different content percentages in different ranks of coal and have strong relationships with coal rank. However, the method is highly empirical, and there is large standard deviation between experimental data and calculated results. The equation correlating the coal quality parameters to determine SHT should be improved with more experimental data.This paper reports on the development of a new system for predicting the spontaneous combustion potential of U.S. coals, based on coal composition data from the U.S. Geological Survey’s coal quality database. First, the user is provided with a quantified classification of coal rank. Second, based on experimental SHT data covering a wide range of ranks from lignite to low-volatile bituminous coal, the original USBM correlation for predicting SHT is improved for the respective rank of coal. The relationship between the rank and SHT of U.S. coals was developed and plotted. The plot diagram can be used for a quick estimate of the SHT of a U.S. coal and as a cost-effective tool for the initial risk assessment of a new mine development."

Jan 1, 2015

By Yang Xianwan, Zhu Xiaoyun, Guo Zhongcheng, Zheng Yanping, Zhai Dacheng

"Corrosion resistance of RE-Ni-W-P-SiC composite coating and 3 l6L stainless steel in corrosion media of H2SO4, HCl, H3PO4 and FeC13 solutions at different concentrations by means of immersion methods and anodic polarization curves obtained by DHZ-1 electrochemical synthetic tester and HDV-7 transistor constant potentiometer. Immersion experiment results show that corrosion rate of RE-Ni-W-P-SiC composite coating as-deposited in HCl solutions increases with the rise of HCl concentrations, on the contrary, the corrosion rate of the composite coating after heat treatment decreases with increasing the HCl concentrations the corrosion rates of the coatings as-deposited and after heat treatment in H2SO4 and H3PO4 solutions respectively decrease with the rise.of H2SO4 and H3PO4 concentrations the corrosion rate of the deposit as-deposited in FeC13 solutions decreases with increasing FeC13 concentrations, while the rate of the composite coating after heat treatment increases .with the rise of FeC13 concentrations.In addition, the corrosion rate of 3 l 6L stainless steel in the corrosion media of H2SO4, HCl, H3PO4 and FeC13 solutions at different concentrations increases with rising of concentrations. Furthermore, the corrosion rate of 316L stainless steel in the corrosion media of H2SO4, HCl, H3PO4 and FeC13 solutions respectively is much greater than that of the RE-Ni-W-P-SiC composite coating as-deposited and after heat treatment in the same corrosion media.1. IntroductionAll the materials and their products, when processed, stored and used, it is inevitable that the corrosion, wear, fatigue and crack occur owing to the actions of surroundings. Those early failure and abrasion, through all kinds of departments and profession that corrosion consumes one percent of tens of the steel products of the whole world; and two or four percent of the GDP is lost because of the corrosion."

Jan 1, 2000

By Fangming Liu

The key problems of current flowsheets and equipments are analyzed. A new steel slag's crushing flowsheet whose key equipments are the improved inertia cone crusher and inertia vibrating jaw crusher is proposed. An advanced two stage open-circuit crushing method is adopted in the flowsheet, with 90% of particle size crushing under 6mm. Using inertia vibrating technology and selective crushing principle the crushers can realize steel slag separating fully into steel and slag and with flexible transmission mechanism the crusher can be protected when iron lump is passing. The flowsheets can enhance the recovery of metal greatly, and expand the application range of tail slag and added value.

Sep 1, 2012

By Yuhua Wang, Haitao Zheng, Guangli Zhu, Yuehao Zhao, Fushun Yu, Dongfang Lu

"Spodumene, feldspar and quartz possess similar surface properties, which make the difficult to separate spodumene from other silicate minerals by flotation. The differences of crystal structure, surface property and floatability of three minerals were studied by various technical means. The results show that Li-O and Al-O bonds in spodumene structure are not strong and easy to be broken. However, Al-O and Si-O bonds in feldspar and Si-O bond in quartz are very strong and not easy to be broken. High contents of Al and Li on spodumene surface were found by XPS measurements, which is benefit for the adsorption of anionic collector. The surface energies of main cleavage planes of spodumene (110), feldspar (001) and quartz (001) are 1.88 J/m2, 2.97J/m2 and 2.68J/m2, respectively. Hence, the exposed surfaces of feldspar and quartz are not saturated and easy to adsorb OH- ions from solution and cause the lower IEP than spodumene. The contact angles of three minerals in water are lower than 16º, suggesting that the hydrophilicity of three minerals is high, and the order of hydrophilicity is quartz > feldspar >spodumene. Correspondingly, contact angles and flotation recoveries of spodumene are bigger than that of feldspar and quartz in presence of a combined anionic and cationic collector named YOA.INTRODUCTION Flotation technology plays most important role for the recovery of spodumene from pegmatite ore. Generally, spodumene with fresh surface is easy to be floated using soap and oleic acid as collector, and the best flotation pH range is 4.0 to 9.0. However, the flotability of spodumene will become worse when its surface was polluted by slime which produced by the weathering of spodumene and other silicates (Dresler et al. 1998; Moon and Fuerstenau 2003; Menéndez et al. 2004; Yu et al. 2015). In addition, the species of Ca2+, Fe3+, Mg2+ and other metal ions in pulp can not only activate the flotation of spodumene, but also the activation of gangue minerals, and then the flotation selectivity of spodumene from gangue minerals became wores (Wang and Yu 2007; Yu et al. 2014). In order to eliminate the negative effects of slime and metal ions on the flotation of spoddumene, the desliming and long time scrubbing with the addition of NaOH and Na2CO3 were adopted. Usually, NaOH shows the activation for spodumene flotation, and the recovery of spodumene increases with the increase of NaOH dosage. Na2CO3 can eliminate the non selective activation of Ca2+, Fe3+, Mg2+ ions in the pulp, and the concentrate grade of spodumene increases with the increase of Na2CO3 dosage. Anionic collectors such as chelants, hydroxamic acid, oxidized paraffin soap, naphthenic acid and oleic acid were widely used for the flotation of spodumene (Dresler et al. 1998; Moon and Fuerstenau 2003; Menéndez et al. 2004; Yu et al. 2015)."

Jan 1, 2018

By Mingmei Zhu, Lang Hu, Yu Wang, Hongpo Wang, Congjing Zhang

Magnetic field has a great effect on the crystallization behavior of mold flux and properties of the flux film between mold and strand, on which the surface quality of strand was deeply depended in continuous casting process. Therefore, studying the change law of the crystallization properties of mold flux in magnetic field is of great significant. In the present work, based on intensity of the applied magnetic field with the range from 0mT to 60mT, the crystallization ratio, crystal size and mineralogical phases of the flux film were discussed. The results show that crystallization ratio increases with the increasing magnetic field intensity, and the crystal size becomes bigger at the same time. The magnetic field promotes the crystallization ratio and growth speed of the crystallized grains of mold flux. However, magnetic field doesn’t change types of the mineralogical phases.

Jan 1, 2015

By Zhang Qin

Dolomite is main impurity mineral in phosphate ores. In practice of phosphate ores production, the grade of concentrates is only containing P2O5 31-32%.In this study, even the increasing of floatation reagent consumption and decreasing of floatation recovery, economic performance is estimated high according to the decreasing of H2SO4 consumption in subsequent production of phosphate fertilizer and the increasing of products value. In floatation stage, influence factor include the synergism impacts of floatation collector, the stages, time, concentration of ore pulp, which were discussed respectively in this paper. Raw material is characterized by mineralogy, chemical analysis, the grain size analysis and milling test . The results show that the grade of concentration can reach to P2O5 36% by deeply de-magnesium oxide from phosphate ores by floatation , which yield a high added value.

Jan 1, 2009

By J. Chai, Y. Qiang, D. D. Zhang

"In order to control Quaternary loose layer settlement in East China, there are monitoring results based on the 3 water level observation holes and 7 sand layer of fiber Bragg grating (FBG) strain sensor. Un-der the conditions of upper group water injecting to lower group of loose layer, the deformation characteristics of upper, middle and lower group of loose sandy soil layer changing with time and relationship with the water level are studied. The constitutive relation of stress-strain is also studied at different sand layers. Research results show that using water injecting from upper group into lower group of loose layer can ease the loose layer compression deformation. With the water level dropped, in East China soil creep deformation occurred, which accord with viscoelasto plastic model. The deformation of lower sand group has clear later effect and no direct relationship with water level. The results provide an important basis for the study East China stratum settlement model and water management. INTRODUCTION Ground-surface subsidence is a common geological disaster, which has the features of continuous, changing slowly, concealment (Y.P. Yin et al. 2005). Today, due to underground mining and constructions in formation compression, surface subsidence is wide-spread in the world, which is the environmental geological problems in the worldwide that cannot be ignored (Y.Q. Xu et al. 2006, D.L Gallo-way et al. 2000, Qiu, B. et al. 2011). The eastern region of China has generally geological disasters in coal mine geological caused by the thick loose layer settlement like as mine shaft failure. Stratum dehydration consolidation is a major cause of loose layer settlement (H.Y .Liu et al. 2007). A method of water injection using ground water to stable water level is proposed, which can effectively control the loose layer caused by compression settlement(J. Chai et al. 2012&.2013). Accurately knowledge the characteristics of strata deformation is the premise of settlement management (Q.C. He et al. 2006). Previous re-search (J.F. Miu et al. 1996, X.Y. Gu et al.1998, Y. Zhang et al. 2006), mainly studies are focused condition of the city pumping irrigation, de-formation characteristics of middle and up loose layers. On a group of aquifer in East China, the loose layer losing water is caused by coal mining, bottom water drainage and overlying strata water flowing fractured zone hydrophobic induced by mining, which the dehydration conditions have great difference from one to another. The Position of water loss is centralized in bottom aquifer, and the formers of ground subsidence geological environment and settlement mechanism are different. According to the study of stratum settlement, usually the de-formation of sand layer is ignored(C.H. Liu et al. 2004), but few studies show that the sand layer have the plastic deformation, and contains the creep deformation, water content of sand soil may become the main settlement layer (Z.X. Wei, 2002, C.H. Liu et al. 2004)."

Jan 1, 2015

By Sun Chuanyao, Cao Fei, Sun Desi, Zhou Dezhi

"The research applies the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Density functional theory (DFT) was applied to investigate the electronic properties of O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) and O-isopropyl-N-ethyl thionocarbamate (Z-200). The calculation results show that both the energy of highest occupied molecular orbital (EHOMO) and the lowest unoccupied molecular orbital (ELUMO) of IP-BIAN are smaller than that of Z-200, electronegativity of IP-BIAN is higher than that of Z-200. According to the Klopman’s generalized perturbation theory, the collecting power of the two compounds is predicted to be Z-200 > IP-BIAN, the selectivity of IP-BIAN is better than that of Z-200. Then the thionocarbamate molecular is synthesized, and the compounds are characterized by nuclear magnetic resonance (NMR). It turns out that the test result identifies the prediction after the flotation verified test of pure mineral and actual mineral. The results demonstrate that the EHOMO and ELUMO are smaller in the thionocarbamate after a nitrogen atom is bound to benzyl, the thionocarbamate has strong selectivity and low collecting power. The lower the LUMO energy of thionocarbamate is, the stronger the back donation covalent p-bond between collectors and chalcopyrite is, thus improving flotation power for chalcopyrite and selectivity against pyrite. The result proves the feasibility of design and synthesis of the novel thionocarbamate through the frontier orbital properties of the collectors.1. INTRODUCTION Thiocarbamate is a kind of nonionic polar collector and is now widely used as flotation collector for copper-sulphur separation. The flotation power of thiocarbamate to chalcopyrite is stronger than pyrite, so it has high selectivity against pyrite. The frontier orbital theory and density functional theory (DFT) has been widely applied to study the structure-activity relationship of flotation collectors [1-6]. The flotation test results can be interpreted by using the reaction energy criteria and quantum-chemical parameters, such as the energy of the highest occupied molecular orbital (EHOMO) and the energy of the lowest unoccupied molecular orbital (ELUMO) of collector [7-11]. In turn, there are rarely reports about screening the novel flotation collector, by the frontier orbital properties such as HOMO and LUMO of flotation collectors. In this thesis, we apply the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Based on the previous findings of the structure-activity relationship of xanthogen formats [12], it has stronger collecting ability to chalcopyrite while the xanthogen formats after a nitrogen atom is bound to benzyl. Thus, in this study, a novel thionocarbamate molecule O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) will be constructed, when the group structure connected with N atom in the known collector O-isopropyl-N-ethyl thionocarbamate (Z-200) is replaced with ethyl by propyl. The collectors (IP-BIAN and Z-200) have been calculated by DFT methods in quantum chemistry. By analyzing the reaction energy criteria and the frontier orbital properties (HOMO and LUMO), this research predicts flotation performance of novel collectors (IP-BIAN), then the synthetic experiments and flotation verified tests are conducted. The research provides a new theory reference for screening out the high-effective flotation collectors of copper-sulphur separation. This technology adoption will contribute to the sustainable development of mineral resources as it shortens the research cycle of new collector molecules and reduces the investment."

Jan 1, 2018

Study on Desulfurisation and Deashing for Medium-High Sulfur Coal Using Shaking Table As important coal resources, medium- high sulfur accounts for a significant part of the coal reserve in China. The environmental regulations and fuel standard requires sulfur and ash to be removed before it is used, so as to save energy and decrease the emission. Therefore, the effective desulfurisation and deashing technologies are urgent needed. However, due to the local characteristics of the coal, specific technology with optimum operation parameters is required to develop for different local coal. Qinglong is a district of Guizhou Province, which has large medium to high sulfur contained coal reserve. In this paper, medium-high sulfur coal is sampled from Qinglong, Guizhou province. Some basic characteristics such as the mineralogical composition of the coal rock, the monomer existing state and the granulometric composition are determined by X-ray diffraction quantitative analysis and polarisation microscope analysis respectively. Adopting the classified feed method, shaking table tests show that the feed pulp concentration is 20 per cent, the stroke is 13mm, the frequency of the stroke is 380 per min, the cross slope is 3¦ and the volume of wash water is 5.2 L per min. Under such condition, aggregate processed coal yield is 72.87 per cent and sulfur content decrease to 1.31 per cent With shaking table technology of 'First stage rough and intermediate further fine benefication', the yield of concentrate coal increased from 72.87 per cent to 81.21 per cent, while the sulfur content reduced to 1.35 per cent.

Sep 13, 2010

By Wang Jingsong, Ma Tengfei, Feng Fu, She Xuefeng

In this paper the direct reduction melting separation-leaching process is investigated on recovering rare earth from rare earth Bayan Obo complex iron ore (REBOCIO). The REBOCIO was reduced and melting separated to produce iron nugget and rare-earth-rich slag at 1400°C for 12 or 15 min. The RE2O3 is enriched into Ce 4.667(SiO4)O or Ca 3Ce2[(Si,P)3O4]3F, which closely depend on chemical components, especially basic. The optimal acid-leaching parameters of rare earth elements from the rare earth slag are suggested as the hydrochloric acid concentration, the ratio of solid to liquid, leaching temperature, and the leaching time are 1 mol/L, 1:14, 50 °C and 120 min, respectively. The rare earth elements leaching efficiency are more than 95%. Adding of calcium CaCO3 and sodium Na2CO3 in direct reduction process have great in fluence on leaching ef ficiency of thorium.

Mar 1, 2018

By Zhucheng Huang, Zhikai Liang, Ronghai ZHONG, Lingyun Yi

In this work, research of reduction process was studied by means of rotary kiln (u1.5 m /C215 m) process anatomy in order to provide fine guidance to large-scale operation. It was shown that the average reduction degree of 89.96% and metallization ratio of 85.15% were obtained at the highest temperature of 977°C and total residence time of 90 min. The generation amount of metallic iron in section of temperature higher than 900°C and lower than 900°C was 34.15 and 56.38%, respectively. The section of lower temperature of 830–900 °C played an important role in formation of metallic iron, making it possible for mini-pellet to reduce quickly at lower temperature. Two main tasks were completed for mini-pellets in rotary kiln: the reduction of iron oxides in the range of 15.0–4.5 m as well as migration and bene ficiation of metallic iron, facilitating the subsequent separation of iron and gangue minerals.

Mar 1, 2018

Study on Dynamic Characteristics of Inertia Cone Crusher and Its Application

Sep 13, 2010

By Yongquan Zhu, Zhengguo Zhu, Zhichun Liu, Chao Kong, Xinqiang Gao

"The aim of the study is to have a good understanding of the change in the seepage field during and after the tunnel excavation in weathering alteration rock. Field tests are used to monitor the changes of the water table and the numerical model is used to analysis the influence of the seepage filed with different operation conditions during and after the tunnel excavation. Results indicate that the depth, diameter and pumpage of precipitation well are the main factors that have a great influence on the drainage effect. Results also indicate that different operation conditions had various effects on the decrease in water yield during tunnel construction and the recovery in groundwater level after construction.INTRODUCTIONAs a potential disease during tunnel construction, Gushing water not only affected construction schedule, increased construction cost, as well as affected tunnel stability and safety during operation, but also decreased ground-water level. What’s more, the fall of water table caused by gushing water in tunnel would have influenced surrounding residents’ living water, agricultural water and ecological environment around tunnel. In recent years, enough emphasis has been paid to the influence on environment due to the construction of tunnel as a result of the reinforcement of people’s environmental protection awareness.As a result of water collection and drainage after excavation, groundwater was discharged into the tunnel, which caused a loss of water resources in the adjacent mountain mass. Furthermore, during tunnel operation, it was difficult for groundwater level to resume its original condition, which caused a bad ecological environment, because drainage system during tunnel construction destroyed its original hydrologic dynamic balance.In order to study whether decreased groundwater level resulting from tunnel construction could be restored during operation to its original condition, this paper gave a field monitoring on tunnel displacement during construction and simultaneously, generalized model of regional hydrogeology was created according to field hydrogeology to carry out a calculation of stable seepage flow and draw comparisons between recovery conditions of various water levels."

Jan 1, 2015

By Li Ma, Shaoguo Chen, Gele Qing, Qihang Liu, Keng Wu

Olivine contains higher MgO element, which can be added into blast furnace burden to improve slag stability and fluidity. Effect of calcined olivine and untreated olivine on low silicon pellet production process and quality was studied in this paper. The results shows, calcined olivine has no effect on bursting temperature of green pellet, however the bursting temperature of green pellet will decrease with increase of untreated olivine ratio. Untreated olivine has slight effect on green pellet strength than calcined olivine while the ratio is higher than 2%. The compressive strength of low silicon pellet will increase first and decrease afterwards with increases of calcined olivine ratio under firing temperature of 1250°C, whereas, the changing sequence is reverse fired under 1280°C. The result of untreated olivine pellet compressive strength is same as calcined olivine pellet. However, the compressive strength and metallurgical property of calcined olivine pellet is slightly higher than that of untreated olivine pellet under same condition.

Jan 1, 2015

By T. X. Hu

Pyrite ore is one of the main raw materials in the production of sulfuric acid. For a long time, the raw material containing the pyrite, which is used to produce sulfuric acid, generally contains S only 32%~45%. A plenty of residue from the sulfuric acid production contains 40%~50% Fe and 1%~2% S. Some of the residue also contains Cu, Pb, Zn and other harmful elements like As, thus it pollutes environment seriously and is solid waste. The research on comprehensive utilization of the residue has been made by many scholars. Through the study, the residue can only be used to pro-duce iron concentrate and the iron oxide red pigment. But because of the complex techniques, the low recovery, the low grade of iron concentrate , high sulfur in iron concentrate, causing second waste residue and the environmental pollution, the residue is mainly used as an accessory material in the production of cement, and is of a low value. Therefore, the iron resource in pyrite has not been used efficiently until now. In the paper, the flotation condition test, the flotation open circuit test and the flotation closed circuit test to produce high-purity pyrite concentrate with the low-grade pyrite ore in oceanic ore deposit have been carried on. Flotation reagent scheme of sulfuric acid used as activator and butyl xanthate as collector is determined. After four times depth cleaning, high-purity pyrite concentrate containing 52.82% S, 44.29% Fe, and only 2.89% impurities has been obtained. The S recovery is 99.13%, and the Fe recovery is 96.00% in the high-purity pyrite concentrate. The oxidizing roasting depth desulfurization experiment of the high-purity pyrite concentrate has been conducted. The results show that the Fe grade in the residue obtained is 68.58%, the content of S is 0.25%, the content of P is 0.0084%, the content of As is 0.0065%. The residue is a kind of high-quality iron-smelting raw material. Based on the above experiments, the industrial experiments on producing high-purity pyrite concentrate with the low-grade pyrite ore, and producing sulfuric acid and iron concentrate with high-purity pyrite concentrate have been done. The results indicate that the high-purity pyrite concentrate with the S grade of 51.24%, the Fe grade of 44.15% has been obtained. The iron concentrate obtained with 65.73% Fe and 0.23% S is a sort of high-quality iron-smelting raw material applied to the production of steel and iron smelting. Through the experimental study, the sulfur and iron resources in the pyrite ore have been recovered and utilized efficiently.

Jan 1, 2014

By Jing Zhan, Tian-zu Yang, Wei-feng Li, Li-Hua Jiang, Shi-yan Xu, Jian-yang Huang, Chuan-fu Zhang, Yan-qing Fan

The amount and activity of coal, reduction temperature and other parameters of the process of bottom-blown reduction of liquid high lead slag were investigated in laboratory. Methods to strengthen the bottom-blown reduction process were studied by industrial production. The results were in the follows: the reduction temperature was 1150℃; reduction time was 1.5h; the reductant was anthracite; lead content in slag was controlled to 2%; the rate of coal was 7% and gasification loss of coal in high temperature was severe; liquid lead slag reduction rate was faster with coal; prolonging the reaction size had little effect on reducing lead in slag; the size of the reactor can be further reduced.

Jan 1, 2015