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By S. N. Monteiro, N. A. Cerqueira, E. B. Zanelato, J. Alexandre, M. T. Marvila, B. C. Mendes, A. R. G. Azevedo, G. C. Xavier

Mortar is a widely used building material and has its application in buildings in extremely vulnerable environments and susceptible to degradation, such as facades. The objective of this work was to evaluate the loss of mechanical resistance to compression and flexure and the loss of mass of the mortars with effluent sludge from paper industry, when exposed to saline environments. The specimens were done with 0, 5, 10 and 15% of incorporation in lime paste and subjected to saline mist equipment that sprays salt solution in cycles simulating natural degradation conditions using literature data. It can be concluded that mortars with a15%incorporation obtained a significant loss of mass and a decrease in their mechanical resistance, which impairs their use in civil construction and influence in other properties of the material, with a level of incorporation of 10% the results within Brazilian standards.

Mar 1, 2018

By Namavari. H., M. Ashouri, M. R. Sarhadi, S. H. Mansouri, A. Sarrafi

The splash phenomenon and its effective parameters in metallurgical converters have been studied thoroughly for decades. The detailed studies of processes such as tuyere blockage, wave formation during air injection, entrapped phases, and also processes which control the formation of bubbles in viscous fluids are not feasible yet. In this research, we have used a converter-shaped vessel made of flexi-glass. Water and oil have been used as matte and slag phases respectively. The effective operational factors responsible for creation of splashing have been studied such as air flow rate, tuyere angles, depth of tuyere submergence, tuyere blockage, density and viscosity of liquids, liquids heights, etc. The results have been found as follows: the amount of splashing increases slowly as air flow rate increases. However, as the air flow rate reaches a critical value (depending on the physical specification of converter) the amount of splashing rises sharply, because the flow of air inside the liquid changes from bubbling into a jet stream; and most of the splashed materials are in the form of filaments instead of droplets. Changing tuyere angle from horizontal towards vertical position will increase the turbulence level on the fluid surface and causes an increase in the amount of splashing. The effect of tuyere submergence is related to the converter opening angle. As the converter opening angle is shifted towards the hood position, the amount of tuyere submergence and splashing will increase. As density of the liquid increases, the number of droplets splashing increases with a decrease in drop size. Therefore, the total amount of splashing decreases. However, as viscosity of the liquid increases, the splashing material increases due to the changes in the splashed material from droplet shape into filament form. The height of liquid inside the converter, depending on the relative height of heavy phase and light phase, is an important parameter regarding splashing. As the relative height of heavy phase to light phase increases the splashing will decrease. The tuyere blockage will cause the pressure in the inlet manifold to increase; and in real cases will increase the splashing. Finally, we have development a model based on dimensional analysis to relate the above parameters in order to calculate the amount of splashed material.

Jan 1, 2007

By Ji-He Wei

The ESR of Cu-Cr-Zr alloy has been experimentally investigated. The remelting experiments have been carried out with different slag fluxes in the Cal, + Nal, CaF2 + ZrO2 and CaF2 + NaF + ZrO2 systems on an ESR furnace of 25kg capacity; using a water-cooled copper mould of 96.5 mm diameter, with the forged square bar electrodes of 50x50 mm2. The slag amount was taken to be 1.5 kg. The remelting current and voltage used were 1600-1800A and !5-25K, respectively. The influence of the slag composition on the stability of the remelting process and the losses of alloying elements (2r and Cr) has been considered and examined. The technologies of hot working and heat treatment of the ES ingot have been described and discussed. Some physical properties of the slag in a CuF2 + NaF + ZrO2 system and the remelted Cu-Cr-Zr alloy have been determined. The results indicated that with the slag flux of CaF2 + NaF + l0 mass % ZrO2 and the other operation parameters employed, a high quality ingot of Cu-Cr-Zr alloy may be obtained at the considerably high yields of Zr and Cr by means of ESR. For the remelted Cu-Cr-Zr alloy with a specified composition of 0.5 mass % Cr and 0.1 mass % Zr, the appropriate electrical conductivity, hardness and softening temperature are as high as 45-46S/m, HRB 82-84 and 550°C. respectively. The properties of the Cu-Cr-Zr alloy products are in accordance with and superior to the requirements and specifications of ISO5l82-l99l(E).

Jan 1, 2000

By Chengguo Zhang, Bruce Hebblewhite, Faham Tahmasebinia, lsmet Canbulat

"Coal burst is a dynamic release of energy within the rock (or coal) mass leading to high velocity expulsion of the broken/ failed material into mine openings. This phenomenon has been recognised as one of the most catastrophic failures associated with the coal mining industry, which can often lead to injuries and fatalities of miners as well as significant production losses. This paper aims to examine the mechanisms contributing to coal burst occurrence, with an emphasis on the energy release concept. In this study, a numerical modelling study has been conducted to evaluate the roles and contributions of difference energy components. The energy analysis presented in this paper can help to improve the understanding of energy release mechanisms especially under Australian conditions.INTRODUCTIONCoal burst is one of the most hazardous problems encountered in underground coal mines, which occurs at different locations in a variety of mining systems and operations. This phenomenon always involves a violent and dynamic energy release with large rock mass/coal deformation and ejection that can cause severe damage to openings, equipments and may result in fatalities and injuries.The first coal burst occurrence was reported in Britain in 1738 (Dou 2001). Since then, international experiences are available in Canada, South Africa, USA, former Soviet Union, China, India, France, Germany, Poland and Czechoslovakia. Rice (1935) classified coal bursts as two general types, namely excessive pressure bumps and shock bumps and he further mentioned that pressure bumps are caused when pillar stress exceeds bearing strength. Shock bumps are induced by the breaking of thick, massive strata at a considerable distance above the coal-bed, causing the immediate roof to transmit a shock wave to the coal."

Jan 1, 2016

By Yushuai Xian, Youjun Tao, Fangyuan Ma

This study compared particle size distribution and density distribution of crushed products for waste printed circuit boards (WPCBs) before and after heat treatment. The crushing process for heat-treated WPCBs is a selective crushing process; more metal is concentrated in the coarse particle range of 1.0–0.5 mm and high density range of 2.8–2.96 g/cm3. WPCBs were separated using the Falcon separator to recycle useful metals. The Box-Behnken module of Design-Expert was used to obtain optimal separation parameters, namely, rotational frequency of 25 Hz, recoil water pressure of 0.025 Mpa and feed speed of 34 ml/s. On this basis, the separation indexes for WPCBs with and without heat treatment were compared. Experimental results show that the recovery effect is better for heat-treatedWPCBs than for thosewithout heat treatment. Comparedwith the non-heattreatedWPCBs, the product grade of heat-treated WPCBs is 1.95% higher, and its recovery is improved by about 14%. Finally, characteristics ofWPCBs before and after heat treatment were analyzed on the basis of stress experiments and scanning electron microscopy (SEM), respectively. Results of mechanical characterization indicate that the stress experiment for non-heat-treated WPCBs has a maximumpressure load of 212 N and displacement of 20mm, but heat-treatedWPCBs only need 140 N stress and 14 mm displacement. SEM shows that copper foil and fiberglass cloth are deformed in different directions and sizes after heat treatment to form gaps, which promote liberation of copper foil and fiberglass cloth.

Sep 10, 2020

By L. B. Tsymbulov, N. A. Fedorova

The equilibrium of exchange reaction (Cu20)+[Ni]=(Ni0)+2[Cu] taking place in the course of interaction of metallic nickel-containing copper melts with different oxide melts (Cu20-NiO, Cu20-NiO-Si02, Cu20-NiO-FeO(Fe203)) in the area of their homogeneity has been studied. The studies, based on the known value of equilibrium constants and defined copper and nickel activity indices in metallic melts and equilibrium concentrations of Cu, Ni, Cu20 and NiO, determined the YNio/ycu2o ratios in the oxide melts of the above systems. For the equilibrium between nickel-containing copper and binary oxide melt Cu20-NiO, values of YNiO and Ycu2o were determined both by calculation and experimentally. Based of the data conclusions regarding oxide melts construction are presented.

Jan 1, 2007

By D. R. Bomberger

An automatic microscope has been developed to .measure the size and populations of macerals and minerals in fine coal particles. Differentiations are made on the basis of reflectance. This study is concerned with the size distribution of pyrite inclusions. Most fine coal cleaning processes do not remove pyrite as completely as a straight density separation. Consideration of the pyrite size distribution is suggested as a more accurate method of predicting sulfur reduction by a cleaning process. Analyses of float-sink results and Deister Table operation in terms of pyrite particle sizes are made. Other potential applications of automatic microscopy are also discussed.

Jan 1, 1963

Lignite is a kind of easy-to-slime and low rank coal. It is hard to be separated by the conventional wet coal beneficiation technologies. Meanwhile, in recent decades, a large amount of fine coal (-6 mm) is generated as the mechanized mining technology has been progressively deployed in coal sector, which causes a great difficult for lignite beneficiation and upgrading due to lack of efficient technology available. In this paper, a vibrated gas-fluidized bed was used to separate the -6 mm fine lignite particles. Separation experiments of -6+3 mm and -3+1 mm lignite were carried out in a laboratory-scale vibrated gas-fluidized bed. The effects of several parameters including the superficial air velocity, vibration intensity, bed height and exterior moisture content on the separation performance were experimentally studied. The results show that the optimal separation performance was achieved when the superficial air velocity is 0.3, the vibration intensity is 1.4, the bed height is 50 mm, the exterior moisture content is below 4% (-6+3 mm) and 2% (-3+1 mm). And the probably error E values of -6+3 mm and -3+1 mm size fraction of lignite are 0.202 and 0.225 respectively. The results indicate that a vibrated gas-fluidized bed can provide an effective solution for -6 mm lignite separation.

Feb 23, 2014

By Esperidiana A. B. Moura, Elizabeth Carvalho L. Cardoso, Glauson Aparecido F. Machado, René R. Oliveira

Plastics global annual production exceeds 250 million tons and more than 40% of the total plastic production is used as packaging materials. In recent years polymeric materials derived from biomass have received great attention due to scarce petroleum resources and environmental concerns. PLA is one of the most extensively studied bio-based and bio-compostable aliphatic polyesters; nevertheless, high brittleness and low toughness limits its application. Blending PLA with PBAT (Poly(butylene adipate-co-terephthalate)), an aliphatic-aromatic copolyester, was the solution found due to its high toughness and biodegradability. Differences between PLA and PBAT solubility parameter values lead to the formation of immiscible blends as well as reduction in their mechanical performance besides a poor morphology; so, 5% of pre-irradiated PLA and a previous compatibilized PLA/PBAT (EcovioTM) were added to PLA/PBAT blends in order to improve miscibility phases. Investigations were accomplished on phase morphology (SEM), mechanical properties, thermal behavior and X-ray diffractions (XRD).

Mar 1, 2017

By J. Quinteros-Riquelme

Despite increasing demand, the supply of silver is limited by its inadequate recovery from ores. Due to its scarcity in nature, its high ore variability and complex mineralogy of current silver deposits, its recovery by mineral froth flotation presents a real challenge for process engineers. A silver ore often contains significant amounts of five to ten different silver minerals and knowledge of the mineralogy is a necessary precursor to flotation testing. In this work, a complex silver ore was treated by using batch laboratory flotation, in an effort to find the best experimental conditions to obtain the optimal silver recovery. Mineralogical characterization of feed samples was conducted using a combination of tools, namely the mineral liberation analyzer (MLA) and inductively-coupled plasma mass spectrometry (LA-ICP-MS), which indicated that most of the silver occurred as ?invisible? silver in pyrite. The pyrite assay of the ore was approximately 4%. The ore was processed in two flotation stages. The first stage, sulphide flotation, aimed to collect a sulphide mineral rich concentrate; then a non-sulphide flotation stage was performed by adding sodium sulphide and collectors to the remaining material in the cell, with the objective of obtaining a pyrite rich concentrate. To reach the target recovery of silver from this ore, various variables were altered. In the first stage: mixed collectors, activators, dispersants, and mainstream inert grinding were assessed. In the second stage, the conditions for sulphidization and subsequent flotation were both investigated. From the grade recovery curves for silver and sulphur it was possible to observe a similar metallurgical behavior for both elements, supporting the results given by the mineralogical characterization. Keywords: silver oxide, froth flotation, sulphidization, mig

Sep 1, 2012

By A. Haldar

The major problem encountered in the casting of hypereutectic Al-Si alloys is the stoppage of flow below the rigidity level of solid fraction. In this study, the flow stoppage mechanism was studied using three Al-Si alloys with 14%, 18% and 22% silicon. The horizontal foam patterns used were 12.50 mm (0.50 inch) wide with two section thicknesses 12.50 mm (0.50 inch) and 6.25 mm (0.25 inch) with a common sprue. The primary silicon distribution along the length of the casting was studied to determine the mechanism of flow stoppage. It was found that the surface of the flow tip of Al-14%Si alloy was smooth with a few undulations. As the silicon level increased, undulations at the flow tip increased. The number and size of undulations were maximum for the Al-22%Si alloy. Microstructural analysis using optical image analyzer revealed that the flow tip consisted mainly of eutectic silicon in the aluminum matrix and a few primary silicon crystals (PSC). The PSC were in the interlocked condition few centimeters behind the flow tip. It was also found that the gap between the flow tip and the PSC concentrated area increased with an increase in silicon level. Phase characterization was done with SEM-EDX to identify the precipitating phases.

Jan 1, 2007

By A. Wahab Khair

"This paper presents an analysis of fracture mechanisms in coal subjected to bi-axial state of stresses, indentation of laterally confined coal specimen. Coal specimens were loaded to failure by the straight wedge indenters at various lateral confinement pressures. Strain distribution and acoustic emission characteristics of coal specimens under stress were recorded. The influence lines of vertical forces acting on the horizontal straight boundary of the coal specimen for each type of wedge indenter have been established using holographic interferometry technique. The effects of wedge indenter angle, confinement pressure, and coal anisotropy on fracture types, failure modes, and post-failure conditions were studied. The results indicated that combined application of holographic interferometry and acoustic emission monitoring techniques is not only suitable ·for studying deformability of heterogeneous and microscopically discontinuous material under stress but it also enhances the mode of fracture during the post failure stage. INTRODUCTIONOne of the relevant processes in the coal cutting technology is the application of indentation theories. Since most cutting tools in the coal industry are wedge shaped most of the indentation research is found for a wedge shaped tool.A wide range of behavior is found in different rocks subjected to the wedge penetration. A rock which is elastic brittle at standard pressure might become elastic plastic at high confining pressure (Gnirk and Cheatham, 1963). It was also observed that some rocks will merely be crushed and indented by a wedge whereas others will crack and form chips, furthermore the existence or non-existence of chips depends mostly on the geometry of the indenter, type of rock and the depth of penetration (Evans and Murrel, 1958). However, coal cutting technology is mostly explained by models which use rigid wedge to penetrate into a brittle material in which both crushing and chipping will occur (Evans and Murrel, 1958, 1962)."

Jan 1, 1988

By D. Watson, T. J. N. Grainger-Allan

A technique for studying the mechanism of the froth flotation process in which continuous froth removal does not take place but, instead, an equilibrium is reached between froth and pulp is described. A flotation cell, specially designed to facilitate equilibration, and froth and pulp sampling procedures are described. The main advantage of the technique is that the ability to measure the steady-state froth height allows froth-stability effects to be separated from pulp-process effects. In the flotation of hematite front quartz, linear relationships are found between airflow rate and froth height and between airflow rate and the ratio at equilibrium of mass of values in froth to mass of values in the pulp. A simple mechanistic interpretation of these results is given. It is suggested that froth-stability effects may play a more important role than hitherto allowed. In particular, the way in which concentration and size distribution of gangue particles may affect overall flotation rate is shown.

Jan 1, 1975

By Mani Manimaran, Inna Dymov, Mariam Melashvili, Chris Fleming, Joe O’Day

This paper presents experimental evidence that supports the use of bromine/bromide as a potential alternative to conventional cyanidation for gold leaching. The study evaluated a brominebased lixiviant, Stabilized Bromine, with considerably lower vapour pressure than liquid bromine. Using a rotating device, the rate of gold dissolution was determined at various concentrations of this reagent. The reactivity of pure pyrite, arsenopyrite and chalcopyrite minerals was also evaluated in stabilized bromine reagent. Furthermore, bromine leaching of gold in a number of gold bearing ores was undertaken. Results showed that significantly higher gold recovery can be achieved with bromine than with cyanide when leaching gold encapsulated in sulphides, but bromine consumption was high owing to simultaneous oxidation of the sulphides. The greatest promise for the bromine leach process was with oxidized gold ores. The recovery of gold from oxide ores with bromine was comparable to that achievable with cyanide and bromine consumption was reasonable when leaching was conducted at a near neutral pH of ~6. In the case of oxidized gold ores containing copper mineralization, it is possible that bromine consumption may be lower than cyanide consumption, since there is evidence to suggest that bromine is less reactive than cyanide with copper minerals.

Jan 1, 2014

By Larissa Agrizzi Ronqueti

The effect of coiling temperature on selective oxidation behaviour of binary and ternary iron-based model alloys containing different contents of Si or Mn were investigated by SEM and SIMS. The experiments were carried out with a temperature ranging from 450 °C to 700 °C, under N2-5%H2 gas flow with a Dew Point of -3.3°C, for different durations. SEM images of binary iron-based model alloys revealed a decrease of grain boundary oxidation depth with increasing Silicon or Manganese content. At 530°C and 600°C SIMS results showed no Silicon diffusion toward surface, contrary to the results analyzed for Fe-x%Mn. Tests results and Wagner’s theory application (specific cases Fe-0.2%Si and Fe-0.5%Si) showed that grain boundary oxygen diffusion coefficient “DoGB” is almost 60 to 70 times faster than oxygen bulk diffusion coefficient. These results helped to broaden knowledge of single-element effects on grain boundary oxidation, in addition, will contribute of the future works in new steels with complex alloy compositions.

Aug 17, 2017

By Suresh Chikati, Gangadharan Santhanam

Twin tunnels were constructed to a length of 863m using TBM in one of the underground metro projects. The tunnels pass through complex geological conditions (soil, rock and mixed conditions). This paper presents the consideration of volume loss and the corresponding ground settlement associated with the excavation of twin TBM tunnels by analytical and numerical methods. Empirical methods were used to calculate the ground settlement induced by the excavation of twin tunnels. The ground settlement values were directly derived from the two parameters: the volume loss and trough width parameter. These parameters are calculated based on the geological conditions at the tunnel face and tunnel overburden. The finite element software, Plaxis 2D was used to model the soil parameters with appropriate geological conditions. Twin tunnel excavation is simulated in Plaxis 2D and the effect of tunnelling on the ground was simulated by percentage volume loss. The suitable line contraction value was applied to the tunnel linings to simulate the volume loss. The surface ground settlement was directly obtained from Plaxis 2D. Instrumentation arrays were proposed along the twin tunnel alignment, to provide the ground settlement monitoring data within the influence zone of tunnelling activities. The derived ground settlement values from analytical and numerical methods were compared with the actual field instrumentation and monitoring data. From the field instrumentation data, the actual volume loss values were calculated. The compatibility of ground settlement and volume loss calculated using analytical and numerical methods and those measured using field instrumentation data is discussed in this paper.

Sep 1, 2022

By Jiwei Duan

The energy transferred from a hammer to the pile top is considered as the effective energy in this paper. The effective energy is related to the pile dimensions, soil and pile-soil interface properties. This relation may be expressed as an equation based on the dimensionless theory. The relationship between pile capacity and effective energy was studied by performing a series of wave equation analyses using a commercial software called GRLWEAP (Wave Equation Analysis Program) by GRL Engineers, Inc. The results show that the pile capacity increases with the blow count when the effective energy is constant, however, it has a little change as the blow count is over 100 blows per foot. The pile capacity decreases as the ratio of pile penetration depth to pile diameter increases if the effective energy is constant. The pile capacity will increase as the pile diameter and wall thickness increases if the effective energy is constant. The pile stickout (pile length above the ground surface) does not have a significant effect on the effective energy and may be neglected. Curves for pile capacity versus effective energy are presented to be used for preliminary hammer selection according to effective energy and hammer efficiency. Finally, a case from PDA testing was studied. Measurements of the effective energy and pile capacity by CAPWAP were presented and compared with the results by GRLWEAP.

Jan 1, 2006

By Xinhua Wang, Xuefeng Liu, Die Yang, Lifeng Zhang, Wen Yang

"CSP thin slab continuous casters are well used in recent years. The control of heat transfer in the mold is very important because it is correlated with several slab defects. The mean heat flux of CSP mold was studied based on the plant production data of LCAK steel and weathering steel. The effect of various operation conditions on the heat flux was analyzed and discussed. The results showed that the heat flux was 2.1-2.6 MW/m2 on the wide face and 1.2-2.2 MW/m2 on the narrow face for the casting of LCAK steels. During the casting of weathering steel, the heat flus was mostly 2.05-2.5 MW/m2 on the wide face and was 1.1-1.8 MW/m2 on the narrow face. The heat flux depended largely on the casting speed. The heat flux on the wide face increased obviously with increasing casting speed when the casting speed was relatively low; however, at high speed, the heat flux increased slowly or kept constant. At low casting speed, the heat flux depended little on the superheat of the molten steel. The mean heat flux depended little on the level fluctuation at continuous casting mold.IntroductionCSP thin slab continuous casters are used more frequently in recent years for its low cost of construction and manufacturing. The structure of CSP mold is very different from that of conventional thick slab casting mold, inducing the difference of heat flux between them. There have been some studies about the heat flux of thick and medium slab casters [l, 2]. Heat transfer in the mold is very important for the solidification of molten steel because it is correlated with several slab defects such as slab break-out, longitudinal crack, and surface depression. Moreover, higher casting speed is desired to improve the productivity. The control of solidified shell is extremely important. The heat flux is largely influenced by several casting parameters such as the cooling intensity of the mold, the casting speed[3], the mold flux powder [3, 4] and the carbon content of steel as well [5]. The investigation on the heat flux and affecting parameters can help to understand the solidification of molten steel in the mold."

Jan 1, 2013

By Fumihiko Sumiya, Shinya Tanaka, Yukio Kato, Kenji Tanaka, Tetsuya Sawada

When explosives are heated under an acidic environment due to metal sulfide and sulfuric acidity, their decomposition temperature falls remarkably and decomposition reaction occurs quickly, and then explosives have the risk of the deflagration to the detonation transition. Heat resistant commercial explosives which can be used under conditions of high temperature of 200ºC and an acidic environment were studied. We developed the explosive composition consisted of ammonium perchlorate (AP) as oxidizer, saturated hydrocarbon oil as fuel and binder, and calcium carbonate as decomposition inhibitor. The characteristics of this explosive composition show a heat resistance over 24 hours at 200ºC, and a detonation velocity over 2,500 m s-1. This explosive composition has a cap-sensitivity at temperature higher than 100ºC. Cost effective heat resistant commercial explosives were created by the optimization of the grain size of AP as a main component, the addition of saturated hydrocarbon oil and calcium carbonate, and the control of bulk density by the addition of micro-balloons.

Jan 1, 2003

By Denise Corrêa de Oliveira

Common dry batteries use zinc as the negative electrode. Producers commonly use additives such as mercury to prevent corrosion and to increase the mechanical resistance of the zinc anode. Alkaline batteries also contain it, as an anti-corrosive agent. When mixed with the common municipal solid waste, heavy metals as zinc and mercury pollute soil and ground water supplies, moving to the food-chain and affecting human health. Due to these possible damages, this kind of waste must be properly disposed, or recycled. Thus, even in low amounts (ppm) in batteries, mercury has to be eliminated or, at least, its content should be reduced. This work presents the use of pyromettalurgical processes, to reduce mercury content and recover zinc. The tests involved batteries treatment at temperatures from 300° to 1000°C. Mercury is eliminated up to 650°C, and zinc is evaporated at higher temperature treatment. C

Jan 1, 2001