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By Y. Huang

Corrosion of GaAs in aqueous electrolytes is a major limitation in implementing GaAs-based photoelectrochemical solar energy conversion systems, In this work, the corrosion behavior was investigated by electrochemical methods and surface analysis approaches, in both H2SO4 and NH3?H2O solutions, Open-circuit measurements showed that the cleaned GaAs surface was very sensitive to water/air, Impedance measurements for n-GaAs showed that an inductive loop only appeared at a high corrosion rate because a reaction intermediate is the oxidant for a further decomposition step in combination with chemical reaction with water, The results suggest that the same corrosion/decomposition mechanism occurred on n-GaAs in the two solutions, When the surface-hole concentration was low, the hole injection or generation process was the rate-determining step, At large reverse bias on n-GaAs, with high-hole concentration, the corrosion rate was limited by a Faradaic adsorption process, involving an adsorbed intermediate, The different surface compositions after corrosion in the two solutions can be explained by the dissolution of As(0), Further oxidation of As(0) to As(III) in NH3?H2O solution is still slow, as suggested from X-ray photoelectron spectroscopy (XPS) analysis,

Jan 1, 2005

Gas-liquid contacting in the packed bed is a common operation in metallurgical reactors. Research has shown that, unlike wetting flow, non-wetting liquid flows in the form of discrete droplets or rivulets. Thus, modeling of the liquid phase as a continuum is in contradiction to the observations. Also, for the non-wetting case, continuum models have failed to describe liquid flow path when the liquid source is a point source. The aim of the current work is to put forward a combined Lagrangian-Eulerian approach to model the liquid and gas flow in the packed bed. Liquid is assumed discrete and modeled using a force balance approach. Gas is assumed to be interpenetrating continua and modeled using k-emodel for turbulent flow. Structured packing is assumed and x- ray imaging technique is used to visualize liquid flow lines in the bed. Simulation results for liquid flow path compared with the experiments.

Jan 1, 2006

By Chen Song

In the experiments of purifying the solution of chlorine leaching from nickel concentrate with N235, the effects of organic phase composition on purifying efficiency have been studied. From the results obtained, the optimal organic phase composition is found to be 25%N235+12%isomerous alcohol +63%sulfonic kerosene (VIV) and the saturated content of cobalt in organic phase is7.95 g*dm3. And then the serial experiment is carried out. The results show that at the given organic phase composition, the purified solution contains p(Ni) >200 gm dm3, p(Ni)l p(Co) >50000 and the contents of Cu, Fe, Mn, Zn meet the technical criterion of standard nickel electrolyte. The cobalt chloride solution contains p(Co) >I10 g L-1, p(Co) lp(Ni)>50000 and the enrichment of cobalt has been achieved.

Jan 1, 2006

By Jin Liu, Torstein A. Utigard

At its Copper Cliff Smelter, Vale Inco Limited processes a bulk copper-nickel concentrate in two Inco oxygen flash furnaces. Coke supplies a minor proportion of the process heat requirements, limiting the flash furnace matte grade to the target 45% CuNiCo. Coke addition to the furnace offers a potential means of establishing a reducing barrier on the surface of the molten bath. Such a practice would be conducive to producing sulfur deficient (partially metallized) matte. At the same iron content, the iron activity of sulfur deficient matte is higher than that of regular matte. A supernatant coke barrier could, therefore, be expected to lead to higher nickel and cobalt recoveries, reduction or even elimination of magnetite furnace bottom build-up and increased sulfur elimination as SO2 in the flash furnace. Extensive experiments were conducted in a miniplant flash furnace to investigate the effect on process metallurgy of the suggested modified scheme. The introduction and description of the experimental set up were given in Part 1 of this paper and an early paper published in Yazawa symposium1 together with the results and some in depth discussion on metallurgy. This paper intends to discuss the kinetics of the miniplant flash furnace testwork.

Jan 1, 2015

By Alok Tripathy

A simulation code called SIMJIG and the user interfaces have been developed using discrete element method (DEM) and the .NET platform respectively for the jigging process. DEM platform is used for tracking of particles in the jigging operation. DEM uses the net force balance on the particles to track the trajectory of the particle. Simulation results are compared with experimental results obtained by jigging of low grade iron ore lumps. Two different iron ore samples one from Chatishgarh and one from Odisha were used for the experimental studies. The Alljig? stratification test rig meant for batch laboratory experimental studies has been used in the present work. The behavior of different sizes of material on jigging has been examined. Later, the particle size behavior during jigging at different layers of the jig bed has been studied. Further stratification profile across the jig bed has also been studied. It was observed that simulation results are matching quite nicely with the experimental results. The SIMJIG simulator developed in the present study could be used for predicting the performance of the jigging operation effectively. Keywords: DEM, gravity concentration, jigging, iron ore, simulation

Sep 1, 2012

By Polezhaev S. Yu, I. V. Ukraintsev, Boduen A. Ya, Saburbayeva L. Yu

"Comparison studies of different technologies are performed when selecting optimum option for gold ore and concentrate processing. Methods of ultrafine grinding, oxidizing roasting, bacterial leaching and pressure oxidation are used to extract gold from refractory ores and concentrates. Refractory gold flotation concentrate produced from pyrite-arsenopyrite ores of Bestobe deposit is a case study in this paper. The results of the experimental tests of the direct leaching of flotation concentrate and pre-oxidation products using different methods (oxidizing roasting cinder, pressure oxidation and bacterial leaching cakes) are the following: - cyanidation of original flotation concentrate provides recovery of Au at 46.6 %; - oxidizing roasting increases gold recovery from 46.6 % to 85 %; - BIOX increases gold recovery up to 86 %; - preliminary pressure oxidation of flotation concentrate ensures steadily high Au extraction in the follow-up cyanidation at 94.9-96.5 %. Pressure oxidation and bio-oxidation has changed dramatically the strategy of refractory gold ore processing. These solutions provided for development of ore deposits that considered earlier non-commercial. However, refractory ore processing has a complex character in terms of developing process flowsheet and requires large amount of studies to be performed for each new project. Gold extraction is the basic but not the only criteria to technology selection for gold ore and concentrate processing. Opex and capex, ore reserves, regional geography, developed infrastructure and skill personnel should be considered. Process studies and feasibility study of the developed technology shall be provided for each specific gold ore deposit. INTRODUCTION Due to changes in available feedstock and depletion of easy-to-process ores, refractory ores containing finely disseminated gold and silver in sulphides (primarily, in pyrites and arsenopyrites) are more and more involved into processing. Experts say that such ores amount above 40 % of the world’s gold reserves. Conventional technologies of gold extraction from refractory ores include flotation, roasting and cinder cyanidation (Fraser etal., 1991). However, today’s best available practice for refractory gold ore processing are bacterial (BIOX) and pressure (POX) oxidation."

Jan 1, 2018

By A Crosky, S Saydam, H Chen, H L. Ramandi

Cable bolts and rock bolts are used as primary and secondary anchoring systems in many underground mines. Reports on the premature failure of cable bolts and rock bolts due to stress corrosion cracking (SCC) in underground coalmines have been increasing in the past two decades. The previous studies found that the SCC in both rock bolts and cable bolts occur as a consequence of atomic hydrogen diffusion into the material, which is known as hydrogen-induced stress corrosion cracking, HISCC (Craig et al, 2016; Wu et al, 2018b). While research to understand the process of SCC occurrence in underground mines is still required, finding a prevention solution to protect the bolts from HISCC is crucial. In this study, we analyse a variety of commercially available coatings for steel corrosion prevention, including barrier coating (ie epoxy, polyester TGIC) and sacrificial coating (hot-dip galvanising). We test the coating on coupons manufactured from rock bolts and cable bolts used in the coal mining industry.

Nov 29, 2022

The probability of detachment of quartz particles from air bubbles during bubble oscillations was investigated by means of a vibration method. Theoretical calculations of the detachment force based on the work of Nutt and Schulze for a single spherical particle show a correlation with the experimental results described. However, the forces that were determined experimentally were considerably lower than the theoretically derived values. Some of the factors which were expected to affect the probability of detachment, such as particle size, bubble size, collector concentration and vibrational acceleration, were also investigated

Dec 1, 1991

By Shuoshi Lu

The Cu-Co ore studied here belongs to the oxide type. The oxidation rates of copper and cobalt are69.30% and 78.78%, respectively. The content of Cu in ROM is 1.34% and that of Co is 0.096%. The ore contains 4.64% carbon.Based on the process mineralogy and previous metallurgy tests, the principalprocess flow-sheet of ?grinding fines 80% -0.074mm, sulphide flotation followed by oxide flotation, and flash flotation for oxides? has been determined.The handling of carbon is determined through tests. The depressant PNL-1 depressed carbon effectively, improved the recovery of sulphide minerals and reduced the reagents consumption.The operation of the flow-sheet was also changed to better at the same time. Keywords: Cu-Co oxide ore, process mineralogy, carbon depression, efficient depressant of carbon

Sep 1, 2012

By P. Zhang, W. D. Xiao

"A process mineralogy study was conducted to guide the development of a process for the extraction of vanadic oxide (V2O5) and aluminum compounds from bone coal and its ash as well as the production of byproducts. Results show that to extract the targeted metals at higher recovery rates, one must find a suitable agent capable of destroying the structure of the mica and breaking down the lattices in which these metal-bearing minerals occur. For such minerals, metal extraction efficiency is usually low if the approach is simply adding an oxidant that cannot destroy the structure. In this research, a byproduct fluosilicic acid (H2SiF6) at 20 percent concentration from an operating phosphate fertilizer plant was found to be powerful and effective for the leaching of vanadium-bearing minerals such as mica. This environmentally friendly process improved the leachability of valuable constituents in the bone coal significantly, with the leaching rate of V2O5 increased to 94 percent, from 83 percent, and that of aluminum oxide (Al2O3) increased to 75 percent, from 40 percent. X-ray diffraction and chemical analyses showed that the structure of mica can be destroyed using fluosilicic acid either alone or in combination with sulfuric acid. Based on the process mineralogy study, a processing flowsheet was tested, which resulted in a final V2O5 powder product with purity of 99.2 percent and an overall recovery rate of higher than 85 percent. The flowsheet consists of leaching, ion exchange and ammonium precipitation. With this process, various byproducts could also be generated, including aluminum fluoride, cryolite, aluminum sulfate, calcium sulfate, ammonium chloride, sodium chloride and cement admixtures.IntroductionVanadium is an important rare metal broadly used in the production of steel alloys and nonferrous alloys as well as in the chemical field as a catalyst. Vanadium-bearing bone coal and clays are abundant in China, and they contain other valuable metals such as aluminum. Bone coal is a type of carbonaceous shale. The vanadium-bearing minerals mainly exist in mica, kaolin, iron oxides, tourmaline and garnet. According to previous studies (Xiao, 2007; Xu, 1989; Xu and Chen, 1991; Ji and Xu, 1991; Chen and Xu, 1992; Xu and Heng, 1992), vanadium occurs from the isomorphous substitution of V3+ for Al3+ or Fe3 + in the crystal lattices of mica, tourmaline, garnet, dolomite and aluminosilicate minerals. In iron oxide and kaolin minerals, vanadium appears as an adsorption form. The isomorphous substitution of vanadium is more stable in tourmaline, garnet and silicate minerals. Therefore, vanadium in bone coal may exist in three phases: vanadium-containing kaolin and oxides, vanadium-containing mica, and tourmaline and garnet (Xu and Chen, 1993; Xu and Zhang, 1993; Xu and Wang, 1994; Feng, et al., 2005; Lin and Fan, 2001)."

Jan 1, 2015

By Denise Y. Dixon

The objectives of this study were to (1) document the hydrologic impacts of longwall mining on ground water, (2) identify the factors which affect the extent of dewatering, and (3) develop empirical trends to predict the extent of dewatering and recovery in advance of mining. The study was confined to three mine sites in north-central West Virginia. At each site, available ground water supplies were identified and monitored for dewatering effects and recovery. Mine A, located in Upshur County, West Virginia, has relatively thin overburden (approximately 715-280 feet). At this site domestic water supplies and specially constructed monitoring wells were monitored, continuing with an earlier study done by Cifelli arid Rauch. Most such supplies were completely dewatered over the longwall panel. Some of these wells have shown significant recovery, especially near a stream. Extensive monitoring of two nested piezometer wells revealed that dewatering generally started in advance of undermining in the lowermost monitored overburden zones first and then progressed upwards. Most dewatered wells completed in bedrock have shown no recovery, except. for valley drilled wells located within 100 feet of a Stream. Affected dug wells completed in valley alluvium rend located within 200 feet. of the nearest stream have shown significant recovery. Some wells have partially collapsed following mine subsidence. Mine B, having relatively thick overburden (approximately 585 to 900 feet), is located in Monongalia County, West Virginia. Ground water supply surveys have been conducted there in an attempt to study past dewatering effects. Owners reported Chat several wells were dewatered by longwall mining arid vertical air shafts that preceded longwall mining. Dewatered wells over longwall panels hove shown some recovery within 3 ½ years of mining. Mine C also has relatively thick overburden (approximately 585-900 feet), and is located mostly in Greene County, Pennsylvania. In addition to a survey of domestic water supplies at this site, five specially constructed monitoring wells were tested. The shallow monitoring wells suffered drops in water level due to mining but totally recovered within one day to three weeks after dewatering occurred. However, they did occasionally exhibit partial collapse during mine subsidence. Subsidence fracturing was beneficial in increasing the lateral hydraulic conductivity by a factor of about S to 22 for rock strata located within 124 feet of the surface, indicating enhanced shallow aquifer potential. One deep well suffered both partial dewatering and structural damage, with the state of water recovery bring uncertain. Also, two shallow domestic supplies out of five located over the mine were reportedly dewatered, but this claim could not, be substantiated.

Jan 1, 1988

By P. H. Agson Gani, T. Sitorus, N. P. Widodo

"PT ANTAM UBPE Pongkor underground mine use blasting to develop its tunnels which will cause poisonous and dangerous gases trapped inside mine. To analyze this case, a study of mine ventilation, the dispersion of carbon monoxide (CO) gas concentration and diffusion coefficient is commenced. At the end, the re-entry time formula will be determined. Results indicate that this study is site specific and could only be applied in the place this study executed. The aim of this study is to be further developed by applying Principal Component Analysis (PCA) to find a universal re-entry formula. KEYWORDS Mine Ventilation, Re-Entry, Smoke Clearing, Diffusion Coefficient, Carbon Monoxide Gas, Gas Dispersion INTRODUCTION Pongkor underground mine is using cut and fill as its mining method. Thus, its development and production processes require blasting to develop its tunnel. This process caused poisonous and dangerous gases spread and trapped inside the mine, one of them is carbon monoxide (CO) gas. CO is formed in an unbalanced reaction of explosives detonation and could be the cause of headache, blackout and death to people who inhale CO at certain concentration (McPherson, 2011; Hartman, Mutmansky, Ramani, & Wang, 2012). Mine ventilation system is installed in the mine to resolve this problem. Mine ventilation play an important role to disperse CO gas by absorb the poisonous/dangerous gases and deliver clean air into mine. The important parameter is diffusion coefficient, because diffusion is affecting particulates or gasses spreading from its sources throughout the mine. Diffusion coefficient is the total diffusion in axial direction of turbulent flow mainly by convection of bulk motion, advection and eddy diffusion, while the effect of molecular diffusion is appreciably negligible (Widiatmojo et al, 2015). Taylor (1953, 1954) develops a theory about the dispersion by inducing a slow stream of solvent into a capillary tube. Taylor used Reynolds assumption of radial diffusivity to be analogous with the transfer of the matter in turbulent flow as well as the transfer of momentum and heat. Then, Taylor proposed the formula of diffusion coefficient, D (m2/s), against pipe diameter and turbulent shear velocity are as follow:"

Jan 1, 2019

By B. Hart, J. Marois

"Scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM–EDX), and Time of flight secondary ion mass spectroscopy (TOF-SIMS)were used to analyze pyrochlore grains from Niobec froth flotation plant. Samples from the mill feed, pyrochlore rougher feed, pyrochlore rougher concentrate, and tail were analyzed in order to identify a potential relationship between pyrochlore matrix composition and selective separation. SEM-EDX analyses indicate that pyrochlore grains with high Fe content appear to be less recoverable than those with a lower Fe content and that the flotation response is related to matrix Fe rather than Fe occurring as inclusions. TOF-SIMS was used to analyse the surface of high Fe and low Fe pyrochlore, in order to identify a potential relationship between pyrochlore matrix composition and the related effect on cationic collector adsorption (tallow diamine). Surface analyses of pyrochlore from a conditioning test show that species indicative of the collector favour the surface of Fe poor pyrochlore relative to the Fe rich variety. The results from the conditioning test illustrate a negative relationship between collector loading and the presence of Fe and related oxidation species. This study identifies the link between pyrochlore matrix Fe content and, the presence of surface oxidation products, to collector loading. Poor Fe rich pyrochlore recovery noted in the Niobec froth flotation plant may be partially explained by this mechanism.INTRODUCTIONPyrochlore, the most abundant niobium containing mineral (Perrault and Manker, 1981) is economically recovered in Brazil, China, and Canada (Niobec) (Kouptsidis et al., 2008). Since 1974 Niobec has been extracting niobium from the St-Honorécarbonatite deposit. Niobec is the only operating Nb extraction facility in North American and one of the three major world producers of ferroniobium (Dufresne and Goyette, 2004; Belzile, 2009).Flotation is the preferred and most cost-effective method for pyrochlore recovery (Burks, 1958; Shapolov and Polkin, 1958; Zakharov et al., 1967; Razvozzhaev and Nikiforov, 1972; Bogdanov et al., 1973; Abeidu, 1974; Raby and Desrochers, 1975; Wilson, 1979; Biss and Nadeau, 1982; Biss, 1985). With the aim of optimising the flotation process for the Niobec ore, numerous experiments were performed on the influence of surfactants and type of water to optimise pyrochlore recovery and grade during flotation (Gomez et al., 1987; Rao et al., 1988; Dufresne and Goyette, 2004; Belzile, 2009)."

Jan 1, 2013

By S. Tuylu, D. Adiguzel, A. Bascetin, E. G. Savas, O. Ozdemir

"Paste Technology has some advantages comparing to other surface disposal methods. With this method, it is possible to pump high concentrated solid materials to very long distances without segregation problem. However, it is known from Literature that pumpability of materials is completely related to rheological properties of the materials. For this reason, in this study, the rheological parameters (e.g. yield stress and viscosity values) of the paste material prepared from Pb-Zn tailings at various solid ratios (60-85%) were obtained in order to determine the pumpability of the paste material. Additionally, slump tests, which are usually used in mining industry, was carried out. Finally, regression analysis was made between the slump values and rheological parameters of the paste material to find a correlation between two independent parameters. The results showed that there is a great correlation between the slump values and the yield stress of the material. On the other hand, there was no correlation with viscosity: ty=430.28-16.877Sv (R2= 0,94; ty: Yield Stress (Pa), Sv: Slump Value (cm)). Based on the results obtained from this study, it can be clearly concluded that the slump values obtained from a simple test can be used to predict yield stress values of paste materials. INTRODUCTION Recently, surface disposal of mining tailings has become one of the biggest problems in mining industry in terms of environmental issues. Therefore, several researches have been focused on this subject in order to find a best solution or method for this problem. These studies showed that paste technology has some advantages compared to other conventional methods. Tailings thickened to the extent show no segregation of particles during transportation, and relatively small amount of settling occur post-deposition which are often called “paste” (Cincilla et al. 1997). Paste tailing technology has two applications in the industrial area as underground paste fill and surface paste disposal. Paste tailing technology was first started to be used in Grund mine, Germany in the late 1970s (Grice, 1998). Process tailing material, water and - if needed - cement materials, which are the components of the paste, must be blended to obtain a homogenous mixture suitable for pumpability. Consistency behavior of the paste material is determined using a conventional sedimentation cone concrete test (slump). Meanwhile, the slump value of the paste must be between 200 and 250 mm for surface applications (Newman et al., 2001). Additionally, in the case of underground paste system, the optimum slump value must be between 150 and 200 mm. On the other hand, the water content and density of paste at certain slump value change depending on the amount of fine particles in the tailing sample. While moisture of the material will be high, its density will be low because of surface area of particles which increases with decrease in particle size (Meggyes and Debreczeni, 2006). For pumpability of the paste to long distances, slump value of the paste must be good enough to be accepted for use of surface paste disposal. Paste material has a yield stress because they show non-Newtonian behavior and generally is classified as a Bingham plastic fluid. (Cooke, 2008; Theriault, 2003). In addition, the appropriate viscosity value of the paste along with the yield stress must be between 100 and 250 Pa (Bascetin et al., 2013; Bascetin et al., 2014; Bascetin et al., 2015)."

Jan 1, 2016

By C. E. Johnson, R. L. Bauer, E. M. Johnson

In industry, the strength of a blasting cap is often equated to the type of explosive it can detonate. Comparable cap strength is becoming less important as nearly all caps manufactured today can initiate high explosives, such as primasheet, with ease. Previous studies were conducted to assess the quantity of energy released by various detonators into the directional propulsion of the detonator’s casing. However, the question of how much of this propulsion energy is needed to initiate an explosive remains unanswered. This study will assess the fragmentation size and velocity needed to initiate a high explosive when they are not in direct contact. For this study, primasheet was used as the main charge as it is relatively insensitive and can be situated in different positions relative to the detonator. Electric, non-electric and electronic detonators were used to evaluate initiation potential. The primasheet is observed in response to being in contact with a detonator, and not in contact with the detonator at various distances and angles. This allowed the quantity of energy transferred into the primasheet to be observed and for the initiation of the sheet to be recorded using high-speed video. This study will report the energy necessary to initiate the primasheet at various distances and angles from the charge from a number of widely used, commercial, hot wire blasting caps.

Feb 6, 2023

By Jacob Masliyah, Zhiang Zhou, Tshitende Kasongo, Jianjun Liu, Zhenghe Xu, Jeawon Choung

"Slime coating is a recognized challenge in fine particle flotation, not only in decreasing recovery, but also in reducing the selectivity and hence froth quality. In this presentation, a novel method based on electrophoretic mobility distribution measurement to study slime coatings is described. By measuring electrophoretic mobility distribution of individual minerals and their mixtures, the interactions between these minerals can be evaluated.For illustrative purposes, a model system of fine coals, or oil sands with two different types of fine clays was studied. Flotation tests showed a significant decrease in coal (bitumen) flotation recovery with montmorillonite but not with kaolinite clay addition. When electrophoretic mobility distribution of a fine coal/montmorillonite clay mixture was measured, a single modal zeta potential distribution was obtained, in contrast to a bimodal distribution for fine coalkaolinite clay mixture. This finding suggests a stronger adhesion of montmorillonite than kaolinite clays on fine coal surfaces. In the case of bitumen, the bimodal zeta potential distribution was measured for the mixture of bitumen emulsion and kaolinite or montmorillonite, indicating a weak attraction of the clays by bitumen. In the presence of calcium, however, a single modal zeta potential distribution was obtained in the mixture of bitumen emulsion with montmorillonite but not kaolinite clays. These findings are in excellent agreement with bitumen flotation results, demonstrating that the electrophoretic distribution measurement is a powerful tool to study slime coating phenomenon in a complex fine particle flotation system."

Jan 1, 2002

By Dif A. E N, Abdalla MH

The effect of multiple tunnels /cavities on the stress and deformation field of the soil media was investigated by using a two dimen- sional plane strain boundary element model. The soil was considered as an elastic, isot- ropic and homogenous media. The interaction of two circular and parallel tunnels/cavities was investigated. Depth of burial, tunnel spacing and surface load width were the system variables considered. The results of this study indicated that the vertical displacements of the soil media increases by decreasing the distance between the adjacent openings, the interaction between the two tunnels/cavities can be neglected for K/D > 5, while the load width has a minor effect except in the dis- tance of D from the center line of the load and for a depth of 2D.

Jan 1, 1987

By A. Koizhanova

Kumistinskoye gold- and silver bearing ores (Republic of Kazakhstan) as well as standardized test solutions containing gold, silver, copper, zinc and iron were studied. The best results in silver and gold recovery from Kumistinskoye gold- and silver bearing ores were achieved through use of complex cyanide-thiosulfate solutions as compared to individual cyanide solutions and thiosulfate solutions. It was found that such complex solutions substantially step up leaching process herewith increasing precious metals recovery rates. Thermodynamics of studied chemical processes was calculated. Reaction order, kinetic constant and activation energy of gold leaching process through use of cyanide-thiosulfate solutions were identified. We managed to prove that the sorption rates and holding capacity in process of gold anions recovery with anionite AM-2B are comparable to sorption characteristics for cyanide solutions. Keywords: gold, silver, copper, zinc, iron, cyanide-thiosulfate solutions, anionite AM-2B

Sep 1, 2012

By J. Petersen, K. Shaik

The traditional route utilised for the recovery of Platinum Group Minerals (PGMs) in South Africa involves the concentration of ore by flotation, followed by smelting to produce a PGM rich matte, which is then digested hydrometallurgically to solubilise base metals and Platinum Group Elements (PGE). HCl/Cl2 is conventionally used for PGE dissolution from concentrated material, which is an aggressive reagent associated with high maintenance costs as well as environmental concerns. Of interest is the leaching of PGMs directly from mineral ores, low grade concentrates and tailings in a cyanide-ferricyanide system as a more sustainable alternative. This system has shown favourable Pt recoveries among the Pt minerals, but with sperrylite (PtAs2) displaying highly refractory behaviour. The dissolution of sperrylite is investigated in a cyanide-ferricyanide system in the context of an electrochemical study involving OCP, chrono-amperometry and cyclic voltammetry. This approach allows the assessment of leaching characteristics as well as the investigation of surface passivation, which is believed to contribute to poor Pt recoveries. Some evidence is presented that such passivation is related to the formation of arsenide species on the mineral surface. Keywords: Sperrylite, PGMs, cyanide, ferricyanide, electrochemistry

Jan 1, 2020

By D. M. Wyslouzil

"This paper was prepared for presentation at the 16th Canadian Mineral Processor's Annual Meeting, Ottawa, Ontario, Jan. 17 to Jan. 19, 1984.This paper gives an account of the development of treatment procedures for the differential flotation of refractory copper-zinc ores. Special references are made to the effectiveness of various zinc depressants and their combinations.Studies carried out on refractory copper-zinc ores demonstrated that conventional zinc depressants such as cyanide and zinc sulphate were not particularly effective when secondary copper minerals were present in the ore; the flotation activity of sphalerite was enhanced in the presence of cyanide.Among the various zinc depressants evaluated, the following depressant combinations were found most effective: Zn(OH) 2-S02 , 802-CaO, Na2S-Na2S03-S02, Na 2 S-S02 and Na 2S-S0rDS22.The practical application of any of these systems depends on the type of ore treated and other conditions such as pH, levels and points of collector and depressant additions.In this paper the effect of each depressant combination on different ores is described with reference to the selection of collectors."

Jan 1, 1984