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By S. L. Weber, D. E. Banks

"Silicosis was first reported by the ancient Greeks and is apparently as old as human history. The prevalence of this illness peaked in the last half of the 19th century and the early part of this century, when mechanized industry was developing and the relationship between dust exposure and disease was less well understood. Yet, even today in devel-oped countries, sporadic outbreaks of silicosis occur when workers are consistently exposed to silica particles of respir-able size (0.5 to 5.0 µm in diameter) at levels exceeding those recognized to be safe.Silicon dioxide or silica. is the earth's most abundant mineral. Silica is considered to be either free (i.e.. unbound to other minerals) or combined. Minerals with high amounts of free silica include quartz (including granite) flint. Chert, opal, chalcedony, and diatomite. Combined forms of silica are called silicates and include, among others, asbestos talc and kaolin.In the crystalline form, silica exists as quartz, cristobalite, and tridymite (Fig. 28). Of these quartz is ubiquitous in the environment and occurs as sand and as a part of many rocks. Cristobalite and tridymite occur naturally in lava and can be formed by the heating of quartz or amorphous silica. Cristo-balite is more tibrogenic than quartz. Amorphous silica is noncrystalline and, therefore, is relatively nontoxic and does not cause silicosis. It occurs as diatomite (skeletons of pre-historic marine organisms) or as vitreous silica (glass), the result of carefully melting and then quickly cooling free crystalline silica. Heating diatomite with or without alkali (a process known as calcining), forms cristobalite and adds the respiratory toxicity of free crystalline silica.There are many opportunities for occupational exposure to respirable crystalline free silica. Some of the commonly en-countered occupations in which the risk of silicosis exists are reported in Table 20.Silicosis. the pulmonary disease caused by the inhalation of silica particles of respirable size, is most commonly cate-gorized by findings on the chest radiograph. The most typical presentations simple silicosis and progressive massive fibrosis appear different radiologically but are grouped under the category of classic silicosis because they are a part of the radiographic spectrum of this illness. Radiographically, simple silicosis appears as small (less than 10 mm in diameter), rounded opacities, typically predominant in the upper lung zones. Progressive massive fibrosis is the result of the coalescence of these small nodular opacities and appears as larger opacities (more than 10 mm in diameter), again typicallydistributed in the upper lung zones."

Dec 1, 1995

By R. C. Burtan

Long before recorded history, man began to dig into the earth's crust in a never ending search for useful materials. It is well known that more than half of the earth's crust is composed of silicon dioxide (SiO2), also known as silica. Silica and silica-containing material have a great many uses in modern society. This material, however, is potentially an extreme health hazard. Silicosis: Not a New Disease Centuries before the Christian Era, Hippocrates wrote of a lung disease common to those who mined in hard rock. He was obviously describing silicosis. It is also apparent from ancient writings that the Egyptians were aware of this malady. Dioscorides also wrote on this subject in the fifth century B.C. It is undoubtedly the oldest and best studied of the occupational lung diseases. Silicosis was certainly described by Agricola in his De Re Metallica published in 1556. Here he described lung disease among hard-rock miners. The original document was written in Latin and then translated in 1912 by Hoover and Hoover. One of these translators was Herbert L. Hoover, a former US president who once made his living as a mining engineer. More recently, there are numerous references in medical literature in the 19th and 20th centuries relating silica exposure to silicosis. There are specific references to mining in hard rock, as well as to sandblasting and a host of other industrial exposures. In 1919, Winslow described standards for measuring the efficiency of exhaust systems in polishing shops using sandblasting. These standards were equally applicable in the mining industry. As early as 1920, Winslow explored the efficiency of certain devices used to protect sand-blasters against the dust hazard. These devices were equally applicable in the hard-rock mining industry. The medical community recognized the silica health hazard in the early 1900s. Middleton described the illness in the British Medical Journal in 1929. He noted the danger to health at that time. D. Hunter mentions in his book, The Diseases of Occupations (1969), the monumental work of Merryweather in 1936, in which he surveyed the silicosis risk in Great Britain. He showed statistically that the average employment length of sandblasters who ultimately died of silicosis was 10.3 years, compared to 40.1 years for all fatal cases, irrespective of occupation. Sandblasting and hard-rock mining and drilling, obviously, are very hazardous occupations. Weil and Zisking of Tulane University wrote in 1975 that "it was known as early as 1935 that the course of silicosis is much more rapid in sandblasters than in miners or foundry workers. This can be explained by the fact that sandblasters are exposed to an almost pure siliceous dust containing high concentrations of respirable particles within the range of 1 to 3 micron size." Protecting the Worker The medical community recognized in the early 1900s the need for proper protective equipment for all of those who worked with siliceous materials. Middleton, writing in 1929, said: "The worker is then protected by a close fitting helmet with an air feed, much as in the case of an underwater diver. In spite of these precautions, cases of silicosis among sandblasters are being met with today. It is a matter for serious consideration whether a substitute, such as steel or iron grit, could not be used to replace the siliceous grit as the abrading material." C. E. A. Winslow, a professor of public health at Yale School of Medicine, and others wrote of the need to protect sandblasters by

Jan 7, 1984

By Clifford S. Gibson

THE Workmen's Compensation Ace defines Silicosis as "a fibrocic condition of the lungs caused by the inhalation of silica dust sufficient co produce a lessened capacity for work". This fibrocic condition muse exhibit a specific appearance in the X-ray picture of the chest-an appearance which is not characteristic of several lung conditions which can cause lessened capacity for work and which are not due co silicosis. The layman is sufficiently familiar with this subject co know chat, as far as our knowledge goes, quartz is one of the principal objectionable factors in the production of this condition. He should also know that silicosis respects neither geographical nor industrial boundaries. It is as much a factor in some industrial processes (e.g. foundry work, sandblasting) as it is in mines handling ores containing quartz. Its development co a recognizable stage is usually a matter of many years. As yet, its cure is unknown. Its prevention is possible in varying degrees. The layman should also know that the development of fibrosis may be accelerated by breathing in, or living in, any atmosphere containing dust. Few normal adults, particularly those above a certain age, have clear lungs, and fibrosis in varying degrees is noted in the farmer, the steel worker, the clerk, and many others in varied occupations. It is not restricted to miners. Medical and industrial journals, and at times the press, are crammed with data pertaining to this subject, much of which is misinformation. This is particularly true of certain !laces where the preventive and compensation measures for the good o those earning their livelihood in an industry in which silicosis may be contracted are not so far advanced as in our own Province. A great many of these publishings are alarming to the layman. They leave him with the impression that he is taking his life in his hands if he elects to work underground, particularly in a gold mine-that he has at once sold his heritage of health and chat sooner or later he will succumb to the ravages of this ailment. Nothing could be farther from the truth. Actually, under present conditions in Ontario mines, a very small percentage of the men employed ever become impaired by silicosis to the extent chat they must withdraw from the industry. I propose to tell you briefly something of this subject as it affects our mines.

Jan 1, 1937

By R. C. Burtan

Long before the dawn of recorded history, man began to dig into the earth's crust in a never ending search for useful materials. It has been well established that prehistoric man discovered flint. "The Flintstones" were aptly named. The flintknappers of southern England and Wales still exist today in ever dwindling numbers as they seek out chunks of flint. It is a well known fact that more than half of the earth's crust is composed of silicon dioxide (SiO2), also known as silica. Silica and silica containing materials have a great many uses in modern society. However, this material is potentially extremely hazardous to our health. Centuries before the Christian Era, Hippocrates wrote of a lung disease common to those who mined in hard rock. It is obvious to us that he was describing silicosis. It is also apparent from ancient writings, that the Egyptians were aware of this malady. Dioscorides also wrote on this subject in the fifth century, B.C. It is undoubtedly the oldest and best studied of the occupational lung diseases. It was certainly described by Agricola in his "De Re Metallica" published in 1556, in which he described lung disease among hard rock miners. This publication, I'm sure, is of special interest and perhaps known to many of you in the mining community. The original document was written in Latin and was translated in 1912 by two gentlemen, Hoover and Hoover. One of these translators was Herbert L. Hoover, a former president of the United States, who made his living before his presidency as a mining engineer.

Jan 1, 1984

By D. Fleury

"This paper describes the challenges of mining a sill pillar under various types of paste backfill quality. From 1994 to 2002, Louvicourt mine produced approximately 12,600,000 t grading 3.5% Cu, 1.5% Zn, 27 g/mt Ag, and 0.85 g/mt Au. The mining method is transverse blasthole stoping, mining primary and secondary stopes. The production of this 4,300 t/d operation was accomplished using two mining horizons; from the 655 m level to the 415 m level and from the 860 m level to the 680 m level. The main sill pillar is between the 680 m level and the 655 m level. The second sill pillar is between the 885 m level and the 860 m level representing a quarter of the main sill pillar in size. Since 2002, production has gradually decreased and mining activities are expected to end in mid-2005. The sill pillar production will represent almost 25% of the total mine production. The overall recovery of the sill pillars stopes will be discussed in this paper. To recover the sill pillars, more than 1,500 m of development was planned in or under paste backfill. The first sill pillar stopes under paste backfill were mined out in 2002 with excellent results."

Jan 1, 2005

By A. P. Grobbelaar

Andalusite is a member of the sillimanite group of minerals consisting of andalusite, kyanite, and sillimanite. These minerals are the structural polymorphs of Al,Si05 (the anhydrous silicate of aluminium) and although chemically similar, they differ in physical properties due to their different crystal structures. For further information on the sillimanite group, see the chapter on Kyanite and Related Minerals that follows. The minerals are generally the products of the metamorphism of alumina-rich sediments and are found in schists, gneisses, or hornfelses, which have undergone either regional or thermal metamorphism from their original form. Sedimentary deposits may also form since the minerals are chemically and physically resistant to breakdown. When heated to a sufficiently high temperature the sillimanite group minerals convert to mullite with a resultant volume expansion and the liberation of silica. Due to the stability of the mullite formed, its high hot strength and resistance to chemical and physical erosion, they are widely used in the manufacture of refractories and special ceramics (Table 1). The reaction can be represented as follows: [ ] The worldwide use of these minerals depends to a large degree on their availability (Fig. 1). Andalusite, with its lower conversion temperature and the lowest volume expansion on being heated is the natural choice as a raw material to produce energy-saving refractories without prior calcination. The Republic of South Africa holds by far the largest minable andalusite deposits of the world, estimated at some 70 Mt of known in situ reserves. The only other large commercial production of andalusite comes from France, with known reserves of about 5 Mt. Potential new deposits are known from China, Ireland, Australia, and South America. World consumption of andalusite in special performance refractories has risen from less than 10 ktpy in 1960 to nearly 300 ktpy in 1990, which is due to cost effectiveness in many industrial applications compared to other conventional refractory products. Andalusite-based refractories have traditionally been used in Europe, South Africa, and the Far East; usage in America was limited in the past due to relatively high delivery costs and availability of other local refractory minerals. However, there is a significant trend towards greater use of andalusite in North America, thus opening new markets and replacing other traditional refractory raw materials. GEOLOGY Andalusite occurs in metamorphosed rocks of clay-like com- position, as in the andalusite-hornfelses in thermal aureoles (contact metamorphism), formed under conditions of high temperatures and low stress, and in regional metamorphic rocks, such as the andalusite-schists. These schists are mostly unconnected with definite igneous intrusions but were presumably also formed at high temperatures and under low stress. Andalusite can also appear in alluvial deposits associated with the primary deposits. At depths of 10 to 20 km, temperatures of up to 450°C might be expected. Another result of increasing depth is an increase of pressure due to the load of the rock cover. The load stresses involved in metamorphism is generally believed to lie in the range 0 to 10 000 bars. During contact metamorphism the increase in temperature is brought about by the injection of magma. The temperature reached in the country rock at some distance from the igneous body will always be less than the initial temperature of the intrusion, which is presumably less than 1 200°C, and will vary with time and distance from the contact. A simple metamorphic reaction involving dehydration of an aluminous sediment can be: [ ] At higher temperatures sillimanite would form at the expense of andalusite, while kyanite would be the mineral formed at higher pressures, as can be seen in the phase diagram of A12Si05 (Fig. 2).

Jan 1, 1994

By Roberto Antoniolli

"IntroductionSINCE ancient times, the precious metals have played an important role in influencing the course of history. Silver and gold happened to occur, although in small amounts, in those countries where the early civilizations developed. Their persistent brightness certainly amazed the primitive people, who also found it easy to shape them into ornaments •and implements. Ever since then their properties have made them seem desirable possessions.Use of precious metals as money was the natural consequence of man's desire for them. The possibility of changing an ornament into a tool or food at any time, and the ease with which such medium of exchange could be carried and hidden, further increased the demand for the two metals.Silver was probably discovered after gold and copper, and was undoubtedly found by prehistoric man as native silver. The oldest silver articles have been discovered in Chaldean tombs and date back to 5000 B.C. The earliest ascertained producers of silver were Asia Minor and the Iberian Peninsula. The Romans worked deposits in Spain, Britain, and France. In the Middle Ages, some silver was extracted from German deposits, and near the end of the Middle Ages systematic workings were carried on at Freiberg, Schneeberg, and Joachimsthal (1).Before the discovery of the New Continent, the Aztecs and Toltecs in Mexico, and the Incas in Peru, had made extensive use of silver. In the 16th century the Mexican deposits became the largest source of the world silver."

Jan 1, 1954

By J. Mackintosh Bell

External trade strongly influences the well being of all nations. In the modern economic mechanism, no country is so well endowed that it has not to import commodities from others and to export its products in turn to make good its deficiencies, to rectify or improve its financial structure. From the standpoint of international commerce, Canada is strategically well placed. On the south she is bounded by the richest country in the world. On the east she faces the Atlantic, on the west the Pacific. On both coasts there are fine harbours to which lead great lines of railway that span the continent. Canada is now fifth among the exporting nations of the world. For disposal abroad, she has enormous quantities of primary commodities and substantial amounts of manufactured goods as well. But she is far from being self-sustaining. She is unusually dependent on foreign trade, not only because of the commodities she has to sell but because of the lack of many essential articles she does not or cannot produce. To Canada, external commerce is vastly more important than internal trade. The wealth of nations is decided by their ability to produce more than they need, to sell more than they buy, and to build up favourable balances resulting from trade or services. With few countries, however, are returns perennially satisfactory. Fruitful periods are followed by leaner years. In times of prosperity foreign credits are increased, monetary systems strengthened, reserves accumulated to withstand recurring days of strain. Today, the foundations of financial systems are being re-examined, "dogmas hitherto accepted as canonical are being questioned" . It is not only in Europe and America that men search for illumination in problems arising from monetary restrictions.

Jan 1, 1933

By Larry A. Enloe

The 16-to-1 milling operation is Sunshine Mining Company's first new silver and gold producing facility. The 16-to-1 underground mine and mill are located approximately 64 km (40 miles) southwest of Tonopah, Nevada. Ore re- serves in the epithermal vein deposit are estimated at 0.91 Mt (one million st) of ore, at an average silver grade of 206 to 240 g/t (6 to 7 oz/st) and an average gold grade of 1.2 g/t (0.035 oz/st). The underground mine uses a large diameter blasthole stoping system of mining using highly mechanized rubber-tired equipment. The mill uses conventional cyanide leaching with countercurrent decantation and Merrill-Crowe precipitation. The mill start-up was in February 1982 resulting in the first pour of dore' in March 1982. The mill's present annual production is approximately 31.1 t (1.0 million oz) of silver and 264 kg (8500 oz) of gold.

Jan 1, 1984

By D R. Swinbourne, T Lehner

Study of the distribution of minor elements between copper matte andfayalite slag is important in determining appropriate methods tomaximise the recovery of valuable metals and the rejection of harmfulelements. Boliden Mineral AB operate a large copper smelter in northern Sweden, where they had noted that the loss of silver to the slag in the settling furnace appeared to be a direct function of the tin content of the slag. This work was aimed at determining whether or not this was a cause-and-effect relationship. Copper matte containing approximately 50 wt per cent copper and small amounts of silver and tin was equilibrated with silica-saturated fayalite slag at 1250¦C, then quenched. The matte and slag were then analysed for their silver and tin contents. It was found that there was no relationship between the silver distribution and the tin distribution. The silver matte/slag distribution ratio had a value of 120 ¦ 40 while that for tin was 2.8 ¦ 0.3. It is suggested that the most likely cause of the relationship observed at the Boliden smelter was matte entrainment in the slag.

Jan 1, 1999

By Dolf W. Fieldman

Most recently the geologic setting of the mineral deposits in the Silver Cliff district is described by William M. Sharp in ?Geologic Map of the Silver Cliff and Rosita Volcanic Centers, Custer County, Colorado?, (U. S. G. S. Map I- 1081). The discussion will relate only to the southern half of the Silver Cliff volcanic center and differences in geologic interpretation, which are largely structural, will be pointed out as they arise. Only the manganese/silver zone of the Kate Area will be discussed in detail.

Jan 1, 1980

By W. M. Luff

The Brunswick No. 12 Deposit is a large polymetallic massive sulphide deposit, occurring in Ordovician age rocks of the Tetagouche Group. Silver is contained within the sulphide zones and economically it is the second most important commodity produced. Brunswick is one of the largest silver producers in Canada. The distribution of silver within the mine is presented, with examples from various levels. The concentration of silver can be shown to be related to both stratigraphy and structure. The mineralogy of silver in mill products is also presented.

Jan 1, 1986

By W. M. Luff

Introduction The Brunswick No. 12 mine is located about 27 km (17 miles) southwest of Bathurst, New Brunswick. The deposit is a stratiform massive sulfide deposit occurring in a series of sedimentary and volcanic rocks of the Tetagouche Group. These rocks are generally considered to be Ordovician in age. Ore reserves at Brunswick No. 12 are 104 Mt (115 million st) grading 3.72% lead (Pb), 9.01% zinc (Zn), 0.32% copper (Cu), and 97.9 g/t (2.8 oz per st) silver (Ag). Production in 1984 was 3.5 Mt (4 million st) at 3.57% Pb, 8.91% Zn, 0.32% Cu, and 100 g/t (2.9 oz per st) Ag. Total payable silver production that year was 211 t (6.8 million oz). This made Brunswick one of the largest silver producers in Canada. Bathurst-Newcastle area and Brunswick Mining Interest in the Bathurst area was aroused in 1897 when W. Hussey discovered an iron formation at Austin Brook, just south of Brunswick No. 6 deposit. This area, and the current No. 6 area, was explored from 1897 to 1907. Iron ore was mined at Austin Brook from 1907 to 1913 and from 1942 to 1943. Any occurrence of sulfides was overlooked until 1952. In 1952, M. J. Boylen Enterprises investigated the small sulfide body associated with the Austin Brook iron formation. Other electromagnetic anomalies associated with the iron formation were investigated. The No. 6 deposit was found late in 1952, when hole B12 intersected 97.5 m (320 ft) of massive sulfides. The No. 12 deposit, 10 km (6 miles) to the north, was found in 1953. More than 30 massive sulfide deposits have since been identified in the Bathrust area. In the 1950s, St. Joe Lead Co. did extensive test work on the No. 6 and No. 12 deposits, including shafts at No. 12, lateral development at No. 12, and testing at both deposits.

Jan 10, 1986

By S. F. Ye, L. Xiao, Y. L. Wang, P. W. Han

"Copper anode slime is a precious secondary source for the recovery of silver. However, current recovery process are constrained by either sever pollution or high cost. To cover the drawbacks of current process, this research employed a novel strategy by using the manganese dioxide as the oxidant in acid solution, which avoided the generation of sulfur dioxide while high silver extraction rate was achieved. The effects of manganese dioxide, sulfur acid concentration, stirring speed, temperature and leaching time on silver extraction rate were investigated. The silver recovery reached to 91.68% under the conditions of 1.2 g manganese, 2.0 mol/L H2SO4, 300 rpm, 80 °C and 6 h. INTRODUCTION Copper anode slime is generated from the electrolysis refining of copper and is extremely precious for its containing noble metal such as silver (Chatterjee, 1996; Amer, 2003; Yldrm et al., 2014; Syed, 2016; Wang et al., 2017). Therefore it is of great significance to extract silver from anode slime for the full utilization of resource. Pyrometallurgy is the most mature process for the extraction of silver because of its stability and adaptability (Hait et al., 2009; Zhao et al., 2010; Gao et al., 2017). However, it also suffers the drawbacks of high operating cost, low extraction rate of silver and severe pollution of smoke dust (usually containing lead and arsenic) (Ludvigsson and Larsson, 2003). To cover the drawbacks of pyrometallurgy process, more and more attentions are giving to the semi-hydrometallurgy process which usually includes a pretreatment process of sulphatising roast or low temperature oxidizing roasting (Tishchenko, 1964). After pretreatment, the refractory silver bearing phases (silver selenide, silver sulfide and silver) are converted into readily leached forms which are often extracted by ammonia, sodium sulfite in alkaline solution (Valiuniene et al., 2010; Wojciech, and Kitka, 2017). Despite its relatively high extraction rate and low investment, it still has the disadvantages of releasing harmful gases since the sulfur dioxide are generally generated in the pretreatment process. In addition, the use of ammonia can easily lead to a leaking into the atmosphere once not carefully dealt with (Aylmore and Muir, 2001). As for silver recovery by sulfite leaching, the consumption of sodium sulfite is rather high which often results in a pipe blocked (Yang et al., 2006)."

Jan 1, 2018

By W. M. Scheding

"There has recently been a resurgence of interest in unit flotation of mill discharges. At the Kidd Creek concentrator, this technique has been successfully applied to silver flotation in a 3050 mtpd silver-copper-lead-zinc division. The major incentive has been improved silver payment through increased overall recovery and better distribution between the sequential copper, lead and zinc concentrates. A large, but variable fraction of the silver in the ore is present as native silver and, being dense and malleable, is susceptible to overgrinding. Grinding circuit surveys showed high concentrations of silver in both primary and secondary circulating loads. Laboratory testwork confirmed that this was selectively flotable, identified the secondary ball mill discharge as the best feed stream and optimized flotation conditions. A 10 t/h pilot plant campaign confirmed that the rate of accumulation of silver was sufficient to sustain continuous production of a silver concentrate and that flotation of the whole stream was not necessary.The present 30 t/h production circuit recovers from 5 to 50% of the silver in the ore at a concentration ratio between 25 and 250. The circuit also contributes to a better understanding of ore mineralogy, as an 'on-line' indicator of elemental silver content."

Jan 1, 1985

By J. G. George

A brief review of the silver industry is presented to set the stage for the analysis of the distribution of silver production by source from various types of mines in Canada and of the changing relationship between the total output of silver and the total output of base metals. The decline in the average grade of the Canadian mines is also discussed and a trend for the future is proposed. The report then examines in broader aspects the world primary silver production and concludes, in the section on outlook, that the effective supply in primary silver will grow at a rate significantly lower than the growth rate expected for base metals. A cumulative deficit of some 900 million ounces is projected for the period 1975-1980 and a further deficit of some 1,100 million ounces if projected for the 1980-to-1985 period.

Jan 1, 1977

By A. P. Pavia

Investigation on profitable ways to recover significant quantities of silver remaining dissolved in highly concentrated chloride solutions frequently pass through the development of solvent extraction (SX) routes. In this work, the general pathways involving Ag(I) extraction by dibutylthiourea (DBT) or tetraethylthiuram disulfide (disulfiram, DSF), from concentrated acidic chloride solutions, are investigated. With this purpose, the dependence of Ag(I) distribution coefficient on ligand and chloride concentrations has been analysed. Furthermore, in order to check whether there is some protonation at any site of DBT or DSF after contact with adequate chloride phases, lH NMR has also been used. The collected spectroscopic data suggest that anionic Ag(I) extraction reactions are not likely to occur. Based on the overall results achieved, proposals for the most probable Ag(I) extraction reactions are made.

Jan 1, 2001

By D. M. Wyslouzil

The fundamentals of dissolving silver and silver minerals are discussed in the following sections: 1) Basic chemical reactions in the silver system 2) Leaching of pure silver minerals 3) Leaching of silver-bearing ores 4) Description of processes The basic chemical reactions of silver are an important guide to the mineral processor or the extractive metallurgist, particularly for systems in which complex formations are balanced against solubilities. The competition of other cations for free ligands can shift the equilibrium to the detriment of silver. Solubilities of pure silver minerals in specific solvents may not be a good indication of the solubility of silver minerals in ores. The abundance of silver minerals which usually appear in a typical ore precludes the selection of a single method that would result in the best extraction of silver from all minerals in the ore. Frequently, the recovery of silver from host minerals requires a destructive pretreatment such as intensive leaching, oxidation with or without elevated temperature and oxygen pressure, or roasting. The transformation of the host or the silver minerals does not always result in a leachable species? and this requires additional treatment before the precious metal can be recovered.

Jan 1, 1990

By Cengiz Karagüzel, Ömer Canıeren

The mobility of gold and silver metals from refractory ores is very low due to free metal ions in their bodies that bind the transportable and free metal molecules or they are encapsulated in minerals such as sulfides, arsenosulfides, carbonaceous, and clayey materials which make it difficult to extract them. As known from the literature, the enrichment of oxide refractory gold, silver ores, Ag, and Au-rich flotation concentrated from sulfur refractory ores can be leached in the chloride-hypochlorite solutions. In this work, the leaching approach was studied to extract silver ions from refractory ores in the presence of hypochlorite media under high pressure. The mineralogical and scanning electron microscopy analysis of the sample indicated that the silver was encapsulated in barite and quartz minerals in fine sizes. In order to obtain the optimum leaching conditions for the silver ore, the effects of several parameters, namely, temperature, leaching time, NaCl and NaOCl concentration, solid ratio, and particle size on the leaching recovery were investigated in detail. The leaching experiments showed that the highest silver recovery of 62.35% was obtained under the following conditions: temperature of 150 °C, oxygen pressure of 1800 kPa, leaching time of 2 h, concentrations of 2 mol/dm3 and 0.4 mol/dm3 for NaCl and NaOCl, respectively, the solid ratio of 30%, and particle size (d80) 15 μm. The results obtained from this study indicated that the enrichment of refractory silver ores to extract the silver encapsulated in barite and quartz minerals could be possible in the chlorite-hypochlorite under high pressure, a relatively shorter leaching time compared to conventional cyanide leaching.

Jan 28, 2021

By O. Espinoza Ortega, S. Song

A process scheme has been devised to improve the silver recovery and the grade of concentrates from the scavenger concentrate of a silver ore flotation circuit. Based on modal analysis studies it was found that silver sulfide minerals in the scavenger concentrate were associated as simple binary particles and finely disseminated in sulfide and non-sulfide gangues. Fine grinding of the concentrate improved the grade-recovery curve of silver to a very limited extent owing to heterocoagulation between liberated fine silver sulfides and coarse particles of gangue. This heterocoagulation phenomenon was prevented by grinding the concentrate in the presence of the dispersing reagent sodium hexametaphosphate. The silver grade-recovery curve was improved by practicing. before the conventional flotation step, a selective aggregation step for the fine silver sulfide particles using the non-polar oil kerosene, the sulthydryl collector Aerophine 3418 and conditioning the pulp under strong agitation conditions.

Jan 1, 2004