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By Éder Domingos Oliveira, Carlos Antonio Morais, Ruberlan Gomes Silva

The objective of this work was to assess the influence of parameters such as residence time, solid content, and temperature in a process route towards purified rare earth liquor which could be adequate to produce marketable rare earth products. The steps of the process route proposed in this study comprised water leaching of a sulfated rare earth ore and removal of impurities through the purification of the rare earth sulfuric liquor, which is the product of the water leaching step. The sample used in the water leaching experiments was a sulfated rare earth ore produced by the reaction of a beneficiated rare earth ore with sulfuric acid followed by roasting at 700 °C for 2 h in a muffle furnace and cooling at 20 °C. The water leaching experiments showed that the best condition comprised a residence time of 30 min, temperature of 20 °C, and solid content of 10% w/w, resulting in a recovery of 71.3% of the rare earth elements (REE) and a lower impurity extraction, e.g., only 15.0% of Fe, representing the main impurity in the rare earth ore. Even when presenting low amounts of impurities, the rare earth sulfuric liquor still needed to be purified before it can be used in the production of marketable rare earth products. In the study, the rare earth sulfuric liquors were purified in two consecutive neutralization steps, first by dosing the limestone pulp to pH up to 3.5 and secondly by adding the lime pulp to raise the pH from 3.5 to 5.0. The application of two consecutive purification steps at 20 °C resulted in the highest overall REE recoveries (65.4%) throughout all the steps of the process, being 71.3% in the water leaching, 99.6% in the partial purification with limestone pulp, and 92.1% in the purification with lime pulp at 20 °C. Under this condition, there was a total elimination of Fe, P, and Th and a significant reduction in the Al, U, and sulfate concentrations in the purified rare earth liquor. The purified rare earth liquor attained through the experiment is expected to be amenable to be used in the production of marketable products due to the lower impurities/REO mass ratios.

By Yongjun Peng, Yufan Mu

Pyrite depression in the flotation of copper ores is difficult due to the activation of Cu2+ ions on pyrite surface. In this study, the radical chain reaction involving the redox cycling of Cu(I/II) induced by sodium metabisulphite (MBS) was exploited to selectively depress the flotation of copper-activated pyrite at pH 8.0. Electrochemical measurements revealed that the presence of Cu2+ and O2 was essential to the formation of SO•− 5 through sulphite oxidation, the main entity to convert the activating species Cu(I)S on pyrite to Cu(II)-hydroxide/sulphate, causing deactivation of pyrite. The depression role ofMBS on pyrite flotation was closely associated with the type of grinding media which affected the electrochemical conditions of flotation. When forged steel was used as the grinding media, a high dosage of MBS was required to depress pyrite, but a low dosage of MBS could almost completely depressed pyrite when high chrome steel grinding media was used. This is because high chrome steel produced a stronger oxidation condition with a higher amount of Cu2+ and O2 which promoted the formation of SO•− 5

Jan 26, 2021

By Jie-Liang Wang, Yongdan Cao, Zhao Cao

"The effect of ethylenediamine tetraacetic acid (EDTA) on flotation separation of fluorite from bastnaesite and its selectively depression mechanism on fluorite were studied by single mineral flotation, artificial mixed minerals flotation, solution chemistry analyses, Zeta potential and XPS measurements.The results show that fluorite can be deeply depressed by EDTA while the flotation of bastnaesite is almost unaffected when octanohydroxamic acid (OHA) is used as a collector. The separation index (SI) between bastnaesite and fluorite increases with the dosage of EDTA, SI can be raised from 1.18 to 12.66 when EDTA dosage increases from 0 to 2×10-3mol/L.Solution chemistry analyses show that EDTA is able to convert the Ca(OHA)2 hydrophobic precipitation on fluorite surface to a soluble Ca-EDTA complex but cannot complexly dissolve the Ce(OHA)3 precipitation on bastnaesite surface. Therefore, the Zeta potential of OHA conditioned fluorite can be reduced significantly by EDTA while the reduction degree to Zeta potential of bastnaesite is relatively low. XPS measurement shows that EDTA removes the chemically adsorbed OHA from fluorite surface but has little effect on the adsorbed OHA on bastnaesite surface. As a result, fluorite can be selectively depressed by EDTA in bastnaesite flotation, which behaves an important industrial application prospect in rare earth ore flotation.INTRODUCTIONNowadays, Rare earth elements (shortened as RE) and compounds are of significant importance for a range of rapidly expanding industrial applications including catalysis, metallurgy, renewable energy, and special materials due to their unique electrical, magnetic, optical and chemical properties [1]. The seventeen RE elements, including the lanthanide-group fifteen elements, yttrium and scandium, could be divided into three groups, i.e., light, medium and heavy RE elements based on the different solubility of RE sulfates [2]. Bastnaesite ((Ce,La)CO3), containing approximately 75% REO, is one of the most important light RE minerals [3]. Flotation is the common method to recover basetnaesite [4-6]. Nonetheless, basetnaesite is often associated with calcium-bearing gangue minerals such as fluorite, and the separation of basetnaesite and fluorite by flotation is usually difficult due to their similar surface properties and therefore floatability [7-9]. Therefore, research on high selective flotation reagents of bastnaesite over gangue minerals has attracted a lot of attention [10]."

Jan 1, 2018

By M. Leroux, P. Lacombe, S. R. Rao, J. Y. Kim, J. A. Finch, G. Labonté, N. Macminn, M. Ounpuu

"Laboratory investigations on two complex ores, the A1 zone ore from Les Mines Selbaie and the Lyon Lake ore from Mattabi Mines Ltd. (Division of Noranda Minerals), have been carried out to determine some of the main variables in collectorless flotation. In particular, the effect of pulp potential (controlled by gas composition), conditioning time, pH and grinding media have been studied.Chalcopyrite showed the greatest response to collectorless flotation among the four major sulphide minerals present, followed by galena. Flotation of sphalerite was variable from minimal to important depending on the mineralogy and the pre-treatment performed. Appreciable silver recovery was achieved collectorlessly for the Lyon Lake ore while it could not be achieved for the A1 zone ore of Les Mines Selbaie. It appears that the difference between the two ores is related to silver's predominance as tetrahydrite in the Lyon Lake ore while it is as argentite and native silver in the A1 zone ore.The response of the ores to collectorless flotation is strongly dependent on the pulp potential, Ep, and pH. Using different gas compositions and different conditioning times it was found that collectorless flotation occurs when Ep is +195 to +295 mv (vs SHE). The actual on-set potential for collectorless flotation is dependent on the ore. A too high potential or prolonged oxidation leads to a decrease in selectivity. Some other factors were examined, notably the effect of pH and the type of grinding media on the selectivity achieved in the laboratory.Preliminary results from a plant trial at Mattabi Mines Ltd. confirmed that collectorless flotation occurs and that it is preferential for chalcopyrite and to a lesser extent galena. Collectorless flotation was not attempted at Les Mines Selbaie. However, examination of the distribution of collector between the different addition points in the copper circuit suggests that it may be present."

Jan 1, 1990

By Jin Duan, Qi Zheng, Bo Yan, Li-cheng Ma, Xiao-kui Che

"The aim of this study was to develop an approach for the selectively removal of Zn(II) from heavy metal-bearing-wastewaters produced by gold chemical industry using magnetic chitosan based adsorbents. Chitosan beads were prepared by cross-linked modification of Fe3O4-chitosan bead using epichlorohydrin as the cross-linker. Both Zn(II) inprinted magnetic chitosan hydrogel bead (Zn-MCHB) and unprinted magnetic chitosan hydrogel bead (MCHB) were prepared and batch adsorption experiments were used to evaluate their adsorption capacities and selectivities. Single adsorption of Cu2+, Pb2+, Zn2+ and Ni2+ showed that both MCHB and Zn-MCHB adsorbs all the four metals and had an affinity in the order of Cu2+ > Pb2+ > Zn2+ > Ni2+. The binary adsorption revealed that the two adsorbents preferentially adsorb Cu2+/Pb2+ from Zn2+-Cu2+/ Zn2+-Pb2+ binary systems. However, MCHB does not show any selectivity in Zn2+-Ni2+ system. In contrast, Zn- MCHB preferentially adsorbs Zn2+ from Zn2+-Ni2+ binary system. Furthermore, the adsorption selectivity is predictable from stability constants of the metals with the amino group of chitosan. The information revealed in this work can be used for further applications in the treatment of wastewater containing a range of heavy metals from the gold chemical industry."

Jan 1, 2014

By Joni M. Barnes

A strain of Pseudomonas stutzeri isohted from selenium contaminated surface waters, was found to be effective . in reducing selenate (Se04 2) stoichiometrically to selenite (Se03 2 '), which was further reduced to elementaJ selenium (Se0 ). These reactions were concurrent with the microbial oxidation of lactate. In order to assess quantitatively the amounts of seilenate and selenitein solution, improvements to existing analytical methods (ion exchange chromatography and inductively coupled plasma atomic emission spectrophotometry technique) .were made.

Jan 1, 1991

By I. Girón

El siguiente estudio revela la importancia del cultivo del selenio, propiedades, combinaciones y distintos usos en la industria y sistema de comunicación telefónica. Asi también describr el proceso de purificación y obtención de este compuesto mineral en Cerro de Pasco Corporation, destacando al Perú como uno de los países productores a nivel mundial, pese a su reducida proporción.

Jun 20, 1954

By Phil Pennington, D. Jack Adams

Mining and processing of minerals, metals, and fossil fuels can release selenium and arsenic into wastewaters. Both selenium and arsenic are difficult to remove to levels that meet current drinking water and discharge criteria. These metalloids can be used as electron acceptors by microorganisms transforming them back to reduced states, thus removing or stabilizing them. Bioremediation cost effectiveness will be discussed in terms of site information required, microbial populations, co-contaminants, pH, redox, and nutrients. Full-scale, economical ex situ and in situ biotreatments are possible and can produce 1,000’s of times less sludge than conventional precipitation technologies.

Jan 1, 2005

By G. Apsey

Eutectic freeze crystallization (EFC) is a novel technique for the recovery of pure salt and pure water from hypersaline waste brines. It is therefore a promising technology for the treatment of industrial waste waters. The impurities caused by crystallizing salt out of multi-component brines by EFC have not yet been investigated, however. To these ends, the selenium impurity found in sodium sulphate, produced from the waste brine of a platinum operation, was investigated. It was believed that the similarity between sulphate and selenate ions allowed isomorphous substitution of selenate ions into the sodium sulphate crystals, which was the likely cause of impurity uptake. It was found that the presence of sodium chloride in the industrial brine promotes the uptake of selenium, while ionic strength of the brine and mass deposition rate of sodium sulphate did not have a significant effect on the selenium uptake. Isomorphous substitution is predicted to be the most significant mechanism by which all impurities will be taken up when applying EFC to other industrial waste brines.

Jan 1, 2013

By J. Fu

"Since it was first identified in 1817, selenium has received considerable interest. Native selenium and a few selenium minerals were discovered several decades later. With the increasing number of selenium minerals, the occurrence of selenium minerals became the focus of much research. A great number of selenium deposits were reported all over the world, although few independent selenium deposits were discovered. Selenium is obtained mainly as a byproduct of other metals, and is produced primarily from the anode mud of copper refineries. This paper presents a comprehensive review of selenium minerals, as well as the treatment of copper refinery anode slimes for the recovery of selenium. Our focus is on the selenium minerals, including their discovery and occurrence, and the distribution of selenium resources. In addition, the main methods of recovering selenium from copper anode slimes are summarized. IntroductionSelenium (Se) was first observed in 1817 in a laboratory (Greenwood et al., 1984). The discovery of selenium was made by the Swedish chemist J.J. Berzelius and J.G. Gahn, who isolated selenium from a red residue in sulphuric acid from pyrite mined at Fahlun, Sweden. Selenium was named from the Greek word selene (moon), since it resembled tellurium, which had been discovered a few years earlier and named from the Latin word tellus (Earth).After the first observation of selenium in the laboratory, selenium received considerable interest. In 1954, E.P. Kaiser pointed out that Se is enriched in sulphide ores and often associated with Bi, Co, Sn etc. (Kaiser 1954). In 1959, Hawley and Nichol investigated selenium in Canadian sulphide minerals, and presented the content of selenium in sulphide from several deposits of different types. They also proposed that Se is enriched in lowtemperature hydrothermal pyrite (Hawley and Nichol, 1959). The thermodynamic conditions for forming native selenium and selenium minerals in sedimentary rocks were discussed, as well as geochemical behaviour of selenium near the oxidation zones of sulphides in the 1970s (Howard III, 1977; Zhu et al., 2003). Zhu et al. examined the morphology, features, and genesis of native selenium from Yutangba, Enshi City, Hubei Province, China in 2004, and pointed out, from the different forms of native Se, that selenium can be activated,transformed, remobilized, and enriched at sites such as in the unsaturated subsurface zone or in the saturated zone (Zhu et al., 2005). The transport and deposition of selenium in felsic volcanic-hosted massive sulphide deposits of the Yukon Territory, Canada was studied and reported by Layton- Matthews et al. (2005)."

Jan 1, 2016

A study was undertaken to remove the Se from waste solutions using a raw form of the biomass called Iota Chips derived from the seaweed, Eucheuma spinosum. Removal of Se from solutions was investigated as a function of time, pH, conc. of Se in solution (0.1 to 100 ppm) and lota Chips to liquid ratios of 10-2 to 10-5. For solutions containing initial conc. of 0.1 ppm Se, with the addition of Iota Chips at a solid to liquid ratio of 10-3, the Se conc. decreased to 0.03 ppm in about 3 hours. Iota Chips absorption capacity to the Se and its application to the treatment of the metallurgical processing effluents are discussed.

Jan 1, 1992

By Wainer da Silveira e Silva, Marco Antonio Teixeira, Robisom Damasceno Calado, Carlos Alberto Chaves, Tone Takayama Filho

A preocupação com o adequado tratamento de resíduos industriais surgiu com o conceito de desenvolvimento sustentável criado pelo Clube de Roma e contribuiu para o uso racional dos recursos naturais ao longo dos últimos 50 anos. A preocupação com a produção responsável e uso judicioso de recursos naturais priorizou a reciclagem de materiais na agenda das empresas, tornando-se numa atividade de alta relevância, vital para a sustentabilidade econômica e ambiental. Este trabalho aborda os aspectos técnicos, econômicos e ambientais da reciclagem de resíduos contendo zinco através do estudo de caso de reciclagem de resíduos gerados no processo de fabricação de aço em Forno Elétrico, denominado pó de Aciaria Elétrica (PAE). A indústria ainda está em busca de tecnologias para redução da geração e reciclagem desse resíduo. A relevância do estudo está na utilização da Análise Hierárquica de Processo (AHP) para avaliação e seleção da melhor alternativa, entre várias, para tratamento e reciclagem do PAE. Como resultado, demonstrou-se a eficácia do uso da metodologia no empreendimento de reciclagem de resíduos contendo zinco implantado pela Votorantim, em Juiz de Fora, Minas Gerais.

Nov 12, 2019

By Bráulio Salumão de Oliveira

Este estudo avaliou oportunidades de integração entre requisitos ambientais e econômicos durante etapas iniciais do desenvolvimento de produtos. Como principal ferramenta foi utilizado o Mapeamento de Fluxo de Valor, associando conceitos de manufatura enxuta, Design for Manufacturing and Assembly (DFMA) e Ecodesign, aplicado a um item de mobiliário aeronáutico em material compósito. Os resultados apontam que o tempo total de fabricação poderia ser reduzido em até 43%, além da otimização logística. A forma de construção influencia diretamente os impactos ambientais e oportunidades de utilização de matérias-primas menos agressivas foram apontadas como sugestões. O aspecto visual dos Mapas de Fluxo de Valor facilita a análise das informações e a tomada de decisão na seleção de materiais e processos que minimizem desperdícios e impactos ambientas na manufatura.

Oct 30, 2017

By Claudemir Ribeiro

A lança de injeção de carvão pulverizado (PCI) é um método consolidado na indústria siderúrgica, que possibilita a redução do consumo de carvão vegetal ou de coque de carvão metalúrgico enfornado, além do ganho de produtividade. A seleção de materiais adequados para a lança de injeção é de suma importância para agregar ainda mais valor ao método. A finalidade deste trabalho é nortear a seleção das ligas aplicadas em alta temperatura, visando o melhor custo benefício, por meio das análises da resistência à corrosão, fluência e estabilidade estrutural. Foram realizados testes em uma usina siderúrgica chinesa com as ligas Sandvik 253 MA™ (UNS S30815) e UNS S32109. A experiência demonstrou como as siderúrgicas podem obter ganhos com a seleção adequada da liga. O custo-benefício do 253MA que é ligado ao Cério, Silício e Nitrogênio, mostra-se como uma ótima alternativa para o processo de injeção de carvão, devido a sua alta resistência à oxidação, à fluência e à erosão. Outras ligas como UNS S30403, UNS S31009 e UNS N08810, que são muito utilizadas em alta temperatura nas indústrias em geral, também foram analisadas como comparativo.

Aug 17, 2017

By Ali Porbaha

The use of soil nailing technology as a cost effective alternative for excavation support and slope stabilization has substantially increased in the United States during the last decade. For example, in the past thirteen years, more than 185,800 square meters of soil nail walls have been constructed in California alone. The conventional soil nail systems pose difficulties when ground conditions are subject to caving, for instance for silty sand (sugar sand) or cobbles and boulders. The construction industry has developed self drilling hollow bar systems (or pressure injected bored, IBO) that combine both drilling, placing and grouting in a single operation as a solution to speed up construction. While the system is extensively used for temporary applications, nevertheless, some concerns, particularly about corrosion, has limited the use of this technology as a permanent system in North America. This study presents several issues related to self drilling soil nail systems, the results of a field investigation and a summary of the research project.

Jan 1, 2006

By D. G. Klaren

Self-cleaning fluidized bed heat exchangers are conquering the world for reason that they are able to solve any severe fouling problem in indirect heat transfer due to the circulation of cleaning particles through the tubes of vertical shell and tube exchangers. In most cases, these particles consist of chopped metal wire. Moreover, self-cleaning fluidized bed heat exchangers perform with excellent heat transfer at very low liquid velocities, which makes completely new designs of shell and tube configurations possible. Further, self-cleaning fluidized bed heat exchangers show a strong shear thinning effect in non-Newtonian liquids. All the above characteristics make the self-cleaning fluidized bed heat exchanger an ideal tool for the indirect heating of laterite nickel slurry in High-Pressure-Acid-Leach (HPAL) plants. Preliminary tests and evaluations of these heat exchangers have shown that the performance and price of these heat exchangers used for the production of nickel and cobalt from a laterite slurry, cannot be matched by existing conventional heat exchange systems. This article explains the principle, design, lay-out and enormous advantages of the self-cleaning fluidized bed heat exchange technology in a plant suitable for an annual production of approx. 45,000 ton nickel and 4,500 ton cobalt from laterite slurry through high pressure'acid leaching.

Jan 1, 2002

By D. G. Klaren, E. F. de Boer

Self-cleaning fluidized bed heat exchangers have demonstrated unparalleled performance internationally for the implementation of indirect heat transfer in severely fouling fluid environments. The ingenious configuration of recirculated cleaning particles through the tubes of vertical shell and tube heat exchangers provides the ability to solve any problems that arise as a consequence of tube-side fouling during indirect heat transfer to process fluids or slurries. In most cases, the cleaning particles consist of chopped metal wire, however other process-specific materials have been used. In addition to the mitigation of fouling effects, a number of other significant benefits for slurry heating are afforded by the mode of operation of the self-cleaning fluidized bed heat exchangers. Increased turbulence at the slurry/tube interface is imparted by the action of the fluidised particles, resulting in very high heat transfers at relatively low liquid velocities. Furthermore, given the thixotropic nature of most process slurries, the action of the fluidised particles imparts additional shear to the process slurry, resulting in shear thinning effects with a consequent reduction in pressure drop and enhancement of heat transfer across the heat exchanger. The benefits provided by the self-cleaning fluidized bed heat exchanger make it the ideal option for the indirect heating of laterite nickel slurry for High-Pressure-Acid-Leach (HPAL) plants. This article explains the principle and application of the self-cleaning fluidized bed heat exchanger technology for the processing of laterite nickel and cobalt slurries in HPAL plants. It also presents an elegant method to revamp existing direct heated laterite nickel and cobalt processing plants into an indirect heated configuration employing self-cleaning fluidized bed heat exchangers.

Jan 1, 2004

By Sheer T. J, Van Rensburg J P

The primary objective of this research was to address the demands imposed on self- contained self-rescuer (SCSR) performance dur- ing simulated escapes. The results clearly indicate that SCSR performance, apart from the inherent technological features, is a function primarily of the physical and anthro- pometric features of the wearer, and of the particular nature of the escape route. These factors consequently play a major role in the planning of any escape strategy, which may vary from mine to mine. It is therefore concluded that each mine would have to formulate its own escape strategy which in turn would depend on the choice of SCSR, and the particular escape Route.

Jan 1, 1988

By Thomas E. Ban, Charles D. Thompson, Charles A. Czako

Continuous sintering-a metallurgical process for more than 50 years-has broadened from its origin in nonferrous metallurgy to present-day applications in ferrous, chemical, and nonmetallic fields. During the past year, self-fluxing sinter production has been a subject of active interest to iron metallurgists in North America. Accomplishments however, have come predominantly from Europe and proper interpretation of these reports requires an understanding of European raw materials and European economics. The technology, of course, can be applied universally.

Jan 10, 1959

By Mario Mauro, Jeff Taylor, Carlos Morales

"In 2007 the US Army Corps of Engineers classified the Herbert Hoover Dike in Florida as a Dam Safety Action Classification (DSAC) 1 dam, and started the implementation of one of the largest dam rehabilitation projects in the nation. The construction of the cutoff wall is a key feature of this rehabilitation work to upgrade the dike to current dam safety criteria. The cutoff wall installation is currently being completed on Reach 1, which extends from Port Mayaca to Belle Glade, under a Multiple Task Order Contract based on performance specifications and stringent verification criteria.For the construction of the cutoff wall TREVIICOS selected the self-hardening slurry method. Since the cutoff wall is installed through a layer of highly variable limestone with Unconfined Compressive Strength (UCS) up to 14,000 psi, the excavation requires the use of the hydromill equipment. This is the first successful application of the hydromill technology with self-hardening slurry in a large scale project in the US. This paper presents the details of the method utilized, the quality control procedures, and the experience gained over seven miles of cutoff wall installed.INTRODUCTIONProject LocationThe Herbert Hoover Dike (HHD) system, around Lake Okeechobee in South Florida, consists of a series of levees, culverts and locks and is approximately 143 miles long (Figure 1).Lake Okeechobee is the second largest freshwater lake in the lower 48 states of the United States. The lake is the primary drinking water source for numerous communities around the lake and to millions of people living along the lower east coast. The lake is also a vital source of irrigation for the agricultural industry in the South Florida region.Lake Okeechobee is 33 miles wide from north to south and 30 miles wide from east to west and has a surface area of 730 square miles. The average water depth of the lake is 9 ft."

Jan 1, 2017