Search Documents

By Y. H. Zhan

A new P(MAAA) latex was developed and used in separation of ultrafine apatite from calcite and silica by means of selective flocculation. The latex was found to flocculate selectively apatite from apatite/calcite and apatite/silica mixtures in the presence of sodium tripolyphosphate and sodium silicate over a pH range from 9.1 to 9.4. The separation of apatite from calcite was more selective with sodium tripolyphosphate, while the results of the separation of apatite from silica were better when sodium silicate was used. In the apatite/calcite system, 90% apatite recoveries into a concentrate containing 34% P2O5 were possible in the presence of 4 mg/l of sodium tripolyphosphate at a latex dosage of 2.2 kg/t. In the apatite/silica system, 80% of apatite could be recovered into a concentrate containing 33% P2O5 in the presence of 20 mg/l of sodium silicate at a latex dosage of 1.1 kg/t. Deposition tests were used to study the interaction between the latex and the mineral surfaces. The results revealed that deposition density of the latex on apatite was higher than on calcite; the differences between the deposition onto these two minerals were higher at pH 9.2 than at 7.2. The results point to the stronger interaction between the latex and apatite surface when compared with the latex-calcite interactions.

Jan 1, 1998

By H. Sis, D. Dahlin, S. Chander, C. Summers

Bench-scale selective-flocculation tests were conducted on samples of Florida and Western phosphate process tailings. Physical, mineralogical, and surface characteristics were determined for both types of samples. The flocculation tests investigated dispersant and flocculant types and doses, pH, and slurry percent solids, while other parameters were held constant. Where selectivity was achieved, phosphate minerals remained dispersed, whereas silicate minerals flocculated and settled. In single-stage tests, flocculants having low to medium anionic character effectively upgraded products at moderately elevated pH. Multiple-stage tests, and tests in which flocculants of lower molecular weight were used as site-blockers, gave improved results.

Jan 1, 2002

By W. C. Hirt

Selective flocculation was used to produce superclean zinc concentrate with minimized silica contamination. Research was carried out on a flotation concentrate from the Jersey Miniere Zinc Company (JMZ) in Gordonsville, Tennessee. The material was first dispersed with sodium silicate and then causticized tapioca starch was used to selectively flocculate the sphalerite, leaving the silica in suspension. This technique has been applied commercially to iron ore beneficiation but has never been used for processing zinc. The feed material assayed 0.45% Si02. Use of 0.56 kg/tonne (1.13 lb/st) of sodium silicate and 0.070 kg/tonne (0.141 lb/st) of causticized tapioca starch resulted in 98.2% zinc recovery in a purified zinc concentrate assaying 66.0% Zn and 0.24% silica. The present target level for silica contamination in JMZ zinc concentrates is 0.3% Si02. This work has shown that selective flocculation offers a potential method for cleaning flotation concentrates, particularly where low silica products are required.

Jan 1, 1993

By A. D. Read

Selective flocculation was investigated as a possible method of recovering values from mineral slimes which are too finely divided to be treated by conventional mineral processing methods. It has proved possible to flocculate selectively either haematite or a silicate from a stably dispersed mixture by varying the anionic character of the high-molecular-weight, partially hydrolysed polyacrylamide employed. Different separation methods have been developed for hard and soft water media. Electrokinetic and infrared techniques have been employed to elucidate the mechanism whereby selectivity has been attained in the different cases. The following influences on the various selective flocculation parameters have been investigated: (a) the level of the different reagent additions and (b) the shear conditions during and after flocculant addition. A feature of the particular system studied was the high solids content at which it was possible to achieve good selectivity. Probable reasons for this are advanced, and the possibilities and potentialities of the process are discussed.

Dec 1, 1971

Poor floatability of fine particles is known to be the main cause of the low recovery of ilmenite in Panzhihua, which is the largest titanium mine of China. To get an optimum ilmenite recovery, selective flocculation, and flotation of fine ilmenite was investigated through flotation tests, particle size analysis, zeta potential tests and scanning electron microscopy. The results indicate that carboxymethyl cellulose (CMC) shows flocculation effect for both ilmenite and titanaugite without selectivity, while selective flocculation could be realized by the combination of water glass and CMC. It is because that competitive adsorption would take place on these two kinds of mineral when water glass and CMC are used together. On the surface of ilmenite, the adsorption ability of CMC is stronger than that of water glass, so that CMC can absorb to the same extent irrespective of the presence of a pre-adsorbed layer of water glass and ilmenite particles is flocculated by CMC. The same cannot be said of the titanaugite phase as water glass strongly adsorbs onto the titanaugite, and the adsorption of CMC is hindered. Therefore, the titanaugite particles keep dispersion. Furthermore, the flotation of fine ilmenite particles is feasible as the ilmenite floccules could react with sodium oleate. In the flotation separation of Panzhihua ilmenite ore, the recovery of TiO2 increased from 52.63% to 68.28% by selective flotation. Keywords: ilmenite, flotation, selective flocculation, adsorption

Sep 1, 2012

By Yosry A. Attia

One of the most significant advances in Mineral Processing in recent years, is the development of the selective flocculation technology. The technology is primarily aimed at recovering the mineral values from ultrafine ore suspensions. This is achieved by selectively aggregating the mineral particles in question to such size as to enable their effective separation from the suspension. Selective flocculation utilizes the differences in the physical-chemical properties of the various mineral components in the mixed suspension. It is based on the preferential ad- sorption of an organic flocculant on the particular solids to be flocculated, leaving the remainder of the particles in suspension. In order to understand the mechanics of this process, selective flocculation may be divided into four major sub processes; these being: ore slurry dispersion, in which all the particles are stably and uniformly distributed in the suspension with the individual particles being essentially separate; flocculant selective adsorption and floc formation; floc conditioning, which aims at obtaining flocs with desire properties for their subsequent separation and with minimum entrapment of dispersed particles; and floc separation from the suspension. These sub processes will be reviewed later in this article.

Jan 1, 1982

By K. Sasaki, S. Kuroiwa, H. Miki, Y. Aoki, T. Hirajima, Y. Orii, G. P. W. Suyantara

Selective flotation to separate copper minerals from, for example, Mo- and/or As-bearing minerals is a continuing problem because the selectivity of current systems is imperfect. Selective Cu-As flotation is currently difficult, and the most common Cu-Mo selective flotation method uses NaHS; this must be done in an enclosed system because, under acidic conditions, this method produces hydrogen sulfide. In this paper, some novel alternative flotation processes that use redox reactions are discussed; these methods have a much lower environmental impact. Oxidation and reduction reactions can be used to make copper minerals more hydrophilic and Mo-bearing minerals more hydrophobic. X-ray photoelectron spectroscopy (XPS) analyses indicated that the copper minerals became hydrophilic because hydrophilic iron precipitated and several hydroxides covered the copper minerals’ surfaces, whereas the molybdenum minerals remained hydrophobic because their sulfide surfaces were not covered. Flotation experiments on these minerals after redox treatments indicated that excellent separation of Cu-minerals from Mo-minerals can be achieved. Possible mechanisms for this separation were investigated using detailed surface analyses and thermodynamic calculations. The additives used to initiate the redox reactions are easy to handle and make these new flotation procedures better than current processes because the new methods do not emit effluent gas and because they are commercially viable. Keywords: Flotation; chalcopyrite; molybdenite; oxidation; reduction

Jan 1, 2020

By J. D. Miller

Low-level radioactive contaminated soils (10-500 pci/gm) created by defense-related activities at certain superfund sites, such as Nevada Test Site (NTS), is a current environmental concern. Many of these contaminated sites may require appropriate cleanup and restoration, which could cost billions of dollars and put tremendous pressure on our limited financial resources. Therefore, the development of a selective flotation process to separate such radionuclides from contaminated soils should be considered. In this study, both a pure depleted UO2 sample and three synthetic UO2/soil mixtures were used to evaluate surface chemistry features and to examine the possibility for the flotation of fine UO2 particles from selected soils. It was intended that this model system would be a reasonable representation of contaminated soils such as those found at the Nevada Test Site which are reported to be contaminated by PuO2 fallout. The effect of reagent schedule, particle size distribution, and surface charge are discussed with respect to the flotation separation of the UO2/soil mixtures. It was found that both commercial fatty acids and reagent grade sodium oleate are effective collectors for UO2 flotation provided the pH is adjusted to the range of pH 8-9. The bench-scale flotation results successfully demonstrated that froth flotation technology can be used to remove UO2 from such model contaminated soils with appropriate flotation chemistry conditions which depend on the soil characteristics and other pretreatment procedures. In the best case, 90.2% of the UO2 was removed from a UO2/NTS soil mixture (119 ppm UO2) and the soil reduced in UO2 contamination from 119 ppm to 17 ppm in a single stage bench flotation. The impact of clay slimes present in the soil is revealed by the results which show that, for example, for a deslimed soil (28x400 mesh and 100 mg UO2/kg soil) 85¬90% UO2 recovery can be obtained with a reduction in contamination to 4.6 mg U02/kg soil.

Jan 1, 1995

By M. A. D. Azevedo, J. D. Miller, R. Kobler, E. Mutkowska

Up to 3 million tons of automotive shredder residue (ASR) is generated annually in United States. Plastics are the most valuable component of the ASR material making up approximately 25% of the total weight. In order to reuse these plastics, a selective process is required to separate each plastic, with very high purity and favorable economics. One separation technique, which may be able to selectively recover the plastics from ASR, is flotation. The preliminary flotation results have demonstrated that acrylonitrile-butadiene-styrene (ABS) and polycarbonate (PC) can be selectively separated from the model ASR feed, the PC/ABS/PA 66 system, by appropriate control of the surface chemistry.

Jan 1, 2001

By Masanori Mori, Hajime Miki, Osamu Ichikawa, Tsuyoshi Hirajima, Mitsuru Sawada, Keiko Sasaki

For pretreatment of selective flotation, surface oxidation of chalcopyrite and molybdenite was applied by oxygen plasma then the minerals were washed by solution at pH 9 with oxygen bubbling. Surface characteristics of these minerals were investigated with AFM, XPS, zeta potential and contact angle measurements. Contact angle of chalcopyrite and molybdenite decreased a lot by plasma treatment. When they were washed with pH 9 solution with oxygen bubbling, contact angle of molybdenite increased whereas chalcopyrite one kept low. Adhesion force measurements indicated similar behavior. Result of flotation experiments indicated low recovery of both chalcopyrite and molybdenite after plasma treatment and only molybdenite recovery became higher after washing. Selective flotation of chalcopyrite and molybdenite could be achieved with this process. Possible mechanism of selective flotation was proposed from the results of XPS, AFM, etc.

Jan 1, 2014

By I Ametov, S Harmer, R Alford

A process that allows selective flotation separation of low Cu/S ratio minerals (chalcopyrite and pyrite) from high Cu/S ratio minerals (bornite and chalcocite) from a mixed copper mineral concentrate under controlled oxidative-reductive potential conditions has been developed. The process has been extensively tested on samples with varying mineralogy using laboratory batch flotation tests and mini pilot plant trials.In this process, the mixed final copper mineral concentrate is purged with nitrogen, and then treated with sodium dithionite to achieve a slurry Eh in the -200 to -100 mV standard hydrogen electrode (SHE) range. Flotation was then carried out using nitrogen gas. As a result, a low Cu/S ratio concentrate (<1.3) and a high Cu/S ratio (>1.6) tailing stream were produced. QEMSCAN analysis of the flotation products showed that more than 85 per cent of the chalcopyrite and 95 per cent of the pyrite reported to the froth concentrate. Chalcocite and bornite were almost evenly distributed between the concentrate and tailing streams.Surface analysis studies, focused on the mechanism of separation, showed that at a negative redox potential xanthate and possibly dixanthogen are the dominant hydrophobic species on the surface of chalcopyrite and pyrite. As a result, the flotation of these minerals remained unaffected. In contrast, a much lower concentration of xanthate species on the surface of chalcocite and bornite particles was observed. Therefore, it is likely that at low Eh the copper xanthate complex desorbs from the chalcocite and bornite surfaces, causing a decrease in surface hydrophobicity and the diminished floatability of chalcocite and bornite.CITATION:Ametov, I, Harmer, S, Grano, S and Alford, R, 2014. Selective flotation of chalcopyrite and pyrite from a mixed copper mineral concentrate under controlled redox potential conditions, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 131–140 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By T. N. Matveeva, L. B. Lantsova, N. K. Gromova

"Multimetal gold-antimony ores are complexed processing products, since they are characterized by veindisseminatedsulfide mineralization with fine-dispersed submicroscopic gold, low content and uneven distribution ofAu, which is concentrated together with iron sulfides (pyrite, arsenopyrite, pyrrhotite). Such ores are classified asrefractory ones and characterized by low gold recovery rates during cyanation. A particular feature of gold-antimonydeposits is the presence of antimony in industrial concentrations therein, along with gold that significantly increasesthe value of these deposits. The main antimony mineral is antimony sulfide - antimonite (stibnite). Gold-antimonyores undergo flotation concentration with producing collective gold-containing concentrates or gold sulfide andantimony concentrates. The purpose of the work is an experimental study of the flotation separation mechanism ofsulfide minerals of copper, antimony and arsenic using tannin-containing modifiers during processing of multimetalgold-bearing ores. During the research it was established that for the selective separation of antimony and arsenicsulfide minerals into concentrates of different kinds, it is possible to use vegetable reagents capable to be selectivelyadsorbed on the arsenopyrite surface. Using the laser KEYENCE VK-9700 and electronic LEO-1420 VP INCA-350microscopy methods, it has been established that the film of a vegetable modifier was not washed off with water andfixed firmly enough on the surface of the polished sections of arsenopyrite. In the X-ray spectrum there are C and Obands related to the reagent structure. The vegetative reagent is fixed both on the pre-adsorbed phase of the collectorand on the areas free from the collector. On the polished sections of antimonite before and after a contact with thetannin solution, only partial adsorbed tannin phases are detected, which disappear as a result of subsequent washingwith water.The reported study was funded by RFBR according to the research project ? 16-05-00646 ?."

Jan 1, 2018

By Leoncio Méndez, Jesús Arguijo, Juan José Frausto, Daniel Castruita, Daniel Aguilar

Minera Sabinas (Grupo Peñoles), localizada en Sombrerete, Zacatecas, México, produce concentrados de cobre y zinc. Su proceso es un circuito de conminución de quebradoras y dos molinos de bolas en circuito cerrado con hidrociclones seguido de un circuito de flotación, a partir de mineral polimetálico extraído de una mina subterránea. Su problemática consiste en que la recuperación por flotación disminuye significativamente cuando minerales con contenido de pirrotita son procesados. La flotabilidad natural de la pirrotita supera la cinética de flotación de las especies de cobre y zinc y limita la capacidad de la concentradora para generar concentrados vendibles. Este artículo presenta un diagnosticó de los problemas que se tienen cuando se procesan minerales con alto contenido de pirrotita, así como resultados de un programa experimental a escala laboratorio realizado en el CIDT de Peñoles y en sitio. La investigación se enfocó en definir un esquema de reactivos para poder procesar minerales con pirrotita en su composición. Compósitos de alta y baja ley de cobre fueron usados en la investigación. Se identificó el agua de proceso como una fuente de iones calcio y sulfato. Se desarrolló un esquema de reactivos orientado a promover la selectividad de las especies de valor respecto a la pirrotita, incluyendo tratamiento del agua de proceso.

Sep 20, 2019

By Brig M. Moudgil

It was reported earlier that francolite and dolomite from the South Florida deposits cannot be selectively floated using conventional conditioning with sodium oleate as the collector. However, dolomite could be separated from francolite if the minerals were first conditioned at pH 10 followed by reconditioning at a lower pH. An optimum separation was achieved at a reconditioning pH below 4.5. Reconditioning pH and collector concentration were determined to exert a major influence on the selectivity. Flotation, adsorption and transmission infrared spectroscopic results are presented to elucidate the mechanisms underlying the observed selectivity.

Jan 1, 1984

By Subhas G. Malghan

Feldspathic deposits occur widely throughout the United States, but North Carolina, California, Connecticut, and South Carolina accounted for over 80% of the total domestic feldspar output for the year 1973.1 Pegmatites and granites constitute the major feldspar reserves of the United States, 2 and in addition, feldspar is produced as a byproduct by firms whose major products are spodumene and mica. 3 Feldspar flotation is practiced in the United States, Mexico, Finland, Norway, West Germany, Japan, and the USSR. According to the US Bureau of Mines estimates, the production of feldspar in the United States and rest of the world were 704,000 and 2,514,000 t, respectively. Feldspar is principally used as a flux in making glass, pottery, porcelain, enamel, tile, and other ceramic products. In recent years, the domestic feldspar industry is faced with a number of problems. As a result of increased cost of energy and the introduction in 1972 of new legislative programs relating to air, water, and noise pollution, land-use restrictions, and mined-land rehabilitation, the production costs have increased. Apart from the increased cost of operation, an operational problem exists with the feldspar producers in North Carolina, especially those in the Spruce Pine area. This problem is concerned with the use of hydrofluoric acid in the feldspar flotation. Feldspar producers in Spruce Pine, NC, have been discharging process waste water into the North Toe River. The mill waste water contains active fluoride ions. Fluoride in excessive concentrations is undesirable in waters used for drinking. It is stated that water containing 0.9-1.0 ppm fluoride will seldom cause mottled enamel on children's teeth; and for adults, concentrations less than 3-4 are not likely to cause endemic cumulative fluorosis and skeletal effect. Although the literature on this subject is rather confusing and inconclusive, the inference that concentrations over 4 ppm may affect bone structure is clear. According to the recent Federal Register,4 maximum fluoride level of 1.4 ppm at 79°-98°F is considered to be adequate and safe for the protection of health of the consumers. The EPA and state environmental agencies have accelerated their drive to reduce water pollution on a faster schedule. By 1977, the EPA specifications for maximum contaminant level of fluoride ions in the discharge waters of feldspar milling operatins is expected to be reduced to 2.0 ppm. The other problems of using hydrofluoric acid are the following: toxicity, hazards of handling and storage, and high cost as compared to other inorganic acids (almost 16 times the cost of sulfuric acid). In order to reduce fluoride levels in mill discharge waters, mining companies have taken the following steps: I) Recirculating a part of their mill water. Even though recirculation of mill water seems to be a novel method of reducing fluoride contamination of the discharge water, there are certain operational and handling problems. 2) Conducting research on the treatment of fluorides in mill waste water. The technology of treatment of fluoride ions has received considerable interest in the recent years. A recent research report5 estimates that the cost of fluoride ion removal to meet the present specifications in the feldspar industry is approximately $0.25/t of ore processed, and about $0.50/t of feldspar produced. At the request of the feldspar producing industries in North Carolina, the North Carolina State University (NCSU) Minerals Research Laboratory has taken up a research program directed towards overcoming the fluoride ion pollution problem. After a close study of the operational, technical, and economic aspects of feldspar flotation, it was decided to attempt to replace the conventional hydrofluoric acid process. Conventional Feldspar Flotatin Using Hydrofluoric Acid Since the inception of the feldspar flotation process using hydrofluoric acid by O'Meara2,6 the process has achieved a great commercial success. In the conventional flotation separation of feldspar-quartz, hydrofluoric acid is used to suppress quartz and activate feldspar, and a long chain amine salt (acetate or chloride) is used as a collector. The bulk of amine collectors used in current feldspar operations are applied as the water-soluble acetates of the free-base amines. These products are pastes or waxy solids which are available in a range of acetic acid neutralization levels generally 50 to 100% neutralized. In spite of the problems mentioned in connection with the use of hydrofluoric acid, this process is extremely stable with respect to changes in the process variables. With the exception of a few operations, alaskite and pegmatite are the major sources of feldspar.7 In the flotation treatment of a pegmatite that contains iron-bearing minerals (heavy minerals), mica, feldspar, and silica, a logical order of removal presents itself considering the following:8 1) Mica is readily floated by an amine collector in a pulp pH 3.5. Some iron-bearing minerals will usually respond to amine collector in acid circuit with the mica concentrate. 2) Since iron minerals tend to occur invariably in the feldspar concentrate, it is desirable to remove most of these prior to feldspar flotation. A fatty acid or a petroleum sulfonate collector used in this flotation step in acid circuit will float iron-bearing minerals. 3) Using hydrofluoric acid to maintain pH of 2.5, an amine collector employed in a final step will float feldspar away from silica, usually leaving the latter in the tailing as a high-grade silica concentrate. The problems connected with the flotation separation of feldspar-quartz arise due to the similarities in their chemical structure. Therefore, any reagent system that is likely to succeed in feldspar-quartz separation should have adsorption affinity towards one of the minerals and depression effect towards the other mineral.

Jan 1, 1979

By James S. Browning

The Bureau of Mines conducted laboratory and small--scale continuous tests of weathered mica pegmatite ores from Hart County, Ga., to determine the technical feasibility of recovering commercial-grade mica concentrates by flotation. Two modifications of the Bureau-developed anionic-cationic method were used. In one method, sodium carbonate and calcium lignin sulfonate were used for pH control and quartz depression; this method yielded mica concentrates containing 98.5 percent mica with a recovery of 91.4 percent. In the other modification, lime and sodium silicate were used with the calcium lignin sulfonate; concentrates containing 98.9 percent mica with a recovery of 86 percent were obtained.

Jan 1, 1966

By Rosa Malena Fernandes Lima, Kerollan da Silva Ramos, Joyce de Assis Silva, Geriane Macedo Rocha

This study evaluated the effects of collector type amide-amine compared with those of conventional etheramine acetate (both cationic collectors) on the surface properties of quartz and hematite. An examination of certain properties of the reagents indicated that the new collector amide-amine has CMC (critical micelle concentration) and pKa values (100 mg/L and 8.2, respectively) significantly lower than those of etheramine (800 mg/L and 9.4, respectively). Microflotation tests showed that the recoveries of quartz with amide-amine in all the concentrations tested were higher than those with etheramine. This is attributed to its lower CMC and pKa values. The selectivity window between quartz and hematite flotation using amideamine was higher at pH 10.5 (approximately 80% for 5 mg/L). Therefore, the use of starch is not necessary in siliceous itabirite flotation by amide–amine collector. Zeta potential measurements and infrared spectra reveal that the adsorption of amide-amine collector on quartz surface occurs mainly by electrostatic attraction. Considering the better collectability of amide-amine for quartz flotation and lower adsorption affinity for hematite surface than etheramine, the amide-amine is a promising collector to be used in reversal iron ore flotation.

Jul 30, 2021

By M. Leroux, S. R. Rao, J. A. Finch

"Poor Pb-Zn selectivity during Pb flotation in laboratory tests on a Mississippi Valley-type Pb-Zn ore was traced to apH effect. In the pH range, 9.5 to 11.0 sphalerite floated readily without copper activation. Compared to sphalerite flotation with copper activation this procedure gave equivalent selectivity but reduced flotation rate.Possible mechanisms of this sphalerite flotation without copper activation are discussed. Activation by Fe(OH)2 is suggested, the Fe- + ions being derived from superficial oxidation of pyrite in the ore. IntroductionGalena and sphalerite commonly occur together. A typical procedure, using xanthate collectors, is to float the galena first, at pH - 8, followed by flotation of sphalerite after activation with copper (II) sulphate at pH - 10 (to depress pyrite).Flotation tests following this procedure in an undergraduate laboratory course with a Pb-Zn ore from Polaris failed to achieve consistent selective flotation of galena. Occasionally a considerable amount of sphalerite, even though unactivated with CUSO4, floated. This was traced to accidentally high pH. A systematic study was carried out which revealed that sphalerite floated readily in the pH range 9.5 to 11.0 without activation by CuSO4 This paper describes the results of the study and discusses a possible mechanism of this flotation of sphalerite."

Jan 1, 1987

By Wei Sun, Xiangsong Meng, Xiaodong Li, Weisheng Huang, Yuehua Hu, Chonggao Cao, Haisheng Han, Wensheng Chen, Runqing Liu, Central South University

"The similar flotability of scheelite, fluorite, and calcite resulted in the difficult separation by flotation. This work revealed the effect of water glass on the flotation of scheelite by FTIR and the wettability change of the usual cleavage plane, and proved that water glass inevitably influenced the flotation of tungsten minerals to a large extend in traditional fatty acid flotation process. A new collector, benzohydroxamic acid complexes, was found to be selective for the separation of scheelite and calcium minerals with little water glass. Hence a novel flotation process was developed for the recovery of tungsten minerals in shizhuyuan mine in China. Normal temperature flotation of tungsten minerals was developed to instead of the classical “Petrov's process” for scheelite-calcite-fluorite type ores. Compared with the traditional process, the recovery was improved by 10% and the grade of scheelite concentrate was above 55%. The disappearance or decreasing of water glass contributed to improving the recovery of tungsten and fluorite and the circulation of water and reagents.INTRODUCTIONChina is rich in tungsten resources and the proved reserves accounted for 60% of the world's reserves (Cai Gaipin et al., 2009). However the wolframite has been dried up and the scheelite resource has become the main resource of the tungsten metal. Scheelite deposits were classified to scheelite-silicate type and scheelite-calcite-fluorite type based on the associated gangue minerals. Scheelite was easy to separate from the silicate minerals. Flotation separation of scheelite from calcium minerals creates difficulties because of the existence of the same cation in the minerals and similar physicochemical characteristics such as solubility, hardness, specific gravity, PZC (point of zero charge) etc.(Arnold & Warren, 1974; Yongxin & Changgen, 1983; Ozcan & Bulutcu, 1993a; Deng et al., 2015, 2016;). The conventional collectors used in the flotation of scheelite ores are generally fatty acids or fatty acid derivatives ( Yongxin & Changgen, 1983; Oliveira & Sampaio, 1988; Sivamohan, 1988; Shi et al., 2014; Bo et al., 2015). It is difficult to separate scheelite especially from calcite with these reagents because the adsorption mechanism of these collectors occurs through chemisorption of the oleate ion onto the mineral surface (Atademir et al., 1979; Changgen and Yongxin, 1983; Hiçyìlmaz et al., 1993; Hu et al., 2011). Therefore, it is almost impossible to separate them by fatty acid flotation without using any selective depressant. Although oleoyl sarcosine was used as a selective collector in the flotation of fluorite and siliceous scheelite ores (Ozcan & Bulutcu, 1993b; Ozcan et al., 1994), this selectivity is not adequate for a low-grade calcitic scheelite ore. Unfortunately, the reagents such as organic colloids (dextrine, starch), quebracho, sodium phosphates, sodium silicate solutions containing polyvalent cations (hydrosols), etc. (Yongxin and Changgen, 1983; Schubert et al., 1990; Shi et al., 2014; Bo et al., 2015) used for calcite depression also depress scheelite to a large extent."

Jan 1, 2016

By Hossein Zarei, Masoud Kashani, Mehdi Safari

The feed of flotation unit in Angouran mine, as a part of Iranian Lead and Zinc National Corporation, contains about 34.26% zinc (about 12% Zn sulphide) and 10.14% lead (about 2% Pb sulphide). The grade of Pb and Zn in the final concentrate (rougher+scavenger), under optimal conditions (200 g/ton PEX, 500 g/ton zinc sulfate, 30 g/ton MIBC and pH = 7.5), was 63.18% and 13.01%, respectively, and the total Pb (sulphide-oxide) recovery was about 19% which included 95% Pb sulphide. The grade of Pb and Zn in rougher concentrate step was about 71.86% and 5.97%, respectively, when PEX (Potassium Ethyl Xanthate) was used as collector. While in the presence of PAX (Potassium Amyl Xanthate), the grade of Pb and Zn in rougher concentrate step was 66.8% and 10%, respectively. Tailing of the galena flotation (with 8.48% Pb grade and 34.92% Zn grade under the optimal conditions) was used as a feed for sphalerite and oxide section flotation.

Jan 1, 2014