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By H. Dho

The role of sodium silicate in the anionic flotation of a Florida phosphate ore was investigated using laboratory continuous flotation tests, frothability tests and SEM observations. In the absence of sodium silicate, Ca++ promoted the unwanted activation of quartz by forming calcium bearing precipitates. The addition of sodium silicate enhanced the flotation efficiency through: (1) the removal of impurity minerals and calcium-bearing. precipitates from quartz surfaces by dispersion, (2) drier and more persistent froths stabilized by oily droplets containing calcium silicate precipitates, and (3) higher specific flotation rates of phosphate relative to quartz, leading to faster flotation rates and increased selectivity of separation.

Jan 1, 1990

By S. G. Malghan

This paper describes uses of sodium sulfide in the flotation of oxide and sulfide minerals of copper, lead, and zinc. The activation and depression effects of sodium sulfide are of particular importance because of their applications with oxidized lead and copper ores. In spite of its industrial importance; however, the nature of the heterogenious reactions between sulfide ions in solution and the surface of oxidized minerals has not been fully understood. Hence, proposed mechanisms of the sulfide action in flotation, methods of measuring and monitoring of sodium sulfide in flotation pulps, and variables influencing the sulfide addition are analyzed. A review of recent studies shows that sodium sulfide addition to flotation pulps can be monitored and hence the optimum dosage controlled using the platinum and/or sulfide specific ion electrodes. The use of these electrodes for improved reproducibility of bench-scale experimental data and plant implementation of laboratory results is described.

Jan 1, 1985

By E. L. C. Martins, M. J. Nicol, D. Majuste, A. D. Souza

The effects of organic compounds on the current efficiency (CE), morphology, crystal structure and mechanical properties of the metal deposited during the electrowinning of zinc are described. A flotation collector and lubricating oil were selected based on observations made during the industrial production of zinc from silicate ores, in Brazil. The analysis by Fourier transform infrared spectroscopy of these compounds, which may be present in minor amounts in the electrolyte solution, indicated the presence of a polar amine group in the collector, while the lubricating oil is a non-polar compound. The average CE value obtained from organic-free industrial solution was 91.15 ± 0.26 %. The CE dropped to 54.35 ± 0.73 % in the presence of 100 mg·L-1 of collector in the solution, and a negative effect was also observed in the presence of similar amounts of oil (88.84 ± 0.61 %). The characterization of the deposits by scanning electron microscopy and X-ray diffraction revealed the formation of pores in deposits obtained from solutions containing the oil, while a different growth pattern (perpendicular zinc platelets) was identified when the flotation collector was added to the industrial solution. In the presence of these contaminants in the solution, guided-bend tests revealed that the deposits have a higher resistance to deformation, but lower ductility, properties that may affect the performance of the stripping stage. As a result of this work, simple control and optimization actions were applied in the industrial plant, which resulted in important improvements in the electrowinning process.

Jan 1, 2014

By L Besra, A. R. Prasad, B. P. Singh

The role of surface-chemical phenomena and the physical processes that participate in the dewatering of a suspension of alumina trihydrate were subjected to a systematic investigation, which has increased understanding of the influence of surface tension, contact angle and adsorption in the process. The residual moisture content of the cake can be reduced significantly through the use of surface-active agents in slurry pretreatment or as wash-water additives. The effectiveness of a particular surfactant is hard to predict from any single parameter, but is dependent on its ability to reduce surface tension and possibly to modify the solid-liquid contact angle. If scaled up to industrial operation of the dewatering step of the Bayer process in India, the use of these chemical additives could substantially improve its process economics, reducing the fuel costs for thermal drying by a much as Rs 50/t

Jun 21, 1905

By F. Stober, D. Wanblad, J. Ndlovu, L. R. Nelson, L. P. S. de Villiers

The single six-in-line furnace of the Polokwane Smelter is the largest installed high-intensity furnace for platinum group metals (PGM) base metals sulphide smelting in the world. The furnace employs state-of-the art technology to deliver a planned throughput of 650 000 t/a dry concentrate at a design 68 MW power input. This furnace, at double the capacity of previously existing PGM furnaces, offers low unit operating and capital cost through the resulting economies of scale. Key features of the design include:

Jan 1, 2005

By H. H. Li

Reverse flotation is usually used for hematite/silica or bauxite/clay flotation separation in which the silica or clay is floated and rejected. Some properties of these silicate minerals such as particle size and surface characteristics have significant effect on their flotation behaviours. Firstly, the silicate mineral particles (especially clay minerals) generally have fine particle size (< 5 microns) in their natural states or due to overgrinding and they display poor flotation kinetics, consequently having low flotation recovery. Secondly, the wettability difference on different particle basal planes influences the affinity for adsorptions of different types of chemicals such as collectors or macro-molecule. Common polyacrylamide (PAM) flocculants can be used to minimize the exposure of the most hydrophilic planes of clay particles via hydrogen bonding but they can not efficiently enhance the overall particle surface floatability due to the hydrophilic properties of this type of macromolecules. A novel method to improve both flotation kinetics and surface wettability of silicate minerals has been developed and studied. That is to use a temperature-sensitive polymer, poly (N-isopropyl acrylamide) (PNIPAM), as a process aid in the flotation of silicate minerals. Unlike PAM polymers, PNIPAM can induce a hydrophilic/hydrophobic transition on the particle surface when the temperature is changed to be lower or higher than its critical solution temperature (CST). At a lower temperature, the PNIPAM adsorbs on the particle surface via hydrogen bond similar to PAM. It induces strong hydrophobic aggregation when the temperature is increased above the CST. Thus, both floc size and mineral floatability are greatly increased. The flotation results show very good flotation performance and the addition of conventional flotation collector was no more required because the increased particle surface hydrophobicity induced by PNIPAM. Contact angle measurements explained the role of PNIPAM in manipulating particle surface hydrophilic/hydrophobic transition.

Jan 1, 2014

The overall systems approach to blast furnace aerodynamics is explored including the time and spatial inter-relationships that exist between the furnace lines, tuyeres, burden characteristics, distributor capabilities and furnace operating practice. Attention is called to the time dependent, three dimensional aspects of blast furnace aerodynamics and to the existence of several zones within a furnace where the flow characteristics are different. Changes in furnace operating practice to take further advantage of fully beneficiated burdens including formed coke are discussed from a practical viewpoint. Lessons learned in a variety of shaft furnaces used for other purposes are discussed insofar as they have a bearing on aerodynamics in an iron blast furnace. Questions are raised about the penetration of hot blast in large furnaces. Operating practices and.proposed solutions are evaluated where tuyeres over iron and slag notches are restricted or plugged. Opportunities are presented for using on-line hierarchical computer systems with adaptive tuning algorithms to provide non-linear control of changing process conditions in real time. This will make it possible for the blast furnace operator to optimise a variety of interrelated paramaters, each with different response times. Potential increases in productivity, fuel savings and improved quality control are believed to be within reach.

Jan 1, 1975

By William F. Abercrombie

The role of the laboratory is described in relation to the prospecting and exploration of kaolin clays. Test methods used to evaluate crude ore samples of kaolin clay for commercial consideration are reviewed. A background of the kaolin mineral and known means of prospecting this mineral are presented. Common analytical methods are discussed with special emphasis on those in use today.

Jan 1, 1982

By Bruce Cavender

Historically, the processing function has been regarded as efficiently managed as long as production costs were kept low, recovery was adequate and sufficient plant capacity was avail-able. In this paradigm, processing is viewed as capable of making only a limited contribution to a company?s competitive advantage. However, the processing function can provide a primary vehicle for building critical competitive capabilities. Processing organizations should be encouraged to become so accomplished they generate new opportunities for other functional groups and thereby influence a company?s overall strategy. This requires a deep shift in processing?s role, in its self-image and in the expectations of it held by managers in other functions. Specific plant improvement techniques ? total productive maintenance (TPM), loss control, etc. ? should be viewed primarily as means for building strategically valuable processing capabilities. Different improvement strategies create different kinds of capabilities and present new strategic options. Broadly speaking, a mineral-producing company seeks competitive advantage through two principal activities: the development of new mineral production and reserves and the optimization of existing operations. These lead to increases in ore reserves, production levels and cash flows that are manifested in increased profitability and, hopefully, increases in the price of the firm?s stock. The profitability of a minerals company is a function of the overall profitability of the industry sector in which the company participates and the firm?s competitive position within that sector relative to those of its competitors. Competitive advantage within the industry comes from two sources: the ability to maintain lower prices than competitors for the same product (cost leadership), or from the sale of products with unique properties that justify higher prices (product differentiation; Porter, 1980). Most mineral companies produce fungible commodities that are sold to anonymous customers, and sustainable cost advantage is the only long-run strategy available to these companies to enhance profitability.

Jan 1, 2008

The traditional technological flow sheets for processing of ferrous quartzite (magnetite ores) al-low production of the iron concentrates with Fe content of 65%~68 % and recovery level about 55 %. The losses of iron with the tails of wet magnetic separation are related to hematite and quartz-magnetite particles, which are not extracted under low magnetic field employed. This work presents the results of the application of reverse cationic flotation for production of hematite concentrates with weak silica content from the tailings of wet magnetic separation of mag-netite. Fine particle size, complex mineralogy and presence of locked particles determine the impos-sibility of direct production of hematite concentrate by flotation or magnetic separation. The gravity concentration allows obtaining of iron concentrate from the well-prepared feed (size fraction -53+20 µm) but with very low recovery. Thus, hematite concentrates with weak silica content and satisfactory iron recovery were obtained by reverse cationic flotation, when it was fed with iron pre-concentrate produced by high gradient magnetic separation. The best flotation results were obtained by the use of formulations based on amines of different molecular structure that modulate the structure of adsorption layer, and favour a shifting of hydro-philic-hydrophobic balance on the surface of silicates with adsorbed starch and their preferential transfer into the froth product.

Jan 1, 2014

By W. G. Stevenson

With the author's background of extensive experience, this paper delineates the role of the prospector in modern-day exploration programs. The stages in the development of a prospect to a producing mineral district are outlined, and examples are given from the Ross River area of the Yukon Territory and the Peachland and Highland Valley areas of British Columbia.

Jan 1, 1970

By William H. Hamilton

INTRODUCTION It was not very many years ago that tunneling machine manufacturers spent considerable time trying to convince contractors and mine operators of the advantages of mechanical tunnel boring over conventional drill and blast methods. Today there are few doubters left. There is universal agreement that, not only are tunneling machines here to stay, but the ratio of bored rock tunnels to blasted rock tunnels is increasing at an accelerated pace, and within the next twenty years I predict almost all tunnels will be bored by machine. I believe we are today at a very important mile-post in the development of tunnel boring systems. Felix Gaye stated in his recent article (1) "It is important to disseminate between the efficiency of cutting tools and the overall efficiency of the boring operation". Mechanized tunnel boring in the past placed almost total emphasis on the rock cutting and boring ability of the tunneling machine. With advancements in technology and better solutions to the problems of rock fracture, steering control, and structural design, the emphasis today can be placed on the total-system concept. Tunneling machine design, as one of the key elements in the overall system, presents many problems that are not totally solved today. These design problems are, in the most part, not related with rock fracture, but rather with criteria associated with the over-all operation.

Jan 1, 1997

By A. K. Sheik, W. G. Pariseau

A small underground mine in northern Idaho was used as an experimental facility for studying the role of water in the analysis of mine opening stability. Laboratory test data, borehole measurements and geological mapping assisted in constructing a coupled finite element model of the rock mass. The model was used to make quantitative estimates of: 1) rock stress, strain and displacement changes, and 2) water pressure and flow velocity changes that occurred during historical mining. Stope cuts and wet fills were included in the analysis. Stability of crown pillars between stopes was of particular interest. The relatively low effective stress and high rock mass strength showed that water pressure changes were of no great consequence in agreement with experience. The computational tools used in the analysis may be applied to other wet mines with appropriate changes to site-specific input data.

Jan 1, 1999

By A. K. Sheik

A small underground mine in northern Idaho was used as an experimental facility for studying the role of water in the analysis of mine opening stability. Laboratory test data, borehole measurements and geological mapping assisted in constructing a coupled finite element model of the rock mass. The model was used to make quantitative estimates of: 1) rock stress, strain and displacement changes, and 2) water pressure and flow velocity changes that occurred during historical mining. Stope cuts and wet fills were included in the analysis. Stability of crown pillars between stopes was of particular interest. The relatively low effective stress and high rock mass strength showed that water pressure changes were of no great consequence in agreement with experience. The computational tools used in the analysis may be applied to other wet mines with appropriate changes to site-specific input data.

Jan 1, 1999

Roles of Mineral Impurities and Sulfur in the Leaching Behaviour of Pre-Reduced Ilmenite Ores

Sep 13, 2010

By Hyun Kyu Shin, Byeong Deok Lee, Young Eun Lee

The reduction of Mn oxides at pre-smelting steps is an integral part of smelting processes for Mn alloys, and an understanding of its reaction mechanism is expected to contribute to the improvement of processing efficiency for Mn alloys smelting. The phase diagram shows that five Mn carbides are operative in the Mn-C system. Although they are expected to participate in the reduction of Mn oxides, no specific information is available yet to clarify their roles in presmelting carbothermic reaction of Mn oxides. Experiments with composite pellets prepared with Mn oxides and graphite powders show that Mn3O4 is reduced initially to MnO at about 1130oC and, subsequently, to Mn7C3 carbide as temperature increases further. At 1331oC, Mn7C3 carbide dissociates to Mn alloy and carbon. The degree of reducing reaction increases with increasing carbon balance in composite pellets and increasing temperatures.

Jan 1, 2014

By Michael Brandner

HSM can be divided into different groups such as Conventional HSM with Roughing stands and HSM without Roughing stands = Mills with just finishing stands. The roll requirements for different stands are quite different. In Roughing stands the temperature of the slab is very high. Therefore the resistance against thermal wear/fatigue is the most dominating factor. Today mostly Chrome Steel, Semi HSS and HSS rolls are applied. A comparison and evaluation of such rolls will be described. In the finishing mill the tendency/wish is to use HSS rolls in all the stands. The grade HSS is defined by at least a certain amount of carbide forming elements such as V, W, Mo, Nb etc. The matrix and other precipitations can be adjusted according to the need and situation in the mill. In the pre-finishing stands the HSS is already well introduced. In the last finishing stands the original HSS tended to stick and the cobble rate increased. New development decreased the problem and gave some very promising results. In the last finishing stands beside the high performance a higher resistance against incidents is needed. Solutions in this direction including e.g. residual stresses and special core material will be discussed. Proper testing and grinding procedures can avoid losses and reduce the TCO. Data sourcing and evaluation in regards of rolling and grinding is the key for the optimization of the TCO. Several examples and comparison between different applications will be given in detail and explained. Future possibilities will be discussed as well as results of latest trials in mills.

Aug 17, 2017

By D. L. Murr, J. R. Jensen

Testing was conducted on a Minnesota Iron Ore concentrate with Cook Clay as a binder using compressive sheer mixing to enhance the performance of the agglomeration mechanism. The testing was conducted on a bench scale at the Midland Research Center the summer of 2004. Results of the test program will be presented that shows the impact of compressive sheer mixing had on the strength achieve in a green ball.

Jan 1, 2006

By Konrad Krimpelstätter

The need for more effective and flexible roll-gap lubrication technologies in hot and cold rolling mills is steadily increasing due to ever-greater requirements placed on the rolling process and the final products. In particular, the rolling of high-strength steels poses enormous demands for both the rolling mill and the coolant/lubricant to be used. The presented paper focuses on two innovative technologies for highly efficient roll-gap lubrication for hot and cold rolling, which were developed utilizing extensive knowledge and expertise about the tribological interactions in the roll-gap. The advanced work-roll lubrication package (A-WRL) for hot rolling and ESP mills is using specially designed mixer-nozzle units to mix the water/oil emulsion very close to the nozzles to minimize the risk for contamination and clogging. The nozzles are quickly exchangeable and are optimized to ensure uniform lubricant distribution, high plateout efficiency and minimum oil consumption. This eco-friendly solution does not require any chemical additives or cleaning agents and significantly reduces electrical energy consumption and work-roll wear. The roll cooling system on mill entry and exit side remains switched-on, which is of vital importance especially for highperformance hot strip mills. Minimum Quantity Lubrication MQL® represents a new generation of roll-gap lubrication technologies for cold rolling, which applies minimum amounts of pure rolling oil finely atomized with pressurized air directly onto the work roll surface. This allows controlling the oil film thickness depending on actual process and product parameters, providing increased lubrication flexibility, significant improvement of strip surface cleanliness through reduction of strip wear. MQL® was successfully installed and tested on two industrial tandem cold rolling mills in Europe. Advanced WRL and MQL® represent Primetals’ latest technologies that feature a robust and reliable system comprising standardized interfaces and flexible communication options. Both packages can easily be integrated into existing or new hot strip mills, ESP lines or cold mills.

Aug 17, 2017

By O. Barron, C. Felix

In 2023, polymer electrolyte membrane fuel cell membrane electrode assemblies accounted for about 62% of the global fuel cell market share and this demand is expected to grow. Commercialisation requires technologies capable of cost-effective, high-volume manufacturing. The membrane electrode assembly is crucial and represents a significant cost to polymer electrolyte membrane fuel cell manufacturing. Manufacturing the electrode components for membrane electrode assemblies at high volumes can reduce production costs while delivering on the forecasted industry demands. Roll-to-roll is a mature coating technology applied in various manufacturing industries such as batteries, printed electronics, microelectronics, photovoltaics, printing, paper consumables, etc., with significant potential for polymer electrolyte membrane fuel cell manufacturing. While the high-volume production process for membrane electrode assembly manufacturing differs from laboratory-scale, the membrane electrode assembly structure remains unchanged. Roll-to-roll is a continuous coating process with speeds of 10 m/min being achieved. In this work, MicrogravureTM and slot-die coating methods have been adopted and have shown promising outcomes for producing gas diffusion electrodes for membrane electrode assemblies. An overview of the MicrogravureTM and slotdie coating methodologies is provided, and a discussion on preliminary results and challenges are presented. Work on MicrogravureTM gas diffusion electrode manufacturing has already achieved comparable performance with spray-coated gas diffusion electrodes. The influence of coating parameters and drying on the coated catalyst layer quality is discussed.

May 27, 2025