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By B. K. Shibler

During the investigation of the occurrence of manganese deposits in the Western United States, examining engineers of the Bureau of Mines collected 2-ton samples from five manganese properties near Golconda, Nev. Extensive laboratory tests were made to determine the amenability of these ores to standard ore-dressing methods of concentration. The Tom Major property, one of those sampled, is situated 12-1/2 miles south of Golconda, Humboldt County, Nev. The deposit is described as a bed about 5 feet thick in a thinly bedded shale and dolomite formation. The sample tested was obtained from the manganese bed, but the examining engineer reported: "The mining of an appreciable tonnage at reasonable cost would perhaps cut in half the grade represented by the sample."

Jan 1, 1951

By Erik Bengtsson

Phenol was discovered in coal tar by Runge (1)1/ in 1834 and was isolated (2) in 1841 as pure phenol by distilling the tar, extracting with caustic soda, acidifying the extract, and fractionating the tar acids. Later, o-cresol was isolated (3) through careful fractional distillation of the tar-acid mixture. The m-and p-cresols distilled within a boiling range of about 1.50 c. and had to be separated by other means. Raschig (4) fractionated the tar-acid mixture to obtain pure o-cresol, sulfonated the mixture of m-and p-cresols, and treated the cresol-sulfonic acids with superheated steam at 1200 to 1300 c. to hydrolyze the m-cresol sulfonic acid, the p-isomer was not affected at that temperature. He also attempted to make use of the different crystallizabilities of the m-and p-cresol sulfonic acids (5). When treated with sodium bisulfate and sodium pyro-sulfate at 100° to 110° C. or with sulfuric acid (90/0) at 20° C., only the m-cresol was sulfonated (6). Hoffman-La Roche (7) treated the meta-para mixture with concentrated sulfuric acid at 40° to 100° C., when m-cresol and part of the p-cresol was sulfonated, and precipitated the m-cresol sulfonic add by diluting with water. The same sort of separation may be carried out by means of 80 percent sulfuric acid at 35° C. and 35 mm pressure (8).

Jan 1, 1950

By James J. Dowd

The investigation to evaluate the reserves of coking coal in the United States suitable for the manufacture of metallurgical coke is being made by the Bureau of Mines in three parts: (1) To estimate known (measured plus indicated) recoverable reserves of all coking coal; (2) to study the carbonizing properties of coals and coal blends not now widely used for metallurgical coke making; and (3) to upgrade marginal coals through effective preparation. This is the second7j of a series of reports giving the results of studies by counties under part (1) of the investigation. This report covers Indiana County, Pa., which comprises parts of the Smicksburg, Punxsutawney, Elders Ridge, Indiana, Barnesboro, Latrobe, New Florence, and Johnstown Quadrangles. (See fig. 1.) A base map for each bed in each Quadrangle was made to the scale 1 inch equals 1,200 feet. Maps of mines, locations of drill holes, bed and total coal thicknesses, and the outcrop of the bed were plotted on the maps. With all available data plotted, isopach lines were drawn to limit areas of known unmined reserves in beds 0 to 14 inches thick, 14 to 28 inches thick, 28 to 42 inches thick, and over 42 inches thick. These areas of coal reserves also were divided into "measured" and "indicated" categories. All areas in each thickness range and in each category, mined-out areas, areas excluded from the estimate, and areas outside of the outcrop were measured by planimeter on the base maps. Estimates of total reserves 14 inches and more thick and maps for individual beds were prepared from these data.

Jan 1, 1950

By A. L. Engel

Simple treatment methods, employing the least possible equipment, can sometimes be established for marginal ores and economical results achieved. In continuation of a long-established part of the hydrometallurgical and ore-dressing program of the Reno Station of the Bureau of Mines, typical ores from newly discovered or recently explored mining districts have been investigated. The purpose of such investigations is to encourage the search for and development of mineral resources and particularly to assist in the economical exploitation of low-grade and marginal ores, as well as the conservation and recovery of values in products from former operations that were discarded because of past inability to treat them economically. Several of these investigations have been limited to preliminary tests of samples from prospecting operations, whereas some involved samples of old dumps or tailings piles. The test, work in these cases was not extensive enough to warrant publication as individual reports, but is of considerable interest inasmuch as it indicates the possibilities as well as the limitations of treating the respective materials; and because, inasmuch as the samples were representative of the districts from which they were obtained, this in-formation should be helpful in the future development of these districts. The present report is a compilation of results of brief preliminary tests on oxide ores only, which contained gold and silver and in some cases base metals. The methods of treatment used include gravity concentration, amalgamation, flotation, and cyanidation. For the most part, only standard laboratory procedures were employed. No attempts were made to develop new methods for the low-grade refractory ores in this group of samples if simple treatment was not successful, as the stage of development of the properties did not warrant extensive experimentation on the samples submitted.

Jan 1, 1951

By Frank J. Wiebelt

As a result of the examination of many copper-zinc properties in the West Belt area of California, nine were chosen for exploration projects by the Bureau of Mines. This was part of the Bureau's wartime mineral-development program aimed at maintaining production of essential metals and increasing ore reserves. The properties explored were the El Dorado, El Dorado County; Copper Hill, Newton, and Gray House, Amador County; Constellation, North Keystone, and Collier, Calaveras County; and American Eagle and Akoz, Mariposa County. In addition to surface sampling and mapping, 41 holes, aggregating 18,134 linear feet, were diamond-drilled. Detailed results of the work done on all properties except the El Dorado and Akoz are given in this report. The El Dorado and Akoz were discussed in Reports of Investigations 3896 and 4144, respectively. Figure 1 is an index map showing the location of the mines covered in this publication.

Jan 1, 1951

By Cecil Q. Cupps

Results are presented of a comprehensive study of the characteristics of the original oil in the Weber sandstone reservoir, Rangely oil field, Colorado. Through the medium of subsurface sampling, adequately representative samples of the original reservoir oil were obtained from many parts of the reservoir over a period of 5 years concurrent with active development of the reservoir. Data of differential gas liberation, pressure-viscosity, and. pressure-volume-temperature relationships are shown for 12 subsurface oil samples. Data also are given of reservoir pressure and. temperature, composition of liberated or solution Gas, composition of 22 produced-gas samples, and Hempel analyses of crude-oil samples from 18 wells. The characteristics or physical properties of the 12 subsurface oil samples, as determined by laboratory analyses, were correlated with elevation of the top of the Weber sandstone. These relationships of oil characteristics to elevation in the reservoir show that only the oil in contact with the initial gas cap was gas-saturated at the existing pressure and temperature. The characteristics of the original reservoir oil were marked by an appreciable decrease of saturation pressure and solution gas-oil ratio and increase of viscosity and density with depth below the gas-oil contact. The composition of solution gas and of' produced was also was found to vary with elevation of the oil in the reservoir.

Jan 1, 1951

By A. L. Engel

In the period of 1942-1945, medium-grade, oxidized, lead-silver ore was mined and shipped from the Diamond district near Eureka, Nev. An encouraging tonnage of low-grade ore was developed during these operations and partly blocked-out for future mining. If the low-grade ore could be treated profitably, further development of the district would result, and production of an important strategic metal might be increased. A representative sample of Diamond district ore was obtained through the Reno office of the Mining Division for the studies described in this report. The sample consisted of lumps and fines of a highly altered siliceous rock containing much earthy red hematite and some granular black hematite. Examination with the binocular microscope showed the lead carbonate mineral, cerussite, in seams and disseminated in the hematite. No zinc or silver minerals were identified, and no sulfide minerals were present. Analyses of the ore showed:

Jan 1, 1951

By William L. Crentz

This study of the preparation characteristics of the coals in Indiana County, Pa., is the second in a series of Bureau publications appraising the Nation's coking-coal reserves by counties and the practicability of upgrading marginal deposits to metallurgical standards. The first publication dealt with the preparation characteristics of the principal coal beds in Cambria County, Pa. Over 95 percent of the coal remaining in Indiana County is in the Upper Freeport, Lower Freeport, and Lower Kittanning beds. Isolated patches of Pittsburgh-bed coal are present, and the Upper Kittanning bed is found in minable thickness at some locations, but production from these sources is not large. The greatest production is from the Freeport beds, which account for nearly 70 percent of the Indiana County coal output. These beds usually contain two or more shale or hone partings and in many places are high in sulfur. The large proportion of bony coal in the Freeport beds 'produces a relatively high-ash product. Mining practices vary from place to place, but it is frequently necessary to leave certain bony portions of the bed in place in order to load a satisfactory product. Table 1 shows the county's coal production, by beds, during 1948.

Jan 1, 1951

By O. C. Blade

This report on the properties of motor fuels sold through service stations in the United states was made in accordance with a cooperative agreement between the American Petroleum Institute and the Bureau of Mines of the United states Department of the Interior. This paper is a continuation of a series made in cooperation with the Coordinating Fuel Research (CFR) Committee of the Coordinating Research Council (CRC). Inc. The first of this series of reports presented data on motor gasolines sold during the winter of 1935-36, and succeeding reports described motor gasolines sold during the summers and winters to and including the summer of 1941. No reports were made on motor gasolines sold during the winter of 1941-42 and during the summer of 1942. However, starting with the winter of 1942-431' the semiannual reports were resumed.

Jan 1, 1950

By Foster Fraas

Electrostatic separation depends on a number of electrical and mechanical properties such as conductance, contact potential, dielectric constant, and particle shape. In routine testing it is desirable that the application of each of those properties be investigated. The conductance property is best utilized in a separator having an ionic field, whereas the contact potential requires a separator with a pure static field. Dielectric constant and particle shape also influence the response in these two fields. There is no separator on the market that can be adjusted for all these requirements. The separator described in this paper is satisfactory for this purpose and is provided with a dielectric electrode, which permits formation of high-intensity static fields.

Jan 1, 1951

By K. C. Dean

During investigation of the occurrence of manganese deposits in the western United States, examining engineers of the Bureau of Mines collected samples from several properties in Montana. Extensive laboratory tests were made to determine the amenability of these ores to standard ore-dressing methods of concentration to produce marketable-grade products. The Tzarena claim, one of the properties sampled, is on the western end of the Rama or Black Chief vein in the city of Butte, Silver Bow County, Mont., on the southwestern periphery of the mining district. The Black Chief 'WAR system contains one of the largest and most extensive known rhodochrosite deposits in the world. Test work was conducted on two samples of Tzarena ore. Sample 1 is representative of a vain 5 feet wide on the 150-foot level of the Tzarena shaft. Sample 2 is representative of a vein 8 feet wide in the 100-foot level of the shaft. The Minnie Jane mine, 1/2 mile northwest of the Tzarena claim, contains ore similar in mineralogical composition to Tzarena ore but differing materially in manganese content and to some extent in physical characteristics. Ore-dressing investigations were made on three samples of Minnie Jane ore. Sample 1 represented stock-piled ore, sample 2 represented ore from Minnie Jane mine having a considerable sulfide content, and sample 3 represented low-grade ore.

Jan 1, 1951

By Ralph H. Espach

In the spring of 1943, when it was evident that the Tensleep sandstone in the Elk Basin field, Wyoming and Montana, held a large reserve of petroleum, Bureau of Mines engineers obtained samples of oil from the bottom of nine wells and analyzed them for such physical characteristics as the volumes of gas in solution, saturation pressures or bubble points, shrinkage in volume caused by the release of gas from solution, expansion of the oil with decrease in pressure, and other related properties. The composition of the gas in solution in the oil was studied. The pressures and temperatures existing in the reservoir and the productivity characteristics of the oil wells were determined. The data obtained indicate that the oil in the Tensleep reservoir of the Elk Basin field has unusually varying physical characteristics, such as a saturation pressure of 1,250 pounds per square inch absolute and 490 cubic feet of gas in solution in a barrel of oil at the crest of the structure, and a saturation pressure of 530 pounds per square inch absolute and 134 cubic feet of gas in solution in a barrel of oil low on the flanks. The hydrogen sulfide content of the 6a r; in solution in the oil varies from 18 percent for oil on the crest to 5 percent for oil low on the flanks of the structure. Of even greater significance is the fact that these and other variable characteristics of the reservoir oil are related to the position of oil in the structure. Many geologists and petroleum engineers have considered all the oil in a petroleum reservoir to have uniform physical characteristics and that equilibrium conditions prevailed in all underground accumulations of oil and gas. That such is not always so is borne out by the results of the study made by the writers.

Jan 1, 1951

By Carl Belser

This report is the first of a series dealing with the oil-shale reserves of the Green River formation in the Rocky Mountain Region. The known oil-shale reserves of northwestern Colorado at present considered to have economic value apparently are confined to the Piceanco Creek basin between the Colorado and White Rivers. The number of sampled sections is small, but there can be little doubt that the Piceance Creek basin is a potential source of enormous quantities of liquid fuels and the related byproducts obtained from oil-shale processing. The partly blocked and inferred oil-shale reserves of 25-gallon-a-ton shale are estimated to have an oil yield of 125 billion barrels and the reserves of 15-gallon-a-ton shale are estimated to have an oil yield of 494 billion barrels. The number of available sampled sections is inadequate for making firm estimates.

Jan 1, 1951

The United States has not begun commercial operations to tap its largest poten-tial sources of oil supply - oil shale and coal. The reason is that domestic petrol-eum has been plentiful in the past and liquid products probably could be produced from it at the lowest cost. In view of the ever-increasing need for petroleum in the United States, the critical international situation threatening foreign supplies, the growing demands for steel, and the heavy costs to industry of constantly discovering and developing new oil fields, it is believed that the prompt development of a synthetic fuel industry based on oil shale and coal is not only requisite to safeguard our oil supply but is an economically sound course for the foreseeable future. To neglect its development is to close our eyes and minds to our own resources at a time when they are needed critically. It also is apparent now that neither the Government nor industry would be taking any considerable economic risk in starting the initial plants, especially as measured against their potential value in meeting critical oil and chemical demands and in building a new industry in the West.

Jan 1, 1951

The United States has not begun commercial operations to tap its largest poten-tial sources of oil supply - oil shale and coal. The reason is that domestic petrol-eum has been plentiful in the past and liquid products probably could be produced from it at the lowest cost. In view of the ever-increasing need for petroleum in the United States, the critical international situation threatening foreign supplies, the growing demands for steel, and the heavy costs to industry of constantly discovering and developing new oil fields, it is believed that the prompt development of a synthetic fuel industry based on oil shale and coal is not only requisite to safeguard our oil supply but is an economically sound course for the foreseeable future. To neglect its development is to close our eyes and minds to our own resources at a time when they are needed critically. It also is apparent now that neither the Government nor industry would be taking any considerable economic risk in starting the initial plants, especially as measured against their potential value in meeting critical oil and chemical demands and in building a new industry in the West.

Jan 1, 1951

By Russell R. Trengrove

The Copper Canyon lead-zinc mine is in the Battle Mountain. District, Lander County, Nev. It was discovered in 1866 and mined for copper until 1935 and for copper and gold until l948, when the main production became lead-zinc ore. The rocks in the area are carboniferous (Pennsylvanian and Mississippian) sedimentaries that have been intruded by quartz monzonite of Mesozoic age. They have been intensely folded, faulted, and tilted. Lead-zinc ore occurs as sulfides disseminated along fractured zones in a conglomerate arid hornfels. Development was carried out by the Bureau of Mines in cooperation with the U. S. Geological Survey and comprised a study of the geology, making maps and. cross sections, and exploring the deposit by diamond drilling from underground. Eighteen holes were drilled, for a total of 2,594 feet. This report contains a brief history of the property and a description of mining methods and beneficiation of the ore, geology, ore deposits and drilling done by the Bureau of Mines. It also contains detailed analyses of the ore samples taken and logs of the holes drilled.

Jan 1, 1951

By Boyd Guthrie

As the American petroleum industry surveyed its position in early 1937, it had many reasons to be optimistic concerning its future. The industry had emerged successfully from the depression, and for the first time since 1929 it had produced over one billion barrels of crude oil in a single year. The demand for gasoline and fuel oils was up, and reserves of crude petroleum and production capacity seemed adequate for the future. Although production of crude oil dropped slightly in 1938, the oil industry was still in a good position with respect to its supply of raw material, which improved economically in 1939 with the decrease of crude-oil stocks in storage above ground. However, by 1940 a threatening cloud (the invasion of France and its rapid surrender) had appeared on the horizon. This aroused Somme fears as to the industry's immediate future, and these fears were intensified the following year when the United States entered World War II. As the war progressed, more and more ships, planes, and vehicles were produced, and the problem of obtaining enough liquid fuels to supply them intensified. Hearings were held in August 1943 before a subcommittee of the Committee on Public Lands and Surveys of the 78th Congress to determine the advisability of passing legislation to promote the development of synthetic liquid fuels.

Jan 1, 1951

By H. A. Watson

The introduction and use of synthetic materials in various applications may lead to potential hazards from toxic, gaseous, decomposition products if these materials are subjected to conditions abnormal to their intended use, such as high temperatures or burning from accidental causes. This report covers an investigation of such possible hazards from toxic gases produced by the burning or thermal decomposition of some low-density, expanded, synthetic materials, three of which consisted of polyvinylchloride and one of acrylonitrile. In the production of certain expanded plastic materials, Chemical blowing agents frequently are used to produce a cellular structure. One of these blowing or foaming agents contains azo-bis-isobutyronitrile, which is designated in this report as PN. Information indicates that a product of decomposition of this blowing agent, formed in the blowing operation, is tetra-methyl-succino-nitrile, designated as TSN, Which is significantly toxic. Decomposition of the blowing agent, with release of its azo nitrogen, is represented by the following reaction:

Jan 1, 1951

By William E. Eckard

Production of oil from a narrow shoestring sand presents problems unique in the oil industry. Especially important, from both an engineering end an economic standpoint, are the limitations imposed upon well patterns and spacings by the shape of the field. This report concerns a study of the Paola shoestring, Miami and Franklin Counties, Kane., where well density of 0.85 acre per well was not uncommon to insure profitable primary recovery in a reasonable time. However, such a great number of wells increased the operator's investment and reduced his profit considerably. It was the purpose of this study to investigate various well patterns and spacings applicable to water-flooding a shoestring reservoir and the effect of these factors upon recovery of oil and the most profitable operation of the pool. The designer of well patterns for a shoestring sand should evaluate carefully the edges of the shoestring, even though they may be considered too thin to drill. These comparatively thin edges contain large quantities of recoverable oil; moreover they are resaturated with oil as the pool is water-flooded.

Jan 1, 1951

By Graham W. Marks

The general positions of the absorption maxima of aqueous solutions of the violet and green isomers of chromic sulfate the visible spectral region have long been known, but, to the knowledge of the writer, no comprehensive studies have ever been made. To gain further knowledge concerning these inorganic complexes and to investigate the possibilities of developing an analytical method for determining the concentrations of the violet and green isomers in a mixture, a more complete investigation was made in the spectral range from 325 to 850 millimicrons.

Jan 1, 1951