Search Documents

By Wilbert J. Huff, Raymond H. Moore

"Black powder is employed widely in peace and war. Its properties are therefore of considerable interest to many. The Bureau of Mines frequently is asked to furnish information on its use and safe handling in the mining and mineral industries in times of peace and is now engaged in studies of its application to the arts of war.Black powder has been the agent in many accidents - some very disastrous - and its handling and use are deemed very hazardous. The belief is widespread that the hazards are due principally to the ease with which the powder is ignited by a hot spark or flame in contradistinction to high explosives; these usually are ignited only with difficulty, and some burn incompl0tely and to a certain extent are self-extinguishing. Primary precautions, .therefore, should be taken to prevent the access of heat, spark, and flame.In black powder manufacturing operations a frequent source of disaster is the initiation of fires and explosions in the wheel mills in which the sulfur, charcoal, and nitrate are incorporated. Long experience has indicated that the wheel mill probably will fire if the powder is not kept moist enough; manufacturing supervision calls for the maintenance of a minimum moisture content, at least during the milling. Accidents occur elsewhere in the manufacturing line, and in an endeavor to minimize these, particularly those happening in corning mills, one of the writers suggested many years ago that a suitable humidity be maintained in other operations in the hope that it would serve protectively as in the wheel mill. The experience of one company for many years with this practice was favorable. It seemed desirable therefore, to explore the question experimentally."

Nov 1, 1944

By Thomas Jenning, C. M. Keithly

"INTRODUCTION This report is one of a series. 4. 5. 6/ concerned with presenting historical development, and operating data on secondary-recovery projects in various States to stimulate interest in sound secondary-recovery programs. Preceding reports in this series have dealt exclusively with descriptions of and results obtained by water flooding in three states, but no recent publication of comparable purpose describes gas-injection 7/ practices. The authors intend to present material relevant to the development and operation of gas-injection projects in Illinois, with particular emphasis on those producing from oil-bearing horizons that had been depleted to a point near the economic limit of operation by past oil-recovery methods.Most operators realize that the energy expended on the movement of fluids through gas-expansion- or gas-cap-type oil reservoirs to producing wells must be supplemented to attain maximum recovery of the oil present. Under favorable conditions, many operators choose to maintain oil-propulsive forces at or near their original magnitude by injecting extraneous fluids into a reservoir or recycling produced fluids early in the life of a field. More common, and less desirable, is the practice of replenishing these forces after primary producing methods become unprofitable. The lattes practice has been adopted in many stripper fields in Illinois and most of the oil-producing States during the last 40 years, but other old oil fields, and oil properties within those fields which were partly exploited by secondary--recovery methods, also may offer favorable opportunity for further development. To encourage and, aid operators in the development of gas-injection projects in the old oil fields of the United States, four projects have been described in detail in this report."

Nov 1, 1944

By G. A. Apell

"SUMMARYThe quality of Moose Creek coal is considered superior to that of any now being produced in the Matanuska field of Alaska. In rank it is classed as roar coking high-volatile B bituminous coal.At present the Moose -Creek mines are accessible from the Glenn highway by 6 miles of well-maintained gravel road. The nearest railroad loading point is Moose Creek siding; 7 miles by road from the Buffalo mine. Palmer, 12 miles south of Buffalo mine, is the nearest town. Anchorage is 50 miles south of Palmer by road and-railroad.Core drilling and trenching by the Bureau of Mines revealed 2,375,500 short tons of coal in the Buffalo series on the Buffalo Coal Co. leasehold. Of this, 514,200 tons is considered measured coal and 489,900 tons indicated coal. Existence of deeper beds over the same length increased the tonnage of coal of all categories to 3,279,300 tons. The property has an assumed life, of 16 to 22 years, depending on the number of beds mined, based on an output of 500 tons of coal a day and 100-percent recovery. Coal from some of the beds car be marketed without washing however, a washery is necessary if all beds are mined. Beds in the Buffalo series not mined in the ""first mining"" will be irrecoverable at any later date.The Bureau of Mines completed exploration of approximately one-third of the local coal-bearing areas during 1943. Knowledge gained from this work makes it possible to investigate the rest of the area by drilling an estimated additional 5,000 foot of hole."

Dec 1, 1944

By G. W. Jones

"INTRODUCTION As part of its work in promoting safety, the Bureau of Mines is investigating various means of eliminating or mitigating the explosion hazards of combustible gases encountered in mining and industry. Information has been obtained and a procedure developed whereby the explosibility of many complex gaseous mixtures may be calculated in a rather simple manner without the necessity of performing laborious laboratory experiments. An earlier publication 3/ described the method of determining by calculation the limits of inflammability of gaseous mixtures, including methane, hydrogen, carbon monoxide, nitrogen, carbon dioxide, and oxygen. The information published in the above report permitted calculation of the limits of inflamnability of such gases as are liberated by mine fires, gases from explosives, automobile exhaust gases, gases present after mine explosions, blast-furnace gas, and other gases of similar type.Gases liberated in certain potash mines in the western part of the United States sometimes contain ethane, in addition to the gases named. An investigation was made to obtain data from which the limits of inflammability of such gaseous mixtures could be determined by calculation. 4/Similar data have been Published covering all types of natural gases containing wide ranges of concentration of nitrogen and carbon dioxide.5/"

Dec 1, 1944

By Homor N. McDonald, G. Dale Coe, Will H. Coghill

"INTRODUCTION Sporadic beneficiation tests have been made on the Birmingham (Ala.) red iron ores for the last 55 years. Now, gravity-concentration plants are in operation, of tables are in use. A major problem, as seen by the present writers, is to obtain a coarser concentrate and add to the recovery without increasing the quantity of slime. The oily practicable solution found so far is to recover, by means of concentration (hydraulic) classifiers, the coarse concentrate normally lost in the table middling and, by a similar method, to recover middling particles from the table tailings The size and shape of the coarse concentrate Particles combine to cause them to report in the table middling rather than in the table concentrate. Similarly, mineral is lost in the tailing. Because of this, the nature of the ore, the deportment jerking table, plant tests on classifiers and tables, and the suitability of small concentration classifiers to treat table zonal middlings are discussed herein.The work was done by the Southern Experiment Station, Bureau of Mines, in cooperation with the University of Alabama, Tuscaloosa, Ala."

Jan 1, 1935

By R. S. Dean

"INTRODUCTION The idea of direct steel is by no means new. Although the work of Bessemer and Siemens provided simple and effective moans for converting pig iron into steel and established the ""blast-furnace route"" as the almost universal method of producing steel, metallurgists have not ceased to dream of direct steel. By direct steel is meant any process by which iron oxide in ore is reduced to Iron of the same or greater purity than the final steel or wrought iron. That is, carbon or alloying elements would be added as needed, not reduced in unwanted quantities into the iron and then removed more or completely by refining (Bessemer or open hearth) only to be readded in desired quantities.In general, direct-steel processes are ""sponge-iron"" processes, because reducing iron oxide without simultaneously alloying the iron with carbon, phcophorus, sulfur, and silicon present in ore and fuel succeeds only if the temperature is below the melting point of the iron. Such solid iron formed by reduction of iron oxide at relatively low temperature is sponge iron, which is butlery and porous. When the reduction proceeds at the higher temperature at which the particles of metal can weld together or finally even melt to yield pellets or balls that do not have the porosity and low-density characteristic of sponge iron, the product might preferably be called simply ""direct iron."""

Jan 1, 1945

By J. R. Thoenen, J. L. Vallely, M. C. Malamphy

"SUMMARYMagnetic and gravimetric surveys wore conducted over an area of ap¬proximately 1,400 square miles in the bauxite district of central Arkansas. The primary purpose of these surveys was to discover any possible buried and hitherto unknown syenite masses favorable for the occurrence of bauxite and to determine the approximate position of the buried flanks of the known syenite masses which might offer conditions favorable for the discovery of new ore bodies.Those surveys indicated that the various syenite outcrops were domes or bosses on a large batholith and that ether similar domes occurred on the batholith but did net outcrop.Drilling on the local geophysical anomalies proved the presence of 10 buried domes, but only 2 of them were found to project above the upper surface of the Midway clays, a requisite of conditions favorable for the occurrence of bauxite ore bodies. The geophysical data indicated the approximate configuration of the buried flanks of the known syenite coutcrops, and the portions of these flanks that project above the Midway have now been outlined more accurately by drilling.The geophysical surveys have produced evidence permitting the elimi¬nation of a large area as unfavorable for the occurrence of bauxite.Magnetic surveys extending along the Midway-Wilcox contact from Gurdon, in Clark County, on the southwest to Searcy, in White County, on the northwest have proved the improbability of the existence of other syenite masses similar to those found in Pulaski and Saline Counties. A detailed magnetic survey of the Magnet Cove area in Hot Spring County has proved that the syenite mass exposed in that locality is an isolated intrusion and entirely unrelated to those of Pulaski and Saline Counties. This syenite mass does not occur under conditions believed to be favorable for the occurrence of bauxite."

Feb 1, 1945

By Wilbert J. Huff

For the past 9 years , the technical studies conducted by the Explosives Division of this Bureau have been summarized in a series of reports issued annually . The following account presents investigations undertaken from July 1 , 1943 , to June 30 , 1944. The work is detailed under a number of main headings corresponding to the organizational structure of the Division , the various activities being under the immediate direction of unit chiefs , who report directly to the author . Specific credit , however , is due to the individual unit leader and his assistants .

Jan 1, 1945

By M. R. Geer, H. F. Yancey

Fuel requirements of the Pacific Northwest have been increased greatly by the war . To the normal peacetime demands for fuel have been added the requirements of new industrial and metallurgical plants engaged in war production , the increased demand arising from expansion of existing industrial establishments , increased amounts of railroad fuel required to handle wartime traffic , and increased quantities of domestic fuel required by the influx of war workers . In the face of these augmented demands for fuel shipments of fuel oil have been curtailed , wood fuel which normally is an important factor in both industrial and domestic markets of the area is less abundant , and the production of coal in Washington has decreased sharply . The fuel requirements of the region have been met so far by shipping large tonnages of coal into the Pacific Northwest from Utah , Wyoming , Montana , and Colorado ; the quantity received from these States and Canada in 1943 amounted to 2,688,9124/ tons , 175 percent of the Washington production . or The proximity of the Washington coal mines to large centers of war production has resulted in widespread migration of miners to employment in shipyards and aircraft plants ; the ensuing shortage of miners largely accounts for the decreased production of coal in the State . Hence , strip mining , which requires relatively few workers and a shorter time for development , offers an attractive means of alleviating the local coal shortage and obviating the necessity of shipping coal from the producing areas of the Rocky Mountain States to the Pacific.coast . So urgent has been the necessity for augmenting local coal production that any coal property that promises to be amenable to strip mining , even though the coal may be inferior in quality , has warranted examination . Even low- grade coals that cannot compete in the normal market can be used locally , thus releasing better coals for shipment to critical centers. of consumption ... One such deposit of low- rank fuel examined by the Bureau of Mines is in western Lewis County , about 9 miles east of Toledo , Wash . The coal is lignitic and on the as - received basis has a heating value of 6,000 to 6,500 B.t.u. per pound . The property is of interest primarily because the physical conditions favor operation by stripping and offer opportunities for low- cost production with very low manpower requirement .

Jan 1, 1945

By O. C. Blade

This report on the properties of motor fuels sold through service stations in the United States is a continuation of a series of reports made in accordance with a cooperative agreement between the Coordinating Fuel Research ( C.F.R. ) Committee of the Coordinating Research Council ( C.R.C. ) and the Bureau of lines of the United States Department of the Interior . The first of these reports presented data on motor gasolines sold during the winter of 1935-35.4/ Further reports have been issued describing motor gasolines sold during the succeeding summers and winters to and including the summer of 1941.5/ No reports were made on motor gasolines sold during the winter of 1941-42 and during the summer of 1942 . However , starting with the winter of 1942-43 , the semi - annual reports have been resumed

Jan 1, 1945

By Wilber Duvall, Leonard Obert

"INTRODUCTION This report is the first of four to be presented on the microseismic method 4/ of predicting rock failure in underground mining. The application of the microseismic method to one specific case, namely, that of predicting rock bursts in deep mining, has been described in two previous reports. 5/ 6/ Since the publication of these reports 5/ 6/ the method has been extended to other fields of mining, end it is the purpose of this report (Part I) to describe the general microseismic method, giving the empirical facts upon it is based, the different testing procedures, the method of recording and analzing the data, and the interpretations that can be obtained there-from. Part II will describe a series of laboratory experiments that were performed to give information on the origin of microceismims and the microseismic properties of various rocks. Part III will cover application of the method to specific mining problems together with a brief description of a number of investigations performed during, the last three years. Part IV will describe in detail the microseicmic equipment used in the various phases of these investigations."

Feb 1, 1945

By G. W. Jones, R. E. Kennedy

"INTRODUCTION In the manufacture, storage, transportation, and use of combustible gases and vapors, explosion hazards, which at times may be present when air becomes mixed with the gases and vapors, become of primary importance. Such conditions are especially dangerous where large volumes of gaseous atmosphere are involved, because an explosion under such circumstances is capable of doing tremendous damage to both property and personnel.Because of its interest in safety in the mining and allied industries, the Federal Bureau of Mines has investigated, and published results dealing with, the explosibility of various types of combutible atmospheres. The explosion hazards of natural gases have received attention, and results giving the limits of inflammability and ignition temperatures in air have been determined and published. 4/ Other investigations have shown how explosions of natural gas-air mixtures may be prevented by the addition of nitrogen and carbon dioxide. 5/Because of the increased demand for crude oil for war purposes, the application of secondary-recovery methods of stimulating oil production have received considerable attention during the last few years. The process consists in the injection of natural gas into partly depleted oil wells to cause the oil in the sands to flow into producing wells and so increase the amount of recoverable oil. 6/"

Feb 1, 1945

By J. Bruce Clemmer, M. F. Williams, B. H. Clemmons, Carl Rampacek, R. H. Stacy

"INTRODUCTION This report is the first of several dealing with the application of flotation methods for beneficiating the calcareous and siliceous red iron ores and ferruginous sandstones of the Birmingham district. The flotation study was part of a general investigation of the concentratability of various iron ores of Alabama and other Southeastern States undertaken by the Southern Experiment Station of the Bureau of Mines, United States Department of the Interior, in cooperation with the University of Alabama, Tuscaloosa, Ala.Batch testing and pilot-plant flotation testing of the calcareous red ores of the Birmingham district have been in progress for several years, and although some phases of the study are not yet completed, enough data are available to indicate that many of the ores will yield marketable-grade concentrates with good recovery.The first flotation tests on the calcareous red ores employing conventional methods either the iron oxides or the siliceous gangue materials failed to give the desired results. The inferior separations obtained or prohibitive reagent requirements made the methods unattractive. Other more effective flotation methods were sought. A laboratory study of various reagents was undertaken. It resulted in the development of two attractive methods embracing anionic flotation of the activated siliceous gangue from the retarded iron oxides. The methods were similar in that fatty acid or soap-collecting agents were employed in strongly alkaline pulps to float the naturally activated quartz from the iron-ore pulps. The methods differed, however, in the addition agent employed to retard the hematite or hematite and calcite. By proper choice and quantity of the addition agent, the calcite could be floated with the quartz or retarded with the hematite as desired. Ability to recover or reject the calcite gives added flexibility to the separation. Although the methods have their limitations and cannot be considered ""cure-alls,"" they have given encouraging results on a number of calcareous red ores that heretofore proved difficult to concentrate by conventional flotation procedures."

Mar 1, 1945

By Howard F. Carl

"INTRODUCTION Talc is a hydrous magnesium silicate mineral found throughout the world in deposits of economic importance. This mineral occurs in different physical forms and varying degrees of purity, both of which affect its ultimate commercial usage. Talc is used in finely ground condition by the ceramic, paint, paper, rubber, cosmetic, and other industries. Most domestic talc production is of this type. Talc also occurs, although much less frequently, in massive, fine-grained, fairly homogeneous bodies; the impure varieties are the familiar soapstones, and the purer form is frequently called ""steatite."" Because of certain properties, the purest grades of this massive variety have a monetary value about 20 times that of the ground talc.One desirable property of this massive talc is its amenability to accurate cutttng, machining, and working in many ways, similar to a hard wood or soft metal, and then firing without warping or appreciable shrinkage into a hard, refractory ceramic body. Consequently, shapes that cannot be formed conveniently by molding and pressing can be produced readily with ordinary machine tools. When talc is fired to about 1,100° C., it is converted to a ceramic body with certain very desirable physical properties. This fired material has a hardness and toughness frequently superior to steel. It is a refractory and an exceptionally good electrical insulator. When formed from a high-grade talc essentially free from iron, it has unusually low dielectric losees, even at very high frequencies."

Feb 1, 1945

By C. E. Julihn, Lowell B. Moon

"INTRODUCTION To increase the supply of ore needed to produce steel the Bureau of Mines has explored 187 mineral deposits containing chromium, iron, manganese, cobalt, nickel, fluorspar, tungsten, vanadium, or coal during the fiscal years. 1940-44, the deposits thus explored were selected from several thousand that were first examined to appraise their possibilities. The objective of the exploration was to determine the tonnage and grade of ores upon which mining, operations might be based, and the metallurgical processing that was most suitable for their utilization.Most of these deposits were sub-marginal by pre-war standards; hence there had been no incentive for their exploration, yet many such deposits were known to exist that probably contained ore sufficient in grade and amount to be utilized as war reserves.Some of the Bureau's exploration projects have disclosed substantial or even very large amounts of ore, much of which is fairly high in grade. In a few of them bodies of high-grade ore have been found, though in others the tonnage has proved to be too small or too low-grade for utilization."

Mar 1, 1945

By O. C. Blade

"An important function of the Bureau of Mines is promoting the conservation and more efficient utilization of a natural resource. Petroleum is such a resource, and its utilization depends to a considerable degree upon its characteristics. For this reason the Bureau of Mines, over a period of years, has analyzed many samples of crude petroleum by the Bureau of Mines Hempel method 3/ and published complications of crude-oil analyses. Among such publi¬cations are several reports presenting analyses of crude oils from fields in Oklahoma. The most recent of these relates to samples from southern Oklahoma. 4/ The present paper provides additional analyses of Oklahoma crude oils, largely from areas and formations not heretofore represented in published reports. The analyses of 248 samples from 153 fields are presented individually and collectively in the tables of this report.Crude oil has been produced in Oklahoma in commercial quantities since 1891, and peak production was reached in 1947. The State's cumulative production to January 1, 1944, is, according to the American institute of Mining and Metallurgical Engineers, 5,186,466,000 barrels. 5/ The annual production of crude petroleum in Oklahoma for each year from 1891 to 1943, inclusive, is given in table 1."

May 1, 1945

By Theron A. Klinefelter, Sidney Speil, Sidney Gottlied

"INTRODUCTION The investigation of domestic talcs by the United States Department of the Interior Bureau of Mines, was initiated in December 1941 at the request Gen. Charles Hines of the United States Army. The urgency for such study was expressed by General Hines as follows:The radio-manufacturing industry has recently been expanded by the Army to provide sufficient, capacity for defense needs, and considerable concern has been expressed by the supply Arms and Services over maintaining continued availability of supplies of the necessary raw material. These ceramic products are used by the Signal Cores in all Army radio equipment, and to a greater degree in the new special ultra-high-frequency equipment. The Air Corps has recently become a user large amounts of radio-grade ceramics for aircraft spark-plug covers required for high-altitude operations. In addition, the use of this material is essential to the proper functioning of the radio-navigation aids of the Civil Aeronautics Board.Progress in the Bureau of Mines studies on talc was made available to representatives of the Army and Navy through frequent interim reports. Through the efforts of the several war agencies concerned with raw-materials supply and the domestic talc producers, the condition of scarcity that developed in 1942 passed to one of ease in 1943, and has so continued to date. Tentative estimate of reserves delineated indicates a supply of high-grade steatite sufficient to meet military war requirements for at least 4 or 5 years."

Apr 1, 1945

By Lloyd R. Michels, Burke Cartwright, S. F. Ravitz

"INTRODUCTION Frequent attempts have be,made in the electrolysis of molten magnesium chloride to regenerate the electrolyte by allowing the chlorice generated at the anwdo to read with magnesium oxide and carbon within the melt according to the following reactions: (1) MgO + C + CL2 = MgCl2 + CO,(2) 2MgO + C + 2C12 = 2MgC12. + CO2.The principal advantages of such a procedure are that (1) the direct source of magnesium is magnesium oxide rather than the more expensive dehydrated magnesium chloride and (2) it is not necessary to handle or dispose of large quantities of chlorine or hydogen chloride.Grätzll 5/ proposed the use of an MgO carbon feed in a more or,less compact form in the anode compartment, of the cell. In a patent issued to Magall Aktiengecellschaft, 6/ a compact mixture of MgO and carbon is used as the anode itself. Kato 7/ and Backer 8/ add the feed in finely divided form to the surface of the anode compartment. The Bureau of Mines 2/ recently made a pilot-plant investigation of the electrolysis of suspension of MgO and carbon from chloride melts, in which it was found that although,current efficiencies of 60 to 70 percent were obtainable, the formation of sludges containing MgO, carbon, and magnesium seriously interfered with the operation of the cell,"

Apr 1, 1945

By E. Don Dilling, W. F. Holbrook, Lloyd R. Michels, James W. Pennington, Dwight L. Harris, Wm. F. Hergert, Cyrus L. Blogett, H. A. Doerner, Ernest A. Reige

"IntroductionA process for production of magnesium by carbothermal reduction was developed at Padentheirm, Austria, by the Austro Americanische Magnesit Corporation& an independent investigation of this and other processes was started in 1937 by the Bureau of Mines at Pullman, Wash., with the cooperation of Washington State College. 10/ A preliminary study of the Radentheirm pro¬cess, as revealed by the meager information then available, demonstrated the following two major disadvantages,The use of hydrogen for shock cooling requires an enormous volume of gas - about 1,000 cubic feet for condensing each pound of metal as a pyrophoric dust which must be completely separated from this gas. Then if the gas is to be recycled for repeated use, the CO produced by the reduction reaction must be separated from the hydrogen. These separations are costly from the standpoint of equipment and operation. 11/The condensate is an impure, pyrophoric metal powder that must be purified and converted to coherent form. This is accomplished by distillation or sublimation of the metal. Distillation on a large scale involves difficulties inherent in the high boiling point (1,107° C.) and the chemical activity of the metal. To avoid these difficulties, the metal is sublimed at 600° C. and of very low pressure. This is quite easily carried out as a batch operation but is a costly procedure. A continuous sublimation process has not been accompli shed."

May 1, 1945

By L. D. Schmidt, Wm. Seymour, W. S. Landers

"INTRODUCTION The relative value of the various individual physical and chemical properties of coke as a measure of its performance in the blast furnace as aroused considerable controversy but it is generally agreed that uniformity in these properties is extremely important if maximum mum pip-iron production is to be attained. The control of,the bulk density or weight per cubic feet of the coal charge in the coke ovens is a major, and frequently overlooked, factor in producing a uniform product and in efficient operation of the coke plant.This report presents a brief discussion of the general problem of bulk-density control and the results of tests on samples of coke-oven charges from several operating plants experiencing difficulties due to lack of adequate control. These tests covered the effect of moisture and oil content on the bulk density of the coal. Some tests on the effect of a wetting agent and furnenous of gained were also made. A description of the methods used to determine the bulk density of the coals studied in this investigation and of the methods used to apply oil to the coal at byproduct-coke plants are included in this product. No theoretical analysis of the data presented in this report, because the primary purpose of the investigation was to obtain data of immediate practical value to the plants concerned."

Apr 1, 1945