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By E. S. Leaver

The gold that is not recovered by a particular process is refractory to that process. A study to determine how the refractory gold is associated in the ore constituents usually indicates the needed improvement in the process or additional methods for bettering recovery. In preliminary work, segregation of the various minerals, gangue or impurities, and data showing the reactions of each in the recovery method readily confines the refractory gold to a certain part on which extensive research can be directed. In this dissecting plan, the microscope is an important aid in locating the refractory gold but should be supplemented by chemical tests. Each ore is an individual problem until the association of the gold has been determined. Knowing the problem through the interfering minerals or elements, the solution often is only the application of part of a former known practice as an auxiliary or additional feature. In the treatment plan for most gold ores, it has been the custom to try each of the usual recovery methods or combinations thereof, accepting the best results on a basis of the lowest cost. A better plan includes knowledge of the association of the gold and the various minerals from which it is to be recovered. This presents reasonable foresight into the problems that should be expected and permits some provision for avoiding probable difficulties. The preliminary work should include: Determination of the percentage of free gold with classification showing size of gold particles to be expected; determination of the percentage of gold associated with each mineral and whether it be freed from the mineral by crushing; and an analysis of representative samples of the ore to include other valuable minerals and the form in which they occur.

Jan 1, 1934

By Paul Hatmaker

Lime was a highly useful commodity thousands of years before the simple chemistry of its manufacturing process was known. The employment of lime for agriculture, building, and even certain essentially chemical purposes is so old that its origin is among the unrecorded details of man's first ventures into the manufacture and use of prepared substances. Lime is a most versatile material and consequently has come to be widely utilized in modern civilization. Immediately before the depression of the early 1930's the annual production of lime in the United States was more than 4 million tons, valued at 33 to 42 million dollars. This output was sold to many industries, so many that mere enumeration becomes tedious. In addition to agricultural and building lime the sales statistics compiled annually by the Bureau of Mines include lime sold to the steel and other metallurgical industries as refractory and fluxing material, as well as that used by paper mills, glass works, tanneries, and water-treatment plants. These major uses normally consume about 86 percent of the domestic sales. The remaining 14 percent includes lime sold for use in the manufacture of alcohol, alkalies, bleaches, calcium acetate, calcium carbide, coke gas and byproducts, glue, insecticides, oils and fats, paints, and rubber, in the refining of salt, in the manufacture of sand-lime and slag brick, in the disposal of sewage and garbage, in the manufacture of silica brick, in the refining of sugar, in the textile industries, and in wood distillation. Many other uses are also known for which complete sales data are not available.

Jan 1, 1934

By Paul Hatmaker

Lime was a highly useful commodity thousands of years before the simple chemistry of its manufacturing process was known. The employment of lime for agriculture, building, and even certain essentially chemical purposes is so old that its origin is among the unrecorded details of man's first ventures into the manufacture and use of prepared substances. Lime is a most versatile material and consequently has come to be widely utilized in modern civilization. Immediately before the depression of the early 1930's the annual production of lime in the United States was more than 4 million tons, valued at 33 to 42 mil-million dollars. This output was sold to many industries, so many that mere enumeration becomes tedious.

Jan 1, 1934

By W. A. SLOAN, G. L. Oldright, J. D. Sullivan, E. K. PRYOR, A. F. HALLET, R. S. Dean, S. L. BROWN, F. S. Wartman, A. J. Thompson

Lack of sufficient publication funds has resulted in the accumulation of considerable unpublished experimental work on copper metallurgy by the Bureau staff . The present report gives extended abstracts of this work , as well as a discussion of the best direction for future efforts . The experimental work reported in this series of papers was done in cooperation with the University of Arizona , Tucson , Ariz . The investigations covered in the third , fifth , and seventh papers were done under the direction of G. L. Oldright and the remainder under the direction of V. H. Gottschalk .

May 1, 1934

By G. R. FITT, S. R. B. Cooke, C. W. Davis, V. H. Gottschalk, C. G. Maier, C. E. Wood, R. S. Dean, S. B. THOMAS, John Gross, E. P. Barrett, T. L. Joseph

Lack of funds has prevented publication of much of the metallurgical work of the Bureau of Mines during the past 2 years . The present progress report covers studies in the direct production of iron and steel . The experimental work was carried out in cooperation with the universities of California , Minnesota , and Missouri . Complete reports will be published when funds are available .

May 1, 1934

By V. B. Royer, C. H. Harty

"MANGANESE-SILOCON ALLOYS AS DEOXIDIZERSThe basic open-hearth process for steel mining requires large amounts of oxidized iron for oxidation of the elements carbon, silicon, manganese, and phosphorus which are to be removed from the metal. Some of this oxidized iron (FeO) dissolves in the metal during the refining process, Subsequent to the elimination of the elements named, a considerable amount of dissolved iron oxide must be removed before the metal may be cast into ingot form. The elements generally used, for iron oxide removal, or deoxidation, are silicon, manganese, and aluminum. Silicon and manganese are always alloyed with iron, either singly or in combinations of various compositions. Aluminum generally is used in a commercially pure state and sometimes in complex alloys. A double deoxidizer of manganese and silicon alloyed with iron for furnace deoxidation has been the subject of an extensive cooperative investigation between the United States Bureau of Mines, the Carnegie Institute of Technology, and the Metallurgical Advisory Board. Certain grader of steel, especially low-carbon rimming steels, require a low-carbon deoxidizer to keep the finished steel within the carbon specification after deoxidation. ACKNOWLEDGMENTThe authors wish to acknowledge the assistance of J. F. Sanderson and S. S. Johnston in the analysis of the alloys used in this work.PURPOSE OF WORKThe need for definite information as to which compositions of manganese and silicon within a certain manganese-silicon ratio and when alloyed with iron would have an allowable carbon content for the particular grade or type of steel on which the deoxidize is used, prompted the undertaking of this investigation to determine the solubility of carbon in manganese, silicon, and iron alloys within the region bounded by 10:1 and 4:l manganese to silicon ratios. These data should be of value to the manufacturer producing such"

May 1, 1934

By A. B. Hooker, E. J. Coggeshall

"Dry cells are modified wet primary cells in which the electrolyte is held by absorbent material so that it does not spill aid the cell jars are sealed to prevent evaporation of the absorbed electrolyte. Most dry cells in commercial use are modifications of the Leclanche wet cell. In their usual form they have a hollow cylindrical zinc negative pole that constitutes the containing vessel. An absorbent material, either as a lining in the zinc jar or a bag, separates the zinc cylinder and a rod or flat plate of carbon placed axially inside. A mixture of crushed coke, graphite, and manganese dioxide is tamped about the carbon rod, and the whole mass is saturated with salaanoniac-zinc chloride solution.Dry cells are suitable for services that require minute currents continuously or larger, though limited, amounts of current intermittently. Though limited in this way, they have a wide use, even in underground mining. This paper details some of the applications of dry cells in mines, particularly from the standpoint of greater safety through their use.APPLICATIONSThere are four fields of application of dry cells to mining: (1) Electric shot firing; (2) auxiliary lighting; (3) signaling; and (4) testing.SHOT FIRINGFiring an electric detonator requires very little electrical energy because although the current flow may be 1 to 3 amperes the duration of flow is so small (1 to 4 milliseconds) that the energy withdrawal per shot is almost negligible. Batteries for shot firing need not be large; they may be used for firing either single or multiple shots."

May 1, 1934

By M. B. Boyer, C. H. Herty, F. A. Hartgen, G. L. Frear

"DEFINITION OF VISCOSITYViscosity has been defined as the resistance experienced by one portion of a liquid moving over another portion, such as one molecular plane moving over an adjacent plane. A measure of viscosity is the force required to keep one plane in motion at Unit velocity, the other plane being considered stationary. Figure 1 illustrates the general idea that the surface friction between two adjacent areas will be greater the larger the molecules. Therefore it may be assumed that viscosity will be increased by molecular association or agglomeration, and likewise dissociation rill decrease viscosity. According to Maxwell (1)6 the unit of viscosity, the poise, is the tangential force per square centimeter of area of either of two horizontal planes 1 centimeter apart, one of which is fixed while the other moves with unit velocity, the space between being filled with viscous liquid of unit viscosity.The need for a satisfactory apparatus and experimental procedure for the determination of viscosity of high-melting materials at temperatures corresponding to those in pig-iron and steel making has been recognized during the past few decades. The condition of the slag during the smelting and refining periods in the iron- and steel-making processes exerts an important influence on the metal product obtained, this slag condition really meaning the state of viscosity or, vice versa, fluidity, which the slag attains under certain conditions."

Jun 1, 1934

By M. B. Boyer, C. H. Herty, F. A. Hartgen, G. L. Frear

"DEFINITION OF VISCOSITYViscosity has been defined as the resistance experienced by one portion of a liquid moving over another portion, such as one molecular plane moving over an adjacent plane. A measure of viscosity is the force required to keep one plane in motion at Unit velocity, the other plane being considered stationary. Figure 1 illustrates the general idea that the surface friction between two adjacent areas will be greater the larger the molecules. Therefore it may be assumed that viscosity will be increased by molecular association or agglomeration, and likewise dissociation rill decrease viscosity. According to Maxwell (1)6 the unit of viscosity, the poise, is the tangential force per square centimeter of area of either of two horizontal planes 1 centimeter apart, one of which is fixed while the other moves with unit velocity, the space between being filled with viscous liquid of unit viscosity.The need for a satisfactory apparatus and experimental procedure for the determination of viscosity of high-melting materials at temperatures corresponding to those in pig-iron and steel making has been recognized during the past few decades. The condition of the slag during the smelting and refining periods in the iron- and steel-making processes exerts an important influence on the metal product obtained, this slag condition really meaning the state of viscosity or, vice versa, fluidity, which the slag attains under certain conditions."

Jun 1, 1934

By R. F. Selder

The material in this paper is intended simply to be an inquiry into some of the theoretical aspects of the occurrence of methane and carbon dioxide in coal, with a brief resume of the more recent literature. Several discussions of various phases of the subject have been published a few of which (4, 20, 25, 88, 90) have more or less extensive bibliographies of the earlier literature. In large measure the pertinent literature deals with the unusual aspects of the subject, and in consequence it might appear that the normal aspects have not been given due consideration here. The latter information is largely a matter of practical field experience, and since that which is normal to one locality is often abnormal to another no sharp differentiation appears to be necessary or, in fact, possible. No attempt will be made to present a critical discussion of the relations between the presence of gases in coal and pertinent geologic features or mining practice. Although the presence of foreign gases in the ventilating air of many mines is not particularly noticeable, in many others the evolution of methane and perhaps small amounts of carbon dioxide (or sometimes the reverse - large amounts of carbon dioxide with perhaps sore methane) is quite apparent. The presence of small quantities of carbon dioxide can be attributed to oxidation of the carbonaceous matter exposed to the air. In the few cases in which this explanation is not sufficient, obviously the carbon dioxide must escape as such from the coal and neighboring strata.

Jan 1, 1934

By George S. Rice

"The emission of hydrocarbon gases from coal beds and contiguous strata causes many accidents in coal—mine workings, the number of fatalities so caused being second only to those due to falls of roof. Gases tend to increase in amount with depth of coal mining, hence the danger of explosion is increased with depth. The pressure of the gas in virgin—coal areas at a distance from mine workings likewise tends to increase with depth from the surface, probably due to corresponding increase in hydraulic head and possibly, when the gas is held in nonporous formations, to greater ground pressure. The rise in gas pressure with depth under usual conditions is shown in wells drilled from the surface and in some coal fields in drill holes into the face of workings; however, under normal conditions of coal formation gas does not issue into workings under high pressure because the coal and adjacent strata have many bedding and joint planes which allow the gas to escape freely at the face of the workings. The rare occurrence of instantaneous outbursts of gas, with violent effects referred to later, constitute the exception.Variations of volume and pressure of fire-damp or methane found in different coal beds by wells at a distance from mine workings, are analogous to variations in volume and pressure of natural gas found in different gas and oil sands, although in general the pressure tends to increase with the depth. Sometimes, however, in tight sands higher in the formation the pressure of gas therein is abnormally high, and on drilling the well deeper gas in the lower strata may be found at lower pressure."

Jun 1, 1934

By R. F. Selden

The material in this paper is intended simply, to be an inquiry into some of the theoretical aspects of the occurrence of methane and carbon dioxide in coal, with a brief resume of the more recent literature. Several discussions on various phases of the subject have been published, a few of which (4, 20, 25, 88, 90)4/ have more or less extensive bibliographies of tie earlier literature. In large measure the pertinent literature deals with the unusual aspects of the subject, and in consequence it might appear that the normal aspects have not been given due consideration here. The latter information is largely a matter of practical field experience, and since that which is normal to one locality is often abnormal to another no sharp differentiation appears to be necessary or, in fact, possible. No attempt will be made to present a critical discussion of the relations between the presence of gases in coal and pertinent geologic features or mining practice. Although the presence of foreign gases in the ventilating air of many mines is not particularly noticeable, in many others the evolution of methane and perhaps small amounts of carbon dioxide (or sometimes the reverse - large amounts of carbon. dioxide with perhaps sore methane) is quite apparent.

Jan 1, 1934

By W. D. Musgrove, B. W. Gandrud, A. C. Richardson

"INTRODUCTION The Cahaba coal field is the second largest coal—producing area in Alabama. This field underlies parts of Shelby, Jefferson, St. Clair, and Bibb Counties and has an area of about 270 square miles. The Cahaba formations contain a number of coal beds, about 8 of which are mined at present. Although the area contains many folds and faults, samples from various mines and beds indicate that, except for the variation in ash content, the coal from this field is very uniform in character and quality. It is a high-volatile bituminous coal used chiefly for steam-raising purposes and domestic fuel. The coal as mined usually contains too high a percentage of impurities to be marketed without some preparation. The majority of the mines have washing plants in which jigs are the favorite type of equipment, although at some mines tables are used for cleaning the slack sizes. The washing characteristics of the coal from the Cahaba field are very uniform and differ from those of the near-by Warrior field, in that the coarser sizes contain a much lower percentage of bony material than the finer sizes. In general, the bone increases with decrease in size. It breaks into thin flakes, making difficult its elimination in the cleaning process, and gives rise to what is known among the washery operators of the Cahaba field as the ""rash problem.""A previous publication 5 referred to rash from the standpoint of jig operation and suggested some means of handling it with jigs. This report presents the results of table tests on two samples of fine coal from the Thompson and Woodstock beds, respectively, of the Cahaba field to determine the influence of rash on table efficiency.This investigation has been made in connection with the study of coal-washing problems now being conducted by the U.S. Bureau of Mines and the University of Alabama, with the cooperation of the different coal operators of Alabama."

May 1, 1934

By J. E. Tiffany, N. A. Tolch

The Pittsburgh Experiment Station has made a survey of the properties and characteristics of the brands of fuse manufactured in the United States ; 25 samples were procured from 4 manufacturers representing the different brands offered on the market when the investigation was begun . It is believed that the field was completely covered except for special fuse made to order for a particular job .

Jun 1, 1934

By Arthur L. Crawford, R. E. Head, Glen Burgener, F. E. Thackwell

"INTRODUCTION This report embodies the results of a detailed statistical microscopic examination of the ore and the mill products of the Silver King Coalition Mines Co., Park City, Utah.The study was conducted under the joint auspices of the United States Bureau of mines is cooperation with the University of Utah at Salt Lake City, Utah. The work was done in the cooperative Microscopic Service Laboratory, which was equipped by contributions from the following companies: Utah Copper Co., International Smelting & Refining Co., American Smelting & Refining Co., United States Smelting, Refining & Mining Co., Tintic Standard Mining Co., Silver King Coalition Mines Co., and Park Utah Consolidated Mines Co. The salaries and the other costs involved in operation of the laboratory were met by contributions from certain supporting companies. In addition to the regular personnel of the laboratory the Bureau of Mines contributed the part-time services of a microscopist-consultant to direct and assist with the technical work.ACKNOWLEDGEMENTSThe authors acknowledge the courtesies extended by the Silver King Coalition Mines Co., through its general manager, M. J. Dailey, in furnishing the various ores and products on which the study was made, together with general information concerning the problems encountered or recognized in connection with the milling of the Silver King ore."

Jun 1, 1934

By J. M. Davidson

The potassium mineral polyhalite (K2SO4.MgSO4.2CaSO4.2H20) found in large deposits in western Texas and southeastern New Mexico is associated with varying amounts of halite (sodium chloride, NaCl) and anhydrite (calcium sulphate, CaSO4). Although the anhydrite, because of its low solubility and slow rate of solution, is relatively inert, the halite is dissolved immediately in any process solution with which the polyhalite comes in contact. Limited quantities of sodium chloride in the liquors used for the hot extraction of polyhalite materially improve the results obtained,4 but only a very small sodium chloride content may be desired in the entering polyhalite in other procedures, such as Bureau of Mines process 75. In. all of the processes suggested for the recovery of potassium sulphate from polyhalite the control of the sodium chloride content will be desirable, if not absolutely essential to efficient operation. OCCURRENCE OF HALITE IN POLYHALITE A preliminary estimate of the amount of halite associated with typical deposits of polyhalite may be derived from drill cores, although it should be remembered that only 50 or 60 core tests have been made in the many hundreds of square miles of the Permian basin. From a mineralogical study of 41 of these cores, Schaller and Henderson6 state: In many of the sections of core that seem when viewed by the unaided eye to consist essentially of polyhalite, both halite and anhydrite are present in greatly varying quantities - with very minor quantities of clay and magnesite.

Jan 1, 1934

By J. M. Davidson

The potassium mineral polyhalite (K2SO4.MgSO4.2CaSO4.2H2O) found in large deposits in western Texas and southeastern New Mexico is associated with varying amounts of halite (sodium, chloride, NaCl) and anhydrite (calcium sulphate, CaSO4). Although the anhydrite, because of its low solubility and slow rate of solution, is relatively inert, the halite is dissolved immediately in any process solution with which the polyhalite comes in contact. Limited quantities of sodium chloride in the liquors used for the hot extraction of polyhalite materially improve the results obtained, but only a very small sodium chloride content may be desired in the entering polyhalite in other procedures, such as Bureau of Mines process. In all of the processes suggested for the recovery-of potassium sulphate from polyhalite the control of the sodium chloride content will be desirable, if not absolutely essential to efficient operation.

Jan 1, 1934

By Sam S. Taylor

In most oil fields, natural gas is the major source of energy causing flow of oil to the well. The amount of gas produced with the oil generally exceeds actual energy requirements, so that in time the gas reserve of the field becomes seriously depleted and the oil production must be stimulated by some auxiliary means. One of these is to repressure the oil formation with natural gas; or, where a as supply is not available, often air is used. Although air is a cheap and convenient repressuring medium, its use sometimes is attended with several disadvantages. First, the return air-gas mixture decreases rapidly in fuel value, often until it can be used no longer as a source of power. At the same time, explosive mixtures may result if recycling is used, causing hazards to life and equipment. Second, sortie fields experience considerable trouble with the formation of emulsions which become increasingly difficult to treat. Although there is no definite proof that air repressuring always causes these emulsions, many operators are convinced that this is the case. The Petroleum Experiment Station of the United States Bureau of Mines at Bartlesville, Okla., has been interested in problems connected with air-repressuring for a number of years. Some time was spent in studying the so-called "bad gas"--return mixture of low fuel value. However, it appeared impossible to attack the problem successfully from this angle, and an approach was made through a laboratory-scale study of direct oxidation of crude oil.

Jan 1, 1934

By Sam S. Taylor, H. M. Smith

"INTRODUCTION In most oil fields, natural gas is the major source of energy causing flow of oil to the well. The amount of gas Produced with the oil generally exceeds actual energy requirements, so that in time the gas reserve of the field becomes seriously depleted and the oil production must be stimulated by some auxiliary means. One of these is to repressure the oil formation with natural gas; or, where a gas supply is not available, often air is used.Although P.ir is a Cheap and convenient repressuring medium, its use sometimes is attended with several disadvantages. First, the return air-gas mixture decreases rapidly in fuel value, often until it can be used no longer as a source of power. At the same time, explosive mixtures may result if recycling is used, causing hazards to life and equipment. Second, some fields experience considerable trouble with the formation of emulsions which become increasingly difficult to treat. Although there is no definite proof that air repressuring always causes these emulsions, many operators are convinced that this is the case. The Petroleum Experiment Station of the United States Bureau of Mines at Bartlesville, Okla., has been interested in problems connected with air-repressuring for a number of years. Some time was spent in studying the so-called ""bad gas""--return,mixture of low fuel value. However, it appeared impossible to attack the problem successfully from this angle, and an approach was made through a laboratory--scale study of direct oxidation of crude oil."

May 1, 1934

By Sam S. Taylor

In most oil fields, natural gas is the major source of energy causing flow of oil to the well. The amount of gas produced With the oil generally exceeds actual energy requirements, so that in time the gas reserve of the field becomes seriously depleted and the oil production nest be stimulated by some auxiliary means. One of these is to repressure the oil formation with natural gas; or, where a gas supply is not available, often air is used. Although air is a cheap and convenient repressuring medium, its use sometimes is attended with several disadvantages. First, the return air-gas mixture decreases rapidly in fuel value, often until it can be used no longer as a source of power. At the same time, explosive mixtures may result if recycling is used, causing hazards to life and equipment. Second, some fields experience considerable trouble with the formation of emulsions which become increasingly difficult to treat. Although there is no definite proof that air repressuring always causes these emulsions, many operators are convinced that this is the case.

Jan 1, 1934