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By R. D. Leitch, W. P. Yant, A. C. Fieldner, R. R. Sayers, S. J. Pearce

"The detection of leakage is a recognized problem in the safe and economic distribution and use of natural gas. Natural gas is practically odorless and therefore lacks he property of indicating significant leakage by the sense of smell, the means most widely used by gas employees and consumers for detecting leaks of the more odorous types of fuel eases. In view of the recognized value of the odor of gas for indicating leakage at the time of occurrence the Bureau of Mines has studied' the possibility of adding small amounts highly odorous substances to types of fuel gas (such as blue water gas and natural gas) that lack warning properties. These studies revealed that the mercaptans were promising substances to accomplish this purpose, not only for odorizing fuel gases but for other purposes° where it was desired to give warning through the sense of smell.Since completing the studies mentioned, the Bureau of Mines jointly with the American Gas Association has conducted further investigations dealing with the use of warning agents for fuel gases. The results of this work will be published later.The Bureau of Mines had been desirous of observing the practical use of ethyl mercaptan for detecting leakage of natural gas, particularly to determine whether the odor would permeate the ground and give indication of lea's in underground pipes. Opportunity for making these observations was recently given by E. A. Munyan, manager, gas department, Union Gas t Electric Co., who requested the bureau's cooperation in making leakage surveys of the company's distributing systems at Franklin and Middletown, Ohio."

Jun 1, 1930

By A. B. Hooker

Many attempts have been made to develop methane detectors that will be safer and more accurate than the flame safety lamps used to detect methane in mines. The development has taken two general forms, namely: (1) Methane detectors, in which the evidence of methane depends entirely upon changes in the appearance of the detecting element, such as a flame or filament; (2) indicating methane detectors or those equipped with scales upon which the approximate percentage is definitely indicated. As an aid in the development of suitable detectors, the United States Bureau of Mines has assembled and published in its Schedule 8B a set of minimum requirements which tests and experience have shown desirable for methane detectors. Any manufacturer may submit his detector for inspection and tests leading to approval under this schedule.

Jan 1, 1930

By W. W. Adams

The United States Bureau of Mines, in cooperation with the National Send and Gravel Association conducted a safety contest in 1929 Among producers of sand and gravel. Only 26 plants were enrolled, as the contest was late getting under way. It is hoped that a ranch larger number of plants will be represented in the safety competition of 1930. Two trophies, both of which were provided by Rock Products magazine, were awarded at the end of the contest; one trophy was given for the best safety record among plants working 100,000 or mare man-hours during the year and the other for the beat record among plants working less than 100,000 man-hours. The trophies were presented to representatives of the winning, companies on January 29, 1930, at the annual convention of the National Sand and Gravel Association at Memphis, Tenn.

Jan 1, 1930

By K. A. Johnson

Marshall and Bird have published the results of a cooperative investigation by the Bureau of Mines in which they developed a procedure for measuring the agglutinating value of coal.4 As stated in their paper, the procedure outlined was suggested by the early worn of Richters5 and Campredon,6 whose procedures were hurriedly modified to meet the need of an investigation then in progress. Since the publicatien of that paper, further work has been done in an attempt to show how the variables involved affect the concordance of the results, in order that such results may be obtained in different laboratories. Briefly, Marshall and Bird's method for determining the agglutinating value of coal consists in carbonizing an intimate mixture of 10 parts by weight of sand and 1 part by weight of coal in a porcelain crucible at a uniform temperature of 950° C. in a, vertical, cylindrical, electrically-heated furnace. After carbonization, the resultant buttons are crushed in a testing machine and the breaking strengths recorded in grams. The agglutinating value reported is the average breaking strength of 10 buttons. The coal for the test is prepared by crushing to pass a 100-mesh screen. The sand used as a diluent is sized between 40 and 50 mesh sieves with openings of 0.381 icon and 0.279 millimeters, respectively.

Jan 1, 1930

By E. B. Nelson, B. W. Gandrud, B. M. Bird

"The Lewisburg No. 2 mine of the Sloss-Sheffield Steel & Iron Company is located in Jefferson County, Alabama, about 7 miles due north of Birmingham. At this point the coal from the Mary Lee seam when coked in by-product ovens yields an excellent quality of metallurgical coke suitable for use in the iron blast furnace; it is also an excellent steam coal. In mining, all three benches are worked. Coarse impurities are largely gobbed by the miners underground.In addition to giving the data obtained from screen-sizing and float-and-sink tests of a representative sample of the raw coal, this report presents the results of slotted-screen tests to show the proportions of flaky particles in selected sizes, and the results of tests to show how much coal is liberated from impurities by crushing the coarsest sizes. These data have been obtained in connection with an extensive study of coal-washing now being conducted by the U. S. Bureau of Mines and the University of Alabama, with U. cooperation of the different operators of Alabama. As the work progresses other reports will follow containing furtner data on the washability both of the Mary Lee seam and of other seams in Alabama and giving the results obtained in preparing these coals by various methods.Although a great amount of investigative work on the preparation of the Mary Lee scam was previously carried on by the various coal companies of the district, comparatively little of this information has been published. In governmental publications three references have been found. Forbes5 gives a number of sections with proximate and ultimate analyses of face samples taken in the mines. Gandrud and Britton'' show sections of this seam at Flat Creek and New Castle; they also give the specific gravity and ash contents of the partings of coal and impurities. In their paper Yancey and Fraser7 include washability studies and washing data from the Sayreton mine of the Republic Iron & Steel Co."

Jun 1, 1930

By W. P. Yant, R. R. Sayers, H. W. Shoaf, John Chornyak

"The contemplated use of dichloro-difluoro methane in domestic and commercial refrigerating appliances and in air-conditioning equipment for Public buildings and possibly homes, brings attention to the health hazards involved in a wide potential exposure of the public to vapors of another new product, and for the first time to vapors of an organic fluorine compound. The objective in the development of this new refrigerant, however, has been the mitigation of health and explosion hazards in automatic refrigeration, and accordingly these factors have been given primary attention. Early in the development, the Bureau of Mines was requested to make a laboratory study of the toxicity and potential hazard:"" and it was on the basis of the results of this work and the results of a preliminary investigation made in another laboratory5 that the compound has been selected for commercial use. Although the investigation conducted by the Bureau of Mines is still in progress, information has been obtained to indicate the order of the toxicity and the magnitude of the health hazards involved in the use of dichloro-difluoro methane as a refrigerant. The following is a summarized report of the work completed to date:Additionally work rich is in progress at the present time includes a determination of the lethal time-concentration curve for animals and a study of the response of persons within the range of safe concentrations.The writers desire to jive acknowledgment to T E. Midgley, Frigidaire Corporation, Layton, Ohio, for suggesting the investigation, for arranging for the cooperation of the Frigidaire Corporation, and for advice during the experimental work; to Robert A. Kehoe, The Eichberg Laboratory of Physiology, University of Cincinnati, Cincinnati, Ohio; and E. R. Hayhurst, college of Medicine, Ohio State University, for consultation and advice in planning the work; and to the following employees of the Bureau of Mines for assistance in performing the experimental work: L. M. Berger, chief scientific aid, S. J. Pearce, junior chemist, and Ethel B. Stead, technician."

May 1, 1930

By R. R. Sayers

The contemplated use of dichloro-difluorco methane in domestic and commercial refrigerating appliances and in air-conditioning equipment for public buildings and possibly homes, brims attention to the health hazards involved in a wide potential exposure of the public to vapors of another new product, and for the first time to vapors of an organic fluorino compound. The objective in the development of this new refrigerant, however, has been the mitigation of health and explosion hazards in automatic refrigeration, and accordingly these factors have been given primary attention. Early in the development, the Bureau of Mines as requested to make a laboratory study of the toxicity and potential hazard, and it was ca the oasis of the results is of this work and the results of a preliminary investigation made in another laboratory6 that the compound has been selected for commercial use. The investigation conducted by the Bureau of Mines is still in progress, enough information has been obtained to indicate the order of the toxicity and the magnitude of the health hazards involved in the use of dichloro-difluoro methane as a refrigerant. The following is a summarized report of the work completed to date:

Jan 1, 1930

By N. L. Kozlinsky, B. W. Gandrud

"The Marvel mines 1 and 3 of the Roden Coal Co. are located in the Cahaba field in Bibb County, Ala., nearly southwest from Birmingham, an airline distance of roughly 30 miles. The coal of the Clark seam at this point has some coking properties, but at present it is sold exclusively as a domestic and steaming coal.This paper, which is the second of a series on the washability of Alabama coals, like its predecessor dealing with the Mary Lee seam,5 contains screen-sizing and float-and-sink tests of a representative sample of the raw slack, and slotted-screen tests showing the proportions of flaky particles in certain selected sizes; inasmuch as this coal is not used for coke manufacture, no crushing tests have been made. These data have been obtained in connection with an exhaustive study of coal preparation in Alabama, now being conducted by the United States Bureau of Mines and the University of Alabama with the cooperation of the different coal operators. As the work progresses, other papers will follow containing further data on Alabama coals and giving results obtained in preparing these coals by various methods.The only published investigative work on the Clark seam is that of Forbes,6 who gives a number of sections of this seam in Marvel No. 3 mine with proximate and ultimate analyses of face samples taken in the mine and also some analyses of delivered coal.The available information on this coal indicated that the preparation problem was one of ash reduction. In order to substantiate this information a complete analysis of the 3/4 by 3/16 inch size, and sulphur determinations and ash-fusibility tests of the float-and-sink fractions have been made; these results are given in Tables 1 and 2. As these results also indicate that the preparation problem is one of ash reduction, the tests and discussion have been devoted to that subject."

Jun 1, 1930

By S. H. Ash

In the early nineties it was observed by several European investigators and by C. S. Rice4 that an explosion could be checked and would not propagate in the parts of a mine where shale or other inert dust was present in large amounts.5 After the disastrous Courrieres explosion in France that killed 1,100 men, coal-dust explosion tests were made in France in 1907 and in Great Britain in 1908 which resulted in the conclusion that if enough incombustible dust were properly spread throughout passageways charged with coal-dust, the propagation of an explosion by the coal-dust could be prevented. In 1908 the Federal government authorized the investigation of the causes of mine explosions and of possible methods of preventing them, with the result that during 1911 the United States Bureau of Mines, after making several tests, suggested that rock-dust be used in gassy or dusty bituminous coal mines. Since that time, experiments and investigations6 have proved conclusively that widespread explosions can be prevented in coal mines by efficient rook-dusting.

Jan 1, 1930

By J. E. Crawshaw

"The few previous observations of the effect of turbulence on limits of inflammability have been made on a small scale in turbulence produced either by a fan or by movement of the mixture.By a suitable amount of turbulence from a fan the lower limit of methane was 5 per cent as compared with 5 per cent observed for quiescent mixtures in the same vessel.3 With a streaming movement of the gas mixture within the range of speed from 35 to 65 centimeters per second (69 to 128 feet a minute) the lower limit was approximately 5 percent,4 For a quiescent mixture of ethane the lower limit was 3.10 per cent ethane, but with fan running at a moderate speed a 3 per cent mixture exploded.5The object of the tests herein reported was (1) to determine the lower limit of natural gas in a mixture of natural gas and air Which would be ignited and propagate violently when the turbulence was produced by explosives fired from a cannon into the mixture; (2) to observe the behavior when the mixture contained less than this low limit; and (3) to determine how turbulence produced by a fan affects thin limit.Four series of tests were run, three of which were to determine the effect of different sources of ignition: Tests with (1) an electric igniter; (2) 3F black blasting powder stemmed with 2 pounds of dry fire clay stemming used to ignite the mixture, and (3) 40 per cent straight nitroglycerin dynamite unstemmed. The fourth was made to study the effect of turbulence produced by a two-speed electric fan, using an electric igniter as the source of ignition.In both series of tests with explosives, charges of 50 and 200 were used to determine the effect of increased quantity of explosives on the lower limit of natural gas."

Jul 1, 1930

By H. M. Lawrence

"Florida, the State that supplied 82 per cent of the phosphate rock sold in the United. States in 19284, has two producing areas - the hard-rock and the land pebble districts. Production of the hard-rock field, decreasing importance in recent years, is now confined to mines near Dunnellon, in Marion and. Citrus Counties. The land-pebble district, with a production of almost 80 per coat of the nation's requirements, is located, in Polk and Hillsborough Counties. In the land-pebble area the phosphate deposits - probably Pliocene in age, derived by marine action from underlying, older, phosphate-bearing formations - consist of beds of phosphate matrix, covered by practically barren sands and clays. The overburden, ranging in thickness up to 45 feet, is removed by hydraulic methods or by drag-line excavators. The matrix, ordinarily less than 25 feet in thickness, is mined by hydraulicking and is pumped to adjacent washing plants for beneficiation. The dried product of the washing plants is the Florida pebble rock that is sold in foreign as well as domestic markets.The beneficiation of phosphate ores in the land-pebble district of Florida has been largely limited in the past to the recovery of the coarser pebbles. By washing and screening the crude matrix a separation is effected at about 20 mesh (0.033 inch). The coarser material is the phosphate-rock product of the plant and the finer material is discarded. The amenability of the washer- rejects to treatment by other processes is being investigated. Of methods that may have some application to the treatment of the low-grade phosphatic sands that comprise the greater portion of the washer-rejects, gravity concentration has received some study.Laboratory experiments to determine the amenability of phosphate sands to gravity methods of concentration were first performed in October, 1927. Later, in the winter of 1928-1929, a further series of teats was made,. In these later tests phosphatic sands were concentrated by hydraulic classification, and. also by hydraulic classification followed by tabling. In these experiments concentrates with an analysis above the minimum grade of commercial phosphate rock (66 per cent bone phosphate of lime - B.P.L.) obtained. The recovery of the phosphate varied but was promising enough to warrant further study. A more comprehensive investigation was therefore outlined. This paper presents the results obtained from an investigation, of classification and tabling of phosphatic sands recently completed by the United States Bureau of Mines Su cooperation with certain Florida phosphate companies, the Missouri School of Mines and Metallurgy, and the University of Alabama."

Jul 1, 1930

By W. W. Adams

"The fifth annual National Safety Competition conducted by the United States Bureau of Mines to determine the best safety records at mines and quarries during the calendar year 1929 has been concluded, and the general results of the contest are presented herewith. To the winner in each of the five groups into which the contestants were divided there has been awarded the bronze trophy 'Sentinels of. Safety,' donated by the Explosives Engineer magazine. The trophy for bituminous coal mines was won by a mine in Alabama; that for metal mines by an iron-ore mine in Michigan; that for nonmetallic mineral mines by a salt mine in New York; that for quarries and open-cut mines went to a limestone quarry in Michigan;. the trophy provided for anthracite mines was, of course, won by a mine in Pennsylvania, as all of the anthracite mines participating in the contest are situated in that State.Winners of the trophies were selected by a committee of sward in accordance with rules governing the contest and on the basis of accident records furnished by the various companies to the Bureau of Mines. These records were summarized by the bureau and the results submitted to the committee. Members of the committee are W. H. Cameron, managing director of the National Safety Council. William Green, president of the American Federation of Labor; James F. Callbreath, secretary of the American Mining Congress; T. T. Read, Vinton professor of mining of Columbia University and editor of 'Mining and Metallurgy'; C. B. Huntress, executive secretary of the National Coal Association; A. J., Curtis, assistant to the general manager of the Portland Cement Association; A. T. Goldbeck, director of the engineering bureau of the National Crushed Stone Association.Thirty-four States were represented in the l29 contest. Among the plants which participated were 68 bituminous coal mines, 29 anthracite mines, 54 metal mines, 19 nonmetallic mineral mines, all of the foregoing being underground mines, and 141 quarries or open-cut mines. A total of 106,533,006 man-hours of work was reported by all of the companies. Accidents during the year numbered 7,008 and represented a period of disability equal to 986,306 man-days. Hence the accident-severity rate for all plants combined represented 9.3 man-days of disability for each thousand man-hours of exposure to hazard. Similarly, the combined accident-frequency rate for all plants showed that 66.3 accidents occurred for every million man-hours of exposure to hazard. Both of these rates indicated an improvement over the combined rates for all plants in the previous year's contest. The reduction in the accident-severity rate centered chiefly in the metal mine group, though all except the quarry and open-cut mine group shared in the reduction; the improvement in the accident-frequency rate was in all croups except anthracite and metal, the rate for the former having increased while that of the latter remained unchanged."

May 1, 1930

By Fieldner. A. C.

"In preparing this paper, an attempt was made to obtain results of plant-scale carbonization tests on washed and unwashed coal tram to same mine. A letter. in which the following questions were asked, was sent to some 50 coke-oven superintendents and others who might be interested:“What is the influence of washing coal on:(1) The chemical and physical properties of coke, as for example, the size, the amount of breeze, the fracture, strength, cell-structure, etc.(2) The quantity and quality of gas and by-products.(3) The capacity of the ovens.(4) The composition of the coal..""Your general opinion, as well as any specific data or results of testa, on this important subject will be greatly appreciated.""Of the 45 replies received, 24 stated that they had never used washed coal; 11 had used washed coal but had no comparative data on similar coals washed and unwashed; 7 answered some of the questions based on their general experience; and 3 gave some test data on Pittsburgh bed coal from western Pennsylvania. In none of the three tests did the washed coal come from the same mine as the unwashed. The washed coals in the three tests were from the same washery - one of modern construction in which the operations are under careful technical control in order to give a uniform product containing a minimum of surface moisture. The unwashed coals which were previously used in these plants were from different nearby mines in the same coal bed, and were supplied by the same company. Obviously, no sweeping or finale conclusions can be drawn from these few tests on coal from a single washery. Therefore, the writer vas obliged to consult the literature, coal-carbonization and coal-washing engineers, and other authorities to supplement the fragmentary information gleaned from the questionnaires in order to present a picture of chat gas engineers may expect from the use of washed coal in a carbonizing plant."

May 1, 1930

By A. C. Fieldner

In preparing this paper, an attempt was made to obtain results of plant-scale carbonization tests on washed and unwashed coal from the same mine. A letter. in which the following questions were asked was sent to some 50 coke-oven superintendents and others who might be interested; "What is the influence of washing coal on: (1) The chemical and physical properties of coke, as for example, the size the amount of breeze, the fracture, strength, cell-structure, etc. (2) The quantity and quality of gas and by-products. (3) The capacity of the ovens. (4) The composition of the coal. "Your general opinion, as well as any specific data or results of tests, on this important subject will be arc greatly appreciated."

Jan 1, 1930

By C. E. Reistle

The generation of steam for drilling operations has visually been accomplished in the past by the use of portable locomotive-type boilers without the aid of auxiliary equipment or advanced for economizing fuel or water consumption. This has been due primarily to the fact that the steam-generating plant of a drilling well must necessarily be of temporary and portable design, and the amount of steam generated has not been considered sufficient to justify the additional expense necessary to obtain more economical operation. However, with the constantly increasing depth to which oil wells are being drilled and the use of larger and heavier equipment, the steam requirements have reached a point where equipment and methods that were previously considered as applicable only to permanent plant installation can be and are being used to a decided advantage by the more progressive operators. As an example of the present-day requirements and the rapidly increasing steam consumption in rotary drilling, a comparison between the requirements during the intensive drilling period in the Seminole end Oklahoma City fields of Oklahoma is of interest. In the Seminole field. There the approximate depth of rotary drilling was 3,500 feet, the general practice was to use three 85 to 90 or 100 horsepower A. P. I. code boilers operating at a working pressure of 175 to 200 pounds per square inch. The fuel end water consumption was approximately 450 to 500 thousand cubic feet of gas and 700 to 750 barrels of water per day. In the Oklahoma City field, where the average drilling depth is approximately 6,500 feet, the general practice is to use either four 100 or 116 horsepower or three 123 horsepower A.P.I. code boilers, operating at a pressure of 250 pounds per square inch. The fuel and water consumption varies from 550 to 750 thousand cubic feet of gas and from 1,000 to 1,500 barrels of water per day.

Jan 1, 1930

By H. M. Lawrence

"The land-pebble district, the larger of the two producing areas of Florida, is situated in Polk County and in the eastern part of Hillsborough County. About 80 per cent at the phosphate rock produced in the United States in recent years has been mined from this area. The phosphate ores, locally termed matrix. are beds of sands and clays containing the phosphate pebbles, considered to be Pliocene in age, derived by marine action from underlying Miocene phosphatic marls, and are covered by practically barren sands and clays that have been deposited more recently. Open-pit mining is practiced; hydraulic mining, which has been intensively developed in this district, is used exclusively for mining the matrix and, by some companies for removing the overburden, although drag-line excavators have become established and are proving economical for stripping operations. From the pits the matrix is pumped to adjacent washing plants for beneficiation. The product of the washers. after drying, enters the world markets as Florida pebble phosphate.In this district recovery of the phosphate pebbles by the washing plants has not been particularly effective in the past. The screening, designed to effect a seperation at about 20 mesh (0.033 inches), has not been well controlled. Washer rejects discarded to the waste dumps have contained appreciable amounts of material analyzing above the minimum commercial grade - 66 per cent B.P.L. (bone phosphate of lime). Such losses of commercial fractions should be considered avoidable, and have been discussed at length in a previous paper.3"

Jul 1, 1930

By C. W. Davis

This is the first of a series of papers being; prepared as the work progresses in a study of the hydrometallurgy of manganese. The investigation is being made in an endeavor to make possible the utilization of lour-grade domestic manganese ores. The value of a hydrometallurgical process for manganese depends on the present and future uses for manganese products.

Jan 1, 1930

By A. J. Kraemer

[During the past several years a great deal of discussion has centered around the question of the permissible limit of sulphur content in fuels for automotive and aviation motors. Under certain conditions of operation, sulphur in motor fuels causes the formation of corrosive substances which attach bearings, wrist pins, and other parts of engines. On the other hand, in making gas¬oline from certain stocks, the gasoline fraction normally contains a relatively large proportion of sulphur compounds. By the generally used processes of reducing the sulphur content, a significant part of the gasoline fraction is lost as motor fuel, and added expenses are entailed for chemicals, labor, and other process costs. This condition has been an economic burden to some refiners of high-sulphur crudes. In some instances the treating losses have been rather severe and the treating costs relatively high, but the data presented in this paper indicate that the reduction of sulphur content of motor fuel is a problem to a relatively small number of refiners and of little or no concern to the remainder; in fact, more then 90 per cent of the 153 samples analyzed passed the Federal specification requirement, which limits the sulphur content to 0.10 -nor cent. 3 This report is based upon the results of an examination for sulphur content, Doctor test, copper strip corrosion, and color of the samples collected during January, 1930, for the twenty-first semiannual gasoline survey of the Bureau of Mines. The results of the gravity and distillation tests of the survey were published as Report of Investigations 2995. The numbering of the samples given in this report is the same' as in Report of Investigations 2995; for example, No. 25 of this report is the same sample as No. 25 of Report of Investigations 2995.]

Jan 1, 1930

By A. J. Kraemer

"During the past several years a great deal of discussion has centered around the question of the permissible limit of sulphur content in fuels for automotive and aviation motors. Under certain conditions of operation, sulphur in motor fuels causes the formation of corrosive substances which attack bearings, wrist pins, and other parts of engines. On the other hand, in making gasoline from certain stocks, the gasoline fraction normally contains a relatively large proportion of sulphur compounds. By the generally used processes of reducing the sulphur content, a significant part of the gasoline fraction is lost as motor fuel, and added expenses are entailed for chemicals, labor, and other process costs. This condition has been an economic burden to some refiners of high-sulphur crudes. In some instances the treating losses have been rather severe and the treating costs relatively high, but the data presented in this paper indicate that the reduction of sulphur content of motor fuel is a problem to a relatively small number of refiners and of little or no concern to the remainder; in fact, more than 90 per cent of the 153 samples analyzed passed the Federal specification requirement, Which limits the sulphur content to 0.10 per cent. 3This report is based upon the results of an examination for sulphur content, Doctor test, copper strip corrosion, and color of the samples collected during January, 1930, for the twenty-first semiannual gasoline survey of the Bureau of Mines. The results of the gravity ad distillation tests of the survey were published as Report of Investigations 2995. The numbering of the samples given in this report is the same as in Report of Investigations 2995; for example, No. 25 of this report is the same sample as No. 25 of Report of Investigations 2995."

Jun 1, 1930

By L. B. Berger

In this investigation, the ampoule type of carbon-monoxide (CO) detector which is manufactured under license of U. S. Patent 1,644,014 (October 4, 1927) was tested for sensitivity and reliability. This detector was devised primarily for examining the air of manholes and sewers for possible dangerous contamination with CO before workmen enter these places, but due to the simplicity of the device it may have a more general usage for examination of atmospheres which are known or suspected, to be contaminated with CO. Some of the suggested uses are the examination of the air in garages, tunnels, mines, around blast furnaces, gas plants, and in the home.

Jan 1, 1930