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The operation of quarries for the production of crushed stone and aggregates, depends heavily on rock blasting efficiency, which usually represents a major share of total production costs. After investigating the causes of this situation, a series of technical aspects have been detected, and they are described for the purpose of contributing to the minimization of costs, which also reduces the effects of blasting on the environment. Utilization of empirical design methods, of inadequate explosive types, and of erroneous drilling pauems with respect to rock properties, are the main factors to be corrected, as a consequence of poor engineering criteria, with scarce use of computational methods and field instrumentation. Several concepts of blasting optimization are pointed out, and their application to industrial operations in a Portuguese limestone quarry indicated clear trends for the reduction of production costs, as well as some of the deleterious consequences of blasting on the environment.

Jan 1, 1990

By H. K. Lin

Residual cyanide in cyanidation tailings can be detoxified by its oxidation to cyanate, as in the Inco and Degussa processes. However, cyanate, the product of detoxification and other oxidation processes, may be reduced to cyanide in reducing environments, e.g., deepwater discharge of cyanidation tailings. This study shows that the reduc-tion of cyanate to cyanide occurs and that the reduction rate increases with decreasing solution redox potential. Solutions with lower pH favor the reduction rate. No significant difference was observed between the results of tests prepared with distilled water and seawater, and the presence of cyanidation solid tailings does not show an effect on the reduction. Because cyanate can be reduced to toxic cyanide, causing environmental concerns, the deepwater discharges of cyanidation tailings must be handled carefully.

Jan 1, 2008

By B. Andresen, S. T. Johansen, H. Tveit, S. Grådahl, B. Ravary

The Norwegian ferroalloy industry has high ambitions regarding environmental standards. Basic research work has been performed to improve the fundamental understanding of ferroalloy processes and the environ-mental aspects. This paper will present work dealing with the understanding of formation and control of NOx, PAH and dioxins. During this work various techniques and methods have been applied, such as comprehensive industrial measurements, laboratory experiments, model development and application of Computational Fluid Dynamics (CFD). The main goal has been to reduce the environmental impact of ferroalloy plants, by means of improving the combustion processes done by introducing new charging routines and optimized furnace operations, instead of installing expensive gas treatment systems. The Norwegian obligations in accordance with the Gothenburg protocol are to reduce the NOx emissions by 30%, compared with the 1990 level within 2010. Measures developed in this work have resulted in 40-60%reduction in NOx emission, and major reductions in PAH and dioxins for ferrosilicon and silicon metal plants. This has been achieved by introducing semi continuous charging and improved furnace operations. Semi continuous charging and optimized furnace operations are shown to reduce the blowing activity (i.e. emission of large quantity of SiO over the charge by direct channelling from the crater zone). It also reduces variation in off-gas temperature and dust production. To understand the processes and to achieve our results we have used online equipment, with fast sample rates and response times, to measure the off-gas compositions and temperatures. Most of the measuring techniques used are based upon optical principles making use of the absorption- and emission spectrum of the gases. In addition a new prototype instrument is developed for continuous measurement of off-gas characteristics, total dust amount and off-gas temperature. The presented work is a result of a long term co-operation research and development teamwork, between the industry and the research community, and has improved both the process and reduced the emissions. The work has introduced new process design and operation standards, and has resulted in ferroalloy production with better environmental standards.

Jan 1, 2007

By Yasushi Sawada

An experimental investigation was carried out to study the rates of reduction of iron oxides dissolved in liquid Ca0-SO2-A203 slags by Fe-C droplets at temperatures ranging from 1325 OC to 1550 OC. The %FeO in the slag was varied from 5.5 to 18. Flash X-ray images were employed to observe the behavior of Fe-C droplets in the slags during the reactions and for determining the slag-gas-metal interfacial area. Effect of P205 in the slag and sulfur in the droplet was also investigated. The reduction rates were determined by measuring the volume of CO evolved as a function of time and the estimated slag-gas- metal interfacial area. The reduction rates have increased with increasing %FeO in the slag and the slag temperature. The experimentally established relationship between the reduction rates and FeO (wt%) in slag is given by

Jan 1, 1992

By G. G. Krishna Murthy

Interactions of wustite and hematite pellets with Fe-C melts were investigated experimentally by examining the effect of pellet size and bath temperature on the reduction rates of the pellets. Experiments were carried out in the temperature range 1473-1923 K. A flash X-ray equipment was used to obtain images of the melt surface during its reaction with an oxide pellet. The reduction rates were calculated using experimentally estimated time for complete reaction of a pellet, tR. The value of tR was determined employing gas mass flow rate, or pressure rise in the sealed furnace, versus time traces. The value of tR was the same for both wustite and hematite pellets of equal weight at or above 1723 K and it decreased with increasing melt temperature. But the reduction rate was substantially lower at temperatures below 1651 K, the melting point of wustite. The rates were defined as the rate of moles of oxygen removed from the pellet per unit area of bath free surface and it was found that the bath surface area affects the reduction rates. It was established that the overall reaction followed nth-order rate kinetics with the values of n falling between 0.3 and 0.4 for temperatures above the melting point of wustite. The apparent activation energy determined using the apparent rate constants obtained from the experimental data was 76.2 + 27.7 kJ/mol-O.

Jan 1, 1992

In the flotation of a copper ore, entrainment of fine silicate and iron sulfide gangue minerals resulted in poor copper concentrate grade. In the cleaning stage, rejection of these gangue minerals was particularly difficult due to severe mechanical entrainment when the rougher concentrate was ground to 10 µm. To reduce gangue entrainment, polymeric depressants were tested. The rationale being that with the use of such polymeric depressants that also possess flocculation power, not only minerals-to-be-depressed can be made hydrophilic, but their particle size can also be enlarged. In this manner both the "genuine" flotation and the mechanical entrainment can be reduced. An effective polymer to reduce entrainment of silicate gangue mineral in sulfide flotation was identified from bench flotation tests conducted on single minerals. It was then applied to the flotation of a copper-gold ore confirming the beneficial role of the polymeric depressant in the reduction of fine gangue entrainment.

Jan 1, 2007

By S. Y. Ezz, K. El•Guindi

A vertical tube, 8 m long and 2.5 cm in diameter, electrically heated to 650°C throughout the majority of its height, was used to study the-effect of ore feed rate and hydrogen flow rate on the reduction of fine iron ore particles. A correlation could be obtained between the combined effect of the amount of reducing gas and reduction time and the per-cent reduction. The results suggest that a method based on the reduction of fine iron ores while falling through up-streaming hydrogen cannot be recommended for industrial application.

Jan 1, 1969

By Maria I. De Rosa

Analysis of mining equipment fires from 1990 through 1999 reveals that there were 340 large mining equipment fires, resulting in 72 injuries and five fatalities. Many of the fires resulted in the loss of equipment and all posed potential or real risks to the operator. In 97 cases, the fires raged out of control due to engine shut­off failure, even upon activation of the machine fire suppression system, due to the spraying of pressurized hydraulic flu­id and fuel onto hot engine surfaces. In other cases, even after engine shutoff, the fires re-ignited, fueled by the contin­ued flow of flammable fluids remaining in the lines onto the hot engine surfaces. In many of the fires, flammable vapors evolved and penetrated the cab, violently igniting, forcing the operator to exit under very hazardous conditions. The use of emergency evacuation lines in the fuel and hydraulic fluid systems, and methods to reduce or prevent the spraying of pressurized fluids onto hot engine surfaces would greatly improve the chances of successfully suppressing large mining equipment fires. In addition, the use of systems for preventing the ignition of flammable vapors inside the cab, and detecting and suppressing fires originat­ing in the cab, would greatly enhance operator safety. The National Institute for Occupation Safety and Health (NIOSH) recently conducted experiments on meth­ods to reduce the fire hazards associated with large mining equipment. These experiments evaluated the use of cab inerting systems to prevent the ignition of flammable vapors inside the cab and sup­press fires originating in the cab, while maintaining a breathable atmosphere for the operator to bring the equipment to a stop and safely exit the cab.

Jan 1, 2008

By Martin Froehling, Curtis Mohns, Rahim Rajwani, Michael Fullam

"The Kemess mining and milling complex is operated by Northgate Minerals Corporation and is located in the mountains of north-central British Columbia, 430 kilometers northwest of Prince George. The complex consists of the Kemess South open pit mine and a 52,000 tonnes per day mill. Hypogene, supergene and leach cap ores are processed using conventional crushing, grinding, and flotation techniques to produce gold-copper concentrates with minor by-product silver value.The rougher flotation concentrate is re-ground in closed circuit before being cleaned to final concentrate grade. Historically, gold losses in the cleaner tailings were primarily associated with pyrite, with only minor amounts of free gold. More recently, with the processing of high pyrite ores, the major losses were found to be free gold less than 10 microns in size. The fine grind required for the high pyrite ores resulted in over-grinding of the free gold particles in the regrind circuit, contributing to poor flotation characteristics. It was thought that if this free gold could be recovered by gravity at coarser size in the regrind circulating load, the free gold losses in the cleaner tailings could be reduced.Preliminary test work carried out by Knelson Gravity Solutions indicated the potential for free gold recovery in the regrind circuit. A Knelson XD-30 Concentrator was installed with variable speed capability, and a series of optimization tests were carried out. In addition, cleaner tailings were characterized with gravity operating and with gravity not operating to determine the overall gold recovery benefit. The single Knelson XD-30 installation recovers ~10% of the total gold in the regrind circuit and increases overall recovery by 3% when high pyrite ores are processed."

Jan 1, 2007

By Fernanda Ferrante, Wagner Reis Modesto Ribeiro, Eduardo Pena Carvalho

CSN Mineração S.A. is the second largest exporter of iron ore in Brazil and is among the five most competitive in the market. Casa de Pedra currently has an approximate production capacity of 30 million tons per year. The fleets of small trucks 6x4 and 8x4 models are responsible for the ore movement, traveling an average distance of 10 km between origin and destination. 116 trucks of this size are used in CSN Mineração for the handling of products. Every month this fleet consumes an average of 550,000 liters of fuel. The objective of the work is to do a fuel consumption analysis by truck through the embedded telemetry system. The reports generated through this system provide the specific consumption of each equipment and also the specific consumption of each Driver. As reports are generated it is possible to assess which equipment had a higher specific consumption and, in this case, the respective trucks with greater consumption are directed to the Maintenance team for analysis and action in the event that a problem is identified in the equipment. At the same time, the analysis of the drivers who had the highest specific consumption and conducted a practical and theoretical training, addressing the techniques for a safer and therefore economical direction, is carried out. In 2019, the economy of fuel consumption type S10 was 204 thousand liters, which represents 9% of all consumption foreseen for the period.

Oct 3, 2019

By Caryn Wendt, Donna Post Guillen, Armando McDonald, Erik R. Coats, Chaston Ellis, Kevin Feris

Dairy operations constitute ~2.5% of annual U.S. greenhouse gas (GHG) emissions, making dairies one of the largest sources of industrial GHG emissions. We are developing a novel, integrated system to achieve a net reduction in dairy GHGs while producing value-added materials and products. This integrated manure-to-commodities system converts dairy manure to bioenergy, sequesters carbon by converting volatile fatty acid-rich fermenter supernatant to bioplastics, and utilizes anaerobic digester (AD) and polyhydroxyalkanoate (PHA) reactor effluents to produce algae that can be harvested and internally recycled to enhance PHA production and sequester carbon. A decision-making tool is being developed for the integrated system that quantifies net GHG reduction, carbon sequestration, nutrient management and economics.

Jan 1, 2016

By Guy Deschênes

Thiourea solutions can be used as leach liquors to treat gold ores or slimes. It is also efficient to elute resins or strip solvents that were loaded in cyanides solutions. The hydrogen pressure reduction is a practical step to recover gold and silver from leach solutions, and strips and eluates without any destruction of thiourea. It is a critical point because these processes have to consider the recycling of the liquors to be irore economical. The effect of temperature, pressure, acidity, compotation of the solution and the nature of catalysts on pressure reduction by hydrogen were investigated. An electranetallurgical study was? carried out to investigate the mechanism. The composition of the products was studied by different analytical methods. The process shows a good selectivity to precipitate gold and silver in a thiourea solution containing iron and copper. Gold and silver concentrations can be decreased to 0.2 ppm and 0.1 ppm at respectively 70 KPa H2 and 28°C. No decomposition of thiourea was evident during the tests. Metals such as nickel powder or platinum activate the reaction and improve the reduction.

Jan 1, 1989

By Thom Seal, S. J. Jung

This paper will combine three SME annual meeting presentations on reducing gold inventory in cyanide heap leaching. Information on Part I – Side slope leaching (SME 2003), Part II – Determining the dry zones using geophysical resistivity (SME 2004), and Part III - Presents a new technology “Hydro-Jex”, to introduce the required lixiviants to the un-leach or under-leach zones in heaps (SME 2005). This paper will describe how Newmont Mining Corporation continues to improve the economics of the heap leaching process for precious metals recovery.

Jan 1, 2005

By D. J. Zhao

The reduction of ilmenite pellets was investigated at 950°C and 1000°C under a CO-N2 gas mixture with 10 L/min gas flow rate. All the reducing reactions were conducted in a furnace with a thermogravimetric analysis system. The reduction rate is higher at 1000°C than that at 950°C. At the early stage of the reactions, with the CO concentration increasing in the gas mixture, the reduction rate increased at 1000°C. In addition, at the early stage of the reactions, a rapid temperature increment and a rapid conversion of oxygen were observed on the curves of temperature versus time and conversion of oxygen versus time under different experimental conditions. The solid reaction products obtained in these experiments were analyzed by Scanning Electron Microscopy (SEM) and Energy Dispersive Spectrometers (EDS). Metallic Fe with small amount of Ti dissolved in it and oxides of Ti were found in the solid reaction products, but the formation of any nitride phases was not found under the prevailing conditions.

Jan 1, 2014

Reduction of Iron Content from Silica by Gravitational Processes In this research work, it was attempted to reduce the iron contents (Fe2O3) in silica sample which was provided from Shenin silica mine using gravitational processes including jig machine, multi gravity separator (MGS), shaking table and spiral. The silica sample contains 93.75 per cent SiO2, 0.44 per cent Fe2O3, 2.78 per cent Al2O3, and 0.08 per cent TiO2 and the Fe2O3 has to be reduced to about 0.1 per cent or less than 0.02 per cent. Mineralogical studies and XRD analysis indicated the presence of haematite, pyrite and goethite as the major iron impurity phases. Mineralogical studies of polished and thin sections yielded that the degree of freedom of silica is more than 80 per cent in the range of -300 +212 mm. After elimination of fine particles, at first nine tests were carried out on crusher product (in two size fractions), wet rod mil product and scrubber product by means of Jig Machine. The best results were obtained with about 0.15 per cent Fe2O3 on rod mill and scrubber product which was not desirable. Thereafter 7 tests were carried out using shaking table; the best results were obtained with about 0.14 per cent Fe2O3 on rod mill and scrubber product which was not desirable. MGS showed the worst result in order to iron removal from silica which was not desirable. Finally 9 testes were carried out using spiral whish is the best gravitational separator for elimination of iron impurities from silica. The best result of spiral tests were achieved on scrubber product. In this test concentrate weight percent and its Fe2O3 grade were 82.32 per cent and 0.085 per cent respectively. Finally a test was carried out using 2 stages of spiral in order to develop flow sheet. In this test concentrate weight percent and its Fe2O3 grade were 78.8 per cent and 0.1 per cent respectively. This product can be used to produce float (clear flat) glass.

Sep 13, 2010

By George Kazonich

The high costs and environmental problems associated with making iron and steel in the United States is driving the development of new technologies to replace the blast furnace. A prototype reactor incorporating rocket technology was designed and built. This rapid rate reactor was operated successfully and consistently made iron metal. Minus 325-mesh magnetite particles could be reduced to iron metal in less than 50 ms in a high temperature flow through reactor. Iron product was recovered inside the reactor and in a downstream cyclonic separator. The results of typical operation and how parametric changes affected the reduction of iron ore concentrates are discussed.

Jan 1, 1993

By U. Kammer

The reduction of the lead content in the separator fraction produced during the mechanical processing of spent lead-acid batteries is an important environmental and economical issues. The reduction of lead down to less than 1 percent is very difficult using hydroseparators that are common in battery recycling facilities. Very promising results were achieved performing experiments on a test rig using a new technology in battery treatment: a discharge-type jigging unit. The materials is fed onto the jigging bed and transported through the machine. Due to the intensive movement of the feed, an additional washing effect is also obtained in addition to separation of the lead and plastic fractions. The knowledge gained from this development work at UVR-FIA GmbH in Freiberg, Germany, led to a patent application. This paper focuses on the results of the development work and the start-up and one year's operation of the industrial-scale application at Harz-Metall GmbH in Goslar, Gennany.

Jan 1, 2000

By H. B. Menardi

THE history, geology, ore deposits and current mining operations of the Huitzuco district have been described by C. W. Vaupell1 and the current mill operations by David Segura.2 This paper completes the story of Huitzuco with a description of the reduction of the flotation concentrates. The predominant ore mineral in the Huitzuco deposit is livingstonite, a rare, mercury-antimony sulphide (HgS.2Sb2S3). Other associated minerals include cinnabar, stibnite and elemental sulphur. The gangue is largely limestone and gypsum. Former operators mined a selected grade of ore, from which the mercury was recovered by an expensive, inefficient operation. A consid-erable tonnage of rejects and fills, carrying mercury and antimony, was left in the mine. In order to recover both mercury and antimony from these fills and also from newly developed ore, a combination method has been developed, by means of which the livingstonite is concentrated by flotation and the flotation concentrates subsequently reduced to metallic mercury and antimony. An essential part of the flotation treatment, as developed by Segura, is the use of copper sulphate as an activating agent. A typical analysis of concentrates now being produced at the property is as follows: Hg, 7.73 per cent; Sb, 26.40; Fe, 1.20; S, 29.68; CaO, 11.50; MgO, 7.25; Si02, 1.63; A1203, 0.65.

Jan 1, 1939

By A. K. Bhattacharya

Cylindrical bridge piers are widely used and equations exist that can predict the maximum depth of local scour around such piers. Scour around piers is an undesirable phenomenon, as it requires the foundation to be placed to a greater depth resulting in increased cost, making it worthwhile to investigate scour-reducing measures. A number of scour-reducing measures have been tried out for cylindrical bridge piers including placing a concrete collar around the pier, having a delta-wing projecting upstream in front of the pier, placing riprap around the pier, using a group of piers instead of a single pier, having a slot in the pier aligned in the longitudinal direction. The objective of this study is to investigate the effect of upstream protective piles on reduction of maximum local scour depth around a cylindrical bridge pier. The upstream piles are placed at different radial distances in front of the pier and the scour depths are observed. The proposed equation of Dey (1997) for determining the maximum depth of scour around a cylindrical bridge pier is used. The reduction of local scour around the pier is compared with local scour around an unprotected pier.

Jan 1, 2009

By A. Warczok, T. A. Utigard

"Slags from smelting of copper concentrates contains from 1 to 15% of copper. Copper is present in the form of copper or copper matte inclusions of size from 2 to 1000 micro, and as dissolved cuprous oxide. Removal of the copper requires the slag reduction, primarily reduction of magnetite and co-reduction of cuprous oxide. Thus, the kinetics of the slag reduction play an important role in copper recovery. Instantaneously, at the contact of carbon and a slag the gaseous film is formed. The magnetite and cuprous oxide reduction is going through a gaseous film, separating the slag and carbon of a coke or electrodes. The thickness of a gaseous film grows to a critical value and gas bubbles, containing CO and CO2, are created and rise up in the slag. Results of measurements of kinetic of the slag reduction with graphite showed high value of activation energy, close to the value of activation energy of Boudouard reaction. Strong temperature dependence of the reaction rate points out the thermal instability of the reacting system. It was found that the slowest process in the reduction stages determines the loop of CO and CO2 transfer and magnetite diffusion to the slag/gas film boundary. Strongly endothermic Boudouard reaction seems to cause thermal instability on the reaction surface. So, heat transfer to the reaction surface is very important. Due to low thermal conductivity of a slag the convection dominates in the heat transfer. So, any slag stirring accelerates the rate of reduction and coalescence of metallic copper or copper matte inclusions."

Jan 1, 2015