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By T. C. Murphy, W. Taciuk

In 1966, the Iron Ore Company of Canada commissioned a wet magnetic scavanging plant for the recovery of fine magnetite values p.resent in spiral tailings discharged from a spiral gravity separation process. The plant includes dewatering, grinding, classification, thickening, mini-wedge screening, and primary, secondary and tertiary wet magnetic separation stages. The source of feed varies in quantity and quality, so the original design included variable operational procedures to deal with these conditions.

Jan 1, 1972

By S. N. McIntosh

Column bioleaching was evaluated by the U.S. Bureau of Mines as a means of recovering manganese from a low-grade ore from the Three Kids deposit in Southern Nevada. Manganese was solubilized from the ore using indigenous heterotrophic microorganisms. Diluted molasses medium was provided as nutrient for the microorganisms. The medium was recirculated through the ore bed until the sugars were spent. Two methods were evaluated to recover manganese from the sugar depleted bioleaching solution: (1) adsorption with a weak cation exchange resin followed by stripping and precipitation techniques, and (2) direct precipitation of the manganese using ammonium carbonate. Both methods removed up to 95 pct of the solubilized manganese from the medium as a carbonate salt. After manganese removal, the medium was replenished with fresh molasses and recycled back through the column. More manganese was effectively leached. This process of manganese solubilization and recovery followed by replenishment and recycling of the medium was repeated until 98 pct manganese was extracted from the ore.

Jan 1, 1993

By Ting Liu, Qian Li, Peng Deng

The wastewater containing Hg2+ and Pb2+ does great harm to the environment and human bodies. Traditional wastewater treatment cannot fundamentally put a stop to heavy metals pollution for producing secondary pollution. In this paper, Hg2+ and Pb2+ in wastewater were removed and recovered by sulfide precipitation- flotation. Sodium sulfide was used as precipitant and butyl ammonium aerofloat was used as collector. Results indicated that Hg2+ and Pb2+ could be reduce to less than 0.03mg/L and 0.16mg/L respectively by both coprecipitation- floatation and fractional precipitation- floatation. In these two methods, fractional precipitation flotation could not only remove Hg2+ and Pb2+ from wastewater, but also could recover mercury and lead effectively. The infrared spectrograms showed that the adsorption between butyl ammonium aerofloat and mercury precipitate or lead precipitate is chemisorption.

Jan 1, 2015

By H. Braun, T. Kind, K. Gloe, D. B. Dreisinger, H. Stephan, O. Heitzsch, G. A. Kordosky

Municipal garbage incineration processes with coupled wet flue gas cleaning systems generate effluents containing toxic heavy metals such as mercury, zinc, cadmium and copper. The separation of these metal ions from the obtained scrubbing solutions is possible using liquid-liquid extraction. Extraction studies has been performed both with commercial extractants Aliquat 336, di(2-ethylhexyl) phosphoric acid and novel chelating agents as acyl thiourea and lipophilic oxathiaaza alkanes. Advantages and disadvantages of the investigated extraction systems are discussed. The paper reports on the basic research as well as on the testing in a laboratory scale.

Jan 1, 1993

By Raj P. Singh

Applications of cementation in the recovery of metal ions from process solutions have been known for a long time. Cementation reactions involve electrochemical precipitation of a noble metal from solutions of its salts on a more electropositive metal which, in tum, progressively dissolves. For example, addition of zinc metal powder in a solution containing zinc and cobalt ions would allow for the precipitation (separation) of cobalt according to the following chemical reaction. This paper pertains to the recovery of cobalt from cobalt process solutions via a cementation reaction on aluminum shavings (metal scraps from cans etc). Specifically, we report on the characterization of cobalt process solutions, a by-product obtained from cobalt chemicals, and the kinetics of cobalt, nickel and manganese cementation from process solutions on aluminum shavings.

Jan 1, 2000

By Paramguru R. K, Jena P. K

Increasing demand for copper, lead and zinc with continuous depletion of good grade ore reserves, warrants the need for utilization of lean and complex ores of these metals. There is worldwide effort to develop suitable processes for these purposes. The present paper deals with the chloride leaching of complex base metal sulphide concentrates of two Indian deposits. A two stage leaching process is suggested keeping selectivity of metal dissolution in view.In the first stage most of the lead and zinc are reacted with dilute FeCI3 (0.3M) solutions at a temperature ono°c where major portion of the lead remains in the residue and zinc reports in solution. After taking out lead chloride by brine leaching, the residue has been treated for copper dissolution. A concentrated FeCI3 leaching at boiling temperature as well as ambient aqueous chlorine leaching have been separately tried to dissolve out the copper from the residue. Based on the results obtained, a flowsheet for the proposed process is presented.

Jan 1, 1981

By G. Bulut

The recovery of copper and cobalt from ancient copper slags from the Küre region of Turkey was investigated. A fayalitic-type of ancient copper slag containing 1.24% Cu, 0.53% Co and 53.16% Fe were subjected to an experimental study. Two different routes were followed to recover the metal values. The first route was roasting the slag with pyrite followed by leaching. The second route was flotation of the slags, roasting of the flotation tailings with pyrite and leaching. The second route was found to be suitable for the treatment of the copper slag studied. In the flotation step, a copper concentrate containing approximately 11% Cu was produced with a 77% recovery while 93% of the cobalt stayed in the tailings. In the roasting experiments, the effects of roasting time, pyrite: slag ratio and roasting temperature on the dissolution efficiencies of Cu and Co were investigated, and the optimum conditions were determined. In the tests, 87% of the cobalt dissolution was observed after one hour of roasting at 500°C with a pyrite: slag ratio of 3:1. The copper dissolution in the tests was 31%. Based on the results of this study, a process flowsheet is proposed for the evaluation of these slags.

Jan 1, 2007

By Nikhil Dhawan, Shrey Agrawal

Feldspar, a low-alumina, and abundantly available aluminosilicate source, is explored in this study to extract aluminum and potassium values. The sample comprises lamellar layers of microcline and albite with quartz containing 17.4% Al2O3, 9.67% K2O, and 66.3% SiO2. Mechanical (milling) and thermal (alkali and acid baking) activation are investigated, followed by HCl leaching. The milling treatment up to 6 h is inefficient in phase dissociation and results in ~ 40% Al and K dissolution. The alkali thermal treatment yielded 80% Al and 71% K extraction. Direct precipitation of the dissolved Al and Si values yielded alumina purity of ~ 29%, and silica gelation separated SiO2 and improved alumina product (94% purity, 71% recovery). Acid baking yielded 98% pure alumina precipitate; however, Al and K extraction were limited to ~ 45% and 65%, respectively. The microwave-assisted alkali treatment was optimal with 800 W and 10 min processing conditions yielding 80% Al and 71% K recovery with 2.26 kWh/kg alumina of thermal energy consumption. The final product contains γ-alumina with a specific surface area of 87 m2/ g. Keywords Feldspar · Alumina · Potassium ·

May 18, 2022

The extinction of zinc from steelmaking dusts has been studied with a laboratory scale reduction-vapour deposition (RVD) process in the absolute pressure and temperature ranges of 13 - 1300 Pa and 1333 - 1513 K respectively. This process consists of pre-reduction of iron oxide by carbonaceous agent, carbothermic reduction of zinc oxide under reduced pressure to produce zinc deposits and subsequent re-evaporation of the deposits to liquedify the zinc. In the RVD, the gas mixture of Zn and CO quenched from the hot zone is separated into Zn deposit and CO which is transferred to the pumping system. The Zn are a layer of fine metallic zinc powders accumulated on the cold wall and removed to the vacuum distillation chamber. The experimental works have been carried out according to the following items: carbothennic reduction of zinc oxide under vacuum, carbothermic reduction o zinc ferrite under vacuum, and 3. distillation of the Zn deposits. It has been concluded from these experimental results that the recovery of metallic zinc from the EAF dusts is successful by this process, and a new concept for a practical zinc winning process has been proposed.

Jan 1, 1993

By H. Reinhardt, P. Haglund, J. Rydberg, B. Lunden

As legislation to minimize pollution in effluent streams becomes stricter, it is important to treat used acid pickling baths before discharge. This is usually achieved by neutralization of the acids and precipitation of the dissolved metals in such a way that neither acids nor metals can be re-used. A process has been designed and tested on a pilot plant scale to recover both acids and metals from a stainless steel pickling bath leaving only Na2SOs in the effluent. In this process, H2SOr is added to the spent pickling liquor and the recovery of the pickling acids HN03 and HF is achieved by solvent extraction, using TBP in kerosene as the organic solvent. The extracted acids are stripped with water, giving an acid concentration high enough for direct use in the pickling bath. Molybdenum is also extracted by TBP and is recovered in a separate step. The other metals, Fe, Cr and Ni, are precipitated from the raffinate as hydroxides, dried and recycled to the metal process. In evaluating this process, comparative experiments with mixer-settler and pulsed column have been performed. The process described is being considered for use by a Swedish company pickling 70,000 tons per annum of stainless steel.

Jan 1, 1973

By Muammer Kaya

This paper reviews the existing and state of art knowledge for electronic waste (e-waste) recycling. Electrical/electronic equipments (EEEs) which are unwanted, broken or discarded by their original users are known as e-waste. The main purpose of this study is to provide a review of e-waste problem, give e-waste management strategies and introduce various physical e-waste recycling processes with special attention towards extraction of both metallic values and nonmetallic substances. The hazards arise from the presence of heavy metals (e.g. Hg, Cd, Pb etc.), brominated flame retardants (BFRs) and other potentially harmful substances in e-waste. Due to the presence of these substances, e-waste is generally considered as hazardous waste and may pose significant human and environmental health risks if improperly managed. This review paper describes the potential hazards and economic opportunities of e-waste. First of all, an overview of e-waste/printed circuit board (PCB) components and substances are given. Current status and future perspectives of e-waste and waste PCB recycling techniques are described. E-waste characterization, dismantling, liberation, classification and separation processes, are also covered. Manual selective dismantling after desoldering and metal-nonmetal liberation at −150 μm with two step crushing are seen to be the best techniques. After size reduction, mainly physical separation processes employing gravity, electrostatic, magnetic separators etc., which are commonly used in mineral processing, have been critically reviewed here for separation of metals and nonmetals. The recovery of pure metals from e-waste after physical separation can be performed by pyrometallurgical, hydrometallurgical or biohydro metallurgical routes, which are not covered here. Suitable PCB recycling flowsheets for industrial applications are also given. E-waste recycling will be a very important sector in the near future from economic and environmental perspectives for both developing and developed countries. Recycling technology aims to take today’s waste and turn it into conflict-free, sustainable polymetallic secondary resources (i.e. Urban Mining) for tomorrow. Recycling technology must ensure that e-waste is processed in an environmentally friendly manner, with high metal/nonmetal recovery efficiency a lowered carbon footprint. Taking into consideration our depleting natural resources, this Urban Mining approach offers quite a few benefits; it provides a substantial secondary resource, while also ensuring that the environment is kept free from harmful toxins in e-waste. This results in increased energy efficiency and lowers demand for mining of new raw materials.

Mar 1, 2017

By Arman Ehsani, Ersin Yazici, Haci Deveci

The downstream treatment of chloride leach solutions of WPCB for recovery of base and precious metals by a combination of adsorption and precipitation processes were carried out. A synthetic leach solution (1 M HCl, 116.5 g/L Cl-, 30 g/L Cu2+, 2.5 g/L Fe3+, 5 mg/L Au3+, 10 mg/L Ag+ and 20 mg/L Pd2+), which was prepared based on the composition of the pregnant leach solution obtained in the previous study was used in the tests. The leach solution was initially subjected to activated carbon (AC) adsorption (20 g/L AC, 80°C) in which gold was selectively recovered over silver and palladium i.e., 88% Au recovery at 0.5 h (92% at 3.5 h) compared with only 3-6% for Ag/Pd. Copper and iron were also observed to adsorb on AC as indicated by 1.4% and 17% decline, in their respective concentrations. Following the adsorption and filtration stage, metallic copper was added into the gold-barren solution to allow reduction of Cu2+ to Cu+, and to cement Pd on metallic copper. Over the mixing period (1 h), 93% of the Pd was recovered while only 1.4% of silver was cemented onto metallic copper. Subsequently, the leach solution was gradually neutralised by NaOH to pH 4, 7.5 and 9.5 for the precipitation of copper as cuprite (Cu2O). It was found that 41% and 46% of Cu and Ag, respectively, were precipitated at pH 4 at which iron was almost totally (99.8%) removed from solution. Precipitation of copper and silver was increased further at high pHs. At pH 9.5, cumulative recoveries for copper and silver were 91% and 85%, respectively. XRD analysis of the precipitates confirmed the presence of cupric copper oxides/hydroxides and revealed that copper losses occurred at pH 4 was due to the undesired presence of cupric copper in the solution.

Jan 1, 2014

By Andrew Wessman

Keywords: Recycling, Electrodeposition, Recovery, Dilute, Dissolved Metal Ions In order to facilitate the recovery of pure metals from solutions containing a mixture of dissolved metal ions, a pulsed electrodeposition method was developed. Using this method, it is possible to selectively remove metal ions from solution based upon the electrochemical potential of the particular ion desired. The use of pulsed electrodeposition rather than direct current electrodeposition creates an electrodeposited material with better morphology, increases electrical efficiency of the process, and avoids problems with short circuiting between electrodes. Using this method, it is possible to recover dissolved metal ions in a purified form in one simple step, and therefore maximizes recovery of the metal ions while obtaining them in a saleable form. This method is likely to be useful in improving the recycling process for numerous complex metal mixtures and alloys.

Jan 1, 2005

By Torma A. E.

Biotechnological processes are considered to be cost effective especially for situations where the recovery of metals from 'Very large volumes containing trace metal concentrations (less than 10 ppm) is concerned. Microorganisms, alive or dead, or their products can be highly efficient and selective biosorbents for metal concentration. It is important that the metal bound to the biosorbent can be stripped by suitable agent(s) and regenerated for repeated use. The stripped solution should be concentrated enough to be introduced into the common metal recovery circuit. The industrial acceptance of biosorption processes is dictated by increased competitive advantage over other processes. This paper reviews the pertinent literature?, regroups the information, and points out future possibilities for the mineral and metal processing industries.

Jan 1, 1992

By Nikhil Dhawan, Amit Barnwal

The present study reports a processing route to recover metals from integrated circuits of discarded random access memory (RAM) units containing ~ 66% printed circuit boards and ~ 33% integrated circuits. The integrated circuits are manually separated, grounded, classified, and subjected to water fluidization for the effective separation of metals. The significant separation was achieved via water fluidization, and the underflow fraction was magnetically separated. The magnetic fraction was thermally exposed in a muffle furnace, and the process optimization was carried out using a Box-Behnken statistical design. The detailed characterization at subsequent steps significantly aids the understanding of metal-plastic separation and enrichment. A concentrate containing 97% metals (Fe-59%, Ni-9.5%, Cu-7.7%, Sn-13.4%, Pb-5.6%, Ag-1.6%) with 96 wt% recovery can be recovered from discarded IC units. The process pursued is simple, adaptable, and environment-friendly, and the product can be used in conventional smelters.

Jun 23, 2020

By Nikhil Dhawan

Electronic waste (e-waste) is a collective name given to discarded electronic devices such as Television, Cellular Phones and Personal Computers. Among the heterogeneous metals present in the e-waste are the base metals: copper, aluminium, nickel, tin, zinc, iron and precious metals: gold, silver, palladium, platinum apart from several hazardous and halogens metals. Hence there is a need to recover these metals from electronic scrap by recycling and then re-use, which can meet large amount of metals demand. Hydrometallurgical processing was employed for the recovery of metals from television printed circuit board (TV PCB). Different lixiviants such as hydrochloric acid, Sulphuric acid, and nitric acid were used to understand the dissolution behavior of copper, iron and lead present in the TV PCB. Effect of increasing concentration of nitric acid was also studied. Selective recovery of tin over 95% in the form of tin oxide was precipitated. The precipitated tin oxide was identified by X-ray diffraction technique. Tin oxide of purity more than 99.9% was obtained.

Jan 1, 2009

By L. C. George

Addition of an acid waste to an alkaline cyanide waste was investigated for five different combinations of electroplating wastes. At the optimum final pH values of the mixtures, metals and cyanides were almost quantita¬tively precipitated. No evolution of hydrogen cyanide was detected by a few additional processing steps, significant amounts of variable metals were recovered for recycling the waste-plus-Waste step is attractive because no reagents are required, metals arc concentrated, and a relatively harmless effluent that meets most water quality Standards for cyanide content is produced.

Jan 1, 1970

US 4,185,078-In the recovery of rhenium values from an aqueous sodium molybdate solution contained in the hydrometallurgical processing of roasted molybdenite, improved results are realized by using a described extractant consisting of a quaternary ammonium compound and benzene or other highly aromatic solvent which dissolves a quaternary ammonium-rhenium complex Essentially all rhenium is recovered from the solution and the extractant can be regenerated and recycled. This patent is a continuation-in-part of US Patent No. 4,049,771, dated Sept. 20, 1977. L R. Quatrini and M.B MacInnis, assigned to GTE Sylvania Inc. Jan 22, 1980. 6 pp (423-49). Flied. 7-19-78 (926,167).

Jan 1, 1982

By Thomas M. Harris

To avoid the escalating cost of disposal of metals-containing wastewater and residues, new wastewater treatments will focus on the recovery of the metals. A combination of ion exchange and electrowinning can produce water suitable for discharge and relatively pure metals. The use of a chelating resin can enhance the selectivity of both the removal process and the elution of metals from the resin. A new, simple method of preparing a variety of chelating resins is being developed. The materials produced by this method exhibit interesting, as well as potentially useful, elution behavior. The performance of one test resin is described.

Jan 1, 1992

By Nicholas E. Vanderborgh

Projections show that domestic coal will serve for the majority of energy supplies during the next decades. Thorough chemical cleaning of this coal can be accomplished in long-residence time, slurry-transport systems to produce high-quality fuel product. Concurrently, mineral recovery from coals will supplement existing ores. This paper describes this concept and gives preliminary engineering considerations for mineral recovery during transport operations.

Jan 1, 1982