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By J. W. Leonard, C. L. Jiang, B. K. Parekh, X. H. Wang

The selective depression of pyrite from the Kentucky No. 9 coal seam was systematically examined using various kinds of inorganic and organic chemicals. Most of the organic chemicals tested showed little selectivity in pyrite depression. It was found that both orthophosphate and pyrophosphate were effective for the selective depression of coal pyrite in coal flotation using fuel oil as a collector. At substantially low concentrations of pyrophosphate, the flotation of coal pyrite was completely depressed over a wide pH range, while the coal flotation remained unaffected. The mechanism of the selective depression of pyrite by phosphates was explained with the help of thermodynamic calculations of iron-phosphate-water systems and zeta-potential measurements. It was shown that pyrophosphate reacts strongly with the iron ions of pyrite to form stable hydrophilic iron pyrophosphate complexes on pyrite surfaces.

Jan 1, 1999

By C. L. Jiang

The selective depression of pyrite obtained from Kentucky No.9 seam in coal flotation with various kinds of inorganic and organic chemicals was systematically examined. Most of the organic chemicals tested showed little selectivity in pyrite depression. It was found that both orthophosphate and pyrophosphate were effective for the selective depression of coal pyrite in coal flotation using fuel oil as a collector. At substantially low concentrations of pyrophosphate, the flotation of coal pyrite was completely depressed over a wide pH range, while the coal flotation remained unaffected. The mechanism of the selective depression of pyrite by phosphates has been explained with the help of thermodynamic calculations of iron-phosphate-water systems and zeta potential measurements. It was shown that pyrophosphate reacts strongly with iron ions of pyrite to form stable hydrophilic iron pyrophosphate complexes on pyrite surfaces.

Jan 1, 1998

By V. G. Papangelakis, S. Peters

Pressure oxidation of refractory gold ores can be conducted on ores with high carbonate content using just water or water with alkaline reagents to promote fast kinetics, and suppress the formation of elemental sulphur and CO2. In this work, a fundamental study was conducted to explore the silica-pyrite interaction in the presence of calcium and sodium carbonate. It was found that an alkaline environment increases the pyrite decomposition kinetics on one hand, but on the other dissolves silica, which encapsulates the dissolving pyrite thus hindering ultimately its complete decomposition.

Jan 1, 2011

By W. G. Hubler

History The Aldermac mine is situated on the Nipissing Central railway near the ' centre of the township of Boischatel, Quebec, and is about ten miles west of Noranda. Aldermac Mines, Limited, is a subsidiary company of Towagamac Exploration Company. The property was staked by Messrs. Alderson and MacKay and McMartin, during the winter of 1922-23. During October, 1925, a copper discovery was made by K. W. Fritzsche, who was in charge of exploration work at that time, the first trench on this discovery averaging 8 per cent copper over a width of ten feet. This led to the discovery of another body 200 feet to the north, with an average of 3 per cent copper over fifteen feet in width. A magnetic survey was then carried out which led to the location of the large pyrite ore-bodies which have been developed in the past few years. Development work was carried on to a depth of 1,125 feet, and approximately three million tons of massive pyrite ore was indicated. Extensive metallurgical tests were conducted in the laboratories of the Mines Branch of the Department of Mines at Ottawa to determine the proper metallurgical treatment and the economic possibilities of the ore. Owing to the comparatively low copper content, and the uncertainty of the copper market, it was doubtful if the mine could be profitably operated for the production of copper alone. Messrs. Alderson & MacKay, however, realized the possibility of utilizing the large tonnage of pyrite as a substitute for native sulphur, 'which in past years has been imported into .Canada for the manufacture of acid and sulphate pulp in paper mills. They therefore organized the Sulphite Research Corporation with the object of developing an economical process of utilizing the pyrite.

Jan 1, 1932

By H. Salomon-de-Friedberg

The amount of pyrite in copper concentrates fed to the CESL Process can vary appreciably. The fraction of pyrite that oxidizes influences both capital and operating costs and is therefore an important variable. The present paper explores operating conditions that influence the extent of pyrite oxidation and the probable overall reaction chemistry under CESL conditions.

Jan 1, 2014

By S. K. Kawatra

In most operating coal-cleaning plants, a significant amount of pyrite is recovered in the froth during flotation of high-sulfur coal. Reducing the pyrite recovery first requires that the primary recovery mechanism should be Identified, as different measures are required for reducing entrainment, locked-particle flotation, or true hydrophobic flotation. In this paper, evidence is presented which suggests that hydrophobic flotation is not an important mechanism for recovery of liberated pyrite from freshly-ground coal when the collector is a neutral oil, and that the bulk of the floated pyrite occurs either as a result of simple entrainment or by mechanical locking with floatable coal particles. Column flotation results are also presented which show that significant sulfur reductions can be achieved by reducing levels of entrainment.

Jan 1, 1992

The roasting of sulphide ores and concentrates is often the first step in the production of metals or chemicals. In many processes, the production of sulphuric acid is viewed as a by-product, while in some plants production is an important economic factor. Regardless of the purpose, a pyrite roasting plant consists of mainly three plant sections: roasting, gas cleaning and sulphuric acid. With the addition of air, the pyrite concentrates are transformed into solid oxides and gaseous sulphur dioxide at temperatures of 600 - 1000° C. After cleaning and cooling, the sulphur dioxide in the roasting gas is further processed to sulphuric acid. Two types of reactors are used depending on the application: stationary or circulating fluid bed . For over 60 years, Outotec has progressively been developing the principle of fluidised bed technology in several different reactor types for a multitude of process applications. The versatility of the fluidised bed reactor system has manifested itself in the treatment of minerals, including solid fuels, and for metallurgical processes both in the ferrous and non-ferrous fields. Process applications have included roasting, calcining, combustion and charring of coals, as well as off-gas treatment. This paper provides a summary of the pyrite roasting technology currently used along with a simple cost comparison of pyrite roasting and sulphur burning processes.

Jan 1, 2009

The roasting of sulphide ores and concentrates is often the first step in the production of metals or chemicals. In many processes, the production of sulphuric acid is viewed as a by-product, while in some plants production is an important economic factor. Regardless of the purpose, a pyrite roasting plant consists of mainly three plant sections: roasting, gas cleaning and sulphuric acid. With the addition of air, the pyrite concentrates are transformed into solid oxides and gaseous sulphur dioxide at temperatures of 600 - 1000° C. After cleaning and cooling, the sulphur dioxide in the roasting gas is further processed to sulphuric acid. Two types of reactors are used depending on the application: stationary or circulating fluid bed . For over 60 years, Outotec has progressively been developing the principle of fluidised bed technology in several different reactor types for a multitude of process applications. The versatility of the fluidised bed reactor system has manifested itself in the treatment of minerals, including solid fuels, and for metallurgical processes both in the ferrous and non-ferrous fields. Process applications have included roasting, calcining, combustion and charring of coals, as well as off-gas treatment. This paper provides a summary of the pyrite roasting technology currently used along with a simple cost comparison of pyrite roasting and sulphur burning processes.

Jan 1, 2009

The roasting of sulphide ores and concentrates is often the first step in the production of metals or chemicals. In many processes, the production of sulphuric acid is viewed as a by-product, whereas in some plants production is an important economic factor. Regardless of the purpose, a pyrite roasting plant consists of mainly three plant sections: roasting, gas cleaning and sulphuric acid. With the addition of air, the pyrite concentrates are transformed into solid oxides and gaseous sulphur dioxide at temperatures of 600?1000°C. After cleaning and cooling, the sulphur dioxide in the roasting gas is further processed to sulphuric acid. Two types of reactors are used depending on the application: stationary or circulating fluid bed. For over 60 years, Outotec has progressively been developing the principle of fluidized bed technology in several different reactor types for a multitude of process applications. The versatility of the fluidized bed reactor system has manifested itself in the treatment of minerals, including solid fuels, and for metallurgical processes both in the ferrous and non-ferrous fields. Process applications have included roasting, calcining, combustion and charring of coals, as well as off-gas treatment. This paper provides a summary of the pyrite roasting technology currently used along with a simple cost comparison of pyrite roasting and sulphur burning processes.

Jan 1, 2009

By DOOLITTLE E. M.

(Canal Zone Meeting, November, 1910.) The following notes are contributed, not with the idea of offering a complete history of the development of this very important process as applied to the Leadville district, but with the hope that the practice, as it was carried out in the Bi-Metallic Smelter, may still be of interest to others. The Bi-Metallic Smelter, at Leadville, Colo., was the first to make a commercial success of the process described in the following pages, which consisted essentially of smelting raw silver- and copper-bearing sulphide ores in blast-furnaces to form a matte, which was generally re-smelted with siliceous ores for a second high-grade matte. Robert Sticht, in his excellent monograph on the subject,1 has outlined briefly the plant belonging to this company. He says, in effect: The Boulder, Mont., enterprise set the example for others with whom the patentee (w. L. Austin) had been negotiating, and the old La Plata lead-smelter at Leadville, Colo., was fashioned into a crude, temporary experimental plant for the Bi-Metallic Company, and the feasibility of the process demonstrated by a trial run. Subsequently, the plant was considerably improved, and, being supplied with very favorable ores, continued to run without interruption from August, 1892, to June, 1893. In September, 1893, smelting was resumed in a completely remodeled establishment, some $200,000 having been expended upon the new work. Thus, aside from the Montana experiments, which, under the direction of W. L. Austin, began as early as- 1885 2 at Toston, and continued with indifferent success for six or seven years, the Bi-Metallic plant at Leadville may be said to have * Formerly Superintendent, Bi-Metallic Smelting Co. + Formerly Chief Assayer and Chemist, Bi-Metallic Smelting Co. 1 Modern Copper Smelting, E. D. Peters, 7th ed., p. 415 (1895). 2 Trans., xvi., p. 259 (1887-88).

Dec 1, 1910

By Hugh Henton

THIS paper is the result of an investigation made in association with Dr. Charles H. Fulton. Early in 1918 a search was started for methods of utilizing, in the manufacture of basic refractories, certain domestic resources in magnesites, dolomites, and magnesian limestones. Much information was collected during that year and during 1919 regarding magnesite and dolomite deposits. During 1920 and 1921 a research was made into methods of calcining dolomite and separating magnesia therefrom. Some success was attained and many new ideas were brought out in connection with the preparation and utilization of magnesia in the form of "caustic" or light-burned material as well as in the form of refractory or "dead-burned" material. Stimulated by this success, much advance has been made in manufacturing processes for the "plastic magnesia," so called, used for magnesia cement, stucco, flooring and otherwise in the structural industries.

Jan 3, 1926

A geologic, petrographic and geochemical study has been performed on the pyroclastic flow deposits in the coastal area of East Zhejiang Province, Southeast China. This study leads to classification of the pyroclastic flow deposits into three associations: the extrusive type, the surge type and the ash flow type welded tuff associations. Through detailed investigation and comparison of the characteristics of these lithologic associations, with emphasis on the welded tuffs, a comprehensive model has been proposed to demonstrate the petrogenesis of the pyroclastic flow deposits.

Jan 1, 1995

By H. M. Woodrooffe

IT IS WELL KNOWN that chrysotile asbestos from various occurrences exhibits varied physical properties and certain differences in chemical corn position, both of which conditions may have an important bearing on the industrial utilization of the fibre. The usefulness of a harsh fibre in the manufacture of asbestos cement products and of low-iron fibre for certain electrical uses are examples. It is also .possible to obtain a fibre with a texture too harsh and brittle to be of economic value. Much research into the structure of the mineral and to a lesser degree observations relating the water of combination to certain physical properties have ?been reported. This paper is an attempt to show that the pyrolysis of ?chrysotile takes place in three stages and that the conditions of pyrolysis are peculiar to the fibre and may afford some clue to the variations in physical properties of asbestos fibres which affect their utilization.

Jan 1, 1956

By Walter E. Dean

Twenty six samples of carbonaceous gold ores and associated rocks from outcrop and mine localities in northcentral Nevada were analyzed for concentrations of major. minor, and trace elements, total sulfur, and organic carbon. Q-mode factor analysis was used to define six distinctive carbonate, organic, and detrital associations of elements, and to group samples based on these associations. The trace metals that have clearly enriched the organic-carbon-rich samples are V, Zn, Ni, Cu, Cr, and Mo, although few of the samples could be considered "metal-rich" when compared to other organic-carbon-rich black shales. Rock-Eval pyrolysis was used to evaluate thermal maturity and hydrocarbon yield of the samples. Unfortunately, most samples were too thermally altered to be suitable for routine organic geochemical characterization of organic matter. The 813C values of organic carbon in rocks from different deposits have a trimodal distribution, but there is no clear distinction between the three groups of deposits that can be related to age, thermal history, or depositional environment.

Jan 1, 1987

By Atsuhiro Nabei, Ken-ichi Yamaguchi

"Wet chlorination process of de-copperized anode slime is followed by de-chlorination stage in which lead-sulfate and metallic silver form silver residue. The silver residue is subsequently reduced to Ag2Se matte and PbO-SiO2 slag to remove lead to the slag in a short rotary furnace. Although this smelting process is proven well in actual operations, few papers have investigated its metallurgical aspects. This paper will describe the effectiveness of controlling parameters adopted at the Naoshima Smelter & Refinery and discuss the decisive factors influencing silver loss to PbO-SiO2 slag.IntroductionThe precious metals plant at Naoshima smelter & refinery was established in 1989, and has produced electrolytic silver, refined gold and platinum-group metals (PGM) from de-copperized anode slime as by-products of electrolytic copper. The process for gold production has been innovated from conventional smelting process to hydrometallurgical process since 2004 [1], while the process for silver production has still remained the same.The process for silver production at the Naoshima smelter & refinery is illustrated schematically in Figure 1. De-copperized anode slime is, at first, concentrated in the froth flotation process, then leached in the wet-chlorination process, and converted to silver residue in the de-chlorination process. The silver residue, which is a mixture of lead-sulfate and metallic silver, is charged to a short rotary furnace for the oxidation roasting to volatilize selenium dioxide and subsequent reduction smelting. In the smelting stage, silver residue and reverts containing selenium are smelted with flux and carbonaceous materials to form PbO-SiO2 slag and Ag2Se matte. Furthermore, Ag2Se matte is transferred to a rotary cupell and oxidized by air with the addition of sodium carbonate and sodium nitrate to produce silver anodes while removing impurities into litharge. Silver anodes are electrolytically refined by the Moebius process. Electrolytic silver is washed, dried and, finally, cast into 30kg-bars."

Jan 1, 2011

By B. Mishra

The major waste product of the alkaline extraction of alumina from bauxite [Bayer Process] is known as red-mud. Approximately, a ton of red-mud is produced for every two tons of bauxite that is mined. The red-mud produced from Jamaican bauxite is rich in hematite, alumina and titanium oxide. It has been shown that over 90 wt. pct. alumina can be recovered from red-mud by soda-ash sintering and caustic leaching. Hematite can be carbothermically reduced with a degree of metallization of over 94 pct. At this stage, the product could be charged through the tuyeres in an iron blast furnace or smelted to produce pig iron. The mineralogical characteristics of the reduced product are not amenable to magnetic separation for iron recovery. The problems associated with the use of reduced red-mud as an alternative to direct-reduced iron [DRI] has also been discussed. Special attention has been paid to lower the alkali content of the reduced material. If smelted, the concentration of titanium oxide in the slag will be significantly high justifying its recovery by an acid-leach process. This paper describes the successful efforts of iron and alumina recovery.

Jan 1, 2000

By J. J. Moore

Combustion synthesis or self propagating high temperature synthesis (SHS) reaction systems are discussed with respect to thermodynamics and kinetics. In particular, tile effect of the process parameters, ego particle size, AHf, ignition and combustion temperatures on these self sustaining reactions is discussed. Combustion theory is used to investigate the effect of the overall activation energy of the SHS reaction on the combustion front propagation rate and in obtaining a clearer understanding of the transition from stable to unstable propagation. Finally, examples of the application of combustion synthesis to advanced materials processes are made, in particular the synthesis of Ni-Ti -X intermetallic shape memory alloys, TiC-Al2O3 and ZrB2 ?Al2O3 ceramic composite materials.

Jan 1, 1991

By Teuku A. R. Putra, Patrick R. Taylor

Various pyrometallurgical methods for treating copper concentrates that contain appreciable arsenic are reviewed. Various aspects of the engineering of these treatment methods are discussed. The methods discussed include: complete oxidation with arsenic fixation; selective volatilization of arsenic; acid baking, soda ash roasting, and others methods. Methods for the ultimate disposal, or marketing, of the arsenic are discussed.

Jan 1, 2014

By Ross R. Bhappu

A theoretical and experimental investigation into pyrometallurgical refining of chloride leach/electrowin copper is described. The two techniques investigated were (i) vaporization and (ii) gaseous halogenation. Experiments were carried out with a packed bed of electrowon copper crystals and a boat of melted copper crystals. Nitrogen gas and Freon 12/nitrogen mixtures were used as the carrier and reac.tive gases. Vaporization was found to be effective in removing Bi, Pb and S while halogenation was effective. in removing As, Bi, Pb, S and Sb. Silver resisted all attempts at removal. Iron was removed but less effectively than the other impurities.

Jan 1, 1985

By H. Antrekowitsch

The decreasing quality of the input materials in copper recycling leads to a higher content of impurities in the anode copper. An improvement of the pyrometallurgical refining process is therefore necessary to produce high quality anodes for the copper refining electrolysis. The behaviour of the most important accompanying elements (e.g. nickel, tin, lead, zinc etc.) at different reaction conditions has to be investigated in order to improve the metal/slag reactions as well as the vaporisation by selective oxidation in the anode furnace. Therefore the thermodynamic conditions like reaction order and the activity coefficients at the copper refining process have to be known for the optimisation of this technique. Additionally the interaction between different elements has been investigated as a function of the temperature, the content of the elements and the slag composition especially for nickel. These investigations were done at the Christian Doppler Laboratory for Secondary Metallurgy of Nonferrous Metals.

Jan 1, 2005