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By Robert Corson

Zinc has a large solubility in Fe and a completely filled ?d? shell. With the discovery of dramatic increase of the magnetostriction in Fe by Ga addition, an examination of element Zinc that is adjacent to Ga in the periodic table is of significant interest. In this work, the effect of binary alloying of Zn with Fe on the magnetic and magnetostrictive properties is examined. The FeZn alloys were processed using powder metallurgy and vapor phase synthesis, and Zn contents were varied from 5% to 30%. An examination of the influence of different processing parameters and the Zn content on the resulting alloy properties is presented. The alloys were characterized using X-ray diffraction and SEM. Magnetostriction measurements were carried out at different pre-stress levels. Magnetic properties were measured using a vibrating sample magnetometer.

Jan 1, 2006

By H. Walqui

The Empire concentrator currently processes magnetite ore from the Empire pit which is approaching the end of its mine life. Over the past two years plant wide tests have been run to access the plant capability of processing ore from the neighboring sister Magnetite pit. The neighboring pit presents challenges to the Empire plant due to its higher feed grade, finer liberation size and higher percent silica which require additional secondary grinding and concentrating capacity to achieve concentrate grade. The following paper summarizes the results from the second full scale test, run during 2009 under a challenging market environment

Jan 1, 2010

By Kanau JL, Kilgour I

This paper describes the metallurgical processes at the 80 000tpd Ok Tedi Mining Limited concentrator, which treats copper- gold ore by single-stage crushing, SAG and ball milling and flotation to produce over 500 000tpa of concentrate. Plant and process developments, including installation of column cells, reduction of fluorine in concentrate, use of sulphidisation and process control improve- ments are also discussed.

Jan 1, 1991

By La Brooy S R, Fenton K

A low grade copper flotation tailing from Telfer containing 1.2% Cu as chalcocite and cuprite and 5 gt-t Au was leached with ammonia, cyanide and ammonia-cyanide mixtures to extract copper and/or gold. Direct cyanidation extracted both copper and gold but consumed about 30 kgt 1 NaCN. Pre-leaching the tailing with an aerated ammonia solution containing 28 kgt 1NH3 and 17 kgtl(NHa)2S0a at pH 10 readily extracted up to 95% Cu in about 6 hours under optimum conditions. However pH and total ammonia concentration were critical factors. Subsequent cyanidation ex- tracted 80% Au using 6 kgt NNaCN. Ammonia-cyanide mixtures werefound to selectively leach gold over copper depending on the concentration and relative proportion of NH3 and CN. The best composition for leaching up to 80% Au from Teller tailing was 1.6 kgt t NaCN and 1.1 kgf 1 NH3 in the presence of 0.3 kgt t Cue+. Such a mixture left only 50 mgL-1Cu in the final solution after precipitation of some of the initially dissolved copper.

Jan 1, 1991

By George D. Coumoulos

The following aspects of diasporic bauxite are discussed: The importance of world reserves of diasporic bauxites; the geological, chemical and mineralogical characteristics of the Greek diasporic bauxite; the uniformity of bauxite deliveries; the significance of the absence of organics; the excellent settling properties of the red mud; the production of sandy alumina from diasporic bauxites; the advantages of applying tube digestion systems in processing diasporic bauxites; the conditions for introducing diasporic bauxite in the existing European refineries.

Jan 1, 1984

By R. H. Hanewald

The processing of EAF baghouse dusts from both the specialty steel industry and low alloy producers will be reviewed. In addition, the INMETCO process has been modified so as to recover nickel, chromium and iron from many other waste materials such as pickling solutions or filter cakes, spent nickel and chromium plating baths, carbon refractories from pickling tanks, and super alloy wastes including baghouse bags. INMETCO is the only North American company presently capable of recycling nickel-cadmium batteries by high temperature metals recovery. This, along with the details of INMETCO's BDAT Test Program and results performed to pre-agreed standards with the EPA will be discussed.

Jan 1, 1992

By Arthur F. Colombo, David M. Hopstock

The Lake Superior region contains extensive deposits of potential iron ore in the form of fine-grained oxidized taconite. To help assure utilization of this resource in an environmentally sound manner, the U.S. Department of the Interior, Bureau of Mines, is conducting bench- and pilot-scale research using wet high-intensity magnetic (WHIM) separation. The advantages and disadvantages of WHIM separation in comparison with other feasible beneficiation methods are discussed. Pilot plant results are given for a flowsheet in which WHIM scavenging is used in conjunction with selective flocculation and flotation. A mathematical model for use in process optimization is given. Practical aspects of matrix selection and separator design for WHIM separation of fine particles are discussed.

Jan 1, 1980

ABSTRACT Inco’s Iron Ore Recovery Plant was operated by Inco from 1955 to 1980 near Sudbury, Ontario. As exposures to specific nickel substances have been associated with adverse respiratory endpoints it is important to understand processes giving rise to such substances. This manuscript discusses the process and equipment, the propensity for aerosol formation, and operational procedures used by Inco in roasting a pyrrhotite concentrate, reducing the nickel in the formed oxide, leaching the nickel in ammoniacal solution, purifying the resulting solution, making green or black NiO, and producing iron oxide pellets. Industrial hygiene measurements are also reported.

Jan 1, 2013

ABSTRACT It is critical that historical processes and concomitant exposures to specific nickel substances be understood because some diseases linked to inhalation of certain nickel-containing substances have a long latency between first exposure and disease onset, and because nickel substances vary significantly in their toxicological properties. A discussion of the smelting history and related processes at Vale Canada’s (Inco’s) Copper Cliff, Ontario, smelter is integral to the understanding of these processes. The post-1950 processing history, equipment, propensity for aerosol formation, operational procedures, and ventilation controls used by Vale Canada in roasting, smelting, converting, and copper-nickel separation is discussed.

Jan 1, 2013

By G. J. de Korte

South Africa’s best-quality coal, located in the central Highveld basin, is becoming depleted and alternative sources of coal, such as the Waterberg coalfield, will have to be developed to supply the country with coal in the future. The quality of the coal being mined in the central basin is gradually becoming poorer. This necessitates that more of the coal be processed to improve the quality to meet customer requirements. The challenge to the coal processing industry is to process low-yielding coals to produce goodquality products and at the same time ensure that coal mining remains economically viable. This requires that more cost-effective coal processing technologies be investigated and implemented.

Jan 1, 2015

By G. Prabhulingaiah, D. M. R. Sekhar

"A phosphate deposit of estimated 6 billion tons of P2O5 is located 180 to 300 meters below the sea level, 185 kilometers north of port Luderitz, Namibia. The ore bed is 6 kilometers wide and 220 kilometers long. The ore deposit analyzing 16% P2O5 is loose sediment of 1.5 meters thick without over burden. Sizing of the ore to - 1.4 mm + 0.150 mm improves the grade to 23.54% P2O5 with a P2O5 recovery at 83.75% containing phosphate pellets and flakes of sea shells. Clay, bacterial debris as organic matter, flakes of broken sea shells and fine phosphate containing particles report to - 0.150 mm fraction and + 1.4 mm fraction contains sea shells and few phosphate containing pellets. The mineralogical composition of phosphate containing pellets is estimated (Droste, T.C., 2004) 80% frankolite, 6% pyrite, 4% illite, 3% quartz, 3% amorphous SiO2, 1% carbonates, 1% organic carbon and = 1% ilmenite, magnetite, zircon etc. The phosphate content in the pellets is around 27.7% P2O5. Trials to separate by gravity or flotation processes were not successful. Leaching of carbonates (sea shell flakes) under mild acidic condition (= 2% acetic acid or HCl solutions) or calcinations followed by leaching however yielded residues (concentrates) of grades 27.85 - 32.74% P2O5 at P2O5 recoveries ranging from 78.45 - 96.8% P2O5."

Jan 1, 2014

By H. Rush Spedden

A process has been developed and piloted to reject copper, lead, iron, phosphorus, bismuth, antimony, elemental sulfur, and insol from molybdenite concentrate without decomposing the contained molybdenite and rhenium. The impure concentrate is first heated with concentrated sulfuric acid at 260 to 290°C for 1 hour. This bake not only oxidizes the contaminating sulfides, but also activates the concentrate for later rejection of insol by flotation. Two stages of leaching follow the sulfation step. The first is an acidified water leach which extracts the oxidized copper, iron, and phosphorous; the second leach rejects the lead, bismuth, and antimony into a warm concentrated solution of sodium chloride. Final upgrading is achieved by conventional froth flotation. The chemistry of the process as well as results obtained from its implementation in a 5,000 lb/day pilot plant are presented.

Jan 1, 1971

By A. R. Sheik, A. A. Baba, M. K. Ghosh, K. Sanjay, R. B. Bale, A. G. F. Alabi, F. A. Adekola, L. Ibrahim

"This paper studies the characterization and dissolution of a Nigerian pyrolusite ore, reporting the results of ore physicochemical analyses and detailed ore characterization before and after leaching at optimal conditions. Ore dissolution rate increased proportional to acid concentration and temperature, but decreased with ore particle size. In a 4 M H2SO4 solution at 80°C with a particle size of –90+75 µm and moderate agitation, ore dissolution rate reached 78.7%. Unleached residue produced under optimal leaching conditions consisted of silica with admixtures of cristobalite and stishovite. The calculated activation energy supported the proposed diffusion control mechanism for the process.RÉSUMÉ Le présent article étudie la caractérisation et la dissolution d’un minerai de pyrolusite du Nigeria, il donne les résultats des analyses physicochimiques du minerai et de la caractérisation détaillée du minerai avant et après la lixiviation sous des conditions optimales. Le taux de dissolution du minerai augmentait proportionnellement à la concentration de l’acide mais décroissait avec la taille des particules. Dans une solution 4 M H2SO4 à 80 °C, avec une granulométrie de –90+75 µm et une agitation modérée, le taux de dissolution du minerai a atteint 78,7 %. Les résidus produits sous des conditions optimales de lixiviation étaient constitués de silice avec un mélange de cristobalite et de stishovite. L’énergie calculée d’activation supportait le mécanisme de contrôle de la diffusion proposé pour le procédé."

Jan 1, 2016

By А. А. Vasiliev, Y. G. Seredkin, А. V. Aksenov, А. Y. Senchenko

Refractory gold-containing concentrates usually contain gold enclosed in sulphides as well as in rock-forming minerals. Another difficulty is that gold often occurs as very fine inclusions of several micrometres, and even smaller than 1 micrometre, or can be part of the mineral composition at the structure level. Processing of such concentrates is a challenge. Ultrafine grinding and further oxidation are applied for gold liberation. The paper deals with the results from the study of gold deportment using Qemscan, and atmospheric oxidation testwork involving Albion Process™ on a gold-containing concentrate with a high content of refractory gold in sulphides and gangue minerals. Albion process testing was performed at Institute TOMS with the participation of Glencore Technology Pty Ltd (Australia). Additionally, conventional cyanidation testwork was carried out for the concentrate processing. As an alternative technology of gold liberation, oxidising roasting with arsenic stabilisation was used. The results from the study make it possible to assess the efficiency of the above-mentioned methods of gold liberation, and applicability of Albion technology to recover gold from the refractory concentrate. Key words: Gold, refractory concentrate, Albion Process, atmospheric oxidation, oxidising roasting, leaching

Jan 1, 2020

By Corby G. Anderson

Antimony has been utilized by mankind for thousands of years. However, due to recent environmental concerns, antimony is often considered to be an impurity element, Since antimnoy is commonly found in precious metal refractory ore bodies, extraction is essential. The Sunshine Mine in Kellogg, Idaho has recovered antimony from its precious metal tetrahedrite deposits since the 1940's. A plant was initially constructed as a primary antimony source during World War II. This facility also decreased the downstream smelting penalty for the silver copper-lead concentrate and provided an industrial commodity from a potential environmental nuisance.' This paper describes the Sunshine antimony processing- facility. Specifically, the relevant process chemistries involved in concentrate leaching, metal electrowinning, and sodium antimonate production will be discussed. In addition, ongoing areas of research to improve unit operations and treatments implemented to meet environmental' discharge requirements will be covered.

Jan 1, 1992

By T. V. Chnyrenkova, J. Troncoso, V. A. Luganov, G. P. Kluev

"Arsenic-gold bearing ores are used as flux in smelting or are leached to extract gold. The main aim is to decrease the arsenic content in processed materials and to break up the ore lattice, thus liberating the gold. Some regulations were established by authorities for sulfidizing of arsenic bearing compounds in a presence of pyrite and for oxidation of ores and concentrates in the presence of soda.This article analyses the results of laboratory and pilot plant testing of dissociating and oxidizing roasting of gold-arsenic bearing concentrates. During the dissociation roasting under vacuum, arsenic is sublimated into elemental and sulfide forms. This process allows for the minimization of the negative influence on the environment, but requires costly engineering solutions. Roasting in a limited quantity of oxygen in the gaseous phase makes it possible to sublimate arsenic in the form of oxides and sulfides and it may be carried out in fluid bed furnaces.Oxidizing roasting of the concentrates in the presence of soda results in formation of water-soluble compounds and forces practically all arsenic and sulfur to remain in the cinder."

Jan 1, 2003

By V. E. Chrapunov, T. V. Chnyrenkova, R. A. Isakova, V. A. Luganov

Arsenic-gold bearing ores are used as a flux in smelting or leached out to extract gold. To decrease arsenic content in processed materials and to break up the lattice to free the gold, raw materials are roasted. This article analyses the results of laboratory and pilot testing of dissociating and oxidizing roasting of gold-arsenic bearing concentrates. During the dissociation roasting under vacuum arsenic is sublimated into elemental and sulfide forms. The process allows to minimize the negative influence on the environment but requires costly engineering solutions. Roasting in a neutral medium or with limited quantity of oxygen in the gaseous phase makes it possible to sublimate arsenic in the form of oxides and sulfides and may be carried out in the autogeneous mode in fluid bed furnaces. If oxidizing roasting of the concentrates is done in the presence of soda, practically all arsenic and sulfur form water-soluble compounds and remain in cinder.

Jan 1, 2002

By T. V. Chnyrenkova, J. Troncoso, V. A. Luganov, G. P. Kluev

"Arsenic-gold bearing ores are used as flux in smelting or are leached out with extraction of gold. For decreasing arsenic content in processed materials and for breaking up the lattice and opening up of gold the raw materials are roasted. Some regularity was established for sulfidizing of arsenic bearing compounds in a presence of pyrite and for oxidation of ores and concentrates in the presence of soda.This article analyses the results of laboratory and pilot testing of dissociating and oxidizing roasting of gold-arsenic bearing concentrates. During the dissociation roasting under vacuum arsenic is sublimated into elemental and sulfide forms. This process allows minimizing the negative influence on the environment but requires costly engineering solutions. Roasting in a limited quantity of oxygen in the gaseous phase makes it possible to sublimate arsenic in the form of oxides and sulfides and may be carried out in fluid bed furnaces."

Jan 1, 2003

By Nikhil Dhawan, Veeranjaneyulu Rayapudi

This study investigates upgrading of low-grade banded hematite quartzite iron ore (Fe ~31%). Conventional beneficiation was found to be futile. The susceptibility of iron phases to microwave exposure and their selective absorption assists in the liberation of iron values. Microwave exposure of coarse particles at 540 W for 10 min yielded a concentrate with Fe 56.30% and recovery of 50.68%. Conventional carbothermic reduction at 500 °C, 60 min and 9% charcoal yielded a concentrate with Fe 57.6% and iron recovery of 68%. The presence of sufficiently bonded silica leads to an easy formation of a fayalite phase. The microwave reduction design yielded FeG of 57.6%, FeR of 47% and a yield of 24% at an optimal condition of 540 W, 8 min and 6% charcoal. It was found that a small fraction of microwave-irradiated ore-charcoal mixture melted rapidly, and pure ferrite balls were observed within 8 min. An optical micrograph of a ferrite ball reveals the retained austenite and martensite phase.

By Nikhil Dhawan, Veeranjaneyulu Rayapudi

This study investigates upgrading of low-grade banded hematite quartzite iron ore (Fe ~31%). Conventional beneficiation was found to be futile. The susceptibility of iron phases to microwave exposure and their selective absorption assists in the liberation of iron values. Microwave exposure of coarse particles at 540 W for 10 min yielded a concentrate with Fe 56.30% and recovery of 50.68%. Conventional carbothermic reduction at 500 °C, 60 min and 9% charcoal yielded a concentrate with Fe 57.6% and iron recovery of 68%. The presence of sufficiently bonded silica leads to an easy formation of a fayalite phase. The microwave reduction design yielded FeG of 57.6%, FeR of 47% and a yield of 24% at an optimal condition of 540 W, 8 min and 6% charcoal. It was found that a small fraction of microwave-irradiated ore-charcoal mixture melted rapidly, and pure ferrite balls were observed within 8 min. An optical micrograph of a ferrite ball reveals the retained austenite and martensite phase.