Search Documents

Deposit of Jinbaoshan platinum group metals (PGMs) ore ranks the second in Yunnan province, China. Study on process mineralogy shows that the grade of copper and nickel in the ore is just 0.16% and 0.20% respectively. Moreover, the impurities magnesium and iron and silicon are rich in the ore. The copper and nickel sulfides in the ore, especially the minerals of PGMs, are finely disseminated with the gangues like serpentine. Fine grinding is necessary, and high content of MgO in the concentrate is inevitable through traditional flotation technology on the basis of process mineralogy studies. Achievements on process mineralogy studies are applied to guide the flotation tests successfully. Progress on flotation has been made through comprehensive studies. Suitable grinding by two stages is required for the finely disseminated PGM sulphide ore to achieve the liberation of valuable minerals. Stage grinding and stage separation shall be conducted for a better recovery of valuable minerals. The oxidation state of mineral surface of sulphides has a profound effect on flotation of the ultra-fine sulphides, especially the pentlandite. The combined use of collectors enhances the selective collecting on the ultra-fine and low-grade valuable minerals, is of critical importance.

Jan 1, 2014

By T Vizcarra, G Sandoval, C L. Evans

One of the challenges in the development of mineral processing simulators is modelling the liberation characteristics of particles produced by comminution circuits. Understanding the mineral characteristics of these particles is one of the keys to predicting their behaviour in separation circuits. While more fundamental research seeks to model the non-random breakage of ores this work examines whether we can move forward now by using observed characteristics of ores to model the composition of particles generated in comminution processes. Several researchers have noted the similarity of the liberation characteristics for a selected size fraction of particulate material, whether the fraction comes from a coarse material, such as the product from a jaw crusher, or a more finely ground material, such as the product from a ball mill. In most cases these observations were reported as an aside and were not the main focus of the published work. This observed behaviour has the potential to be a useful tool for modelling the particle characteristics in mineral comminution and separation circuits, particularly as we move towards the development of multi-component models. However, before the behaviour can be used widely we need to understand which ore types follow the observed pattern and which do not. The current work examines a range of ores and identifies which exhibit the pattern of similarity of composition for particles in a given size class that has been produced as the result of a variety of breakage conditions. The impact of mineralogy and texture on the evolution of liberation characteristics for both valuable and gangue minerals is discussed.

Jan 1, 2008

By Song Mao, Local Joint Engineering Lab of Efficient Util of Dominant Mineral Resources from Karst Regions, Guizhou Key Lab of Comprehensive Utilization of Non-metallic Mineral Resource, Xianhai Li, Qin Zhang, unjian Ye, Guizhou University, Wei Cheng, Zhihong Liu

"Phosphate tailing is a kind of industrial waste that emitted from separation processing of phosphate ores, which is usually discarged to the tailing pond without treatment. Recovery of phosphorus from tailings is of great significance for comprehensive utilization of phosphorus resource. Chemical composition of a micro-fine cryptocrystalline phosphate tailing was investigated by X Ray Fluorescence (XRF) and Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES), and mineral composition and occurrence of harmful elements were analyzed by optical microscope and Scanning Electron Microscope (SEM), X ray Energy Dispersive Spectrometer (X-ray EDS) and Mineral liberation Analyzer (MLA). On the basis of above, effects of those on mineral processing for phosphate tailing was analyzed. Chemical analysis results in combination with microscopy indicated that there is a certain amount of iron and aluminum and it should focus on the removal of them in separation processing. The cryptocrystalline structure, especially the micro banding structure and micro porphyritic structure indicated that there is quite amount of phosphate in fine particles and it should recovery the phosphorus as much as possible when designing the flotation technology for this difficult separation fine phosphate tailing. This study can provide theoretical guide for efficient phosphorus recovery of from fine phosphate tailing by flotation.INTRODUCTIONPhosphate rocks are vital nonrenewable resources and are essential components in agricultural fertilizers and phosphorous-based chemicals (Gharabaghi et al., 2009). About 95% of the phosphate produced around the world is consumed in the fertilizer industry (page 60 Abdel-Zaher, 2008; Jasinski, 2007). Froth flotation, a solid wettability based separation process is widely used in separation of phosphate rock and shown to be effective (Yehia et al., 1990; Singh et al., 1992; Elgillani and Abouzeid, 1993; Al-Fariss et al., 2013) .Poor selectivity and low recovery for micro-fine particles are hard issues in flotation of middle-low grade phosphate ore because Phosphate resources is becoming poor, fine and complex as the rich ores run out since the 1970s. The rapid depletion of high grade ores forces minerals industry to process low grade ores where finer grinding is required to achieve required liberation of the values, making the fine particle flotation inevitable. the performance of conventional flotation deteriorates rapidly as particle size decreases to below 10-20 µm, depending on the density of the particles (Feng and Aldrich, 1999). To date, fine particle flotation is still considered to be a challenge in mineral processing (Li et al., 2015) ."

Jan 1, 2016

By Richard D. Hangi

Process mineralogy techniques are uniquely applicable to industrial problems related to the extractive metallurgy of nickel, cobalt, and associated metals. Reflected 1ight microscopy, together with selected determinations by scanning electron microscopy-energy dispersive spectrographic analysis and electron probe microanalysis, provides the means to identify the ore minerals cobalt and nickel ores, determine the abundance of each ore mineral, assess the extent of intergrowth between the cobalt and nickel minerals and other ore and gangue minerals in the ores and concentrates, and predict the potential success of cobalt and nickel extraction by grinding, flotation, pyrometallurgical, and hydrometallurgical treatments. In addition, the extent of locking of the cobalt and nickel minerals with each other and with the gangue minerals can be directly observed by reflected light microscopy. Where ores have been treated by hydrometallurgical procedures, reflected light microscopy can serve to determine the causes of excessive leach consumption. Finally, the partitioning of cobalt and nickel between high-temperature synthetic phases produced by pyrometallurgical treatment can be precisely determined by process mineralogy techniques. Case histories from cobalt and nickel deposits illustrate the value of applied mineralogical techniques in the study of cobalt and nickel ores, beneficiation, hydrometallurgial, and pyrometallurgical products.

Jan 1, 1993

By V. V. Ramarao

Grinding and flotation operations deliver better-optimized performance when they are monitored and controlled in terms of the minerals they process rather than as elemental assays that we usually refer to. Mesh of grind (MoG), liberation, floatability, grade and recovery etc. are more directly related with the minerals and their characteristics rather than the elemental assays. Hence, online analyzers only provide the status for the grade and recovery of metals and not the direction for the enhanced performance. Central Research and Development Laboratory (CRDL) and Rampura Agucha Mine (RAM) mill section of Hindustan Zinc Limited (HZL) jointly undertook various survey campaigns in the grinding and flotation process streams. Grinding circuit surveys involved systematic collection of representative samples from different grinding circuit streams under stabilized conditions for monitoring particle size and process mineralogy details across individual grinding circuit. Flotation survey campaigns included study of fort-nightly / monthly composites of un-ground flotation feed, lead concentrate, lead tailing, zinc concentrate and final tailing samples for size distribution details in the 150 ? 38 micron range, chemical analysis and mineral characterization through optical microscope. This work details the investigations results and their implications on beneficiation performance. Grinding circuit survey campaigns supported the task for modifying the originally installed configuration of hydrocyclones, to limit recovery losses due to excess grinding of soft galena and related silver minerals. Flotation plant surveys helped in adjusting flotation circuit process parameters to reduce loss of liberated and floatable galena and sphalerite grains into their respective tailing streams. Keywords: grinding circuits, survey campaign, hydrocyclones, mineral liberation and locking, lead-zinc ore beneficiation operation

Sep 1, 2012

By David Sutherland

The treatment of a complex orebody requires a thorough understanding of its mineralogy. If there is a poor appreciation of the mineralogy involved, difficulties can emerge with the efficient exploitation of the resource. Recently, there has been a lot of interest in automated image analysis systems, which aim to improve the reliability and accuracy of the data, which can be gathered. In this sense, the paper point out the process mineraloggy for complex ores. Mineral modal analysis a description of texture and liberation studies are the basis of these measurements. They have been applied to a wide range of mineral systems including copper, lead, zinc, silver and gold.

Sep 13, 2001

By T. Grammatikopoulos, SGS Canada Inc.

"The Nechalacho rare metal deposit, located in the Northwest Territories, Canada, is currently being taken through Feasibility Study by Avalon Rare Metals Inc. QEMSCAN analysis and supplementary electron microprobe analysis were utilized to identify and quantify the mineralogy of the deposit, and determine REE distribution among the minerals. QEMSCAN mineralogy was performed to provide textural information on the mineralization, determine the variability of the ore and identify REE domains, and the liberation and association of the REE minerals. The sample matrix consists predominantly of silicate minerals. The REE minerals include allanite, monazite, synchysite, columbite, fergusonite, and bastnaesite. Zircon is present in considerable amounts and is a REE carrier. Fergusonite and zircon account for most of the HREE, and monazite, allanite, synchysite and bastnaesite the LREE. QEMSCAN mineralogical data is extremely valuable in assessing the mineralogy of the ore. The data are implemented to define the mineralogy of the ore body, support metallurgical test work, and predict recoveries and grades.INTRODUCTIONThe term rare earth elements (REE) is used to describe the 15 lanthanide elements or metals and, more recently, the metals yttrium and scandium, which display similar physical and chemical properties.Economic and potentially economic REE deposits form two main groups, a more commonly occurring “light rare earth element” (LREE) group containing lanthanum, cerium, praseodymium, neodymium, and samarium and a less commonly occurring “heavy rare earth element” (HREE) group which, in addition to the LREE, contains elevated concentrations of the more valuable REE, europium, gadolinium, terbium, dysprosium, holmium, yttrium, erbium, thulium, ytterbium, lutetium and scandium. The first group is hosted primarily by carbonatites and the second by highly alkaline (Na + K > Al) silicate igneous rocks. The LREE are produced mainly from bastnaesite, monazite, etc., while HREE are produced almost exclusively from low-grade secondary ion adsorption clay deposits in which the REE are adsorbed onto the surfaces of kaolinite and halloysite, clay minerals produced by the weathering of granite and sediments. HREE are also found in fegusonite, zircon, xenotime, etc but are not produced presently from these minerals. China is responsible for 97% of the World’s production of the REE, mainly from the giant Bayan Obo, carbonatite-related deposit and from the clay deposits mentioned above.Quantitative automated mineralogy is increasingly being applied to ore deposits. It helps users to understand and improve mineralogical parameters for geological and metallurgical purposes. Data include textural characterization, to quantification and distribution of ore and gangue minerals, liberation and association of the REE minerals. The data can be used to define mineralogical domains and predict the metallurgical response of the ore (Gunning, de Souza, & Grammatikopoulos, 2009)."

Jan 1, 2012

By Norman Schapiro

Future ore bodies will, most likely, be more costly to find, mine and process than those now in production because most of them will be of lower grade or found deeper. To evaluate an ore deposit for extraction of metal values it is important to select the optimum economic process from among the many available options. The physical and chemical behavior of the minerals present should govern the process selection. Process mineralogy which combines mineralogy and petrography with process development engineering generates the data on mineralogy, composition and texture of gangue and valuable minerals from which the optimum process steps can be selected in the commercial design of the ore processing plant. These insights also help in solving operating problems caused by changes in the ore body

Jan 1, 1981

By Qiuyang Hong, Bo Li, Dongyun Liang

"A weathering-crust niobium-rare earth-bearing deposit is formed by the weathering alterationof alkaline granite, which is refractory due to its low grade and complex properties. The mineralogicalcomposition of ore, the grain size of majorminerals as well as the occurrence of Nb and REE are studied in this paper using MLA combined with traditional methods. According to the results, a wide range of Nb-Ti-REE compound minerals including titanoniobite, uranpyrochlore, chlopinite, samarskite and ilmenorutile areformed for the extensive isomorphous substitution among the elements of Nb, Ta, REE, Fe, Ti, U and Th. The occurrence of REE is extremely complex. First, the REEexistingas rare earth minerals including monazite, xenotime, bastnaesite,etcaccount for 21%. Second, the REEexist in the lattice of Nb and Zr minerals as isomorphous additions, which account for 18%. Third, the REE exist as colloidal rare earthdeposit,which account for 35%. Last, the REEexistingas ion-adsorption-type rare earth,which are adsorbedon the kaolinite in the form of hydrated hydroxyl ions, account for 26%.Based on the results of mineralogy, the combined technology process "mineral processing- hydrometallurgical separation" is needed to deal with the ore. The mineral processing tests show that, for the feed ore containing Nb2O5 0.065%, REO 0.13%, an Nb-REE concentrate containing Nb2O5 1.38%, REO 1.98% can be gained by "high intensity magnetic separation-regrinding-gravity separation by shaking tables". The recovery of Nb2O5 and REO is 62.42% and 44.78% respectively. The Nb-REE concentrate is dealt by the metallurgy process "direct reduction- acid leaching & acidulating- neutralization & precipitation- chlorination & distillation" and the rare earth oxide of 92.34% REO as well as the Nb-Zr oxide of 24.62% Nb2O5 can be obtained with the recovery of REO and Nb2O5 being 76.83% and 59.37% respectively."

Jan 1, 2014

By D. M. Hausen

The term "auriferous pyrite" relates to an association of gold with pyrite in a variety of textural forms that affect metallurgical treatment. Extraction of the gold depends not only on the grain size and distribution of the gold in the pyrite, but also on the crystal size and surface area of the pyrite. Occlusions of medium to coarse gold may be liberated by moderately fine grinding. The amenability of finely dispersed (submicroscopic) gold depends in part on the activity of the pyrite surface for oxidation. Two types of auriferous pyrite at Carlin, Nevada, have been examined by optical microscopy and SEM methods before and after aqueous oxidation test work to show how differences in morphological features can affect rates of oxidation and amenability to gold extractions by methods of chlorination and low temperature oxidation.

Jan 1, 1981

By Mostafa Benzaazoua, Emilie Ré, Raphaël Mermillod-Blondin, Hassan Bouzahzah, Jean-François Wilhelmy, University of Québec in Abitibi-Témiscamingue

"We analyzed two copper and lead flotation concentrates from the LaRonde mill using MLA technology (Mineral Liberation Analyzer) to identify the contaminants and to quantify their size and liberation. The MLA mineral quantification was compared with traditional mineralogical techniques (Scanning Electron Microscopy, Optical Microscopy, X-Ray Diffraction and Chemistry). The accuracy of MLA data was then quantify in application to metallurgical decision (mineral identification, mineral quantification, particle sizing and liberation quantification). We prepared five well-known materials from pure minerals and analysed them by MLA. MLA concentrates analyses showed the lead concentrate is mainly contaminated by pyrite and sphalerite. These minerals are liberated above 70 % and present a floatable size around 15 to 35 µm. Surface activation by dissolved lead from galena is therefore assumed for these contaminants. The analyses of the known samples show that mineral quantification and size distribution given by the MLA are consistent with the chemical analyses and the laser particle sizer. The liberation measurement is affected by the stereological effect. Modelling quantifies the overestimation of the particle liberation. Based on the modelling, the stereological shift on liberation should not impact metallurgical conclusions on the concentrate contaminations.INTRODUCTIONTo face the diversity of mineral processing challenges, the process mineralogy includes phase quantification, measurement of mineral size, liberation by exposure and by grade, association, surface contact proportion and texture. In the last decades, two SEM commercial tools emerged: MLA and QEMSCAN R. Both are based on specific combinations of backscattered electrons and X-ray images as well as image analysis routines developed at CANMET (Petruk & Pinard, 1976, Petruk, 1989), CSIRO (Frost, O'Hara, Suddaby, Grant, Reid, Wilson & Zuiderwyk, 1977, Reid, Gottlieb, MacDonald, & Miller, 1984) and JKMRC (Hall, 1977, Gu & Sugden, 1995). Recently, TIMA (TESCAN) and Mineralogic MiningR (ZEISS) supplied automated mineralogy for mining industry (Bouzahzah, Benzaazoua, Graham & Cropp, 2015, Gottlieb & Dosbaba, 2015a). In parallel, home-made routine were developped to resolve mineralogy challenges in mineral process but also in geometallurgy and mining environment (Kahn, Mano, & Tassinari, 2002, Knight, Klassen & Hunt, 2002, Mermillod-Blondin, Benzaazoua, Kongolo, de Donato, Bussiere & Marion, 2011, Hunt & Bradshaw, 2015). SEM mineralogy become essential to operation by setting units on mine sites (MacDonald, Latti, Adair, Bradshaw, & Dunn, 2011, Goergen et al., 2013, Dobbe et al., 2014, Gottlieb & Dosbaba, 2015b)."

Jan 1, 2016

By J. Rao Mokka

Extensive exploration has resulted in delineation of a massive sulfide district on the north flank of the east-central Alaska range. The district covers approximately 400 square miles and contains numerous stratiform; transported and some replacement type sulfide deposits ranging in size from less than 1 million tons to 20 million tons. Five types of ores were sampled for the study. Mineralogical analysis revealed that the minerals are too fine grained for conventional grinding and beneficiation. Hydrometallurgical studies were con-ducted using ferric chloride as a lixiviant. Ore microscopic studies as well as electron microprobe analyses of minerals in the raw samples and leach residues explained the low recoveries for certain elements as well as sources of impurities that need to be eliminated from the process streams.

Jan 1, 1991

By Richard D. Hagni

An enhanced Interest in pyrometallurgical dusts has recently emerged due to increased world-wide environmental concerns. Mineralogical study of dusts samples from lead sinter plants. lead smelters, and secondary steel mill electric arc furnaces has shown that they can be readily studied by reflected light microscopy. These dusts typically are composed of small particles sufficiently large that their mineralogical identification and characterization can be conducted under the reflecting light microscope. Scanning electron microscope-energy dispersive spectroscopic analysis (SEM-EDS) has been used to confirm optical identifications and chemical compositions. The sinter and blast furnace dusts at the Doe Run Smelter at Herculaneum, Missouri are commonly about 20-150 11m. They consist predominantly of galena, chalcopyrite, sinter. slag. coke. and particles. Dusts from remote sampling sites 112-1 mile from the lead smelter are composed of similar particles and abundant fine-grained particles, less than 10 um. of locally derived calcium-aluminum silicates. Electric arc furnace (EAF) dusts are mostly spherical and less than 10 11m. They consist predominantly of iron oxides (magnetite. franklinite. jacobsite and solid solutions of these spinels), zincite. and calcium-iron silicate glass, together with smaller amounts of hematite. sylvite. coke and metallic iron. Reflected light microscopy is rapid provides mineralogical data on individual grains within dust particles. and allows direct observations of textural intergrowths in pyrometallurgical dust particles.

Jan 1, 1991

The Manto Verde copper mine (Atacama Region, Chile) is due to go into production in 1996. It will produce 40 000 tonne/year of copper cathode by heap leaching/SX-EW. Mineralogical studies were undertaken in conjunction with the metallurgical testwork program to characterise the ore and its response to leaching by dilute sulphuric acid. The leachable copper mineralogy is dominated by the oxide copper minerals: brochantite and malachite with minor chrysocolla and atacamite. The gangue minerals include abundant orthoclase, specularite, quartz and chlorite with minor muscovite and trace smectite clay, calcite and limonite. The study showed that complete or partial decomposition of calcite, chlorite, smectite and wad consumed acid and generated solution impurities (Ca2+, Fe2+, Mg2+, A13+, K+, Si4+ and Mn4+2+ ). Although these were manageable at Manto Verde, their uncontrolled build-up could have affected the operation in several ways: the degradation of heap penneability and fonnation of crud in the SX plant from the precipitation of gypsum, goethite, colloidal silica and jarosite; and the entrainment of contaminated pregnant leach solution in the SX organic resulting in the transfer of impurities to the electrolyte and subsequent effects on cathode quality and electrowinning efficiency. In conclusion, process mineralogy played an important role in understanding and managing potential mineral-related problems in the heap leaching and SX-EW recovery of Manto Verde ore.

Jan 1, 1994

By D. M. Hausen

Applications of process mineralogy to the exploitation of molybdenum ores begins with early exploration and continues through the evaluation of mineralized prospects, to amenability testwork and pilot plant studies, to the development of a mineable orebody and to the development of a viable process for recovery. After plant construction, a broad range of products from a wide selection of sampling locations, i.e. grinding circuit, flotation cells, smelters and roasting kilns. etc., are evaluated analytically and microscopically, followed by periodic troubleshooting of problem points. The various crystalline phases of molybdenum that occur naturally and throughout various hydrometallurgical and pyrometal1urgica1 processes are identified and characterized by a variety of instrumental methods, including XRD-XRF, optical and electron microscopy, infrared spectrographic and differential thermal analysis.

Jan 1, 1989

Systemic process mineralogy study on Baerbulawu refractory hematite ore in Kazakhstan has been carried out. The ore contains Fe 41.34%, and 87.26 % of which exists in hematite. Most hema-tite occurs as fine or ultrafine grains and its average size is only 0.015mm. The gangue is mainly composed of quartz, mica, chlorite, kaolinite and other clay minerals. The liberation of hematite is only 66% when the ore is grinded to 75% ?0.074mm, while part of gangue is already liberated from hematite under this grinding condition, so these gangue can be cast away by magnetic separation in advance. Hematite will not liberate completely from gangue untill grinding fineness reaches 86% ?0.038mm, at the same time, free particles of ultrafine hematite tend to coagulate randomly with quartz and clay minerals, so appropriate dispersant is necessary to pre-vent hematite and clay minerals from coagulation. Based on the process mineralogy research, final technology flowsheet is high-intensity magnetic separation by coarse grinding?rough magnetic concentrate regrinding?inverse flotation, and an ideal index is achieved. The yield of final iron concentrate is 43.46%, and its grade and recovery are 66.76% and 70.55% respectively. The research result is also useful to other similar iron ores.

Jan 1, 2014

By Larry J. Hulbert, Louis J. Cabri, John L. Campbell, Gilles Laflamme, Chris G. Ryan, Soey H. Sie, Rolando Lastra

"Abstract- The mineralogy of samples from the Wellgreen Cu-Ni-Pt-Pd deposit, Yukon Territory, is complex and the metals of interest are contained within fme-grained minerais which vary in size and mineral associations from sample to sample.The major Ni carriers are pentlandite and violarite; the major Cu carrier is chalcopyrite. About 700Jo of the major Ni carriers and 78% of the major Cu qmier will be liberated at a grind of 80% -'}f,.7 J.Uil (-500 mesh) for typical low-grade gabbro (West zone, sample No. 1). For typical ""clinopyroxenite"" (West zone, sample No. 2) and typical ""clinopyroxene-rich peridotite"" (East zone, sample No. 3) the liberation would be 71""lo and 65% for Ni, 74% and 60% for Cu, respectively. Fine grinding, however, cannot liberate the Ni contained in silicates and pyrrhotite, estimated to total24.5% for typicallow-grade gabbro (West zone, sample No. 1), 15% for typical ""clinopyroxenite"" (West zone, sample No. 2), and 12% for typical ""clinopyroxene-rich peridotite"" (East zone, sample No. 3).The principal Pt carrier (sperrylite) varies considerably in grain-size between samples and fme grinding, required to liberate the major Ni and Cu carriers, may be counterproductive in samples where sperrylite is relatively coarse-grained, as sorne would then be unrecovered (e.g. sample No. 1). In addition, sperrylite in samples No. 2 and No. 3 is closely associated with magnetite.Palladium occurs in diverse ways. It occurs in the form of several Pd minerais (e.g. sudburyite, testibiopalladite, merenskyite), as a replacement for Ni in several tellurides, antimonides and tel­ lurantimonides (e.g. melonite), or as very low concentrations in pentlandite (up to 34 ppm), chal­ copyrite (up to 9 ppm), and pyrrhotite (up to 5.6 ppm). Palladium minerais and Pd-bearing minerals are strongly associated with chalcopyrite in sample No. 1 and will thus report to a Cu concentrate. However, 22% of the total Pd is in solid solution in pentlandite in this sample and will thus report to the Ni concentrate. In samples No. 2 and No. 3, less Pd occurs in solid solution in pentlandite, and the PGM are distributed mainly among pentlandite, chalcopyrite, and magnetite in sample No. 2, and among pentlandite, pyrrhotite, chalcopyrite, and magnetite in sample No. 3. Therefore, the feasibility of magnetic concentration should be investigated for samples like No. 2 and No. 3, in order to improve Pt and Pd recoveries.Rhodium was found to occur as rare hollingworthite, in sparse cobaltite (up to 2.7%) and, as low concentrations in chalcopyrite (to 10 ppm) and pentlandite (to 12 ppm) by proton microprobe. Iridium occurs in hollingworthite (up to 7.8%) and very rarely as the native metal or in an undefmed Re-Ir-Os-Ru alloy. Ruthenium was determined by proton microprobe analyses to occur in pentlandite (up to 13 ppm) and chalcopyrite (up to 10 ppm), in addition to rare laurite and Re alloy."

Jan 1, 1993

By Joe Zhou

"Mineralogical characterization and metallurgical extraction of silver is challenging due to its complex mineralogy and chemistry. Over 200 Ag-bearing minerals have been identified and a silver-rich ore body would typically contain 5 to 10 different silver minerals. Silver can occur not only as discrete microscopic (visible) silver minerals but also as submicroscopic (invisible) silver in other minerals. During processing, silver may form passivation compounds such as silver hydroxide, silver sulphide, jarosite-like silver sulphate, silver halide or silver cyanide precipitate, all of which may negatively impact on silver extraction. Knowing the deportment of silver in the ore and its metallurgical products is important in flowsheet design and plant optimization. This paper begins with the classification of silver ores and minerals and a review of processing techniques, and focuses on the major mineralogical factors to explain why and how these factors affect silver extraction. Case studies are provided to demonstrate the application of silver process mineralogy in flowsheet design and plant optimization.INTRODUCTIONSilver was known to and utilized by mankind since ancient time. Actually, it was one of the earliest metals discovered and utilized by mankind after gold and copper.Silver is the whitest metallic element. It is rare, strong, corrosion resistant, and unaffected by moisture, vegetable acids, or alkalis. Silver is also resonant, moldable, malleable, and possesses the highest thermal and electric conductivity of any substance. The chemical symbol for silver is Ag, from the Latin argentum, which means white and shining. Although silver does not react with many chemicals, it does react with sulfur, which is always present in air at trace amounts. The reaction causes silver to tarnish, and consequently it must be polished periodically to retain its luster.Silver possesses many special physical characteristics and qualities that make it useful to a variety of industries. The photography industry is the biggest user of silver compounds. Silver forms the most light-sensitive halide salts, which are essential to developing highquality photographic prints. Silver also has the highest electrical conductivity per unit volume of any metal, including copper, so it is used extensively in electronics."

Jan 1, 2010

By Manqiu Xu, Andrew Lee, Frederick D. Ford, Cara Wercholaz

"Platinum-group minerals (PGM) typically occur in such low concentrations that quantitative mineralogical evaluation is difficult or impossible. The FEI MLA system used by Vale Base Metals Technology Development has been successfully employed to produce large PGM data sets that are statistically robust. The MLA Sparse Phase Liberation mapping routine produces false colored images that accurately document mineral textures, including intergrowths between various platinum group minerals and between PGMs and other tellurides and sulfides. MLA PGM search results can be used in conjunction with mineral chemistry to calculate platinumgroup element distribution to minerals and the MLA PGM images can be used to produce model grade-recovery curves.INTRODUCTIONThe platinum-group minerals (PGM) found in Sudbury area deposits have been extensively catalogued and reviewed by many authors including, but not limited to: Farrow and Lightfoot (2002), Cabri and Laflamme (1984; 1976) and Cabri (1981). The PGM list currently used has 12 minerals summarized in Table 1. As noted by Farrow and Lightfoot (2002), platinum-group minerals in Sudbury are dominated by tellurides, bismuth-tellurides and arsenides, with an absence of platinum-group element (PGE) sulphides or ferro-platinum alloys such as tetraferroplatinum - PtFe."

Jan 1, 2011

By E A. Agorhom, M Beyuo, C Owusu, I Quaicoe

Understanding the mineralogy and liberation of gold particles in an ore is key to the development and optimisation of gold processing operations, being cyanidation or gravity separation. This can be achieved through basic historic geological information, gold deportment studies, chemical speciation and metallurgical test works. The present study assessed the nature of the occurrence of gold particles (mineralogical composition, liberation, associations and surface chemistry) and its effect on the process route (cyanidation and gravity separation) of a typical paleo placer gold ore deposit within the Tarkwaian Rock system. The investigative approach used involved chemical assay, quantitative X-ray diffraction (QXRD) and quantitative evaluation of minerals using scanning electron microscopy (QEMSCAN). The ore samples (A, B, C, D, E, F) used were obtained from six active pits of a gold mine working on this orebody. The results of the mineralogical analysis revealed that the ore is highly oxidised and comprised quartz (>80 per cent) and Muscovite mica (>6 per cent) as the major mineral phases in all the samples. Trace amounts of hematite, kaolinite and todorokite were also identified in all the samples. The chemical analysis showed presence of gold (Au) in all the samples with samples B (3.62 g/t) and C (3.96 g/t) containing the highest concentrations. Trace amounts of copper (Cu), iron (Fe), sulfur (S), aluminium (Al), arsenic (As) were also detected in all the ores. The QEMSCAN mineralogical liberation and gold association results revealed that the gold grains were relatively coarser in all samples (P80 > 80 µm Au in size) except F (P80 < 32 µm Au in size). Gold grains were highly liberated especially in sample B with the majority of the locked gold grains forming complex associations. All the samples responded well to cyanidation and gravity separation except samples C and F, respectively.

Aug 24, 2022