Search Documents

By N. Kanari

Chalcopyrite concentrates and their pure constituents were chlorinated by C12+N2 between 25 °C and 750 °C. The reaction products were analyzed by SEM, XRD and chemical analysis. The effect of gas flow rate and chlorine content of the gas mixture on the reaction rate were investigated. At room temperature, these solids start to react with chlorine giving metal and sulfur chlorides. Complete reaction is achieved at about 300 °C and the iron and sulfur chlorides were fully volatilized. The chlorination residue is composed of valuable metals' chlorides. A simplified flow - sheet for the treatment of chalcopyrite concentrates by chlorine was suggested.

Jan 1, 1998

By H. W. Parsons

Several low-temperature, dry chlorination processes for the treatment of sulphide minerals are reviewed, in a chronological order. These processes include the following: the Swinburne-Ashcroft, Baker-Burwell, Maim, Comstock-Wescott (Aldermac) and the Mitterburg Mining Process. Dry chlorination investigations at the Canadian Mines Branch (now CANMET) and the U.S. Bureau of Mines are discussed, as is a proposed process by the South Africa National Institute for Metallurgy. The techniques used in the process are discussed, as are the shortcomings, problems and failures of the methods.

Jan 1, 1978

By J. G. Bennett

Coal consumption has increased globally by 57% over the last ten years. Underground mining typically provides coal of the highest calorific value and accounts for the greatest proportion of production. Despite a negative environmental image and indeed impact, this industry appears likely to thrive on the global scale for many years to come. Such mining consumes large amounts of electricity with implications for carbon dioxide emission at power plants and emits substantial quantities of the powerful greenhouse gas methane. In response to this significant carbon footprint, the European Union has funded research to examine the potential for a range of improvement technologies in a project entitled Low Carbon Mine Site Energy Initiatives (LOWCARB). Coal properties related to seams and mines, together with longwall characteristics, provide the basis for research into modelling optimally efficient methane drainage with a view to assisting mining as well as maximising electricity generation at surface and hence oxidation of the methane. Possible systems for the oxidation of very low concentration methane in ventilation air, which contributes the greatest greenhouse gas impact due to the volumes emitted, have been studied and modelled. Simulation and investigation of intelligent optimisation of electricity demand patterns provide the basis for reducing the demand peaks at mines and hence the cost and ultimately the carbon footprint of a mine, while specific investigations have been undertaken into ventilation efficiency at an unusually challenging mine and simulation of mine water pumping in order to develop an innovative method to monitor pumping systems efficiency. For post-mining use, the potential of disused shafts for compressed air energy storage to improve the operation of future electricity grids with high renewable energy penetration by reducing peak generation capacity requirements has been studied. While underground coal mining will always by definition be related to a significant carbon footprint, this paper provides an overview of a set of initiatives that can make a positive environmental impact while controlling costs across a huge global industry.

Aug 1, 2013

By Ronald Erdmann

Today the BOF filter dusts and sludges are mainly dumped due to their zinc contents. By typically ranging from 2 to 5 % they prevent the filter dusts and sludges from beeing recycled via the blast furnace route. Based on the different discharge kinetics of Iron and zinc during the main blowing period In a bottom stirred BOF a simple and efficient system for recovery allow zinc fractions has been developed. The obtained material Is suitable for recycling without nsc of shell formation In the blast furnace. Different subsequent development steps have been performed. By starling with a very simple lime dependent model the sludge from the BOF off gas cleaning system was collected in two different sludge channel systems. This model based an the fact that most of the scrap based zinc Is discharged from the melt within the first eight to ten minutes of the BOF process. To Improve the system a spectroscope zinc sensor was Installed at the hot section of the off gas cleaning system to get more reliable informations on the actual zinc concentation of the BOF dust. By use of the system up to 50 % of the BOF sludge can be recycled.

Jan 1, 1995

By John Manka

Emulsion explosives consist of an aqueous oxidizer phase, a fuel phase, and an emulsifier. The ability to use lower-cost sources for any of these raw materials presents an obvious economic advantage to emulsion manufacturers. This paper focuses on using low cost waste drain oils as the fuel phase in emulsion explosive applications. Laboratory studies showed that emulsions made from waste drain oils and agricultural ammonium nitrate prills were usable for emulsion explosives though their shear stability was weak. Customer field results proved that waste crankcase drain oil could replace half of the virgin diesel fuel in emulsion explosives to make an effective emulsion explosive product with a very low cost.

Jan 1, 2003

By Robert S. Holmes

The U. S. Army Corps of Engineers Explosive Excavation Research Office (EERO) of Livermore, California, has been engaged in research and development of excavation techniques using both nuclear and conventional explosives since 1962. Prior to July 1971, this organization was designated the U. S. Army Corps of Engineers Nuclear Cratering Group. The EERO mission is performed as part of the joint Atomic Energy Commission -Corps of Engineers nuclear excavation research pro-gram. During the period 1962-1969, the Corps executed many cratering explosions using spherical charges of up to 85 tons of nitromethane to model nuclear excavation concepts and to develop design criteria for the nuclear cratering explosions. The experience gained in these modeling tests suggested that explosive excavation using large chemical explosive charges could be applied to excavation projects as an economical substitute for traditional excavation techniques. Consequently, the Corps' research program was broadened in 1969 to include development of chemical explosive excavation as a construction tool. The term "explosive excavation" denotes the use of large buried explosive charges to produce an excavation by fracturing the material and casting it into a desired configuration. In its simplest form, this technology involves detonation of a single explosive charge buried at the proper depth to produce a crater which is roughly hyperbolic in cross section. The types of craters produced by various depths of burial are illustrated by Figure 1. Single or Multiple rows of charges are used to excavate linear cuts required for water conveyance or navigation channels. .More complex explosive excavations include small craft harbors, railroad and highway cuts, and removal of W1denvater rock barriers to navigation. While the literature indicates widespread use of large explosions in the (1) ERRO is a field activity of the Waterway Experiment Station, Vicksburg, Mississippi

Jan 1, 1971

By Paul C. Turner

In 1998, approximately 57,000 tons of titanium metal was consumed in the form of mill products (1). Only about 5% of the 4 million tons of titanium minerals consumed each year is used to produce titanium metal, with the remainder primarily used to produce titanium dioxide pigment. Titanium metal production is primarily based on the direct chlorination of rutile to produce titanium tetrachloride, which is then reduced to metal using the Kroll magnesium reduction process. The use of titanium is tied to its high strength-to-weight ratio and corrosion resistance. Aerospace is the largest application for titanium, and titanium cost has prevented its use in non-aerospace applications including the automotive and heavy vehicle industries.

Jan 1, 2001

By H. Aaltonen, T. G. Robinson, M. Morimitsu

"The energy required to plate pure zinc can be the most significant operating cost for an operator in the production of electrolytic zinc. This paper reports on developments on low energy Outotec coated titanium anode process technology with fully amorphous coatings, MSA®, and its application to brownfield zinc electrowinning operations around the world. This technology aims to reduce the operating cost and increase productivity for zinc producers.INTRODUCTIONZinc electrowinning is an energy-intensive process using more than 3,000 kWh/t of electric energy [1-4], and the reduction of the energy consumption is one of the key issues. The high energy consumption is due to a high cell voltage during electrolysis, which is mainly caused by a high overpotential of oxygen evolution reaction on lead alloy anodes which have been widely used in commercial zinc electrowinning processes. The overpotential of oxygen evolution is 0.6 V or more and which is approximately 4 times higher on average than that of the cathodic reaction (zinc deposition) [3,4]. Therefore, the reduction of oxygen overpotential is significant to reduce the electric energy consumption, and this will become more significant with increasing demand in metal production and rising energy costs.Oxide coated titanium anodes have been widely investigated for the oxygen evolution anodes in order to replace the lead alloy anodes [5-9], because it is known that the oxygen overpotential strongly depends on the material and structure of the anode. The most typical example of such anodes is an IrO2-Ta2O5 coated titanium anode, which is usually prepared at thermal decomposition of a precursor solution containing metal salts at 450 oC or more and obtained mixed oxide coating consists of crystalline IrO2 and amorphous Ta2O5. On the other hand, one of the authors of this paper, Professor Morimitsu, Doshisha University in Japan, has developed a novel oxide coated titanium anode, MSA® [10-25]. The most specialized point of MSA® is that the catalytic coatings are prepared at low thermal decomposition temperature and amorphous IrO2 or RuO2 is contained as the components in the coatings. Such amorphous coatings have high catalytic activity for oxygen evolution compared to lead alloy or crystalline coatings. Outotec acquired the international specialized MSA® patent licensing rights from Doshisha University and has produced and commercialized the amorphous oxide coated titanium anodes. These anodes have already been utilized mainly in copper electrowinning plants worldwide and have demonstrated a significant voltage reduction, a cost-efficiency, and a long lifetime. This novel technology is also effective to zinc electrowinning process, thus this paper presents the characterization and performance of amorphous IrO2-Ta2O5 coated titanium anodes and amorphous RuO2-Ta2O5 coated titanium anodes for oxygen evolution in zinc electrowinning."

Jan 1, 2016

By K. H. Boss

In modern iron pelletizing plants fuel consumption has been optimized to such an extent that only minor savings can be expected in the future. Inspite of this fact, different process parameters were studied with a mathematical model and firing tests. The influence on fuel consumption and productivity was established. Furthermore, the adoption of simplified firing patterns was investigated, in particular for coal firing. In view of high costs of oil and natural gas, only substitution of these fuels by coal can substantially reduce production costs. In existing plants partial replacement of oil and gas can be achieved by addition of coal to the iron ore feed and by firing the pellets with pulverized coal. Two systems have been developed for the Lurgi- Dravo travelling grate process which enables coal to completely replace oil or gas. This paper describes in the first part the potentials for fuel savings available in the Lurgi-Dravo process. In the second part, different techniques for the use of coal as fuel in iron or pelletizing plants and in particular the recently developed Lurgi Multistage Coal Injection and Combustion Process (LMC) are discussed. Combined with the LMC process, a wide variety of iron ores and coals - also with high ash contents - can be used in the Lurgi-Dravo travelling grate process.

Jan 1, 1983

Whilst the fossil fuel-based power industry moves towards carbon capture and storage (CCS) or so-called 'geosequestration', the minerals industry should adapt to reap the benefits of the new technology. If CCS becomes viable, the door is open to potential key developments in mineral processing. For example, truly continuous steelmaking could at last be realised using natural or manufactured gas combined with generic melt circulation. Iron ore fines would form a thin molten layer moving countercurrent to the gaseous reductant on one side of a melt circulation loop with efficient post-combustion without deleterious effects of slag accumulation on the other. This eliminates oxygen steelmaking because carbon has no access to the circulating molten iron. Steelmaking merely requires addition of the appropriate low level of carbon and in-line impurities removal to meet product specification. Concerning non-ferrous smelting, nothing short of virtually zero gas emission will be acceptable in the future. For dolomite-hosted Zn/Pb sulfide ores, typified by those in the Carpentaria region of Northern Australia, the way forward proposed is sulfur fixation at the mine site employing the highly exothermic reaction of SO2 with dolomite, followed by encapsulation of sulfated dolomite in fused ore slag. This releases enough energy for direct ore smelting to individual metal products. However, without CCS the strategy would be unacceptable because of greenhouse gas emissions. The scheme is advocated for direct ore smelting at McArthur River. As a result, the environmental problems of disposal of flotation tailings are avoided. Also, highly energy intensive ultra-fine grinding is eliminated, as indeed froth flotation itself, with overall very significant energy savings and exceptionally high increases in metals recovery. Zinc and lead recoveries approaching 99 per cent are predicted to be entirely feasible.

Sep 13, 2010

By B Mohanty, M P. Roy, P K. Singh

"The measured response of residential structures is a critical indicator of troublesomeor potentially damaging ground vibrations. A study was conducted to evaluate theresponse of structures situated in the periphery of four open-pit coal mines in India. Although, most of the structures were at far-off distances from the present blasting sites, an attempt was made to document the response of structures to blast vibration for future applications to optimize the blast designs for the safety of the structures. The study involved a total 215 blasts, employing one-, two- and three-hole calibration study, and production blasts. The bench height varied from 7.5 m to 42 m, and boreholes loaded with emulsion and slurry explosives were 250, 260, 270 and 310 mm in diameter. The explosive detonated in a blast were between 300-198400 kg whereas in a delay it was 33-24800 kg. Up to 12 tri-axial vibration sensors were located in overburden along a linear array from 25 m to 6.5 km distance from the blasts. Altogether, 1512 blast vibration signatures were recorded. Production and specially fi red single-charge blasts allowed the determination of natural ground frequency. The fundamental frequency of the structures ranged between 3.13 to 10.6 Hz, the same as those of the ground vibrations. The amplifi cation of vibration in the structures was in the range of 1.6 to 5.6. The study details the interaction between ground vibrations and selected structures, and the means to reduce amplifi cation of vibrations in the structures and persistence of vibrations through improved blast design."

Jan 1, 2008

By Gordon A. Gross

Banded siliceous manganese-iron bearing sediments recognized as distinctive facies of Algoma type iron-formation constitute low grade resources of manganese in many countries. Manganiferous facies associated with oxide and carbonate facies of iron-formation have iron to manganese ratios ranging from 0.2 to 2 and commonly about one. Manganiferous facies up to 30 meters thick occurring separately or with other iron-formation facies are associated with cherts, carbonates, shales, turbidites, tuffs and lavas. Primary cherty manganiferous facies and their gondite metamorphic equivalents represent significant manganese resources and are protores for higher grade deposits derived by secondary enrichment processes.

Jan 1, 1982

By Donald P. Ziegler, James F. Klausner, Srinivas S. Garimella

"By 2015, nearly half the world's population will live in ""water stressed"" areas. Production of fresh water utilizing waste heat from industrial processes has been identified globally as a research priority.About 15% of the electricity required to produce aluminum is lost as waste heat in the off-gas. However, the low temperature (low grade) of the heat limits reuse. The off-gases contain 50-150 ppm SO2 ; tightening regulations coupled with increasing coke sulfur levels are motivating SO2 control, for which seawater scrubbing is attractive for smelters with suitable access.We describe a process that produces fresh water, utilizing the waste heat while scrubbing SO2 . It uses direct contact between seawater and off-gas to humidify the off-gas. The vapor is subsequently condensed. In smelter trials, a unit treating a slip stream produced high quality water in the anticipated quantity, attaining over 95% SO2 scrubbing. Future work involves scaling the process to be economically attractive.BackgroundPopulation growth, coupled with industrialization and urbanization, are increasing demand for water. Water scarcity already affects every continent. Around 1.2 billion people, or almost one-fifth of the world's population, live in areas of water scarcity, and 500 million people are approaching this situation. By 2025, 1.8 billion people will be living in countries or regions with absolute water scarcity, and two-thirds of the world's population could be living under water stressed conditions (< 1,700 m3 per person annually) [1]. An assessment by the U.S. General Accounting Office revealed that under normal conditions, by 2013, water managers in 36 states in the USA anticipate water shortages, and that the number might grow to 46 states under drought conditions [2].The obvious choice to alleviate water scarcity is the 97% of available water in the oceans, which is saline and requires desalination for use in biological, agricultural and industrial applications. Technologies developed for desalination include Thermal Distillation, Reverse Osmosis (RO), Electro-Dialysis, and Vacuum Freezing. Distillation and RO are the most commercially prominent. Thermal distillation technologies include Multiple Effect Distillation (MED) and Multi-Stage Flashing (MSF). The report commissioned by the World Bank [3] is one of the many excellent references on desalination technologies. According to the International Desalination Association working paper [4], there were more than 17,348 industrial scale desalination plants installed or contracted by 2004. The total production from these plants is on the order of 8.3 billion imperial gallons per day. RO provides 47.2% of the total capacity. The leading thermal process, MSF, provides 36.5% of the total capacity. Although MSF and RO technologies currently provide the most cost effective means for desalination, their drawback is that they are very energy intensive, and whether or not they remain cost effective strongly depends on energy prices and energy supply."

Jan 1, 2012

Magnetic separation using particle rotation in a continuously rotating magnetic field offers very low to insignificant non-magnetic particle entrapment, and precise magnetic fractions. The precision of rotating magnetic field separations makes the method ideal for dry laboratory magnetic analysis work, where conventional laboratory magnetic separators can give misleading or uncertain data. The very low entrapment characteristics make the method ideal for entrapment-critical separations within the diamond exploration industry or in gold recovery. A single wet rotating magnetic field (RMF) unit is able to achieve a cleaner separation (at similar or better recovery rates) than a three-stage separation using conventional wet drum separators. The RMF separator is able to work effectively at particle sizes below 50 ¦m, and RMF separation could, at least in theory, be used down to single domain particle sizes. Rotating magnetic field (RMF) separation is carried out by magnetically spinning the particles at frequencies up to 300 Hz. The particle rotation itself may be used to roll the particles out of the separator. At angular velocities of 100 Hz, magnetic flocs are unable to form, and any entrapped particles are energetically expelled. In an RMF separator, the outer drum can be stationary while the inner magnet rotor rotates, allowing, for example, the injection of cleaning water underneath the separating magnetics to help remove small suspended non-magnetic particles.

Jan 1, 2000

Physical and chemical properties of the salt flux phase play a significant role in the recycling of UBC in Aluminum melting processes. Particularly knowledge of several properties such as salt vapor pressure, melting temperature, loss of aluminum, corrosion of refractories are useful for the process control decisions in order to attain a good quality of aluminum produced. A literature review and analysis of several salt flux systems for the selection of a flux for the Aluminum melter (low temperature natural gas bath melting) process were made. Based on these analysis two salt flux systems are recommended for further studies. These are NaCl?KCl?LiF system and NaF?LiF?KCl system with small amounts of other salt additives. Application of these fluxes to Al industrial processes are discussed.

Jan 1, 1996

By Andreas Munko

A Outotec está desenvolvendo em escala piloto o queimador de baixa emissão de NOx desde 2012, resultados expressivos foram atingidos (o pedido de Patente já foi depositado). Em 2014 utilizando simulações CFD, os resultados atingidos em escala piloto foram reproduzidos com boa aderência e os resultados em escala industrial se mostram com os mesmos comportamentos em tendências dos resultados da escala piloto, se mostrando promissores também. O presente trabalho apresenta os passos de desenvolvimento, os promissores resultados e o próximo passo deste desenvolvimento é realizar um teste em escala industrial com o queimador desenvolvido.

Aug 17, 2017

By Allen B. Stanton, Parthiv Brahmbhatt, Michael Grimm, Stanley L. Worst

Constructing a circular shaft consisting of secant piles has its own complications which make it more difficult than typical drilled shaft construction. Add to that performing under low overhead powerlines and sitting inside of a 40-foot deep, 50-foot diameter shaft and it becomes more about logistics than the actual drilling. The complexities associated with the Romeo Arm Interceptor Segment 5 Lining project are the focus of this paper, delving into the details that made it work successfully.

Oct 1, 2022

By H Sofatzis, J Kinal, J Siliezar, B Kirkwood

Ernest Henry Mining (EHM) is a copper, gold and magnetite mining and processing operation located 38 kilometres north east of Cloncurry in the Mount Isa - Cloncurry mineral district of north west Queensland, Australia. The EHM ore body is an iron oxide copper gold deposit with an average grade of 1.1 percent copper, 0.5 g/tonne gold and 22 percent magnetite.At the end of 2009, after a series of promising laboratory test work, EHM converted the ball mill media charge from forged steel to high chrome media. Laboratory test work also indicated that with the use of high chrome media, the pH was able to be reduced with no negative impact on plant performance. At high pH values (above 10.5), the forged media is passivated, so as the pH of the system drops the media corrosion rate increases and floods the system with corrosion products, affecting flotation. As the high chrome media is much more inert, pH has less of an effect on copper flotation response.This paper provides an overview of the effects of reducing the pH in the EHM copper rougher flotation circuit. The pH in the roughers was dropped from 10.6 to 9.6 to determine the impact on the rougher performance and the subsequent performance of the whole copper flotation circuit. It was found that there was a slightly increased improvement in copper recovery and no statistical change in either the rougher or final copper concentrate grades for copper and gold.With the reduction in pH, there was a noticeable reduction in lime usage from 0.85 kg of lime per tonne of ore processed to 0.55 kg/t. This reduction in lime is equivalent to approximately $700,000 per annum at current production rates.CITATION:Kirkwood, B, Kinal, J, Siliezar, J and Sofatzis, H, 2013. Low pH trial in the Ernest Henry Mining copper rougher flotation circuit, in Proceedings MetPlant 2013 , pp 371-377 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

"The Ernest Henry Mining (EHM) ore body is an iron oxide copper gold deposit with an average grade of 1.1 percent copper, 0.5 g/tonne gold and 22 percent magnetite. At the end of 2009, EHM converted the ball mill media charge from forged steel to high chrome media. At high pH values (above 10.5), forged media is passivated, so as the pH of the system drops the media corrosion rate increases and floods the system with corrosion products, affecting flotation. As the high chrome media is much more inert, pH has less of an effect on copper flotation response. Given this, the pH in the roughers was dropped from 10.6 to 9.6 and it was found that there was a slight increase in copper recovery and no statistical change in either the rougher or final copper concentrate grades for copper and gold. With the reduction in pH, there was a noticeable reduction in lime usage from 0.85 kg of lime per tonne of ore processed to 0.55 kg/t. This reduction in lime is equivalent to approximately $700,000 per annum at current production rates.INTRODUCTION The Xstrata Copper Ernest Henry Mine (EHM) is situated 38 km north east of Cloncurry, Australia. The mine began as an open-cut operation in 1998 and transitioned to a multi-sourced operation in December of 2011, utilising ore from the newly completed underground mine in addition to ore mined from the Mount Margaret Mining operations. EHM produces a combined copper gold concentrate containing 25 000 t of copper and 35 000 oz of gold annually, utilising a three stage grinding circuit along with a four stage flotation circuit. In addition to this EHM also produces 1 000 000 t of magnetite concentrate annually via a further grinding and three stage magnetic separation circuit. Based on metallurgical test work performed by Magotteaux between 2002 and 2008, the step to change from forged steel media to 18 percent chrome media was taken in 2009 in a bid to alter the pulp chemistry to improve the flotation performance in the plant (Greet, Kinal, Twomey, & Peatey, 2010). This plant trial resulted in: • Increased dissolved oxygen levels within the pulp, • A ball mill discharge Eh shift of 25 mV to more oxidising pulp potentials, and • An EDTA extractable iron percentage reduction. These improvements in the pulp chemistry resulted in an increase of 1.7 ± 0.6 percent in copper recovery and an increase of 2.9 ± 1.7 percent in gold recovery. As the plant trial using high chrome media was successful, the use of the media was adopted as the standard for the ball mill. This implementation opened the door for further process improvements around the flotation circuit."

Jan 1, 2014

By Moxon N. T

A series of low shock energy water resistant emlulsion based explosives have been developed by combining inert materials, such as Perlite P500, into the formulation. The material handling, water resistance and explosive properties of these mixtures were determined as a function of inert additive type, density, charge diameter and emulsion base. Of the emulsion bases tested Emulite produced the best and most stable low density mixtures ranging in density from 0.8 to 1.35 g/cm3 producing velocity of detonations (unconfined) ranging from 3000 to 5500 nits. The mixtures could be detonated successfully at these densities at diameters as low as 25mm. Low shock mixtures formed by combining Emulite with Perlite P500 were successfully trailed at the Cadjebut zinc mine in Western Australia. The performance of the explosive, at three densities, was monitored using both continuous and point to point VOD techniques. The fragmentation produced by the blasts were compared by photographic analysis. During this trial the low shock emulsion mixtures were shown to be as effective as the currently used explosives (packaged emulsion) at a significantly reduced cost.

Jan 1, 1990