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By J. Goyman, K. R. Rawling

"1.1 Location and Transportation ServicesNanisivik Mines Ltd. is located at latitude 73°, 3,200 km north of Montreal and 700 km north of the Arctic circle, on the south side of Strathcona Sound, which is an arm of Admiralty Inlet, in Northern Baffin Island. The orebody and mill site are 4 km distant from Strathcona Sound which provides deep water anchorage for ocean transportation of concentrate to Europe during the short northern shipping season from mid-July to mid-October.The operations and the resident community have direct jet aircraft service from Montreal two days per week, and local nights connect with other Arctic communities in the northern Baffin region. Bulk supplies and general cargo are delivered in the summer shipping season.1.2 HistoryThe Texas Gulf Sulphur Company, now Kidd Creek Mines Limited, staked claims in the Nanisivik area in 1957 and carried out exploration through to 1968. After the Kidd Creek orebody was found, Texas Gulf optioned the property in 1972 to Mineral Resources International Inc. (MRI), which undertook further exploration and completed a feasibility study.Nanisivik Mines Ltd. was formed in 1975, with MRI as the majority shareholder and minority shareholdings held by Metallgesellschaft, Billiton and Texas Gulf. Strathcona Mineral Services Limited was retained to manage the project during both the construction and operational phases."

Jan 1, 1984

By T. Wajima

"A novel carbonaceous immobilizing agent for heavy metal contaminated soil was prepared from rice straw using sulfur immersion and pyrolysis, and the lead immobilization in artificial contaminated soils using sulfur-impregnated carbonaceous material was estimated. The rice straws were cut to 1 cm pieces, and then immersed in 0.1 - 1 M K2S solution for 0 - 24 h to prepare sulfur-immersed materials. The immersed-materials were heated at 400 oC for 1 h in nitrogen gas to produce the sulfur-impregnated carbonaceous material by pyrolysis. The abilities of the product to immobilize lead from aqueous solution were examined to obtain the product with high lead immobilization ability. With increasing K2S concentration, the immobilization ability of the product for lead gradually increases and then above 0.5 M K2S those are almost constant, while 15 min is sufficient for the immersed time to obtain the product with high lead immobilization ability. The product prepared from material immersed in more than 0.5 M K2S solution for less than 15 min has a maximum immobilization ability for lead ion. The lead immobilization using the sulfur-impregnated product is sustainable due to the formation of leadhillite [Pb4SO4(CO3)2(OH)2] and anglesite [PbSO4]. The product can immobilize lead ion in various artificial lead contaminated soils. By mixing artificial lead contaminated soil with the sulfur-impregnated product, the eluted solution became neutral, and the eluted concentrations of lead ion dropped below the Japanese elution standard for soil.INTRODUCTION Soil contamination with heavy metals is a worldwide problem. Accumulation of heavy metals in soils affect soil ecology, agricultural productivity, quality of agricultural products, water resources, and serious health problems for human and animal (Raicevic, et al., 2005). In the United States, for example, approximately 63 % of the sites on the National Priority List (NPL) for the treatment of contaminated soils are contaminated by metals, and lead is the most common metal, found at 15 % of the sites. In Japan, according to a report by the Ministry of Environment, 43 % of the contaminated sites that exceed the environmental quality standards are contaminated by lead compounds. Soil contamination by lead compounds is also prevalent in other developed and developing countries where lead compounds are used extensively in industrial activities without careful contamination management. Lead is a ubiquitous heavy metal pollutant in soils due to their use widely. The primary sources of Pb contamination include industrial activities such as mining, smelting of metals, and the use of Pb-containing products such as paints, lead-acid batteries, bullets, gasoline and pesticides (Cao, et al., 2009). It can damage human nervous (especially children) and reproductive systems (ATSDR, 2007). The high concentration of Pb in the soil poses risks to human and animal health by the leaching of metals from the soil into water and the consumption of edible plants growth in the contaminated soil. Therefore, proper remediation is necessary to reduce metal availability in soil for protecting human health."

Jan 1, 2018

By Clinton H. Crane

IN October, 1925, J. R. Finlay delivered an address entitled, "The Future Price of Lead." Lead was then selling at 8.85c. and Mr. Finlay and most of the rest of us were concerned about the shortage. Now, a little more than six years after, lead is selling for 3.55c., and nobody is worrying about the difficulty of getting plenty of it. For 1931 the U. S. G. S. reports United States produc¬tion as 390,000 tons of recoverable lead in ore. Our estimate is slightly higher than this; nearer 400,000 tons. This is the smallest production since 1911 and 1912, but in spite of this, stocks for the year-have increased nearly 50,000 tons. Our estimate for the production outside the United States is 1,120,000 tons, or more than double the production of either 1920 or 1921, and 30 per cent more than in 1913. Stocks abroad probably have not increased more than stocks in the United States. In other words, foreign consumption is double what it was in 1.920-21, whereas domestic consumption is substantially less. It looks as if Mr. Krueger, president of the Swedish match trust, was right when he said that "This country had better stop worrying about Europe and think a little bit more about its own affairs."

Jan 1, 1932

Lead isotope measurements indicate that lead from the A.B.H. Consols mine and two transgressive veins in Browne's shaft is "Thackaringa" type and not "Broken Hill" type.

Jan 1, 1970

By Walters GW

A countercurrent method of metal refining using crystallization and reflux is discussed. 4n account is given of the development of this technique for the separation of silver and bismuth from lead using bench-scale studies to the present small pilot-plant unit (around one tonne per day) in the "Commonwealth Scientific and Industrial Research Organization (CSIRO)" Division of Chemical Engineering.

Jan 1, 1975

By Gernot Schenker

With the shut-down in the mid-1970s of the last shaft furnaces in the Harz Smelter Plant the long tradition of the Primary Lead Smelter in Oker came to an end. A continuation of the concern was nevertheless possible as a result of the timely commencement with the development and construction of lead production from secondary raw materials. Then as today, the most essential secondary raw material is lead accumulator scrap with over 80 % of the raw material pallet. Already in the 1960?s a method of reclamation lead battery scrap was developed and successfully carr.ied out by Preussag. In 1983 this process was fundamentally modified, also for environmental protection reasons within the framework of a rehabilitation programme of the existing plant. Today Metaleurop's HarzMetall GmbH in Oker is equipped with a modern secondary lead smelter which includes all environmental protection installations required by law. Besides processing battery scrap, the. smelter is in a position to process a ?multitude of other lead bearing residues in an economically useful way, whose waste disposal would otherwise be impossible due to the ever-increasing environmental protection laws or only be achieved at great expense.

Jan 1, 1990

By J. R. Parga

A shortage of landfill space and growing environmental concerns in Mexico are renewing interest in the recyclability of scrap from automobiles. This work describes a pyroumetallurgical process for the recovery of metallic lead from waste lead paste. Argentopyrite concentrate is commingled with lead paste residue and smelted in a fuming process thereby transferring the precious metals into lead bullion. The process consists of smelting lead paste and argentopyrite, sodium carbonate, and metallic iron at smelting temperatures of about 1100 T. The reaction products are slag and molten lead bullion enriched with precious metals. A major feature of this process is the removal of precious metals from the bullion by means of zinc, whereby a silver-zinc intermetallic compound is formed and floats out of the lead. The recoveries of precious metals are about 98%.

Jan 1, 1996

By R. D. Smith

The Bureau of Mines (BOM) evaluated the technology, capital investment, and annual operating costs of emission control for further reductions of lead in ambient air at the East Helena, Montana, smelter, and the Glover, Herculaneum, and Buick smelter-refineries in Missouri. This study seeks to analyze the technology available to the domestic primary lead industry for attempting to further reduce lead emissions below 1985 levels. Through enclosure of concentrate unloading and handling areas and all lead-processing buildings, followed by venting these enclosures to the atmosphere through baghouses and the application of appropriate local controls, emissions can theoretically be reduced by a total of 2,424 pounds of lead per day from 1985 levels at the three Missouri operations. Using conventional technology, aggregated additional capital costs of $250,014,000 and annual operating costs of $18,507,800 are estimated for the four operations, resulting in a total cost of $0.063 per pound of refined lead. Continuous drossing techniques would assist in meeting OSHA standards in process areas. Continuous drossing would change capital and operating costs to $258,344,800 and $16,104,700, respectively, for a total cost of $0.062 per pound of refined lead. First quarter, 1986 open market price for refined lead was $0.184 per pound.

Jan 1, 1986

Lead Removal from Contaminated Soils with Chelating Agents

Sep 13, 2010

By John M. Gaines

Lead concentrates from the Viburnum Trend in the Southeast Missouri Lead district are sintered prior to smelting to bind the particles together homogenize the feed, and reduce the sulfur content. Good sinter forms competent masses about 4 to 6 inches across, that hal!e about 15% porosity and good mechanical strength to withstand transport and the weight of the overlying load in the smelter. Bad sinter has poor mechanical strength and forms fine fragments that retard the circulation of reducing gases in the furnace and lengthen the time required for reduction. The productivity of the lead smelter depends on good sinter feed. Because some lead sinter plants produce bad sinter about 20% of the time, this applied mineralogy study has been undertaken to determine the mineralogical and microtextural differences between good and bad sinter. A reflected light microscopic study of 130 polished sections has shown that good and bad sinters differ distinctly in their mineralogy, tex1ure. and character of, porosity. Good sinter consists of hardystonite, franklinite. lead-zinc-bearing magnesium-calcium silicate, lead silicate matrix, and large crystals of calcium-magnesium-iron silicate, together with minor amounts of lead oxides, lead-zinc silicate, metallic lead, specular hematite, magnetite, lead-iron-bearing zincite and zinc-Iead-magnesium-bearing wustite in a tightly intergrown mesh of crystals and with an evenly distributed porosity of 15% to 20%. Electron microprobe analyses show that the principal phases contain lead (or zinc): hardystonite (4-20% Pb) franklinite (2-14% Pb) and lead silicate matrix (65-74% Pb). Bad sinter differs from good sinter in the greater abundance of lead silicate matrix, galena metallic lead, and lead oxides and the lesser abundance of hardystonite, franklinite and calcium-magnesium-iron silicate. Bad Sinter is characterized by a lack of an intimate intergrowth of the constituent phases. Its porosity is much lower commonly 0 to 5% and those pores are concentrated in local areas rather than distributed evenly throughout the sinter.

Jan 1, 1991

By Kazue Moriya

At the 1980 TMS-AIME world symposium, Dr. Davey mentioned that the traditional lead blast furnace is now being challenged by direct smelting processes. In the copper smelting field both the blast furnace and reverberatory furnace are also disappearing in favour of direct smelting processes such as Outokumpu flash smelting, Mitsubishi continuous smelting, Noranda furnace, Inco furnace and so on. Those new processes all have the following in common: (1) High degree of mechanization (2) Metallurgical reactions carried out in closed vessels (3) Application of oxygen and/or oxygen enriched air (4) Minimization of handling materials and gaseous volume (5) Minimum energy requirements (6) Removal of workers from near the furnace (7) Reduction of emissions of harmful gas to meet environmental regulations. (8) Improvement to the work place environment to avoid occupational hygiene hazards. Direct and continuous smelting of powdered concentrate in one vessel was a romance of the metallurgist since early times. However as mentioned above, in the copper field this objective is being achieved in practice. The industry however can't deny that the serious and severe regulation of environmental pollution in every country was the prime motive for the modernization of smelters. In early days, to meet regulations, it was anticipated that many economic difficulties such as higher capital and energy costs and extravagant use of resources and waste disposal would be the result. "Turn a misfortune into a blessing" is an old saying which reveals the current thinking and reacent developments in the nonferrous industries. In the last ten years in the lead smelting field, about two decades later than copper, commercial scale smelting using new furnance technology has started. The KIVCET process and QSL process, which is flash smelting and bath smelting respectively, are becoming major competitors. They will be sure to upgrade their processes to remain economically and environmentally viable in the comming decade.

Jan 1, 1990

By Clift N

Lead concentrate from the Isa and Hilton lead-zinc concentrators of Mount lsa Mines Limited is smelted at Mount Isa to produce a lead-silver bullion. This bullion is cast into four tonne blocks and shipped to Britannia Refined Metals Co Ltd, NorthDeet, England and to plants in Asia for refining and marketing. The traditional treatment stages at Mount lsa are sintering, smelting, and drossing and casting, with some of the sinter plant feed being pre-treated through an Isasmelt plant.A commercial scale lsasmelt based lead smelter was commissioned in early 1991.

Jan 1, 1993

By B. L. Sackett

LEAD smelting has been an important industry in Utah for many years. The first lead smelting was done, over 60 years ago, at the Rollins mine in Beaver County, by burning heaps consisting of alternate layers of wood and high-grade carbonate ore. The lead thus obtained was. molded into bullets. With the development of. the mines, the problem of cheaper handling of the ore became important. The only outlet for this ore was Swansea or the Atlantic Coast but to ship to either cost $150 per ton or more for treatment and handling. From 1864 to 1871, experimenting was done with blast, Scotch hearth, and reverberatory furnaces, with the blast furnace surviving as, the standard plant. The first crude furnaces were circular or hexagonal in shape, and were made of adobe and stone, which quickly burned out. They were small, about 2 1/2 ft. in diameter, and smelted from 3 to 10 tons. in 24 hr. The metal had to be tapped from the bottom of the crucible, necessitating a shut down of the furnace during this process. This pro¬cedure caused salamanders to form around the tap hole when the furnace was started again, which frequently resulted in freezing. The campaign lasted until a tap of bullion was made. The first successful plant of the crude stone type was operated in 1870. From 1870 to 1872, there was a smelter building craze in the state. During that period, about 20 furnaces were built, chiefly near the mines, and their operation was limited and sporadic. The work was then placed in the hands of trained metallurgists, who standardized on the rectangular form of furnace. In 1871, Daggett, at the Winnamuck mine in Bingham, installed water-jackets around the smelting zone of the furnaces. These furnaces were circular; the diameter at the tuyere line was 3 ft. 6 in. and at the charge floor 5 ft. 3 in. The height from tuyere line to charge floor was 14 ft., height of tuyere line above top of crucible was 3 ft. 8 in. Fur-

Jan 8, 1925

By Jesús L. Valenzuela, José R. Parga, Salvador Aguayo, Héctor Moreno

The Merrill Crowe zinc-precipitation process has been applied worldwide on a large number of operations for the recovery of gold and silver resulting in a higher consumption of zinc dust from cyanide solutions. However, in some of plants this precipitate is of low quality, because lead, cadmium and especially copper are precipitated along with gold and silver. The low quality precipitate also requires more fluxes in smelting and shortens crucible life. In this study, a process is introduced to remove copper, silver, lead and cadmium from barren solutions following the Merrill-Crowe process. Copper and silver are removed by precipitation in a serpentine reactor, using sodium sulfide as the precipitator, and sulfuric acid for pH control. The recovery of lead and cadmium ions with natural hydroxyapatite using cow bone powder (CBP) as a new adsorbent material, is introduced. CBP is capable of removing lead and cadmium ions from aqueous cyanide solutions with 99% efficiency. It has the ability to compete with other existing commercial adsorbents for the removal of lead and cadmium. Results show that pH value has a significant effect on copper cyanide removal efficiency, and it was determined the optimal pH range to be 2 - 3. At this pH value, the copper cyanide removal efficiency achieved was up to 99 %; and for the cyanide associated with copper cyanide complexes, the recovery was 90%. Finally, the precipitate quality was improved 400% .This procedure was successfully run at three mines in México.

Jan 1, 2014

By H. V. Alminas

The U.S. Virgin Islands consist of three major islands (St. Thomas, St. John, and St. Croix) and some 50 smaller islands that are located primarily along the coasts of St. Thomas and St. John. St. Croix, the largest of the islands, is located approximately 160 km south-southeast of San Juan, Puerto Rico and is about 218 km in area (Fig. 1). St. Thomas, the second largest island is located 64 km east of Puerto Rico and incorporates approximately 77 km2. St. John is located immediately to the east of St. Thomas and incorporates approximately 49 km2. The climate in the U.S. Virgin Islands is maritime tropical. The average annual rainfall at higher elevations is 127-152 cm and at lower elevations 51-76 cm. There is no well-defined wet or dry season. Temperatures generally average in the 80's (F°) with only a 5°-7° F variation throughout the year.

Jan 1, 1987

By THOMAS LEONBRD WATSON

I. INTRODUCTION. THE results embodied in this paper are based on a careful field- and laboratory-study of the lead- and zinc-deposits of the Virginia-Tennessee district, begun in the latter part of the summer of 1904 and completed in the spring of 1905, preparatory to the publishing of a State report .on them. A separate description of the individual deposits in Virginia is purposely omitted, since I have already described them in considerable detail in a State report. The Tennessee deposits are described here in some detail for the reason that no detailed record of them has yet been published. Practically, this paper summarizes the results obtained from a study of the geology of the ore-deposits of the district as, a whole. (I had the pleasure of visiting the deposits of Virginia and Tennessee with Dr. H. Foster Bain of the U. S. Geological Survey, in April, 1905. Figs. 21 and 22 are from photographs taken by Dr., Bail.) II. HISTORICAL. . The first authentic records of lead-mining .in Virginia date hack more than 150 years; and the old lead-mines at Austinville, on New river in Wythe county, V a., were the first to be worked. Colonel Chiswell, a native of Wales, and one of the earlier adventurers in southwestern Virginia, was one of the first operators of the Austinville mines. Chiswell's operations at Austinville commenced in the year 1750, and closed shortly after the beginning of the Revolutionary War, in the' year 1776, covering a period of about 25 years. From that time to the present, mining has been carried on almost continuously in the Virginia area. For many years after the Virginia mines were operated, mining was confined exclusively to the lead-ores. The zinc-ores

Mar 1, 1906

By Wei Sun, Ruolin Wang, Wenjuan Sun, Junhao Fu, Haisheng Han, Zhao Wei

Pb–benzohydroxamic acid (BHA) (lead complexes of benzohydroxamic acid) exhibits high selectivity but low collecting efficiency in scheelite flotation. This paper reports the manner in which BHA and sodium dodecyl sulfate (SDS) were employed as ligands to coordinate with the lead ions to obtain a colloidal lead-group multiple ligand complex, i.e., the Pb–BHA–SDS, for improving the collecting efficiency of Pb–BHA. The flotation mechanism of Pb–BHA–SDS with respect to scheelite was investigated from the viewpoint of interface science based on the pure mineral flotation, Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and contact angle measurements. The results showed that the BHA and SDS coordinated with Pb2+ to form novel leadgroup multiple ligand complexes, which are different from the traditional understanding associated with the mixed collectors. Pb–BHA–SDS was a better collector with stronger collecting ability and excellent selectivity in regard to a scheelite flotation than Pb–BHA. The addition of SDS to Pb–BHA enhanced the latter’s adsorption ability on the scheelite surface and improved the hydrophobicity of the collector’s nonpolar groups, rendering Pb–BHA–SDS as a more efficient collector at a low dosage. Keywords: Scheelite; Pb-BHA complexes; sodium dodecyl sulfate; multiple ligands; Pb–BHA–SDS

Jan 1, 2020

By W. J. O'CONNOR

THE production of lead in the United States for the period from 1720 to 1912 was 10,432,668 tons valued at $924,600,000. The average price during this period was 4.4c. a pound, although lead sold at times below 3 cents. We know that in the early days of lead smelting in Montana lead was deliberately lost in the slag and only enough reduced as bullion to collect the silver. This bullion was freighted by ox team to Corinne, Utah, the terminus of the railroad at that time, and shipped to Swansea or Omaha, Neb., for refining. The slag from some of the above mentioned operations contained as much as 15 per cent lead and has since been resmelted. Since 1921 the production of lead has increased each year and the price and tonnage have been as follows :

Jan 1, 1926

By J. J. Brown

Wilkes-Barre Meeting, Julie, runs., THE ore-hearth was the earliest type of furnace used in smelting Mississippi Valley lead-ores, which are very pure, and low in silver-content. The first smelters made no attempts to recover lead from the smoke; and since about 15 per cent. of the lead -in the charge escaped in this manner, early practice with the hearth was decidedly wasteful. At most of the large smelting-plants blast-furnaces with auxiliary roasters were substituted for the hearths long ago. But, upon the introduction of the Lewis and Bartlett bag-process for collecting fume, the ore-hearth was used by companies engaged in the manufacture -of pigments, simply on account of the large percentage of fume made by it. In fact, the extraction of lead was kept down by the use of hot blast and other devices. During recent years, however, several smelting companies have realized that the preliminary roasting of galena for the blast-furnace is not economical, and have, therefore, replaced the roasting-furnace with a modification. of the old Scotch hearth, in which a large percentage of the lead in a charge is recovered directly as pig-lead, while the remainder passes partly into fume and partly into slag low enough in sulphur to be charged into the blast-furnace without further treatment. The results obtained have proved so satisfactory, both As to recovery and operating-expense, that one eminent metallurgist has predicted the universal use of the ore-hearth on non-argentiferous ores. The-ore-hearth, thus employed as an adjunct to a blast-furnace plant, is rather a desulphurizer than a smelting-furnace proper,-the chief object being to make a blue slag suitable for the cupola-furnace. Hence, no special care is taken to obtain from it a large lead-extraction. * Head of Department of Ore Dressing and Metallurgy, Oklahoma School of Mines and Metallurgy, Wilburton, Okla.

May 1, 1911

By Hughes J. C

THE smelting plant consists of five large furnaces operating in the treatment of current flintered material, and one small furnace operating periodically in the treatment of copper dross and antimonial slag produced in the lead-refining process.he following table supplies the leading dimensions and details of the large furnaces:-(a) Crucible - Dimensions 17 ft. 2 in. long x 4 ft. wide x 2 ft. 3 in deep. Capacity - 30 tons lead. Class of lining - firebrick. No. firebricks required - 3000.(b) Crucible Tank - Dimensions 20 ft. 6in. long x 10 it. 6 in. Wide x 4 ft. 3 in. deep. Material - 1/2 in. mild steel.(0) Jackets - Dimensions 6 ft. long x 19 in. wide x 6in. thick. Material - Cast-iron. Average life - 2 years. Number per side - 11, with 13-in. bosh. Number per end - 3, with 9-in. bosh.

Jan 1, 1922