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By L. O. Filipov, N. E. Menad, A. Geneyton

"Zeta potential of synthetic monazites presenting various compositions were measured to investigate the effect of the main lanthanides substitutions on electrophoretic mobility and resulting IEP. The measurements are performed in a CO2 depleted and enriched solutions showing both reduced influence of monazite chemistry and strong influence of ions resulting from the solubilization and dissociation of CO2. The influence of oleic acid on the electrophoretic mobility of those monazites was also investigated. The influence of pH on oleate adsorption was studied using a bubble/particle adhesion system. Adhesion strength measurements were performed on pure synthetic monazite-(Ce) and monazite-(La). An extensive thermodynamic model of monazite in water was developed to highlight correlations between lanthanides hydroxides/carbonates species concentrations in the bulk solution and oleate adsorption. Based on electrophoretic measurements, advanced thermodynamic consideration and adhesion measurements, further details of the oleate adsorption model on monazite surface were proposed.INTRODUCTION Electrophoretic and potentiometric data on monazite and, a fortiori, other rare earth semi-soluble salts such as bastnaesite are extremely erratic (Chelgani et al. 2015). The isoelectric points measured with electrophoretic mobility methods range from 4.7 to 6.5 although sporadic data indicates an IEP (isoelectric point) far from that range. Different explanations are proposed in the literature to explain the IEP variability notably the numerous chemical substitutions that frequently occurred within monazite crystal lattice (Chelgani et al. 2015). Based on lanthanides speciation diagram, several authors highlighted the influence of specific lanthanide species on the flotation performance of rare earth semi-soluble salts when carboxylate or hydroxamate collectors are used. Although lanthanides ions have a great affinity for carbonates groups (Kragten et Decnop-Weever 1987), lanthanide (hydrogen) carbonates were not implemented in speciation diagrams. In this work, an advanced thermodynamic model is proposed to highlight correlation between flotation performance and lanthanide species predominance but also concentrations. Qualitative measurement of the monazite surface hydrophobicity are performed through tests of adhesion of coarse monazite particles onto bubbles. Since flotation and microflotation technics are highly influenced by hydrodynamic parameters, this method was investigated to obtain a sharp contrast between appropriate and inappropriate pH conditions. This paper is to investigate 1) the effect of lanthanides substitution on monazite surface properties through zeta potential measurements, 2) the mechanism of adsorption of carboxylates on monazite surfaces and 3) the effect of CO2 on monazite surface properties and carboxylates adsorption."

Jan 1, 2018

By Scott C. Brown, Ivan U. Vakarelski

The particles commonly encountered in mineral benefication schemes have irregularites that are expressed at many different length scales. In part, this originates from preceding processes (e.g. makedown, comminution, handling and storage), which are known to chemically and physically modify the bulk particle and its surface. Interparticle tribology, dissolution and reprecipitation events along with large-scale mechanical stresses are just a handful of the interactions encountered during processing of particles prior to separation. It is feasible to imagine that each one of these events may impose a fingerprint of characteristic nanoscale, microscale, and macroscale morphological changes that can modify the overall interaction of these particles within a system. Suprisingly there are just a few works on how these resulting features can alter the performance of benefication schemes, and especially flotation.

Jan 1, 2003

By S. C. Brown

A number of studies have suggested that microscale asperities enhance bubble-particle attachment efficiency; however, in practice the roughening of particulate surfaces can also lead to a decrease in flotation. In the present investigation, it is proposed that nanoscale asperities may be partially responsible for this phenomenon. It is suggested that as inter-asperity separation distances are reduced capillary effects are enhanced leading to the formation of stable liquid domains, which adversely impact bubble-particle adhesion. In addition, obstruction of surfactant self-assembly may occur, further limiting flotation.

Jan 1, 2003

By Wilian da Silva Labiapari

Austenitic stainless steels are widely known for their good weldability, excellent mechanical properties for deep drawing and superior corrosion resistance in environments where most of the metals fail. Their uses include many applications subjected to a combination of mechanical and corrosive wear, such as pumps, valves and surgical implants. Although their corrosion resistance has been largely investigated, their resistance to mechanical wear is less studied. In particular, their performance under conditions involving combined corrosive and mechanical wear is not well understood. The aim of this study is to demonstrate the effect of the mechanical component on the electrochemical signal of an anodic polarization curve. A test rig was developed to investigate micro-abrasion-corrosion using a fixed ball configuration. Tests were carried out using stainless steel AISI 304 samples and 25.4 mm zirconia balls as counter bodies. The electrolyte was a 1N H2SO4 solution with SiO2 as abrasive dispersed at the concentration of 10 wt%. The results showed an increase in current density when the counter face roughness and the normal load applied during the tests are increased, evidencing a mechanical influence on the surface activity of this material in a corrosive environment.

Jul 31, 2018

By Matti Kongas, Kari Saloheimo, Antti Remes

"The paper studies the control performance of the flotation process as a function of the measurement accuracy and sampling frequency of an on-stream XRF analyzer, using a simple dynamic model. An additional aim is to assess how the economical result of a mineral flotation process depends on the quality of process control based on the on-line elemental assays.An on-stream XRF analyzer measures the concentrations of slurry lines in a continuous cycle from several process points. The control performance depends on the analytical accuracy and sampling frequency of the concentration measurement. With a long cycle time, the state of the process changes before a new measurement becomes available. With short measurement times the statistical variance of the counted Xray pulses increases, increasing the random error in the analysis. In addition, the measurement accuracy depends on the concentration of the component to be measured from the slurry.To quantify the effect of analysis error and frequency to process control, a simple dynamic process model is created in the Matlab environment. Data from a copper flotation circuit is used as a test case. The process model comprises a first order reaction equation and the grade-recovery -relationship estimated from process data. The control was modeled using the control strategies implemented into a rule based advanced control system. The economical performance of the control was studied by calculating the overall net smelter return at various analyzer parameter combinations."

Jan 1, 2003

By Shengli Wu, Laixin Wang, Minyin Kou, Xinliang Liu, Weidong Zhuang, Yujue Wang

COREX process has obvious advantages in environment protection but still has some disadvantages, for example, it has a higher sulfur content of hot metal than blast furnace. In this paper, the thermodynamics and dynamics of desulfurization have been investigated to obtain the main operation parameters related to the mass fraction of sulfur in the hot metal. In addition, statistical analyses have been carried out to study the relationship between operating parameters and sulfur content of COREX hot metal based on actual plant data. It has been found that the mass fraction of sulfur in hot metal is significantly influenced by the C content in hot metal, MgO/Al2O3 in slag, the concentration of MgO in slag, the temperature of hot metal and binary basicity (R2).A linear model has been developed and subsequently used for reducing the mass fraction of sulfur in hot metal, improve the quality of hot metal and contribute to low carbon ironmaking.

Jan 1, 2016

By Shengli Wu, Mingyin Kou, Laixin Wang, Zhe Wang, Xinliang Liu

The sticking behavior of iron ores in the shaft furnace is one of the most important problems in the COREX melting progress, which directly influence the smooth operation and productivity of shaft furnace. Therefore, it is of great importance to study the sticking behavior of pellets in COREX shaft furnace. The results showed that porous metallic iron produced at the interface of pellets samples was the main reason for the sticking of pellets in the COREX shaft furnace. The SI (sticking index) and metallization rate increased with the reduction temperature and gas flow, and decreased with melting rate. However, the SI of pellets in the COREX shaft furnace could be decreased by the proper match of melting rate and reduction temperature, reduction temperature and gas flow, while the metallization rate of pellets were kept at a certain level. Furthermore, the matching of melting rate and reduction temperature was more effective than the matching of reduction temperature and gas flow.

Jan 1, 2016

By H. C. Roland Kammel

Stannous sulfate electrolytes are widely used nowadays in electrolytic tin production. Characteristic features of this electrolysis process are that dense cathode deposits can only be obtained by additions of organic additives and that so called ?black mud is formed on the anode surface which leads to an increase in cell-voltage. In order to prevent excessive cell-voltages or oxygen evolution the black mud has to be removed periodically. Studies in laboratory scale have been performed about the effect of different organic additives on electrolytic tin deposition and the formation of surface layers on pure and industrial tin anodes. Results reveal that organic addition agents are effective in reducing cathode roughening as well as extending the covering time of the anode ?by black muds.

Jan 1, 1985

By F. Dehghani

The influence of different grinding methods on the shape characteristics of magnetite particles was investigated. Also, the effect of particle shape on the flotation of the magnetite, both alone and in the presence of quartz particles, was investigated. The shape characteristics of the magnetite particles were measured and calculated from images obtained by scanning electron microscopy via an image analysis system. The flotation tests were performed using a laboratory flotation cell. Results showed that in the -250+212 µm and -106+75 µm size fractions, ball mill products have a higher elongation value than rod mill products, while in the -150+125 µm size fraction, rod mill products have a higher elongation value. Particles with higher elongation values and lower roundness values have a higher flotation kinetic constant. Furthermore, the influence of magnetite particle shape on flotation is greater, and the flotation kinetic constant is higher, in the presence of quartz particles than in the flotation of magnetite alone Keywords shape, elongation value, flotation kinetics, magnetite.

Dec 1, 2013

By K. Biswas

So far, all pillar design methods or approaches consider the coal seam as a uniform structure From some mine visits in northern Appalachian Region. it is found that some coal seams have binder or parting material within the coal scan with varying thicknesses and numbers- And it has also been found that these kinds of hinder materials tire prone to weathering when exposed to ambient mine moisture In this paper an attempt has been made to study the weathering susceptibility of parting materials and coal when exposed to moisture and a two dimensional finite element analysis has been carried out to study the effect of the presence of partings on the structural integrity of the coal pillar in terms of short-term and long-term stability.

Jan 1, 1995

By J. Alatalo

Autogenous grinding is a process of reducing the particle size distribution of an extracted ore by using the ore itself as the grinding media. It is a process that is difficult to control and there is a lack of knowledge of the events occurring inside the mill. To find out more about how the mill behaves under different processing conditions, a full factorial test was performed with iron ore in a pilot-scale pebble mill at the LKAB R&D facility in Malmberget. To complement this work, a strain gauge detector was embedded in one of the mill?s rubber lifters, the Metso Minerals continuous charge measurement (CCM) system, and was used to get more information about the charge dynamics. The data from the experiments has been analyzed. For production purposes, an increase in the number of particles smaller than 45 µm can be regarded as a probable increase in the production rate. The analysis shows that there will be an increase in fines at 65% of critical speed, especially when the mill is 45% full. This setting will also increase the power consumption, but improves the grindability of the ore even more. The deflection of the lifters is smaller for lower critical speeds. A higher degree of filling also gives a smaller toe angle and a higher shoulder angle as expected.

Jan 1, 2011

By J. Alatalo

Autogenous grinding is a process of reducing the particle size distribution of an extracted ore by using the ore itself as the grinding media. It is a process that is difficult to control and there is a lack of knowledge of the events occurring inside the mill. To find out more about how the mill behaves under different processing conditions, a full factorial test was performed with iron ore in a pilot-scale pebble mill at the LKAB R&D facility in Malmberget. To complement this work, a strain gauge detector was embedded in one of the mill?s rubber lifters, the Metso Minerals continuous charge measurement (CCM) system, and was used to get more information about the charge dynamics. The data from the experiments has been analyzed. For production purposes, an increase in the number of particles smaller than 45 µm can be regarded as a probable increase in the production rate. The analysis shows that there will be an increase in fines at 65% of critical speed, especially when the mill is 45% full. This setting will also increase the power consumption, but improves the grindability of the ore even more. The deflection of the lifters is smaller for lower critical speeds. A higher degree of filling also gives a smaller toe angle and a higher shoulder angle as expected.

Nov 1, 2011

By B. K. Mohapatra

Small manganese ore bodies in south Odisha, India occurs both as stratiform and stratabound ore bodies. These two ore bodies show contrasting mineralogical, petrographical and chemical characteristics. Stratiform type of Mn-ores consists of manganese, iron and silicate- phases in approximately same proportion. In contrast, stratabound ore bodies contain a high proportion of manganese oxides, silicates and phosphorus phases. Phosphorus is found within apatite in the stratabound ore bodies while in the stratiform ore it occurs as an adsorbed state with iron phase (goethite). Both ore bodies are low-grade (17-23% Mn) therefore do not have a market value. However, the stratabound ores are enriched in phosphorus (P2O5: >1%) compared to the stratiform ores. Both the ore types were processed through gravity, magnetic and roast reduction followed by magnetic separation techniques. The strata bound ore could be upgraded to 33% Mn from a feed of 23% by combination of dry and wet magnetic separation methods. But the phosphorus content also suits up (P2O5: 1.2%) in the processed product making it unsuitable for further use. The stratiform ores do not respond to either gravity or magnetic separation because of close association of manganese with iron phases. However, this could be beneficiated through roast reduction followed by magnetic separation. An ore with 17% Mn content could be upgraded to 40% Mn with a 42% yield and 78% recovery. The goethite, having phosphorus, converts to magnetite and is retained within the magnetic fraction, thereby reducing the concentration of phosphorus in the non-magnetic fraction, which becomes the product. This report demonstrates the influence of ore petrology in determining the up-gradational potential of manganese ore in the southern Odisha, India. Keywords: manganese ore, physical beneficiation, phosphorus rich ore

Sep 1, 2012

By Kenneth R. Krivanek

In recent years the widespread problems of air and water pollution generated by both population and industrial expansion have become a major public concern. Therefore, many municipalities are striving to achieve more efficient wastewater treatment processes so these wastewater's can be reintroduced into the waterways of our nation with little or no detrimental effects on the future beneficial use of that water. With this, improved treatment comes an ever increasing volume of wastewater sludge which must be disposed of in a manner of minimal impact on the environment. Furthermore, with demand for energy continually accelerating in this nation, our concern over high oil prices and our increasing dependency on foreign oil sources, there has been an ever growing interest in the largest energy source that are nation has, coal. However, surface mining of coal can cause many environmental problems when adequate precautions are not faithfully adhered to. These problems include water pollution from silt and/or clay erosion and acid runoff, produced by oxidation and hydrolysis of pyrite; i.e., FeS2 + 3/02 + H20 + FeSO4 + H2SO4. One method of wastewater sludge disposal which can utilize large volumes of sludge for a beneficial project that may not compound our environmental problems is spray irrigation, to either depleted farmland or to abandoned strip-mined soils. Sludge is characteristically high in organics, as well as having near neutral to alkaline pH properties. With these two qualities it possesses a potential for neutralizing acid strip mine spoils, which would enhance the establishment of a vegetative ground cover. Sludge can accomplish this by lowering the oxidation potential, reducing the solubility of iron and aluminum and by the chelation of metals, thereby

Jan 1, 1977

By M Muzammil, S. Mukerjee, S. Saran, M. Bharathi

"This paper presents the results of in-situ tests conducted on a set of under-reamed piles in a silty sand deposit. Three piles (i.e. vertical, vertical with one bulb and vertical with two bulbs) of diameter 0.2 m were cast upto a depth of 5 m. The pile cap had four foundation bolts cast into it so that a mechanical oscillatormotor assembly could be mounted centrally on it. The oscillator-motor assembly was used to generate purely sinusoidal dynamic forces, in either horizontal or vertical directions. For both horizontal and vertical vibration cases, it was observed that (i) the natural frequencies decreased with an increase in the excitation force level, (ii) for the same excitation level, the natural frequencies as well as the maximum amplitude of vibration are almost the same irrespective of the pile geometry i.e. number of bulbs in the pile, indicating that the full pile length is not being excited. For the vertical vibration case, the soil-pile stiffness at frequencies, before resonance, were observed to be higher than those at frequencies after resonance. In the horizontal vibration case, the stiffness of the soil-pile system was found to be decreasing with an increase in the excitation force level. The damping ratio was found to be increasing with an increase in the excitation force level.INTRODUCTIONUnder-reamed piles are piles, normally upto a depth of 6 m, with one or more bulbs along the pile stem. These have been used for structures like transmission towers, structures on expansive soils etc. for a very long time, however it is only in the last 30 years that dynamic response of a pile has been studied. Evaluation of dynamic soil-pile interaction is a very complex problem as the conditions and properties of soil are highly variable and unpredictable. Various models and approaches have been suggested by various investigators for evaluating the dynamic soil-pile interaction problem, but most of them are based on the assumptions that the behaviour of soil is linear and the soil surrounding the pile is strongly adhered to it. But in practice, it is not so. The soil surrounding the pile is always somewhat loosened and undergoes some deformation when a sinusoidal load is applied. This causes the soil-pile system to behave nonlinearly.In earlier studies by Novak, (1974), Novak and Aboul-Ella, (1978) etc. a linear elastic behaviour of soil was assumed. This approach was very useful in understanding the mechanism of soil-pile interaction to a large extent. Subsequently various models were suggested like the lumped mass models with nonlinear discrete springs, dashpots and friction elements Matlock et al. (1978), weak cylindrical zone around the pile model Novak and Sheta, (1980), ideal boundary zone model with non-reflective interface, Han and Sabin, (1995) etc. These approximate solutions give an idea about the mechanism of dynamic pile-soil interaction to a large extent. However, in reality both separation and slippage can occur due to the formation of a weak bond at the contact surface between the soil and the pile when a dynamic load is applied. In addition, the soil column adjacent to the pile experiences large deformations under dynamic loads and thus behaves nonlinearly.Some computer aided model studies on the dynamic response of under-reamed piles have been reported, however, very few insitu dynamic tests on under-reamed piles are reported. Dynamic tests on piles were carried out by Novak and Grigg (1976) on small scale single piles and pile groups in the field. Similar field tests on small scale piles were conducted to study the nonlinear behaviour of a single pile and a pile group under strong harmonic excitation by Han and Novak (1988), Han and Vaziri (1992), Burr et al. (1997), Manna and Baidya (2010) etc. The majority of these experimental studies were focussed on the response of the specific pile groups and compared with the results of a single pile. Hence there was a need to study the influence of pile g"

Jan 1, 2015

By Jonguk Kim

Texture and geochemical composition of hydrogenous ferromanganese crust from relatively adjacent three seamounts (OSM2 at 157°35'E, 13°55'N, Lomilik at 161°37'E, 11°42'N and Lemkein at 165°05'E, 9°18'N) near the Marshall Islands in the western Pacific (Figure 1) were investigated in order to elucidate their growth history. These seamounts, located in different latitudes, are along a line that is parallel with the direction of Pacific plate movement. Thick crusts commonly have three or four distinct layers (Figure 2): (1) layer 1, uppermost layer, is black, dense, and has a botryoidal, columnar, or laminated texture; (2) layer 2, overlain by layer 1, is Fe-stained, porous to vuggy and filled with sediment; (3) layer 3, phosphatized layer, is black, massive, dense, and impregnated by CFA, (4) layer 4 shows parallel to undulatory laminated texture and cut by CFA-filled veins. Layer 1 and 2, unphosphatized young layer, are observed in crust samples collected from all seamounts. However, lower part of the crust shows different textures in different seamounts. Both layer 3 and 4 are found in thick crust from OSM2 but layer 4 is absent in crust samples from Lemkein and Lomilik. All the uppermost layers (layer 1) from three seamounts have similar textural and geochemical characteristics. Layer 2 is overlain by layer 1, is porous, partly Fe-stained, and sediment-infilled. In previous studies, layers 1 and 2 have grown in different oceanic environment. Textural and geochemical properties show that layer 1 has grown under relatively higher bottom water activity and lower productive environment than layer 2. Carbonate and detrital materials in layer 1 are not abundant compared to layer 2. Layer 2 can be assumed to have grown under equatorial high productivity zone (EHPZ) while layer 1 has started to grow when the seamount left from the EHPZ.

Jan 1, 2003

By Nigel Marx

In order to understand (and ultimately to predict) the friction reduction resulting from the use of polymer solutions, the rheological properties of model polymer solutions have been measured over a wide range of shear rates. Both temporary and permanent shear thinning have been observed. By using base fluids of different viscosities it has been shown that permanent shear thinning depends more closely on the shear stress experienced by the fluid than on the strain rate. Hydrodynamic measurements have been made on the polymer solutions using a compliant ball on flat lubricated contact that operates in isoviscous-elastic conditions. The measured friction values can only be predicted with reasonable accuracy if the measured shear thinning properties of the lubricant are taken into account in the hydrodynamic model.

Jul 31, 2018

By V. Labiouse, R. Gärber

The paper aims at clarifying the up-to-now misappreciated role taken by pore water on the design of deep tunnels in saturated porous media. Numerical simulations with a non-dimensional FEM-model emphasise the influence of pore water characteristics (in situ pressure and compressibility) and boundary conditions (lining permeability) on the short and long term underground-structure equilibrium states. These results cannot be achieved by means of monophasic total stress analyses. Dieser Beitrag untersucht den Einfluss des Porenwassers auf die Dimensionierung von tiefen Tunnelbauwerken in wassergesättigtem Untergrund. Numerische Simulationen mittels eines dimensionslosen FEM-Modells betonen den Einfluss der Porenwassereigenschaften (in-situ Druck und Kompressibilität) und der hydraulischen Randbedingungen (Tunnelausbaudurchlässigkeit) auf Kurz- und Langzeitverhalten des Untergrund-Ausbau Gleichgewichts. Diese Ergebnisse können nicht ermittelt werden anhand von Einphasen- und Totalspannungsmodellen. L’article s’intéresse au rôle méconnu de l’eau interstitielle dans le dimensionnement de tunnels profonds creusés dans des milieux poreux saturés. Des calculs adimensionnels par éléments finis soulignent l’influence des caractéristiques de l’eau interstitielle (pression in situ et compressibilité) ainsi que des conditions aux frontières (perméabilité du revêtement) sur les équilibres court et long terme de l’ouvrage. Ces résultats ne peuvent pas être obtenus par des calculs en contraintes totales.

Jan 1, 2003

By Priyadharshini M. R., Premalatha K

"Abstract With the development in the construction of heavily loaded structures, the necessity of pile foundations has increased. For the transfer of heavy loads, it is mandatory that the piles need to be socketed in the underlying rock strata. The load transfer in bored rock socketed piles is by end resistance or the combination of shaft and end resistance which in turn depends on the length of the rock socket. The determination of socketing length of the pile at present is mostly based on a few factors which affect the pile load transfer mechanism. The effect of all the possible factors involved, need to be studied in proposing guidelines for the design of rock socketing length of the pile. Analyses are carried out using finite element analysis software (PLAXIS 3D Foundation) to understand the influence of the thickness of overlying strata for different socket lengths of piles in weak rock. From the load settlement curves, the influence of the overlying soil on the rock socket length isobserved and an effective rock socket length is proposed.IntroductionThe determination of socketing length of the pile at present is mostly based on a few factors affecting the pile load transfer mechanism, which sometimes give a better design and sometimes an uneconomical design. Too much socketing length results in more construction time and higher costs. Therefore, the effect of all possible factors involved need to be studied in proposing guidelinesfor the design of t h e r o c k socket length of the pile.The factors that affect the termination criteria of the rock socketed pile are the capacity requirement, thickness and properties of the overlying soil, characteristics of the founding strata, drilling tools used, roughness of the rock socket and nature of loading.A comprehensive study was performed to understand all the above mentioned factors in different types of rocks. In this paper discussion is made on the settlement results, specifically the influence of overlying sand of different densities above a weak rock. The influence of stress developed is not discussed, keeping in mind the size of the paper under study."

Jan 1, 2014

By Albert Sauveur

THE following experiments were conducted in order to study the influence of the rate of cooling through and below solidification on the dendritic structure (macrostructure) and microstructure of some hypoeutectoid steel. The steel selected was of commercial grade and had the following composition: C, 0.40 per cent.; Mn, 0.85; Si, 0.70; P, 0.099; S, 0.043. After melting in vacuum in an Arsem furnace, the various samples were allowed to solidify and to cool to room temperature as indicated in Fig. 1. Samples were thus obtained representing all possible combinations of slow and fast cooling through the various ranges of temperatures indicated, namely: (1), zone of solidification or primary crystallization, (2) zone of granulation, and (3) zone of secondary crystallization. The location of the different temperature zones in the iron-carbon equilibrium diagram is shown in Fig. 2. The authors adopted. Belaiew's notations. The designations of the various samples readily indicate their treatment, as will be apparent from Table 1.

Jan 1, 1930